西藏柯月锌多金属矿床地质特征及成矿时代初步研究

柯月锌多金属矿床是北喜马拉雅锑金多金属成矿带上新发现的重要矿床。矿体主要呈脉状、透镜状产于近南北向张扭性断裂中,金属矿物主要有方铅矿、闪锌矿、辉锑矿、脆硫锑铅矿、硫锑铅矿、黄铁矿、毒砂、黄铜矿等,非金属矿物主要有石英、铁锰碳酸盐、方解石等。矿石组构以热液充填交代成因为主。流体包裹体初步研究表明,包裹体以液体包裹体为主,还有少量纯气体和纯液体包裹体。成矿流体为中低温、中低盐度、低密度H2O-Na Cl体系。流体中气液成分以H2O为主,液相中局部含有少量的HCO-3、CO2-3和CO2,气相中局部有少量CO2、CH4、N2。根据含矿石英脉中绢云母40Ar-39Ar定年,准确限定柯月矿床成矿热液活动的时限为21.3 Ma。矿床地质特征表明,柯月为中低温热液脉状锌多金属矿床,是后碰撞造山成矿作用的产物。     

塔里木东北缘坡十Ni矿化侵入体中橄榄石和铬尖晶石对成岩成矿及源区特征的约束

坡十Ni矿化超镁铁侵入体的矿化岩相主要为第二侵入期次的（斜长）单辉橄榄岩、（斜长）二辉橄榄岩、 纯橄岩等岩相。坡十超镁铁岩的橄榄石成分变化范围较大, 橄榄石的Fo值在76.8～89.6之间, Ni含量为767×10^-6～4 580×10^-6。铬尖晶石的Mg^#值和Cr^#值变化范围分别为19.4～41.9和49.8～64.8, 原生铬尖晶石中Cr₂O₃和Al₂O₃表现为负相关, 蚀变改造的铬尖晶石则表现为正相关。橄榄石成分剖面显示坡十母岩浆处于一个动态的岩浆系统中, 成分稳定的新鲜岩浆的补给、 持续向上的动力及浅部橄榄石快速分离结晶,造成了不同深度橄榄石成分的不同变化。坡十侵入体母岩浆估算结果为MgO=14.49％, FeO=10.01％,模拟结果显示橄榄石中Ni含量的变化主要受橄榄石结晶分异和硫化物不混溶作用共同控制,其中橄榄石与硫化物熔体发生明显的Fe-Ni交换反应。坡十母岩浆中橄榄石分离结晶造成的硫饱和,是坡十硫化物熔离的重要因素。橄榄石高Fo值、母岩浆高MgO、超镁铁岩中斜长石发育、矿物高结晶温度和铬尖晶石成分的弧岩浆特征显示,塔里木东北缘坡十侵入体是俯冲交代的岩石圈地幔部分熔融形成的母岩浆的产物,表现出低压高温的演化特征,其中源区熔融机制可能与塔里木二叠纪地幔柱提供的热源或该区大规模拆沉作用造成的软流圈上涌有关。     

河北平泉高于庄组凝块石的特征及其成因解析

微生物碳酸盐岩是微生物与环境相互作用的产物,它的发育对古环境与微生物群落有着重要的指示意义。河北省平泉县地区中元古代高于庄组四段发育有凝块石、纹理石、叠层石多种微生物碳酸盐岩。凝块石以其内部独特的凝块组构而显著区别于具纹层构造的叠层石等其它微生物岩类型。根据尺寸大小与排列特点可将高于庄组凝块石中的凝块组构分为3种类型：厘米级别、致密的中凝块,毫米级别、似层状的小凝块与微米级别、层状分布的微凝块。显微与超显微观察显示,所有的凝块组构均由内核与外壳两个结构单元组成。内核主要为丝状细菌、球状细菌等微生物或有机质残留,围绕内核的是呈放射状、扇状分布的方解石外壳,方解石颗粒之间可见有薄片状胞外聚合物（EPS）残留。凝块中微生物残余及EPS的大量发现,表明了凝块组构的形成与微生物密切相关。环境中海水碳酸盐初始饱和度的高低可能是形成不同类型的凝块组构的原因。     

