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11.
Mariana Vezzone Ricardo Cesar Helena Polivanov Aline Serrano Danielle Siqueira Leticia Abreu Miriam Bianchi Maria Elizabeth Correia Zuleica Castilhos Tácio de Campos 《Environmental Earth Sciences》2018,77(21):743
The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation. 相似文献
12.
Trace element and isotopic characteristics of late Carboniferous to early Permian minettes and kersantites have been determined. These lamprophyres have been sampled throughout the Western European Hercynian orogen, from Brittany to the west to Schwarzwald to the east. In spite of sharp petrological differences reflected by mineralogy and major element geochemistry, minettes and kersantites exhibit close identity with respect to trace element and isotopic features. These features comprise enrichment in incompatible elements, highCs/Rb and lowCe/Pb ratios, Ta and Ti relative depletion, high abundance in transition elements and highNi/Mg ratios. Pb isotope ratios are undistinguishable from those measured on Hercynian continental crust. Initial143Nd/144Nd ratios are between0.5120 (εi −5) and0.5122 (εi −1) for minettes and kersantites whereas initial87Sr/86Sr ratios vary between 0.7055–0.710 for minettes and 0.707–0.708 for kersantites. No simple mixing relations are visible on RbSr and SmNd isochron diagrams. The exceptional homogeneity of these geochemical characteristics along a 1000 km traverse does not allow for an hypothesis of enrichment through upper level assimilation and thus leads to propose that these rocks originated through melting of a mantle enriched by recycling of crustal material. 相似文献
13.
14.
Electron microprobe analyses of minerals in low grade metamorphic sandy black shales of middle Paleozoic age indicate that chemical equilibrium was closely approached in authigenic ferro-magnesian or alkali-bearing phases while aluminum silicate minerals appear to have reacted at a slower rate. The K for Mg-Fe in chlorite-chloritöid pairs is 0.19, the latter phase being iron-rich. The pseudomorphism of detrital white micas produces kaolinite, pyrophyllite and intimate mixtures of muscoviteparagonite. New phases forming in other sites include chlorite, chloritöid and rectorite which is an ordered paragonitebeidellite mixed layered phase. These minerals were formed at temperatures below 280° C. This is just above the stability of the illite-smectite mixed layered minerals which have an ISII ordering sequence (85 to 95% illite). It was noted that ferromagnesian minerals attain chemical equilibrium on a thin-section scale while the aluminous phases often seem to respond to chemical potentials operative on a submillimetric scale. 相似文献
15.
Danielle J. Marceau Luc Guindon Mireille Bruel Claude Marois 《The Professional geographer》2001,53(4):546-558
This article addresses the issue of linking temporal and spatial information into a GIS database structure to investigate the land‐use changes in a rural‐urban region over a thirty‐five‐year period. More specifically, it describes the application of a programming package developed to build temporal topology in an historical land‐use GIS database to efficiently perform spatiotemporal queries. The program was created within the MapInfo environment using MapBasic language. Different types of information, such as the rate of change, the relationship between the change of land use and zoning regulations, and land‐use succession were extracted from the database. A user‐friendly interface was also developed to easily address spatiotemporal queries to the database. This approach represents a flexible and performing tool for scientists and planners who need to efficiently capture essential spatiotemporal information required for geographical inquiry and decision‐making. 相似文献
16.
Raman spectra of natural analcime have been recorded at atmospheric pressure and up to 9.4 kbar. The basic Si, Al-O network vibrations are little affected by pressure even though significant volume changes and a minor phase transition take place. However, the 3,557 cm?1 OH-stretch mode is modified in that band splitting takes place indicating at least two O-OH hydrogen bond distances. Thus there are at least three sites of hydrogen bonding in analcime. The bonded water (H2O) in analcime appears to remain in the mineral at high pressure. The bulk volume change, determined previously by cell dimension measurements, can be traced to reduction of the size of the “voids” in the structure. This is deduced from the fact that Si-Al-O vibrations are little affected by pressure but O-H vibrations of water molecules found in the voids are strongly pressure-dependent. 相似文献
17.
Kim Vermonden Marion A. A. Hermus Marije van Weperen Rob S. E. W. Leuven Gerard van der Velde Alfons J. P. Smolders Jan G. M. Roelofs A. Jan Hendriks 《水文研究》2009,23(21):3110-3120
The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
18.
Wildfires cause enormous damage worldwide, particularly in Victoria, Australia, with growing populations in fire-prone ecosystems. Broad-scale prescribed burning is an established, yet controversial, wildfire management policy in Victoria and Australia. But does broad-scale prescribed burning reduce fire damage? The answer depends on how damage is measured. We propose that different perceptions about the efficacy of broad-scale prescribed burning derive from different disciplinary measures of damage (e.g., biodiversity, area burned, or fatalities). Although broad-scale prescribed burning reduces subsequent wildfire size, there is little evidence that it saves human lives and homes. Evidence suggests that small-scale fuel reduction may be more effective at saving lives. The prescribed burning debate might be better focused on what damage we wish to limit, and which measures are most effective at limiting this damage. In this context, the current policy focus on broad-scale prescribed burning targets may distract efforts from more effective lifesaving strategies. 相似文献
19.
Topography and morphodynamics in the German Bight using SAR and optical remote sensing data 总被引:3,自引:0,他引:3
Morphological changes in coastal areas, especially in river estuaries, are of high interest in many parts of the world. Satellite
data from both optical and radar sensors can help to monitor and investigate these changes. Data from both kinds of sensors
being available for up to 30 years now, allow examinations over large timescales, while high resolution sensors developed
within the last decade allow increased accuracy. So the creation of digital elevation models (DEMs) of, for example, the wadden
sea from a series of satellite images is already possible. ENVISAT, successfully launched on March 1, 2002, continues the
line of higher resolution synthetic aperture radar (SAR) imaging sensors with its ASAR instrument and now also allows several
polarization modes for better separation of land and water areas. This article gives an overview of sensors and algorithms
for waterline determination as well as several applications. Both optical and SAR images are considered. Applications include
morphodynamic monitoring studies and DEM generation.
相似文献
Andreas NiedermeierEmail: |
20.
Radovan Pipík Anne-Marie Bodergat Danielle Briot Michal Ková? Ján Král’ Grzegorz Zielinski 《Journal of Paleolimnology》2012,47(2):233-249
The Turiec Basin (TB) of Slovakia formed in the Miocene when the West Carpathians escaped from the Alpine region. The 1,250-m-thick
sedimentary Neogene fill of the basin preserved fossil leaves as well as endemic bivalves, gastropods, and ostracodes. The
paleolimnologic changes recorded in the TB infill were derived from the most abundant fossils, the ostracodes. Five contemporaneous
ostracode assemblages within the Late Miocene lacustrine system were distinguished through statistical analysis. These assemblages
have low species similarity, between 2.1 and 24.1%, and are recognized by shape differences among the Candoninae. The ostracode
assemblages, mollusca fossils, and Sr-isotope ratios suggest a low-salinity environment at the beginning of the Late Miocene,
during a brief connection with the Central Paratethys. When the connection ceased, the basin became an isolated freshwater
lake, with five zones differentiated ecologically and bathymetrically using the ostracode assemblages. Taxonomic comparison
of the faunas of the TB and the freshwater to brackish Neogene basins of Europe demonstrates the endemic character of the
TB ostracode fauna. The biologic characteristics of the ostracode families, along with the geology of the lake basin, suggest
that the longevity of the Late Miocene lake probably exceeded 1 Ma. 相似文献