Long-Term Evaluation of Mulch Biowall Performance to Treat Chlorinated Solvents

Permeable reactive barriers (PRBs), such as mulch biowalls, have been installed at numerous groundwater cleanup sites, and laboratory and field studies have demonstrated biotic and abiotic processes that degrade chlorinated volatile organic compounds (CVOCs) in groundwater passing through these engineered remedies. However, the longevity of mulch biowalls remains a fundamental research question. Soil and groundwater sampling at seven mulch biowalls at Altus Air Force Base (AFB) approximately 10 years after installation demonstrated the ongoing degradation of CVOCs. Trichloroethene was not detected in five of seven groundwater samples collected from the biowall despite upgradient detections above federal drinking water standards. Microbial sampling established the presence of key dechlorinating bacteria and the abundance of genes encoding specific enzymes for degradation, high methane concentrations, low sulfate concentrations, and negative oxidation-reduction potential, all indicative of highly reducing conditions within the biowalls and favorable conditions for CVOC destruction via microbial reductive dechlorination. High cellulose content (>79%) of the mulch, elevated total organic carbon (TOC) content in groundwater, and elevated potentially bioavailable organic carbon (PBOC) measurements in soil samples further supports an ongoing, long-lived source of carbon. These results demonstrate the ongoing and long-term efficacy of the mulch biowalls at Altus AFB. In addition, concentrations of bacteria, TOC, PBOC, and other geochemical parameters suggest a modest impact of the biowalls downgradient. The continued presence of CVOCs downgradient may be attributable to back diffusion from low-permeability shale. However, the biowalls continue to provide benefits by removing CVOCs in groundwater, thus reducing further CVOC loading to the downgradient, low-permeability strata.     

Use of Sonication for Enhanced Sampling of Attached Microbes from Groundwater Systems

The vast majority of microorganisms in aquifers live as biofilms on sediment surfaces, which presents significant challenges for sampling as only the suspended microbes will be sampled through normal pumping. The use of a down-well low frequency sonicator has been suggested as a method of detaching microbes from the biofilm and allowing rapid sampling of this community. We developed a portable, easy to use, low-frequency electric sonicator and evaluated its performance for a range of well depths (tested up to 42 m below ground level) and casing types. Three sonicators were characterized in laboratory experiments using a 1 m long tank filled with pea gravel. These included a commercially available pneumatic sonicator, a rotating flexible shaft sonicator, and the prototype electric sonicator. The electric sonicator detached between 56 and 74% of microbes grown on gravel-containing biobags at distances ranging between 2 and 50 cm from the sonicator. The field testing comprises of a total of 55 sampling events from 48 wells located in 4 regions throughout New Zealand. Pre- and post-sonication samples showed an average 33 times increase in bacterial counts. Microbial sequence data showed that the same classes are present in pre- and post-sonicated samples and only slight differences were seen in the proportions present. The sampling process was rapid and the significant increases in bacterial counts mean that microbial samples can be quickly obtained from wells, which permits more detailed analysis than previously possible.     

Channel precipitation dynamics in a forested Pennsylvania headwater catchment (USA)

Seasonal and event variations in stream channel area and the contributions of channel precipitation to stream flow were studied on a 106‐ha forested headwater catchment in central Pennsylvania. Variations in stream velocity, flowing stream surface width and widths of near‐stream saturated areas were periodically monitored at 61 channel transects over a two‐year period. The area of flowing stream surface and near‐stream saturated zones combined, ranged from 0·07% of basin area during summer low flows to 0·60% of total basin area during peak storm flows. Near‐stream saturated zones generally represented about half of the total channel area available to intercept throughfall and generate channel precipitation. Contributions of routed channel precipitation from the flowing stream surface and near‐stream zones, calculated using the Penn State Runoff Model (PSRM, v. 95), represented from 1·1 to 6·4% of total stream flow and 2·5–29% of total storm flow (stream flow–antecedent baseflow) during the six events. Areas of near‐stream saturated zones contributed 35–52% of the computed channel precipitation during the six events. Channel precipitation contributed a higher percentage of stream flow for events with low antecedent baseflow when storm flow generated by subsurface sources was relatively low. Expansion of channel area and consequent increases in volumes of channel precipitation with flow increases during events was non‐linear, with greater rates of change occurring at lower than at higher discharge rates. Copyright © 1999 John Wiley & Sons, Ltd.     

Apparent redox potential discontinuity (aRPD) depth as a relative measure of sediment oxygen content and habitat quality

As hypoxic conditions spread in our oceans, indices that quickly and efficiently assess oxygen content in sediment pore water, and habitat quality are increasingly becoming desirable. Depth to the appa...     

Aviation-Contrail Impacts on Climate and Climate Change: A Ready-to-Wear Research Mantle for Geographers

Although geographers are highly visible in research into contemporary climate changes accompanying greenhouse gas increases (“global warming”), a relatively little explored component by them is the impact of aviation. This contrasts with the atmospheric science community of cloud physicists, chemists, and numerical modelers, who use geographic tools of trade. Geographers are well positioned to investigate aviation-climate impacts, especially related to contrail clouds, given geographic traditions of environment, spatial variation, regionalization, generalization, and the integrative approach to studying physical and human systems (here, climate, transportation, and energy). We highlight the role played by geographers in contrail-climate studies and advocate for a broader involvement in aviation policy formulation.     

