长江三峡库区全新世环境考古研究进展

充分利用长江三峡工程文物抢救性发掘的宝贵机会,通过对重庆市忠县中坝遗址、丰都县玉溪遗址等典型遗址和神农架大九湖泥炭地层环境考古研究,摸索出了一套利用年代学、沉积学、重矿物组分鉴定、锆石形态统计、地球化学和环境磁学方法辨别考古遗址地层中古洪水沉积的方法;建立了该区地表孢粉-气候的转换函数,并将其用于对神农架大九湖泥炭地层的研究,弄清了该区全新世以来环境演变的背景,并将自然沉积地层环境演变记录与典型考古遗址地层古洪水事件作了对比分析。遗址时空分布研究表明:长江三峡库区旧石器时代至宋代677处遗址时空分布总趋势是从西往东、从高往低逐渐增加的,遗址多沿江河分布,且在河流交汇处呈聚集状态,这与人类多选择河流1～2级阶地为生、河流交汇处鱼类资源丰富有关。研究表明:中坝遗址能延续5000a的原因一方面与其盐业遗址的属性有关,另一方面与其长期具有良好生态环境有关。从该遗址T0202探方出土近20万件动物骨骼的分类统计证明了这一点。7.6kaBP以来,水位在吴淞高程147.024m以上的古洪水至少在玉溪遗址T0403探方中留下了16次沉积记录。神农架大九湖297cm厚的泥炭及其148个孢粉样品和10个AMS14C测年数据表明,该泥炭地层为本项目提供了理想的全新世自然环境演变背景,尤其8.2kaBP前后的降温事件很明显,6.7～4.2kaBP为中全新世最适宜期,4.2kaBP前后由暖湿转为凉干,3.5～0.9kaBP季风降水整体较弱,0.9kaBP前后转为较凉湿。根据对中坝和玉溪两处遗址地层的研究,在8.2～6.7kaBP期间出现有10个古洪水层;在6.7～4.2kaBP全新世最适宜期遗址地层中出现有8个古洪水层;在3.5～0.9kaBP降水减少的时期,中坝遗址中仅出现2个洪水层(即西周时期的37-1和战国早期的第21层);在0.9kaBP以来降水较多的时期,中坝遗址中存在3个洪水层(即宋代中期的11C-1层、清代的5-1层和1981年的2B-2层)。这表明,8.2～6.7kaBP的洪水在三峡地区次数是最多的,6.7～4.2kaBP的洪水数量次之。长江三峡库区的这一古洪水发生规律或许可以解释长江中游的江汉平原在7.8～5.1kaBP期间遗址数量偏少的原因。     

低氧低分压环境下泡塑吸附-石墨炉原子吸收光谱法测定化探样品中的痕量金

针对西藏低氧低分压环境下痕量金的测定,探讨了溶矿介质、解脱时间、吸附温度、Fe3+加入量等对测定结果的影响。确定了最佳测定条件,并较详细讨论了Fe3+在溶矿和吸附过程中的重要作用。方法检出限为0.102 ng/g,测定范围为0.24~300 ng/g,准确度(ΔlgC,n=12)为0.01~0.03,精密度(RSD,n=12)为1.61%~7.33%,很好地解决了西藏地区低氧低分压低温环境下痕量金测定的技术难题。     

Native antimony in the Baogutu gold deposit (west Junggar,NW China): Its occurrence and origin

The Baogutu gold deposit, West Junggar (Xinjiang, NW China), is composed of quartz–sulfide veins and their stockworks and is hosted within an Early Carboniferous volcanic–sedimentary sequence. Three ore-forming paragenetic stages can be identified: coarse-grained quartz–sulfide vein (stage I), gold-bearing fine-grained quartz–sulfide vein (stage II), and native antimony-bearing calcite–sulfide veinlets (stage III). The estimated formation temperatures (approximately 360 to 220 °C), fS₂ (? 7 to ? 15 log units), and fO₂ (? 26 to ? 43 log units) decrease from stage I, through stage II, to stage III. The nature of the hydrothermal fluid changed from weakly acidic (pH: 5 to 6 at stage I) to alkaline (pH: > 7 at stage III).Two different occurrences of native antimony could be identified: one coexists with chalcopyrite and pyrrhotite, whereas the other occurs as isolate grains within calcite veins. Native antimony (up to 100 μm in size) contains minor amounts of As (2.0 to 2.7 wt.%); empirical formula Sb_0.95–0.96As_0.03–0.04. Decrease of temperature and fO₂ at high pH and low fS₂ conditions favored co-precipitation of native antimony–ullmannite assemblages and the decomposition of tetrahedrite. Native antimony crystallized later than the native gold, suggesting fractionation between Au and Sb during the hydrothermal evolution of the deposit.     

