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1.
Air flow was observed above and within canopies of a number of kinds of soybeans. The Clark cultivar and two isolines of the Harosoy cultivar were studied in 1979 and 1980, respectively. Wind speed above the canopy was measured with cup anemometers. Heated thermistor anemometers were used to measure air flow within the canopy. Above-canopy air flow was characterized in terms of the zero-plane displacement (d), roughness parameter (z o) and drag coefficient (C d). d and z o were dependent on canopy height but were independent of friction velocity in the range 0.55 to 0.75 m s?1 · C d for the various canopies ranged from 0.027 to 0.035. Greater C d values were measured over an erectophile canopy than over a planophile canopy. C d was not measurably affected by differences in leaf pubescence. Within-canopy wind profiles were measured at two locations: within and between rows. The wind profile was characterized by a region of great wind shear in the upper canopy and by a region of relatively weak wind shear in the middle canopy. Considerable spatial variability in wind speed was evident, however. This result has significant implications for canopy flow modeling efforts aimed at evaluating transport in the canopy. In the lower canopy, wind speed within a row increased with depth whereas wind speed between two rows decreased with depth. The wind speeds at the two locations tended to converge to a common value at a height near 0.10 m. The attenuation of within-canopy air flow was stronger in canopies with greater foliage density. Canopy flow attenuation seemed to decrease with increasing wind speed, suggesting that high winds distorted the shape of the canopy in such a manner that the penetration of wind into the canopy increased.  相似文献   

2.
Mean wind velocity profiles were measured by means of radio-windsondes over the Landes region in southwestern France, which consists primarily of pine forests with scattered villages and clearings with various crops. Analysis of neutral profiles indicated the existence of a logarithmic layer between approximately zd 0 = 67(±18)z 0 and 128(+-32)z 0 (z is the height above the ground, z 0 the surface roughness and d 0 the displacement height). The upper limit can also be given as zd 0 = 0.33 (±0.18)h, where h is the height of the bottom of the inversion. The profiles showed that the surface roughness of this terrain is around 1.2 m and the displacement height 6.0 m. Shear stresses derived from the profiles were in good agreement with those obtained just above the forest canopy at a nearby location with the eddy correlation method by a team from the Institute of Hydrology (Wallingford, England).  相似文献   

3.
A method for the determination of the zero-plane displacement, d, and roughness length, z 0, for tall vegetation is described. A new relationship between d and z 0 is developed by imposing the condition of mass conservation on the logarithmic wind profile. Further, d and z 0 can be evaluated directly if independent measurements of friction velocity are available in addition to wind profile measurements. The proposed method takes into account the existence of a transition layer immediately above the vegetation where the logarithmic wind profile law is not valid. Only one level of wind speed measurements is necessary within the inertial sub-layer.The method is applied to wind profile and eddy correlation measurements taken in and above an 18.5 m pine forest to yield d = 12.7 m and z 0 = 1.28 m. The choice of height for the upper level of measurement and problems with measuring canopy flow are discussed.Work carried out while on leave at the Institute of Hydrology.  相似文献   

4.
This paper discusses the importance of the aerodynamic characteristics of forest and other similar canopies to modelling of boundary-layer flow and to estimating the diffusivity coefficients of turbulence transfer mechanisms over such canopies.The hypothesis of Marunich (1971) reported by Tajchman (1981) that the zero-plane displacement, d, equals the upward displacement of the flow trajectory, is critically examined. It is concluded that Marunich's hypothesis is conceptually incorrect and that calculations of d based on Marunich's hypothesis are inherently in error.This paper presents a method based on the mass conservation principle and uses wind profiles in and above a forest canopy as the sole input for determining d, z 0 and u *.Sensitivities of calculated results to measurements errors of wind profile data are evaluated. It is found that an error of less than 1% in wind in the logarithmic regime above the canopy can introduce up to 100% errors in calculated values of d, z 0 and u *. It is also found that the high sensitivity to wind data accuracy, characteristic of the present method, can be used as a guide for the selection of high quality canopy wind data.  相似文献   

5.
A new nonlinear analytical model for canopy flow over gentle hills is presented. This model is established based on the assumption that three major forces (pressure gradient, Reynolds stress gradient, and nonlinear canopy drag) within canopy are in balance for gentle hills under neutral conditions. The momentum governing equation is closed by the velocity-squared law. This new model has many advantages over the model developed by Finnigan and Belcher (Quart J Roy Meteorol Soc 130: 1–29 2004, hereafter referred to as FB04) in predicting canopy wind velocity profiles in forested hills in that: (1) predictions from the new model are more realistic because surface drag effects can be taken into account by boundary conditions, while surface drag effects cannot be accounted for in the algebraic equation used in the lower canopy layer in the FB04 model; (2) the mixing length theory is not necessarily used because it leads to a theoretical inconsistency that a constant mixing length assumption leads to a nonconstant mixing length prediction as in the FB04 model; and (3) the effects of height-dependent leaf area density (a(z)) and drag coefficient (C d ) on wind velocity can be predicted, while both a(z) and C d must be treated as constants in FB04 model. The nonlinear algebraic equation for momentum transfer in the lower part of canopy used in FB04 model is height independent, actually serving as a bottom boundary condition for the linear differential momentum equation in the upper canopy layer. The predicting ability of the FB04 model is largely restricted by using the height-independent algebraic equation in the bottom canopy layer. This study has demonstrated the success of using the velocity-squared law as a closure scheme for momentum transfer in forested hills in comparison with the mixing length theory used in FB04 model thus enhancing the predicting ability of canopy flows, keeping the theory consistent and simple, and shining a new light into land-surface parameterization schemes in numerical weather and climate models.  相似文献   