Buruanga peninsula and Antique Range: Two contrasting terranes in Northwest Panay,Philippines featuring an arc–continent collision zone

Alternating chert–clastic sequences juxtaposed with limestone blocks, which are units typical of accretionary complexes, constitute the Buruanga peninsula. New lithostratigraphic units are proposed in this study: the Unidos Formation (Jurassic chert sequence), the Saboncogon Formation (Jurassic siliceous mudstone–terrigenous mudstone and quartz‐rich sandstone), the Gibon Formation (Jurassic(?) bedded pelagic limestone), the Libertad Metamorphics (Jurassic–Cretaceous slate, phyllite, and schist) and the Buruanga Formation (Pliocene–Pleistocene reefal limestone). The first three sedimentary sequences in the Buruanga peninsula show close affinity with the ocean plate stratigraphy of the North Palawan terrane in Busuanga Island: Lower–Middle Jurassic chert sequences overlain by Middle–Upper Jurassic clastics, juxtaposed with pelagic limestone. Moreover, the JR5–JR6 (Callovian to Oxfordian) siliceous mudstone of the Saboncogon Formation in the Buruanga peninsula correlates with the JR5–JR6 siliceous mudstone of the Guinlo Formation in the Middle Busuanga Belt. These findings suggest that the Buruanga peninsula may be part of the North Palawan terrane. The rocks of the Buruanga peninsula completely differ from the Middle Miocene basaltic to andesitic pyroclastic and lava flow deposits with reefal limestone and arkosic sandstone of the Antique Range. Thus, the previously suggested boundary between the Palawan microcontinental block and the Philippine Mobile Belt in the central Philippines, which is the suture zone between the Buruanga peninsula and the Antique Range, is confirmed. This boundary is similarly considered as the collision zone between them.     

Turbulence Statistics Above And Within Two Amazon Rain Forest Canopies

The turbulence structure in two Amazon rain forestswas characterised for a range of above-canopystability conditions, and the results compared withprevious studies in other forest canopies and recenttheory for the generation of turbulent eddies justabove forest canopies. Three-dimensional wind speedand temperature fluctuation data were collectedsimultaneously at up to five levels inside and abovetwo canopies of 30–40 m tall forests, during threeseparate periods. We analysed hourly statistics, jointprobability distributions, length scales, spatialcorrelations and coherence, as well as power spectraof vertical and horizontal wind speed.The daytime results show a sharp attenuation ofturbulence in the top third of the canopies, resultingin very little movement, and almost Gaussianprobability distributions of wind speeds, in the lowercanopy. This contrasts with strongly skewed andkurtotic distributions in the upper canopy. At night,attenuation was even stronger and skewness vanishedeven in the upper canopy. Power spectral peaks in thelower canopy are shifted to lower frequencies relativeto the upper canopy, and spatial correlations andcoherences were low throughout the canopy. Integrallength scales of vertical wind speed at the top of thecanopy were small, about 0.15 h compared to avalue of 0.28 h expected from the shear lengthscale at the canopy top, based on the hypothesis that theupper canopy air behaves as a plane mixing layer. Allthis suggests that, although exchange is not totallyinhibited, tropical rain forest canopies differ from other forests in that rapid, coherentdownward sweeps do not penetrate into the lowercanopy, and that length scales are suppressed. This isassociated with a persistent inversion of stability inthat region compared to above-canopy conditions. Theinversion is likely to be maintained by strong heatabsorption in the leaves concentrated near thecanopy top, with the generally weak turbulence beingunable to destroy the temperature gradients over thelarge canopy depth.     

Hydrogeochemical evaluation of groundwater in the lower Offin basin,Ghana

Alumino-silicate mineral dissolution, cation exchange, reductive dissolution of hematite and goethite, oxidation of pyrite and arsenopyrite are processes that influence groundwater quality in the Offin Basin. The main aim of this study was to characterise groundwater and delineate relevant water–rock interactions that control the evolution of water quality in Offin Basin, a major gold mining area in Ghana. Boreholes, dug wells, springs and mine drainage samples were analysed for major ions, minor and trace elements. Major ion study results show that the groundwater is, principally, Ca–Mg–HCO₃ or Na–Mg–Ca–HCO₃ in character, mildly acidic and low in conductivity. Groundwater acidification is principally due to natural biogeochemical processes. Though acidic, the groundwater has positive acid neutralising potential provided by the dissolution of alumino-silicates and mafic rocks. Trace elements’ loading (except arsenic and iron) of groundwater is generally low. Reductive dissolution of iron minerals in the presence of organic matter is responsible for high-iron concentration in areas underlain by granitoids. Elsewhere pyrite and arsenopyrite oxidation is the plausible process for iron and arsenic mobilisation. Approximately 19 and 46% of the boreholes have arsenic and iron concentrations exceeding the WHO’s (Guidelines for drinking water quality. Final task group meeting. WHO Press, World Health Organization, Geneva, 2004) maximum acceptable limits of 10 μg l⁻¹ and 0.3 mg l⁻¹, for drinking water.     

Investigations in Kenya and Malawi using as-dug laterite as bases for bituminous surfaced roads

Summary In Kenya 1974/5 and in Malawi 1984/5 trial sections of bituminous-surfaced low volume roads were constructed using as-dug laterite in place of stone or stabilized material as a base course.The laterite did not conform with any accepted specifications but performed equally well when compared with adjoining sections of road using stone or stabilized material as a base.The construction procedures employed are described. A period of 4–6 weeks between the compaction of the base and its surfacing is considered essential if the road is to perform satisfactorily. During this period it is exposed to the weather and traffic or to periodic watering and rolling. This treatment fills any cracks with dust or mud and closes them by the kneading action of rubber-tyred traffic. The bituminous surfacing is applied where the base has dried out to about half the optimum moisture content and is extended about 1.5 m beyond each edge of the carriageway.In 1984, $40000 US per km was saved in Malawi in this way, approximately 70% being in convertible currency without incurring additional maintenance or vehicle operating costs.