Hydrochemical and statistical studies of the groundwater salinization combined with MODPATH numerical model: case of the Sfax coastal aquifer,Southeast Tunisia

Shallow groundwater is one of the main water resources in the arid and semi-arid regions. However, it is threatened by not only the reduced rainfall and recharge capacity, but also the water table drawdown and seawater intrusion. Such factors could cause a deterioration of the water quality and consequently the loss of a valuable hydraulic resource. This study aimed to improve our knowledge on the groundwater chemical quality evolution of the Sfax shallow aquifer, one of the most vulnerable areas in Tunisia, by developing a geochemical study using statistical and numerical methods. Salinization was identified by factorial analysis, PCA, and hierarchical clustering analysis in addition to the numerical MODPATH model. These findings confirmed that the groundwater quality has deteriorated due to natural and anthropogenic processes with a different influence of mineralization factors. They also revealed the location of seawater intrusion by focusing on the most vulnerable areas which are Chaffar and Djbeniana. Methodologically, the use of MODPATH model for seawater intrusion determination might be considered as the backbone for future studies in Tunisian coastal aquifers. The numerical model supports the results obtained by the geochemical analysis. Both methods are valuable tools as they contribute to trend determinations, management, and recovery plans.     

Heavy metals in mangrove sediments of the central Arabian Gulf shoreline,Saudi Arabia

To assess heavy metals in mangrove swamps of Sehat and Tarut coastal areas along the Arabian Gulf, 18 sediment samples were collected for Al, V, Cr, Mn, Cu, Zn, Cd, Pb, Hg, Sr, As, Fe, Co, and Ni analysis. The results indicated that the distribution of some metals was largely controlled by anthropogenic inputs, while others were of terrigenous origin and most strongly associated with distribution of aluminum and total organic carbon in sediments. Mangrove sediments were extremely severe enriched with Sr (EF?=?67.59) and very severe enriched with V, Hg, Cd, Cu, As (EF?=?44.28, 37.45, 35.77, 25.97, and 11.53, respectively). Average values of Sr, V, Hg, Cd, Cu, Ni, As, and Cr were mostly higher than the ones recorded from the Mediterranean Sea, the Red Sea, the Gulf of Aqaba, the Caspian Sea, the Arabian and Oman gulfs, coast of Tanzania, sediment quality guidelines, and the background shale and the earth crust. Landfilling due to coastal infrastructure development around mangrove forests, oil spills and petrochemical and desalination effluents from Al-Jubail industrial city to the north were the anthropogenic activities that further enhanced heavy metals in the studied mangrove sediments.     

Constraints of Mantle and Crustal Sources Interaction during Orogenesis of Pre- and Post-collision Granitoids from the Northern Arabian-Nubian Shield: A Case Study from Wadi El-Akhder Granitoids,Southern Sinai,Egypt

The Egyptian older and younger granitic rocks emplaced during pre- and post-collision stages of Neoproterozoic Pan-African orogeny, respectively, are widely distributed in the southern Sinai Peninsula, constituting 70% of the basement outcrops. The Wadi El-Akhder, southwestern Sinai, is a mountainous terrain exposing two granitoid suites, namely the Wadi El-Akhder Older Granites (AOG) and the Homra Younger Granites (HYG). The AOG (granodiorites with subordinate tonalite compositions) have geochemical characteristics of medium-K calc-alkaline, metaluminous to mildly peraluminous granitoids formed in an island-arc environment, which are conformable with well-known Egyptian older granitoids rocks, whereas the HYG display calc-alkaline to slightly alkaline nature, peraluminous syeno-, monzogranites and alkali feldspar granites matching well those of the Egyptian younger granites. With respect to the AOG granitoids, the HYG granites contain lower Al2O3, FeO*, MgO, MnO, CaO, TiO2, Sr, Ba, and V, but higher Na2O, K2O, Nb, Zr, Th, and Rb. The AOG are generally characterized by enrichment in LILE and LREE and depletion in HFSE relative to N-MORB values (e.g., negative Nb and Ta anomalies). The geochemical features of the AOG follow assimilation-fractional crystallization (AFC) trends indicative of extensive crustal contamination of magma derived from a mantle source. The chemical characteristics of the AOG are remarkably similar to those of subduction-related granitoids from the Arabian-Nubian Shield (ANS). The compositional variations from monzogranites through syenogranites to alkali feldspar granite within HYG could not be explained by fractional crystallization solely. Correlating the whole-rock composition of the HYG to melts generated by experimental dehydration melting of meta-sedimentary and magmatic rocks reveals that they appear to be derived by extended melting of psammitic and pelitic metasediments, which is similar to the most of younger granitic suites in the ANS.     

