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21.
22.
Mirta Garrido Fernando Barra Eduardo Domínguez Joaquin Ruiz Victor A. Valencia 《Mineralium Deposita》2008,43(5):591-597
The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic
to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from
the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages
from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite
± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range
between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at
La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous
in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes
and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific
margin of Gondwana during the Early Pennsylvanian. 相似文献
23.
Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain) 总被引:1,自引:0,他引:1
J. Martínez J. F. Llamas E. de Miguel J. Rey M. C. Hidalgo 《Environmental Geology》2008,54(4):669-677
The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and
the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669
soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations
could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition,
we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four
factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb,
As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn,
As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels. 相似文献
24.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
25.
J. L. Simón M. A. Soriano L. E. Arlegui J. Gracia C. L. Liesa A. Pocoví 《Environmental Geology》2008,53(5):1057-1065
Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines),
aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as
well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines
computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times.
According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations
in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast,
rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries
through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not
have an equivalent in observed paleodolines. 相似文献
26.
M. M. Jordán S. Pina F. García-Orenes M. B. Almendro-Candel E. García-Sánchez 《Environmental Geology》2008,55(2):453-462
The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These
materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic
amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients
with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using
columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality,
came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone
materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water
contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order
to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications.
Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium,
phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values
obtained were very elevated. 相似文献
27.
Joanne Muller Malin Kylander Antonio Martinez-Cortizas Dominik Weiss Kevin Blake Raquel Garcia-Sanchez 《Geochimica et cosmochimica acta》2008,72(2):449-463
The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands. 相似文献
28.
Partial Melting and Counterclockwise P T Path of Subducted Oceanic Crust (Sierra del Convento Melange, Cuba) 总被引:1,自引:0,他引:1
Garcia-Casco Antonio; Lazaro Concepcion; Rojas-Agramonte Yamirka; Kroner Alfred; Torres-Roldan Rafael Luis; Nunez Kenya; Neubauer Franz; Millan Guillermo; Blanco-Quintero Idael 《Journal of Petrology》2008,49(1):129-161
Partial melting of subducted oceanic crust has been identifiedin the Sierra del Convento mélange (Cuba). This serpentinite-matrixmélange contains blocks of mid-ocean ridge basalt (MORB)-derivedplagioclase-lacking epidote ± garnet amphibolite intimatelyassociated with peraluminous trondhjemitic–tonalitic rocks.Field relations, major element bulk-rock compositions, mineralassemblages, peak metamorphic conditions (c. 750°C, 14–16kbar), experimental evidence, and theoretical phase relationssupport formation of the trondhjemitic–tonalitic rocksby wet melting of subducted amphibolites. Phase relations andmass-balance calculations indicate eutectic- and peritectic-likemelting reactions characterized by large stoichiometric coefficientsof reactant plagioclase and suggest that this phase was completelyconsumed upon melting. The magmatic assemblages of the trondhjemitic–tonaliticmelts, consisting of plagioclase, quartz, epidote, ±paragonite, ± pargasite, and ± kyanite, crystallizedat depth (14–15 kbar). The peraluminous composition ofthe melts is consistent with experimental evidence, explainsthe presence of magmatic paragonite and (relict) kyanite, andplaces important constraints on the interpretation of slab-derivedmagmatic rocks. Calculated P–T conditions indicate counterclockwiseP–T paths during exhumation, when retrograde blueschist-faciesoverprints, composed of combinations of omphacite, glaucophane,actinolite, tremolite, paragonite, lawsonite, albite, (clino)zoisite,chlorite, pumpellyite and phengite, were formed in the amphibolitesand trondhjemites. Partial melting of subducted oceanic crustin eastern Cuba is unique in the Caribbean realm and has importantconsequences for the plate-tectonic interpretation of the region,as it supports a scenario of onset of subduction of a youngoceanic lithosphere during the early Cretaceous (c. 120 Ma).The counterclockwise P–T paths were caused by ensuingexhumation during continued subduction. KEY WORDS: amphibolite; Cuba; exhumation; partial melting; trondhjemite; subduction 相似文献
29.
Flood hazard delineation combining geomorphological and hydrological methods: an example in the Northern Iberian Peninsula 总被引:2,自引:1,他引:1
Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite
this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed
in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical
flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph)
in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number)
by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling
(one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed
subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with
frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic
method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence
intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional
events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both
methods.
Originally presented at the Sixth International Conference on Geomorphology. 相似文献
30.