吉木萨尔凹陷芦草沟组烃源岩评价及页岩油富集条件探讨

准噶尔盆地吉木萨尔凹陷芦草沟组为一套优质陆相烃源岩, 是我国当前页岩油气研究的热点地区之一.基于吉木萨尔凹陷18口井芦草沟组约为580 m岩心观察、薄片观察、地球化学测试等数据, 对芦草沟组烃源岩岩石类型、地球化学特征等方面开展了研究与评价, 结果表明: 1)芦草沟组烃源岩整体上为优质烃源岩, 且以Ⅰ-Ⅱ型有机质类型为主, 处于低熟至成熟阶段; 2)烃源岩主要划分为5种类型, 包括纯页岩、白云质页岩、纯泥岩, 白云质泥岩和粉砂质泥岩, 其有机质类型和丰度存在一定差异.综合研究得出, 吉木萨尔凹陷芦草沟组优质有效烃源岩的有机质丰度下限值为2.0%, 并认为TOC≥2.0%的烃源岩段也是该区页岩油发育的有利层段.     

交流电弧直读发射光谱法测定地球化学样品中银、硼、锡、钼、铅的方法研究

本文建立了交流电弧直读原子发射光谱法测定地球化学样品中银、硼、锡、钼、铅的分析方法。以K2S2O7、NaF、Al2O3、碳粉为缓冲剂,Ge为内标,优选了分析线对,曝光时间为25s,同时扣除分析线和内标线背景。选取国家一级地球化学标准物质（GBW07103、GBW07104、GBW07107、GBW07312、GBW07302a、GBW07304a、GBW07305a、GBW07307a、GBW07406、GBW07446、GBW07454、GBW07456）作为标准系列,以对数坐标二次曲线拟合标准曲线,并采取两次平行分析取平均值的计算方法。方法检出限为:Ag:0011×10-6、B:054×10-6、Sn:019×10-6、Mo:0034×10-6、Pb:066×10-6,精密度为:Ag:401%～833%、B:377%～786%、Sn:294%～817%、Mo:303%～1094%、Pb:201%～1111%。经岩石、水系沉积物、土壤国家一级标准物质验证,测定值与认定值符合。本方法操作简便、工作效率高,是一种新的测定地球化学样品中银、硼、锡、钼、铅的分析方法,可推广应用于大批量地球化学样品的分析测试。     

A two-surface plasticity model for stiff clay

This paper presents a constitutive model for describing some important features of the behavior of natural stiff clay evidenced experimentally such as the limited elastic zone, the presence of strain hardening and softening, and the smooth transition from elastic behavior to a plastic one. The model, namely ACC-2, is an adapted Modified Cam Clay model with two yield surfaces: similarly to bounding surface plasticity theory, an additional yield surface—namely Inner yield surface—was adopted to account for the plastic behavior inside the conventional yield surface. A progressive plastic hardening mechanism was introduced with a combined volumetric-deviatoric hardening law associated with the Inner yield surface, enabling the plastic modulus to vary smoothly during loading paths. The main feature of the proposed model is that its constitutive equations can be simply formulated based on the consistency condition for the Inner yield surface, so that it can be efficiently implemented in a finite element code using a stress integration scheme similar to that of the Modified Cam Clay model. Furthermore, it is proved to be an appropriate model for natural stiff clay: the simulations of a set of tests along different mechanical loading paths on natural Boom Clay show good agreement with the experimental results.     

Location of <Emphasis Type="Italic">Vibrio anguillarum</Emphasis> resistance-associated trait loci in half-smooth tongue sole <Emphasis Type="Italic">Cynoglossus semilaevis</Emphasis> at its microsatellite linkage map

A cultured female half-smooth tongue sole (Cynoglossus semilaevis) was crossed with a wild male, yielding the first filial generation of pseudo-testcrossing from which 200 fish were randomly selected to locate the Vibrio anguillarum resistance trait in half-smooth tongue sole at its microsatellite linkage map. In total, 129 microsatellites were arrayed into 18 linkage groups, ≥4 each. The map reconstructed was 852.85 cM in length with an average spacing of 7.68 cM, covering 72.07% of that expected (1 183.35 cM). The V. anguillarum resistance trait was a composite rather than a unit trait, which was tentatively partitioned into Survival time in Hours After V. anguillarum Infection (SHAVI) and Immunity of V. Anguillarum Infection (IVAI). Above a logarithm of the odds (LOD) threshold of 2.5, 18 loci relative to SHAVI and 3 relative to IVAI were identified. The 3 loci relative to IVAI explained 18.78%, 5.87% and 6.50% of the total phenotypic variation in immunity. The microsatellites bounding the 3 quantitative trait loci (QTLs) of IVAI may in future aid to the selection of V. anguillarum-immune half-smooth tongue sole varieties, and facilitate cloning the gene(s) controlling such immunity.