Mean Flow and Turbulence Characteristics in an Urban Roughness Sublayer

In this study, a detailed model of an urban landscape has been re-constructed inthe wind tunnel and the flow structure inside and above the urban canopy has beeninvestigated. Vertical profiles of all three velocity components have been measuredwith a Laser-Doppler velocimeter, and an extensive analysis of the measured meanflow and turbulence profiles carried out. With respect to the flow structure inside thecanopy, two types of velocity profiles can be distinguished. Within street canyons,the mean wind velocities are almost zero or negative below roof level, while closeto intersections or open squares, significantly higher mean velocities are observed.In the latter case, the turbulent velocities inside the canopy also tend to be higherthan at street-canyon locations. For both types, turbulence kinetic energy and shearstress profiles show pronounced maxima in the flow region immediately above rooflevel.Based on the experimental data, a shear-stress parameterization is proposed, inwhich the velocity scale, u_s, and length scale, z_s, are based on the level and magnitude of the shear stress peak value. In order to account for a flow region inside the canopy with negligible momentum transport, a shear stress displacement height, d_s, is introduced. The proposed scaling and parameterization perform well for the measured profiles and shear-stress data published in the literature.The length scales derived from the shear-stress parameterization also allowdetermination of appropriate scales for the mean wind profile. The roughnesslength, z₀, and displacement height, d₀, can both be described as fractions of the distance, z_s - d_s, between the level of the shear-stress peak and the shear-stress displacement height. This result can be interpreted in such a way that the flow only feels the zone of depth z_s - d_s as the roughness layer. With respect to the lower part of the canopy (z < d_s) the flow behaves as a skimming flow. Correlations between the length scales z_s and d_s and morphometric parameters are discussed.The mean wind profiles above the urban structure follow a logarithmic windlaw. A combination of morphometric estimation methods for d₀ and z₀ with wind velocity measurements at a reference height, which allow calculation of the shear-stress velocity, u_*, appears to be the most reliable and easiest procedure to determine mean wind profile parameters. Inside the roughnesssublayer, a local scaling approach results in good agreement between measuredand predicted mean wind profiles.     

Comparison of production and degradation of organic matter at a littoral site of the prealpine Lake Constance

Biotic structures and processes of the comparatively large and deep Lake Constance are dominated by pelagic water bodies. Therefore, much more attention has thus far been paid to the carbon cycle of pelagic habitats as compared to littoral areas. Nevertheless, there is also an ongoing debate on the importance of littoral areas for the carbon cycle in this lake. Although actually existing data are certainly insufficient for a realistic carbon budget, investigations made during the past decade provide at least a rough basis for a first evaluation. Accordingly, littoral areas appear to contribute overproportionally (related to surface) both to production as well as to degradation of organic carbon in the lake. However, the relative effect seems to be more pronounced for heterotrophic activities, mostly due to intense degradation processes in littoral sediments. Related to volume, littoral water bodies exhibited similar or slightly higher microbial activities as compared to epilimnetic pelagic water bodies, while microbial abundances and activities observed for littoral sediments exceeded the corresponding overlying water layers by one to three orders of magnitude. As was confirmed by in situ measurements microbial oxygen consumption frequently exceeded photosynthetic oxygen production in the investigated littoral sites. Moreover, significant qualitative differences between water and sediment were found for the degradation potentials of xenobiotics as was exemplified for phenol and nitrilo-triacetic acid (NTA). Overall, a buffer function at the landwater interface may be ascribed to littoral areas due to which the large pelagic water bodies of the lake may become additionally protected against loads of undesired organic substances due to high littoral degradation capacities.     