正态分布检验在地下水检测质量控制中的应用

对地下水调查中37种必测组分检测过程的替代物进行筛选,应用D’Agostino法对替代物的测量结果进行正态性检验。利用正态分布函数"3σ"原则,定义了各替代物质量控制指标的有效区间。应用正态函数随机变量的数学期望和方差,计算得到各替代物有效区间内的正态函数分布概率均大于97%,替代物过程能力指数计算结果表明,二溴氟代甲烷、甲苯-d8、对溴氟苯、1,2-二氯苯-d4、氟苯等挥发性有机污染物分析过程选用的替代物质量控制过程处于稳定的监控状态;2,4,5,6-四氯间二甲苯、二丁基氯菌酸酯、p-三联苯、十氯联苯等半挥发性有机污染物分析过程选用的替代物监控指标分析过程能力不足。建议参考美国EPA方法中有关监控指标质量控制区间的要求,适当放宽对半挥发性有机物检测流程中选用的替代物质量控制区间的有效范围。正态分布在地下水检测过程质量控制中的应用,为实验室检测过程的质量管理提供了科学、有效的数学依据。     

aiNet- and GIS-based regional prediction system for the spatial and temporal probability of rainfall-triggered landslides

We developed a real-time forecasting system, aiNet-GISPSRIL, for evaluating the spatiotemporal probability of occurrence of rainfall-triggered landslides. In this system, the aiNet (a kind of artificial neutral network based on a self-organizing system) and GIS are merged for integrating the rainfall conditions into various environmental factors that influence the landslide occurrence and for simulating the complex non-linear relationships between landslide occurrence and its related conditions. Zhejiang Province (101,800 km² in area), located in the southeast coastal region of China, is highly prone to the occurrence of landslides during intensive rainfall. Since 2003, the aiNet-GISPSRIL has been used to predict landslides during the rainy seasons in the region. The aiNet-GISPSRIL uses the regional 24-h forecast rainfall information and the real-time rainfall monitoring data from the rain-gauge network as its inputs, and then provides 24-h forecast of the landslide probability for every 1 × 1-km grid cell within the region. Verification studies on the performance of the aiNet-GISPSRIL show that the system has successfully predicted the dates and localities of 304 landslides (accounting for 66.2% of reported landslides during the period). During the period from 2003 to 2007, because the system provided the probability levels of landslide occurrences up to 24-h in advance, gave locations of potential landslides, and timely warned those individuals at high-risk areas, more than 1700 persons living in the risk sites had been evacuated to safe ground before the landslides occurred and thus casualty was avoided. This highly computerized, easy-operating system can be used as a prototype for developing forecasting systems in other regions that are prone to rainfall-triggered landslides.     

海拉尔盆地基底晚古生代adakite的发现及其地质意义

海拉尔盆地的前中生代基底隶属中亚造山带东段的兴蒙造山带。 在盆地基底地层中发现了具有adakite成分特征的粗面安山岩、英安岩和闪长玢岩。 这些火成岩与晚古生代沉积地层交互或伴生, 共同构成晚中生代裂陷盆地的基底。 地球化学研究表明, 这些火成岩基本上属于高钾钙碱性和准铝质岩石系列, 具有高SiO₂和Al₂O₃含量, 高Sr、Sr/Y和La/Yb值, 富集轻稀土(LREE), 亏损重稀土(HREE)、Y和高场强元素(HFSE),Eu表现弱的负异常或轻微的正异常, 相容元素Mg、Cr和Ni含量低, 这些特征与增厚下地壳部分熔融成因的adakite非常相似, 而明显不同于典型的由俯冲洋壳熔融形成的adakite。 样品的(⁸⁷Sr/⁸⁶Sr)_i值基本一致,为0.7041, (¹⁴³Nd/¹⁴⁴Nd)_i值为0.51243~0.51247, ε_Nd (t)为正值(+3.7~+4.5), 显示其岩浆源区可能源于弱亏损地幔, 或亏损地幔受到地壳物质混染。 本文认为海拉尔地区晚古生代adakite型岩浆很可能是由当时新底侵的玄武质下地壳在角闪岩相向榴辉岩相过度或榴辉岩相条件下部分熔融形成。 这些adakite岩石的出现反映了兴蒙造山带晚古生代受到了古亚洲洋的俯冲消减引起的强烈的地幔玄武质岩浆底侵作用, 并由此导致地壳垂向上显著的增生加厚过程。     

大兴安岭中南段中生代成矿物质的深部来源与背景

大兴安岭是我国北方一个重要的多金属成矿带。本文从成矿的物质来源和构造作用两方面讨论大兴安岭的成矿系统。Sr、Nd、O、Pb同位素的研究显示大兴安岭成矿物质的深部来源,大兴安岭晚中生代壳幔混熔花岗质岩石组成及其构造环境的研究,表明它们是在板内非造山的伸展环境下形成的A型花岗岩。与南岭花岗岩及其成矿作用的对比研究,将加深对大兴安岭中生代成矿特征的认识。深部构造特征也进一步印证了大兴安岭的成岩-成矿的背景。     

