Compositions and sources of extractable organic matter in Mesopotamian marshland surface sediments of Iraq. I: aliphatic lipids

Shallow surface sediment samples from the Mesopotamian marshlands of Iraq were collected and analyzed to determine the distribution, concentrations and sources of aliphatic lipid compounds (n-alkanes, n-alkanols, n-alkanoic acids, and methyl n-alkanoates) and molecular markers of petroleum in these wetlands. The sediments were collected using a stainless steel sediment corer, dried, extracted with a dichloromethane/methanol mixture and then analyzed by gas chromatography-mass spectrometry (GC–MS). The aliphatic lipid compounds included n-alkanes, n-alkanoic acids, n-alkanols and methyl n-alkanoates with concentrations ranged from 6.8 to 31.1 μg/g, 4.1 to 5.0 μg/g, 5.9 to 7.7 μg/g and from 0.3 to 5.9 μg/g, respectively. The major sources of aliphatic lipids were natural from waxes of higher plants (24–30%) and microbial residues (42–30%), with a significant contribution from anthropogenic sources (27–30%, petroleum), based on the organic geochemical parameters and indices. Further studies are needed to characterize the rate, accumulation and transformation of various organic matter sources before and after re-flooding of these wetlands.     

A stable isotope and fluid inclusion study of the Qaleh-ZariCu–Au–Ag deposit, Khorasan Province, Iran

The Qaleh-Zari copper deposit, located in South Khorasan in the Central Lut region of Iran, is a polymetallic vein deposit with major amounts of Cu, Au, Ag and minor amounts of Pb, Zn and Bi. Mineralization occurs in a series of NW–SE trending fault planes and breccia zones in Paleogene andesitic to basaltic volcanic rocks. Argillization, sericitization and propylitization characterize alteration halos bordering mineral veins. The main ore minerals are chalcopyrite, pyrite, galena and sphalerite, with quartz, calcite and minor chlorite as the main gangue phases. Microthermometric measurements of fluid inclusions in cogenetic quartz indicate homogenization temperatures between 160 and 300 °C and salinities from 1 to 4 wt% NaCl equiv. Boiling occurred in the mineralising fluids at 160–1000 m below the paleo-water table at pressures of approximately 15−80 bar at various stages in the formation of the ore body. The wide range of pressures and temperatures reflects the multi-stage nature of the mineralization at Qaleh-Zari. The δ¹⁸O values in quartz (relative to SMOW) and δ³⁴S values in chalcopyrite and galena (relative to CDT) range from 6.5 to 7.5‰ and 0.0–1.5‰ (mean: 7.0‰), respectively. At 300 °C, calculated fluid δ¹⁸O values are close to 0‰. These data suggest a magmatic origin for sulfur and a surficial origin for the mineralizing fluid. Mineralization at Qaleh-Zari is interpreted as epithermal and low-sulfidation in style and was probably related to a deep-seated magmatic system. Ore deposition was the result of boiling, cooling and pressure reduction.     

Genotypic and environmental interaction in advanced lines of rice under salt-affected soils of Punjab

Sixteen genotypes developed through hybridization and mutation breeding techniques were evaluated during the year 2003–04 on nine locations covering most of the area of Punjab province including Faisalabad, Toba Tek Singh and Jhang. NIAB-IRRI-9, Jhona-379 salt tolerant genotypes and super Basmati, a salt sensitive variety were included as standard checks. The tested material (six genotypes) was generated by crossing fine varieties of rice viz. Basmati-370 and Basmati-385 with three coarse varieties of rice viz. NIAB-IRRI-9, Jhona-349 and NIAB-Rice-1. The mutants (seven mutants) were derived by gamma irradiation of rice varieties, Basmati-370 and Basmati-385. The nine sets of experiments were conducted in the naturally high saline sodic soils having EC range of 9.2–18.13 d/Sm pH=8.65–9.50, and SAR=20.7–37.15. The seed yield data collected at maturity and stability parameters were computed to know genotypic x environment interaction and varietals performance. The combined analysis of variance showed highly significant variance in case of varieties, locations and varieties x locations interaction. Varieties and varieties x Environment (Lin) also showed highly significant differences. It means that genotypes exhibited different behavior in different locations / environments which is due to their different genetic make up. The behavior may be cross over (in which significant change in ranking occurs from one environment to another) or cross over nature (in which case the ranking of genotype remains constant across environments and the interaction is significant because of change in the magnitude of response) depending upon the ranking order of genotypes performance under different environment. In our study, only super Basmati behavior was of almost non cross over nature, while others had cross over type of interaction. Based on overall mean seed performance, mutant NIAB-Rice-4 and DM-38/88 produced significantly the highest grain yield (5.6 t/ha) followed by mutant line NIAB-Rice-5 (5.4 t/ha) and NIAB-rice-2 (5.3 t/ha). The lowest performing genotype was super Basmati (3.0 t/ha). The coarse variety Jhona-349 produced (4.8 t/ha) grain yield. Mutant line DM-38/88 showed significant regression co-efficient differences from unity while mutant line NIAB-Rice-4 showed non significant difference of regression co-efficient from unity. Mutant line, NIAB-Rice-4 also showed non significant difference of standard deviation to regression co-efficient from zero. All the three parameters of stability i.e. overall mean seed yield, regression co-efficient and standard deviation to regression, provided clear evidence that mutant line NIAB-Rice-4 produced maximum stable yield compared to super Basmati.     

