盐卤硼酸盐化学ⅩⅨ——氯柱硼镁石溶解及相转化研究

本文研究了温度、盐效应、晶体用量和搅拌速度对氯柱硼镁石在水中溶解过程及相转化的影响。实验结果表明,该复盐属不同步溶解,先溶脱MgCl·6H_2O,生成中间产物MgO·B_2O_3·4H_2O,随后发生相转化和结晶过程。最终产物在10—50℃时是多水硼镁石,在60℃时是柱硼镁石。提出了相转化机理,计算了溶解度、溶解热等热力学函数。     

黔中铝土矿及其赤泥中钪的某些特征

本文论述了黔中铝土矿和其紧密伴生硬质粘土岩及其炼铝残渣赤泥中的钪和稀土元素含量与分布特征，通过淋滤实验、酸处理实验、人工合成方钠石及电子探针分析等手段，探讨了钪在赤泥中的赋存特征。     

频散效应对Rossby波动量和热量输送的影响

本文分析了扰动的频散效应对Ｒｏｓｓｂｙ波动量和热量输送的影响，分析指出：（１）频散效应是大气大尺度运动中扰动动能向平均动能转换（即能量逆转）的根本原因，也是扰动有效位能转化为扰动动能所必不可少的。（２）正压大气大尺度运动扰动动能转化为平均动能的充分条件为基本气流水平切变的特征宽度Ｌ（１）小于临界宽度Ｌｃ≡｜γ     

Minerogenesis of Shilu iron ores with special reference to Sm-Nd isotope geochemical characteristics of Shilu Group bimodal volcanic rocks in Hainan Island

Presented in this paper are Sm-Nd isotope and major, trace and rare-earth element analyses of bimodal volcanic rocks of the Shilu Group and other stratigraphic units in northwestern Hainan Island, South China. It is shown that there are some N-MORB-type basalts (spilites) in the western part of the bimodal volcanic belt, in addition to some E-MORB-type and initial rift-type tholeiites (IRT) in the middle and eastern parts. Sm-Nd model ages of these basalts range from 545 Ma to 460 Ma. The other extremes of the bimodal volcanics are porphyritic quartz rhyolites. which are characteristic of crustal material source. Sm-Nd model ages of the rhyolites range from 1562 Ma to 1371 Ma. The bimodal volcanic rocks are almost distributed in rifts or faulted depressions, as well as in the Upper Paleozoic rift of Hainan Island. Tholeiites of the Shilu Group can be compared with Cenozoic basalts in the middle and southern parts of the Red Sea Rift Belt in petrology, elemental geochemistry and Sm-Nd isotope geology. Shilu iron ores are closely associated with N-MORB-type basalts located in the western bimodal volcanic belt. It is very interesting to note that the Shilu Fe-Co-Cu deposit can also be compared with Atlantis II Deep in the Red Sea Rift Belt. Therefore, the present authors believe that the Shilu deposit is a kind of hydrothermal deposit related to ocean volcanic belt, where the geotectonic setting belongs to initial extensional rifts in the oceanic crust. On the other hand, the largest Fe-Co-Cu ore deposit in China used to be influenced by Hercynian granites after mineralization, as is clearly observed on both ε Nd (T)-1/Nd and ε Nd (T)-¹⁴⁷Sm/¹⁴⁴Nd diagrams. This project was jointly funded by the National Natural Science Foundation of China and Research School of Earth Sciences. Australian National University, Australia.     

扬子地台东南大陆边缘上震旦统硅质岩的超微组构及其成因

根据显微镜和扫描电镜的观察以及Ｘ射线衍射和能谱分析，在层状硅质岩中鉴定出最古老的海绵骨针和放射虫化石，提出古菌藻类微生物活动在硅质沉淀中起着重要作用。这些微生物活动形成了一系列形状奇特的石英单晶和集合体，生物成因的单晶常呈球状、杆棒状、板状、胶粒状和晶粒状，最常见的集合体是由密集分布的球形石英构成的莓群，被认为是典型的细菌成因。其它蜂巢状，双联球状、链球状和球状集合体可能是藻类细胞硅化的结果，它们     

表面形貌含波纹度的节理的闭合模型

节理的闭合性质主要取决于节理的组合形貌特征，而并不单独地取决于节理面各自的形貌特征。本文分析了节理面及节理组合形貌的形貌特征，提出了含波纹度节理的闭合模型，模型中采用了节理组合形貌参数，可反映接触状态和初始开度对节理闭合性质的影响。实验验证了该模型比不考虑波纹度的闭合模型更接近于试验结果。     

苏南晚二叠世末期双峰次火山岩的发现和单颗粒锆石U－Pb年代学意义

苏南晚二叠世末期双峰次火山岩的发现和单颗粒锆石Ｕ－Ｐｂ年代学意义方中，李惠民，夏邦栋，楚雪君，刘寿和，王学锋（南京大学地球科学系，江苏南京，２１０００８；天津地质矿产研究所，天津，３００１７０）关键词晚二叠世，双峰火山岩，同生锆石，捕虏晶锆石，Ｕ－Ｐ...     

青藏高原钠硼解石在水中溶解动力学和热力学的研究

本工作采用ｐＨ值，电导率和Ｎａ＋、Ｃａ（２＋）选择电极的电极电位四种物理参数跟踪测定了钠硼解石在１０℃～３５℃纯水中的溶解过程，结合取样进行化学分析和对固相的物相鉴定确定了溶解机制．拟合出溶解动力学方程，计算了Ａｒｒｈａｎｉｕｓ活化能，并根据最终平衡的各离子浓度计算出溶度积常数、溶解度、溶解热和溶解熵等热力学函数．     

Li2SO4和MgSO4对C2H5OH—H2O体系的影响

本文首次测定了含Ｌｉ２ＳＯ４和ＭｇＳＯ４盐对醇水混合溶剂工溶度的影响和相关系．Ｌｉ２ＳＯ４盐在室温范围内不会使乙醇─水体系分层，但在ＭｇＳＯ４─Ｃ２Ｈ５ＯＨ—Ｈ２Ｏ体系中加入少量的Ｌｉ２ＳＯ４会使分层温度下降１０℃左右，Ｌｉ２ＳＯ４和ＭｇＳＯ４作为混合盐加入乙醇─水体系中表现出加合性．