Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

Fission track evidence for the Mesozoic Cenozoic tectonic uplift of Mt. Bogda, Xinjiang, Northwest China

1 IntroductionThe Mesozoic-Cenozoic tectonic evolution and ki-netics mechanism of the intracontinental orogen are thekey subjects of continental dynamics (Ma Zongjin andGao Xianglin, 2004) and the key to understanding theregional geological tectonics (Qia…     

A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt

1IntroductionThe northern segment of the South LancangjiangBelt refers to the terrain about200km east of theYunxian-Lingcang granite in the South LancangjiangBelt(Fig.1).During the seventh Five-Year Plan peri-od,Mo Xuanxue et al.(1993)undertook the resear…     

河南省平顶山盐田盐矿床成矿特征探讨

以现有钻孔及区域资料为基础，对平顶山盐田盐矿床形成的构造条件和盐湖的沉积模式、沉积类型成矿物源进行了分析，为平顶山盐田的进一步勘查和开发提供了宝贵资料。     

胶北晚中生代煌斑岩的岩石地球化学特征及其成因研究

胶北煌斑岩分别采自龙口、烟台和威海地区，包括拉辉煌斑岩、斜闪正煌岩和角闪煌斑岩，煌斑岩K—Ar全岩年龄变化于89．3～169．5Ma，为晚中生代岩浆活动的产物。在岩石化学组成上，SiO2=42．02％～54．95％，以钙碱性系列为主．岩石以富集大离子亲石元素（LILE）（Ba，U，K，Th）和LREE，亏损高场强元素（HFSE）（Nb，Ta和Ti）为特征，Mg^#=33．9～53．9，Eu／Eu^＊=0．71～0．89，^87Sr／^86Sr初始比值0．707642～0．709791，εNd（t）为-17．6～-10．4，^206Pb／^204Pb=37．588～38．431，^207Pb／^204Pb=15．423～15．531，^206Pb／^204Pb=17．204～18．179。表明煌斑岩源自俯冲陆壳（扬子下地壳）在地幔源区发生交代作用时形成的富集型地幔的部分熔融体．考虑到煌斑岩具有大陆边缘弧玄武岩的特征，我们认为煌斑岩在成因上同样与古大洋板块的俯冲作用有关，为碰撞后弧岩浆作用形成的脉岩。     

基于VRMap平台上的电子沙盘研制

通过与国内外数字沙盘制作方式及功能的比较，详细介绍了数字沙盘研究方面的一些方法，并以中原油田数字沙盘的研制为例，选择北京灵图公司的VRMap2．3软件作为平台制作中原油田数字沙盘，为油田开发提供基本资料。     

2004年全球重大气候事件概述

2004年全球气候持续偏暖。年初，暴雪席卷欧洲多国，美国受到罕见大雪袭击，南亚和墨西哥遭遇低温严寒。北半球夏秋季，西太平洋、大西洋热带风暴活动频繁。日本、菲律宾和美国受灾严重。年内，非洲、亚洲部分国家发生严重干旱；同时，南亚、南美洲及非洲多国暴雨致洪。年内，欧洲伊比利亚半岛、日本和澳大利亚遭遇高温热浪。     

紫外线模式预报方法的研究和试验

文章介绍了在T106全球谱模式中应用大气辐射传输模式预报紫外线辐射(UVR)的方法,给出了试验运行的结果.UVR强度的划分考虑了到达地表的UVR通量.参考国内、外紫外线(UV)预报服务的经验,制定了5个日光暴露的级别、相应的紫外线指数(UVI)及防护措施.1999年9月起,国家气象中心已在NOTES网上每月不定期地展示UVR预报的一些结果,2000年9月起,在Cray-C92业务操作系统上实施了连续的试验运行.     

沿海表层沉积物中重金属的有效结合态

以浙江沿海表层沉积物为研究对象,系统地研究了重金属有效结合态与沉积环境、矿物组成和人为排放等环境因素之间的相互关系.结果表明:沿海表层沉积物中重金属的积累数量,呈现出潮汐河口沉积物>沿海沉积物>强潮汐河口沉积物的趋势,这反映了不同沉积类型对重金属富集作用的差异;重金属的有效结合态,总体上以铁锰氧化物结合态>碳酸盐结合态>硫化物及有机结合态>可交换态的顺序存在,但是不同的重金属或同种重金属在不同的采点,主要有效结合态的比例存在明显的差异,这不仅与重金属的地球化学性质、沉积环境和沉积物中的粘土矿物组成有关,更受到重金属污染物的人为排放量的影响.