Compressibility of porous rocks: Part I. Measurements of Hungarian reservoir rock samples

Pore volume compressibility is one of the physical properties of a reservoir that must be specified in many reservoir-engineering calculations. In the presented research, the effect of compact pressure, temperature and porosity on compressibility was investigated. A total of twenty-two different cores were tested: five limestone, one friable sandstone, fourteen medium to hard sandstone, and two very dense sandstone. Core samples were placed in the test cell and subject to compacting pressure up to 10,000 psi. Runs were made at room temperature and at 52°C for limestone samples. Although there were some publications concerning measurement and study of the effect of pressure and temperature on pore volume compressibility of reservoir rocks, nothing has been published about compressibility of Hungarian reservoir rocks, except of the work of Tóth and Bauer (1988). The present study showed pore volume compressibility data for different Hungarian fields. The result of the study at high temperature (52°C) shows that pore compressibility increases with increasing temperature.     

Another look at the 1993 and 1995 Gulf of Aqaba earthquakes from the analysis of teleseismic waveforms

In this work we estimated the source process and the source parameters of the 1993 and 1995 Gulf of Aqaba earthquakes. To investigate the source process of both events, we inverted the teleseismic P- and SH-waveform data using an iterative technique in which the rupture is modeled as a series of point source subevents with varying mechanisms. The main source process of the 1993 event can be explained by two subevents with essentially the same mechanism. These two subevents had different focal depths. The second subevent was about 5 s later than the first one and about 70% of the moment rate released with the second one. The total rupture duration time was about 12 s. Our solution for the 1995 Gulf of Aqaba earthquake indicated that the event consists of three subevents with various fault geometries and about 60% of the moment released by the second subevent. The first subevent occurred at a depth of 13 km, and was followed after 9 s by the second one at a depth of 11 km; the third subevent, at a depth of 9 km occurred 19 s after the second one. The total duration of the earthquake rupture process was about 18.7 s. The obtained mechanisms for the 1993 and 1995 Gulf of Aqaba earthquakes are well correlated with the structural setting of the Gulf of Aqaba.     

Recent crustal deformation of İzmir, Western Anatolia and surrounding regions as deduced from repeated GPS measurements and strain field

To investigate contemporary neotectonic deformation in İzmir, Western Anatolia and in its neighborhood, a relatively dense Global Positioning System (GPS) monitoring network was established in 2001. Combination of three spatially dense GPS campaigns in 2001, 2003 and 2004 with temporally dense campaigns between 1992 and 2004 resulted in a combined velocity field representing active deformation rate in the region. We computed horizontal and vertical velocity fields with respect to Earth-centered, Earth-fixed ITRF2000, to Eurasia and to Anatolia as well.The rates of principal and shear strains along with rigid-body rotation rates were derived from velocity field. Results show east–west shortening between Karaburun Peninsula and northern part of İzmir Bay together with the extension of İzmir Bay in accordance with general extension regime of Western Anatolia and Eastern Agea. East–west shortening and north–south extension of Karaburun Peninsula are closely related to right-lateral faulting and a clockwise rotation. There exists a block in the middle of the peninsula with a differential motion at a rate of 3–5 ± 1 mm/year and 5–6 ± 1 mm/year to the east and south, respectively.As is in Western Anatolia, north–south extension is dominant in almost all parts of the region despite the fact that they exhibit significantly higher rates in the middle of the peninsula. Extensional rates along Tuzla Fault lying nearly perpendicular to İzmir Bay and in its west are maximum in the region with an extension rate of 300–500 ± 80–100 nanostrain/year and confirm its active state. Extensional rates in other parts of the region are at level of 50–150 nanostrain/year as expected in the other parts of Western Anatolia.     