Microseismicity and tectonics of Sinai

Five microearthquake seismographs were used at 11 sites in northern Sinai in the period February 1987 to February 1988 to study the microseismicity of the area around the Maghara coal mine for mine-development studies. A total of 270 events were recorded on 850 records. The magnitude, epicenter and depth of each event were calculated using suitable software for an Egyptian Geological Survey and Mining Authority's (EGSMA) XT computer. The interpretation of the seismic activity in the area is given in view of plate tectonics, the Sinai subplate boundary follows the Gulf of Aqaba and the Dead Sea. The plate and subplate boundaries are presently active, and there seems to be a diffuse zone of deformation between “NW Africa” and “Nubia” affecting the Cairo-Suez district.     

A new fault rupture scenario for the 2003 Mw 6.6 Bam earthquake, SE Iran: Insights from the high-resolution QuickBird imagery and field observations

The December 26, 2003 M_w 6.6 Bam earthquake is one of the most disastrous earthquakes in Iran. QuickBird panchromatic and multispectral satellite imagery with 61 cm and 2.4 m ground resolution, respectively provide new insights into the surface rupturing process associated with this earthquake. The results indicate that this earthquake produced a 2–5 km-wide surface rupture zone with a complex geometric pattern. A 10-km-long surface rupture zone developed along the pre-existing Bam fault trace. Two additional surface rupture zones, each 2–5 km long, are oblique to the pre-existing Bam fault in angles of 20–35°. An analysis of geometric and geomorphic features also shows that movement on the Bam fault is mainly right-lateral motion with some compressional component. This interpretation is consistent with field investigations, analysis of aftershocks as well as teleseismic inversion. Therefore, we suggest that the 2003 Bam earthquake occurred on the Bam fault, and that the surface ruptures oblique to the Bam fault are caused by secondary faulting such as synthetic shears (Reidel shears). Our fault model for the Bam earthquake provides a new tectonic scenario for explaining complex surface deformations associated with the Bam earthquake.     

Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Diffusion from a point source in an urban atmosphere

Summary In the present paper, a model for the diffusion of material from a point source in an urban atmosphere is incorporated. The plume is assumed to have a well-defined edge at which the concentration falls to zero. The vertical wind shear is estimated using logarithmic law, by employing most of the available techniques of stability categories. The concentrations estimated from the model were compared favorably with the field observations of other investigators.     

Multiple phases of North African humidity recorded in lacustrine sediments from the Fazzan Basin, Libyan Sahara

The Fazzan Basin of south-west Libya is at present arid with less than 20 mm of rainfall per annum. However, regionally extensive limestones, lacustrine sands and coquina (fossiliferous carbonate rock) deposits show that the Fazzan Basin previously contained a large palaeolake, indicating that the climate in the past was more humid. Optically stimulated luminescence (OSL) dating techniques have been applied to key lacustrine deposits within the basin in an attempt to provide an internally consistent chronology for this humidity record. Results indicate that palaeolake sediments within the Fazzan Basin record a very long history of palaeohydrological change, ranging from present day arid conditions to humidity capable of sustaining a lake with an approximate area of 76,250 km². The existence of humid periods in mid oxygen isotope stage 5 and the early Holocene is confirmed. An older lacustrine event, tentatively correlated to oxygen isotope stage 11, is also recognized. In addition, evidence is presented for at least two humid phases beyond the age range over which the conventional OSL dating technique is applicable. This study demonstrates that OSL dating of palaeolake sediments within the Fazzan Basin offers the potential to provide a detailed record of North African humidity spanning several glacial–interglacial cycles.     

GIS and multi-criteria analysis to select potential sites of agro-industrial complex

The selection of the potential sites to the creation of an agro-industrial complex requires a large amount of spatial information. Geographical information systems are capable of managing this information, providing the ability to integrate multiple layers of information and deriving new ones. This study incorporates environmental, social, economic, geological and infrastructural data. A multi-criteria analysis is performed to select the potential sites to the creation of an agro-industrial complex in the city of Sfax (the southern coast of Tunisia). The comparison by pair method adopted in this paper, based on a linear combination pondered after having assigned to every factor of decision a coefficient of level-headedness, creates many scenarios among which we selected the sustainable development one. This scenario assigned the highest weight to the economical, environmental and social factors (0.3 for each factor), which shows the presence of nine suitable sectors for the creation of an agro-industrial complex. The ELECTRE method enabled us to make a site ordering for the identification of the most three appropriate sites.