丹凤地区秦岭岩群片麻岩锆石U-Pb年龄:北秦岭地体中-新元古代岩浆作用和早古生代变质作用的记录

秦岭岩群被认为是出露于北秦岭地体内最古老的前寒武纪基底岩石,记录了北秦岭造山带的地壳形成和演化历史。本文报道丹凤-西峡地区五件秦岭岩群片麻岩锆石U-Pb年龄结果,限定其形成和变质时代,探讨北秦岭地体的构造归属。定年结果表明,岩浆成因锆石颗粒的年龄集中在1400～1600Ma左右和850～950Ma左右,记录两期主要岩浆活动。6粒锆石具有变质成因特征,低Th/U比值(0.03),206Pb/238U年龄变化在510～465Ma之间,加权平均值477±18Ma。这一古生代变质叠加时代与北秦岭地体南北缘高压变质作用时代基本一致,说明秦岭岩群遭受到北秦岭造山带俯冲-碰撞造山过程的变质作用。秦岭岩群主要形成于中元古代晚期至新元古代早期,基底岩石缺乏早元古代和太古代岩浆活动的记录。在岩浆作用时代上,北秦岭地体与广泛发育新元古代中-晚期岩浆作用的扬子陆块北缘有差别,也不同于晚太古代-早元古代的华北陆块南缘,可能是中-新元古代形成的独立微陆块。     

REE, Mn, Fe, Mg and C, O Isotopic Geochemistry of Calcites from Furong Tin Deposit, South China: Evidence for the Genesis of the Hydrothermal Ore-forming Fluids

The Furong tin deposit in the central Nanling region, South China, consists of three main types of mineralization ores, i.e. skarn-, altered granite- and greisen-type ores, hosted in Carboniferous and Permian strata and Mesozoic granitic intrusions. Calcite is the dominant gangue mineral intergrown with ore bodies in the orefield. We have carried out REE, Mn, Fe, and Mg geochemical and C, and O isotopic studies on calcites to constrain the source and evolution of the ore-forming fluids. The calcites from the Furong deposit exhibit middle negative Eu anomaly (Eu/Eu*= 0.311–0.921), except for one which has an Eu/Eu* of 1.10, with the total REE content of 5.49–133 ppm. The results show that the calcites are characterized by two types of REE distribution patterns: a LREE-enriched pattern and a flat REE pattern. The LREE-enriched pattern of calcites accompanying greisen-type ore and skarn-type ore are similar to those of Qitianling granite. The REE, Mn, Fe, and Mg abundances of calcites exhibit a decreasing tendency from granite rock mass to wall rock, i.e. these abundances of calcites associated with altered granite-type and greisen-type ores are higher than those associated with skarn-type ores. The calcites from primary ores in the Furong deposit show large variation in carbon and oxygen isotopic compositions. The δ¹³C and δ¹⁸O of calcites are −0.4 to −12.7‰ and 2.8 to 16.4‰, respectively, and mainly fall within the range between mantle or magmatic carbon and marine carbonate. The calcites from greisen and altered granite ores in the Furong deposit display a negative correlation in the diagram of δ¹³C versus δ¹⁸O, probably owing to the CO₂-degassing of the ore-forming fluids. From the intrusion to wall-rock, the calcites display an increasing tendency with respect to δ¹³C values. This implies that the carbon isotopic compositions of the ore-bearing fluids have progressively changed from domination by magmatic carbon to sedimentary carbonate carbon. In combination with other geological and geochemical data, we suggest that the ore-forming fluids represent magmatic origin. We believe that the fluids exsolved from fractionation of the granitic magma, accompanying magmatism of the Qitianling granite complex, were involved in the mineralization of the Furong tin polymetallic deposit.     

中国海相油气田勘探实例之十三 塔里木盆地东河塘海相砂岩油田勘探与发现

东河塘油田位于新疆库车县,构造上隶属于塔里木盆地塔北隆起轮台凸起东河塘断裂构造带,是我国发现的第一个高产高丰度海相砂岩油田,它的发现是中国海相砂岩油气勘探理论和实践的一次重大突破。油田发现于1990年7月,至1994年探明石油地质储量3323.13×104t,天然气地质储量15.5×108m3,至2009年底累计产原油825.75×104t。石炭系东河砂岩油藏是东河塘油田的主体,其储层东河砂岩段是一套滨岸相砂体,具有厚度巨大、埋深大、储集性能好的特点;其油藏类型为块状底水背斜油藏,产能高,储量丰度高。论述了东河塘油田勘探与发现的历程,剖析了取得勘探成功的实践认识与意义。