Single piles under horizontal loads in sand: determination of <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">Y</Emphasis> curves from the prebored pressuremeter test

Lateral load-deflection behaviour of single piles is often analysed in practice on the basis of methods of load-transfer P–Y curves. The paper is aimed at presenting the results of the interpretation of five full-scale horizontal loading tests of single instrumented piles in two sandy soils, in order to define the parameters of P–Y curves, namely the initial lateral reaction modulus and the lateral soil resistance, in correlation with the pressuremeter test parameters. P–Y curve parameters were found varying as a power of lateral pile/soil stiffness, on the basis of which hyperbolic P–Y curves in sand were proposed. The predictive capabilities of the proposed P–Y curves were assessed by predicting the soil/pile response in full-scale tests as well as in centrifuge tests and a very good agreement was found between the computed deflections and bending moments, and the measured ones. Small-sized database of full-scale pile loading tests in sand was built and a comparative study of some commonly used P–Y curve methods was undertaken. Moreover, it was shown that the load-deflection curves of these test piles may be normalised in a practical form for an approximate evaluation of pile deflection in a preliminary stage of pile design. At last, a parametric study undertaken on the basis of the proposed P–Y curves showed the significant influence of the lateral pile/soil stiffness on the non-linear load-deflection response.     

新疆南部地区暖冬年与春夏季降水的相关分析

利用春夏季(3~8月)12个站降水资料以及冬季(12~02月)温度资料,通过统计方法选取新疆南部地区温度异常年份与春夏季降水异常年份,并进行相关分析,结果表明:暖冬年份对应的来年春夏季总降水量偏多;反之,冷冬年对应的春夏季降水总量偏少。再利用NCEP/NCAR1960-2000年全球月平均网格点资料分析500 hPa高度场环流特征,结果表明:暖冬年前期环流特征为西低东高型,冷冬年前期环流特征为西高东低型,具有反位相关系。暖冬年后期才为西高东低型,与冷冬年前期相较起点晚,从而影响到来年的环流入夏时间,这可能就是导致暖冬年份来年降水增多的原因之一。     

Groundwater Deterioration of Shallow Groundwater Aquifers Due to Overexploitation in Northeast Jordan

Groundwater is the major water resource in Jordan and most of the groundwater basins are already exploited beyond their estimated safe yield. Azraq basin is one of the most important groundwater basins in Jordan, which supplies Amman with drinking water. However, due to overpumping from the shallow groundwater aquifers, the water level dropped dramatically and signs of salinization and depletion are starting to occur. The severe drawdown in the Azraq well‐field caused a reverse in the hydraulic gradient and consequently, the saltwater in the center of the basin (Qa‐Azraq) started to move in the direction of the well‐field. The salinization in the shallow aquifer (basalt/B5/B4) is believed to result from one of the following scenarios: (i) a reverse flow from Sabkha to the AWSA well field, (ii) an upward leakage from the middle aquifer system (B2/A7) and the combined B3 Aquitard‐B2/A7 aquifer, (iii) a dissolution process between the water and rock matrix due to lowering of the dynamic water levels during pumping which reached the mineralized formations underlying the Basalt. The salinization trend of some AWSA wells represented by the gradual increase of major ions is associated with rather constant stable isotopic contents. This indicates that these constituents originate from the main minerals existing in the matrix of the aquifers and thus this scenario is the most likely to occur.     

Estimating the economic potential for agricultural soil carbon sequestration in the Central United States using an aggregate econometric-process simulation model

The purpose of this paper is to develop and apply a new method to assess economic potential for agricultural greenhouse gas mitigation. This method uses secondary economic data and conventional econometric production models, combined with estimates of soil carbon stocks derived from biophysical simulation models such as Century, to construct economic simulation models that estimate economic potential for carbon sequestration. Using this method, simulations for the central United States show that reduction in fallow and conservation tillage adoption in the wheat-pasture system could generate up to about 1.7 million MgC/yr, whereas increased adoption of conservation tillage in the corn–soy–feed system could generate up to about 6.2 million MgC/yr at a price of $200/MgC. About half of this potential could be achieved at relatively low carbon prices (in the range of $50 per ton). The model used in this analysis produced estimates of economic potential for soil carbon sequestration potential similar to results produced by much more data-intensive, field-scale models, suggesting that this simpler, aggregate modeling approach can produce credible estimates of soil carbon sequestration potential. Carbon rates were found to vary substantially over the region. Using average carbon rates for the region, the model produced carbon sequestration estimates within about 10% of those based on county-specific carbon rates, suggesting that effects of spatial heterogeneity in carbon rates may average out over a large region such as the central United States. However, the average carbon rates produced large prediction errors for individual counties, showing that estimates of carbon rates do need to be matched to the spatial scale of analysis. Transaction costs were found to have a potentially important impact on soil carbon supply at low carbon prices, particularly when carbon rates are low, but this effect diminishes as carbon prices increase. This research was supported in part by the Montana State Agricultural Experiment Station, by the EPA STAR Climate Change program and by the Consortium for the Agricultural Mitigation of Greenhouse Gases. Although the research described in this article has been funded wholly or in part by the United States Environmental Protection Agency through grant R-82874501-0 to Montana State University, it has not been subjected to the Agency’s required peer and policy review and therefore does not necessarily reflect the views of the Agency and no official endorsement should be inferred.