Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.     

A Case Study Of An On-Ice Air Flow Over The Arctic Marginal Sea-Ice Zone

A case study of warm air advection over the Arctic marginalsea-ice zone is presented, based on aircraft observations with direct flux measurements carriedout in early spring, 1998. A shallow atmospheric boundary layer (ABL) was observed, which wasgradually cooling with distance downwind of the ice edge. This process was mainly connected with astrong stable stratification and downward turbulent heat fluxes of about 10–20 W m^-2, but wasalso due to radiative cooling. Two mesoscale models, one hydrostatic and the other non-hydrostatic,having different turbulence closures, were applied. Despite these fundamental differences betweenthe models, the results of both agreed well with the observed data. Various closure assumptions had amore crucial influence on the results than the differences between the models.Such an assumption was, for example,the parameterization of the surface roughness for momentum (z₀) and heat (z_T). This stronglyaffected the wind and temperature fields not only close to the surface but also within and abovethe temperature inversion layer. The best results were achieved using a formulation for z₀ that took intoaccount the form drag effect of sea-ice ridges together withz_T = 0.1z₀. The stability within theelevated inversion strongly depended on the minimum eddy diffusivity K_min. A simple ad hocparameterization seems applicable, where K_min is calculated as 0.005 timesthe neutral eddy diffusivity. Although the longwave radiative cooling was largest within the ABL, theapplication of a radiation scheme was less important there than above the ABL. This was related to theinteraction of the turbulent and radiative fluxes. To reproduce the strong inversion, it wasnecessary to use vertical and horizontal resolutions higher than those applied in most regional andlarge-scale atmospheric models.     

Measurement and research method of metallogenic depths of Jiaojia orefield and Linglong orefield Shandong Province, China

Taking the contribution of the tectonic force to the total hydrostatic pressure into account, the author puts forward a new method on the calculation of the depth of petrogenesis and metallogenesis which is summarized as follows: first the tectonic added hydrostatic pressured P_s is subtracted from the total hydrostatic pressure P, then using their difference P_r, according to the general method the depth of petrogenesis and metallogenesis can be determined in consideration of lateral constraint. By the new method the following data on the depths of the metallogenesis are obtained: 2 243.6 m (No. I and No. II veins with metallogenic epoch of 105 Ma) and 1 632. 38 m (No. III vein with 105 Ma) for Jiaojia orefield, and 3 454.97 m (NE-trending zone with 213.2 Ma), 1 902.79 III (ENE-trending zone with 100.28 Ma), 1 090.97 m (NE-trending zone with 80.67 Ma) and 720.55 m (NNE-trending zone with 71.86 Ma) for Linglong orefield. Project supported by the Foundation of the State Planning Commission, China and the Foundation of the State Science and Technology Commission, China.     

Hypolimnetic density currents traced by sulphur hexafluoride (SF6)

The artificial tracer sulphur hexafluoride (SF₆) has been used to study the density-driven deep water exchange between two sill-separated basins of Lake Lucerne, Gersauersee and Urnersee. The sources of the density gradients between the two basins are (1) salinity differences between the major inlets due to the different geology of their drainage areas, and (2) temperature differences due to spatial variation of wind forcing. Wind speeds are generally larger in Urnersee, especially in spring during the so-called Föhn events, when winds blow from the south. In contrast, Gersauersee is protected form these winds. In spring 1989, a total of 630 g of SF₆ was released at 80 to 120 m depth in the small Treib Basin located between Urnersee and Gersauersee. During about 100 days the distribution of SF₆ in the lake was determined by gaschromatography. Two models are used to quantify the exchange flow, (1) a one-box mass balance model for SF₆ in the deep part of Treib Basin, and (2) a one-dimensional diffusion/advection model describing the temporal and vertical temperature variation in Urnersee. According to the first model, the flow into the deep hypolimnion of Urnersee, decreases from 21·10⁶ m³·d^?1 at the end of March to about 8·10⁶ m³·d^?1 in late April. The second model yields similar flow rates. The decrease of the flow rate during spring, confirmed by both approaches, is consistent (1) with the decreasing strength of the density gradient above the sill during spring and early summer, and (2) with hydrographic information collected in Lake Lucerne during other years.     

ASPI experiment: measurements of fields and waves on board the INTERBALL-1 spacecraft

The plasma-wave experiment ASPI (analysis of spectra of plasma waves and instabilities) on board the INTERBALL spacecraft is a combined wave diagnostics experiment. It performs measurements of the DC and AC magnetic field vector by flux-gate and searchcoil sensors, the DC and AC electric field vector by Langmuir double probes and the plasma current by Langmuir split probe. Preliminary data analysis shows the low noise levels of the sensors and the compatibility of new data with the results of previous missions. During several months of in-orbit operation a rich collection of data was acquired, examples of which at the magnetopause and plasma sheet are presented in second part of the paper.     

A systematic algorithm for obtaining SODAR wind profiles

Summary Current methods of obtaining wind profiles from SODARs generally employ ad hoc strategies for Doppler spectrum peak selection, profile smoothing, and consistency checks. This paper addresses the problem of systematically obtaining vertical profiles of wind vectors from a SODAR. A new approach is to regard every spectrum frequency as a possible estimator of the radial wind component, but to weight these Doppler estimates according to the spectral power at each frequency. This allows the peak detection, smoothing, and assimilation of a priori information to be combined into a constrained linear inversion methodology. The inversion process also allows an estimation of signal-to-noise ratio, degrees of freedom, and information content versus height. Examples are given of profiles obtained using this new inverse method. The relationship to the physical limitations of the SODAR instrument and the atmosphere is discussed.     

Composition of Kerogen in Kupferschiefer from Southwest Poland

Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR).