Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine

To investigate the solubility and the sites of incorporation of hydrogen in olivine as a function of point defect concentration, two-stage high-temperature annealing experiments have been carried out. The first annealing stage (the dry preannealing stage) was conducted at a total pressure of 0.1 MPa, a temperature of 1300° C and various oxygen fugacities in the range 10^?11–10^?4 MPa for times > 12 h. In these heat treatments, the samples were buffered against either orthopyroxene or magnesiowustite, or they remained unbuffered. The second annealing stage (the hydrothermal annealing stage) was performed at 300 MPa and 900–1050 ° C under a hydrogen fugacity of ～ 158 MPa for 1–5 h. Infrared spectra from the annealed samples revealed two distinct groups of bands. Group I bands occurred at wavenumbers in the range 3450–3650 cm^?1, while Group II bands occurred in the range 3200–3450 cm^?1. The hydrogen solubility associated with Group I bands is proportional to f _{O 2} to the 1/6 power for samples preannealed in contact with orthopyroxene, to the 1/3 power for samples preannealed in contact with magnesiowustite, and to the 1/13 power for samples preannealed in the absence of a solid-state buffer. The hydrogen concentration for Group II bands varies with f _{o 2} to the 1/3 power for opxbuffered samples, to the 1/2 power for mw-buffered samples, and to the 1/3 power for unbuffered samples. The dependence of hydrogen solubility on oxygen fugacity and orthopyroxene activity suggests that hydrogen is incorporated into the olivine structure via association with point defects. The presence of two distinct groups of absorption bands indicates that hydrogen is associated with two distinct lattice defects. The following point defect model for the mechanism of incorporation of hydrogen in olivine is consistent with these results: Hydrogen ions responsible for the Group I bands are associated with doubly charged oxygen interstitials, while hydrogen ions responsible for the Group II bands are associated with singly charged oxygen interstitials. Furthermore, the infrared bands observed in naturally derived olivines are present in spectra from our hydrothermally annealed crystals. Thus, the mechanisms of incorporation of hydrogen in olivine under geological conditions are the same as those operative under laboratory conditions. The maximum solubility reached in these experiments was ～ 360H/10⁶Si, which corresponds to ～ 0.002 wt% of H₂O. This value is a lower bound for the solubility of hydrogen in olivine under upper mantle conditions.     

澜沧—耿马7.6级地震前中小地震活动信息熵和分维的研究

从信息论原理和分形几何学的观点出发,采用多种方法,分析研究1988年澜沧—耿马7.6级地震前地震活动的信息、信息熵和分维的变化特征表明,地震前1—2年内,中、小地震活动的信息熵、缺信量和容量维、信息维出现明显的低值变化过程,反映了地震前兆的减熵、降维特点,从一个侧面反映了大震前,一定区域内中、小地震活动的时空变化从无序向有序的演化过程。     

兰州倾斜固体潮潮汐参数的观测研究

本文介绍了兰州形变台FSQ—水管倾斜仪1987—1989年期间观测资料的调和分析结果,讨论了潮汐因子的重复性及其对非潮汐变化的监测能力,分析了气象因素对周日波的影响,並将实测潮汐因子与G—B地球模型理论值进行了比较。     

线性连续变化非弹性介质中地震波射线轨迹与走时研究

地球内部非弹性介质广泛存在,垂向线性连续变化非弹性介质模型具有重要理论与实际意义,本文利用复速度概念推导得到了复速度随深度线性连续变化的非弹性介质中地震波射线轨迹与等时线方程.理论结果表明:在线性连续变化非弹性介质中,射线轨迹呈圆形,等时面的形状为椭圆.最后对射线轨迹与等时线方程的适用性条件进行了讨论.     

北京地区太阳紫外辐射的观测与分析研究

利用北京地区太阳辐射和其它常规气象观测资料，得到了到达地面的太阳紫外辐射的计算公式，并将计算值与观测值进行了比较，两者吻合得比较好。最后给出了北京地区地面太阳紫外总辐射的变化趋势，计算结果表明，地面太阳紫外总辐射对大气浑浊度的变化比对大气臭氧总量的变化敏感得多。     

新疆塔城地区地震地质特征

托里活断层、达尔布特活断层、独山子—安集海活断层及霍尔果斯—卡子湾活断层是塔城地区主要的全新世活断层，均有过多次古地震活动。自１９７７年以来，４级以上地震活动的空区在裕民县西北。据活断层古地震活动复现期及地震活动围空特点分析，今后１０年北天山或塔城西北可能有发生６级左右地震的危险。     

前兆起伏加剧与短临地震预报

起伏加剧是相态突变前的一种临界现象,本文应用这一观点探讨了强地震前小震活动频次和地下流体、气体、地应力等前兆变化的起伏加剧现象,并得到以下初步结果: 1.临近强地震前较大范围内超过平均日活动水平的小震活动的空间分布具有有序性,即出现穿过未来大震区的小地震活动条带,条带的交汇区为未来大震区。2.强地震前的小震高频次活动日大多与外因出现时间同步,目前发现的外因有塑望、节气、中强以上磁暴以及大气压力下降等。这种小震的高频次活动一般出现在震前当天至一个月时间内。3.前兆的起伏时间和小震频次的起伏时间大致同步。它们在成因上有联系。     

K-Ar isotopic geochronology of Lianhuashan tungsten mining district,Guangdong Province

Reported in this paper are K-Ar ages of volcanic rocks, biotite-granite and greisen from the Lianhuashan tungsten mine in Guangdong Province. The isotopic dilution method was adopted in this work. Whole-rock isochron ages of the volcanic rocks are in the range 120.4±12.1 m.y. The petrogenetic age of biotite-granite and the minero genetic age of tungsten ore are close to those of the volcanic rocks. The apparent ages of various types of rock in the mining district generally bias towards younger values, which may be attributed to the effects of late thermal events which took place in the circum-Pacific metallogenetic belt.     

甘肃天水地区1654年罗家堡7(1)/(2)级地震构造背景的初步分析

本文从分析天水地区区域地质构造背景出发着重指出,1654年罗家堡7(1/2)级地震发生在天礼盆地中北东向构造与北北西向活动构造交汇所形成的新生代以来沉陷最深的部位。并对1936年天水镇6级地震发生的构造条件以及天礼盆地的成因进行了初步探讨。     

On the conditions of formation of Gushan iron ore deposit

On the basis of its geological characteristics, the Gushan iron deposit should be assigned to volcano-hydrothermal type with hematite-quartz as its principal mineral assemblage. Iron concentration of the ore solution has been estimated from the ratio of hematite to quartz in the ore. By using experimental and thermodynamic data, the solubility of ferro-minerals at elevated temperatures and pressures have been calculated in the system FeO?Fe₂O₃?NaCl?HCl?H₂O. The effects ofT, P, pH,f _{O 2} and total Cl concentration on the solubility of ferrominerals are discussed. Thermodynamic calculations based on presumed physico-chemical conditions for the ore solution are in good agreement with geological observations. The calculation shows that ferro-minerals were deposited at logf _{O 2}=?21～?25, log(m_HCl+m_H+)=?2.5～?3,P=1?0.75 (or 0.5) kb, andT=400°?350°C. It is believed that the original solution was an acid NaCl-bearing solution of magmatic derivation. However, iron in the solution was enriched with falling temperatures by dissolving pre-existing ferro-minerals in consolidated rocks rather than extracting directly from the magma. Either temperature (below 400°C) or pressure decrease may result in the precipitation of ferro-minerals from the solution, but the Fe/Si ratio in the ore is dependent mainly upon pH. The widespread siliceous veins of later stages are a reflection of decreasing acidity of the solution. An increase inf _{O 2} will also favor the deposition of ferro-minerals. The hypabyssal occurrence and the existence of the Huangmaqing sandy shale have contributed greatly to the formation of hematite.