Effect of siderophores on the light-induced dissolution of colloidal iron(III) (hydr)oxides

Siderophores play an important role in biological iron acquisition in iron-limited aquatic systems. While it is widely accepted that the solubilization of iron-bearing mineral phases is a key function of siderophores, the mechanism of siderophore-promoted mineral dissolution in aquatic systems is largely unknown. In this study, we investigated the effect of siderophores (desferrioxamine B (DFOB) and aerobactin) on light-induced dissolution of goethite and lepidocrocite in the presence or absence of oxalate in aerated and deaerated suspensions at pH 6. For the irradiated two-ligand system (oxalate/siderophore), the experimental results suggest that oxalate acts as the electron donor for the formation of surface Fe(II), and the siderophore acts as an efficient shuttle for the transfer of surface Fe(II) into solution. Furthermore, even in the absence of an electron donor such as oxalate, both DFOB and aerobactin accelerated the light-induced dissolution of lepidocrocite as compared to the thermal dissolution. Experiments with dissolved Fe(III)–DFOB and Fe(III)–aerobactin complexes suggest that this enhancing effect is not due to photolysis of corresponding surface complexes but to efficient transfer of reduced surface Fe(II) into solution, where surface Fe(II) may be formed, e.g., through photolysis of surface Fe(III)–hydroxo groups. Based on this study, we conclude that the interplay of light and siderophores may play a key role in the dissolution of colloidal iron(III) (hydr)oxides in marine systems, particularly in the presence of efficient electron donors.     

Statistical power of detecting trends in total suspended sediment loads to the Great Barrier Reef

The export of pollutant loads from coastal catchments is of primary interest to natural resource management. For example, Reef Plan, a joint initiative by the Australian Government and the Queensland Government, has indicated that a 20% reduction in sediment is required by 2020. There is an obvious need to consider our ability to detect any trend if we are to set realistic targets or to reliably identify changes to catchment loads. We investigate the number of years of monitoring aquatic pollutant loads necessary to detect trends. Instead of modelling the trend in the annual loads directly, given their strong relationship to flow, we consider trends through the reduction in concentration for a given flow. Our simulations show very low power (<40%) of detecting changes of 20% over time periods of several decades, indicating that the chances of detecting trends of reasonable magnitudes over these time frames are very small.     

Improvement of HVSR technique by wavelet analysis

In this work we investigate the application of the wavelet analysis to improve the well-known horizontal to vertical spectral ratio (HVSR) technique for site effect estimation. Wavelet analysis has been widely used in the last decade for its capacity to localise the signal in both the time and frequency domains. The wavelet packet transform and the evaluation of a cost function for every node permit one to remove from the signal the least important components and lead to significant improvements in the identification of the fundamental frequency. In this paper a new algorithm is presented based on wavelet analysis, that allows, in some cases, to improve the identification of the peak in the QTS ratio. A number of examples of application are also presented.     

The 1895 Ljubljana earthquake: can the intensity data points discriminate which one of the nearby faults was the causative one?

The earthquake (Mw 6 from the SHEEC defined by the MDPs) that occurred in the central part of Slovenia on 14 April, 1895, affected a broad region, causing deaths, injuries, and destruction. This event was much studied but not fully explained; in particular, its causative source model is still debated. The aim of this work is to contribute to the identification of the seismogenic source of this destructive event, calculating peak ground velocity values through the use of different ground motion prediction equations (GMPEs) and computing a series of ground motion scenarios based on the result of an inversion work proposed by Juki? in 2009 and on various fault models in the surroundings of Ljubljana: Vi?, ?elimlje, Borovnica, Vodice, Ortnek, Mi?jedolski, and Dobrepolje faults. The synthetic seismograms, at the basis of our computations, are calculated using the multi-modal summation technique and a kinematic approach for extended sources, with a maximum peak ground velocity value of 1 Hz. The qualitative and quantitative comparison of these simulations with the macroseismic intensity database allows us to discriminate between various sources and configurations. The quantitative validation of the seismic source is done using ad hoc ground motion to intensity conversion equations (GMICEs), expressly calculated for this study. This study allows us to identify the most probable causative source model of this event, contributing to the improvement of the seismotectonic knowledge of this region. The candidate fault that has the lowest values of average differences between observed and calculated intensities and chi-squared is a strike slip fault with a toward-north rupture as the Ortnek fault.