6.
How the spatial perturbations of the first and second moments of the velocity and pressure fields differ for flow over a train of gentle hills covered by either sparse or dense vegetation is explored using large-eddy simulation (LES). Two simulations are investigated where the canopy is composed of uniformly arrayed rods each with a height that is comparable to the hill height. In the first simulation, the rod density is chosen so that much of the momentum is absorbed within the canopy volume yet the canopy is not dense enough to induce separation on the lee side of the hill. In the second simulation, the rod density is large enough to induce recirculation inside the canopy on the lee side of the hill. For this separating flow case, zones of intense shear stress originating near the canopy-atmosphere interface persist all the way up to the middle layer, ‘contaminating’ much of the middle and outer layers with shear stress gradients. The implications of these persistent shear-stress gradients on rapid distortion theory and phase relationships between higher order velocity statistics and hill-induced mean velocity perturbations (Δu) are discussed. Within the inner layer, these intense shear zones improve predictions of the spatial perturbation by K-theory, especially for the phase relationships between the shear stress (~ ?Δu/?z) and the velocity variances, where z is the height. For the upper canopy layers, wake production increases with increasing leaf area density resulting in a vertical velocity variance more in phase with Δu than with ?Δu/?z. However, background turbulence and inactive eddies may have dampened this effect for the longitudinal velocity variance. The increase in leaf area density does not significantly affect the phase relationship between mean surface pressure and topography for the two simulations, though the LES results here confirm earlier findings that the minimum mean pressure shifts downstream from the hill crest. The increase in leaf area density and associated flow separation simply stretches this difference further downstream. This shift increases the pressure drag, the dominant term in the overall drag on the hill surface, by some 15%. With regards to the normalized pressure variance, increasing leaf area density increases ${\sigma_p/u_{*}^{2}}$ near the canopy top, where u * is the longitudinally averaged friction velocity at the canopy top and σ p is the standard deviation of the pressure fluctuations. This increase is shown to be consistent with a primitive scaling argument on the leading term describing the mean-flow turbulent interaction. This scaling argument also predicts the spatial variations in σ p above the canopy reasonably well for both simulations, but not inside the canopy.  相似文献   

7.
Aerodynamic Scaling for Estimating the Mean Height of Dense Canopies   总被引:1,自引:1,他引:0  
We used an aerodynamic method to objectively determine a representative canopy height, using standard meteorological measurements. The canopy height may change if the tree height is used to represent the actual canopy, but little work to date has focused on creating a standard for determining the representative canopy height. Here we propose the ‘aerodynamic canopy height’ h a as the most effective means of resolving the representative canopy height for all forests. We determined h a by simple linear regression between zero-plane displacement d and roughness length z 0, without the need for stand inventory data. The applicability of h a was confirmed in five different forests, including a forest with a complex canopy structure. Comparison with stand inventory data showed that h a was almost equivalent to the representative height of trees composing the crown surface if the forest had a simple structure, or to the representative height of taller trees composing the upper canopy in forests with a complex canopy structure. The linear relationship between d and z 0 was explained by assuming that the logarithmic wind profile above the canopy and the exponential wind profile within the canopy were continuous and smooth at canopy height. This was supported by observations, which showed that h a was essentially the same as the height defined by the inflection point of the vertical profile of wind speed. The applicability of h a was also verified using data from several previous studies.  相似文献   

8.
Flux parameters, zero-plane displancement height and roughness length of a forest canopy are determined taking into consideration a transition layer and atmospheric diabatic influences. The present study, unlike previous studies by DeBruin and Moore (1985) and Lo (1990) that accounted for the velocity profile alone, make use of information from both wind and temperature profiles in formulating the governing equations. However, only the top level measurement is assumed to be within the logarithmic regime. In addition to the mass conservation principle (e.g., Lo, 1990; DeBruin and Moore, 1985), an analytic relationship between the Monin-Obukhov length and the bulk Richardson number is employed as the closure equation for the governing system.The present method is applied to profile measurements taken at Camp Borden (den Hartog and Neumann, 1984) in and above a forest canopy with mean crown height of about 18.5 m. Profile data under neutral or near-neutral conditions yieldedd=12.69 m andz 0=0.97 m, which are realistic values. In general,z 0 increases slightly with increasing wind yet remains relatively constant with respect to small variation of stabilities. On the other hand, increases of wind speed reduced values of displacement height,d, by as much as 50%. The influence, if any, of stability ond, however, is not clear from the results of the present study. The validity of using profile data of limited height is also carefully examined. At least for neutral or near-neutral stabilities, the present method can yield realistic results even though the profile heights are substantially below the transition layer height suggested by Garratt (1978).  相似文献   

9.
Analysis of profiles of meteorological measurements from a 160 m high mast at the National Test Site for wind turbines at Høvsøre (Denmark) and at a 250 m high TV tower at Hamburg (Germany) shows that the wind profile based on surface-layer theory and Monin-Obukhov scaling is valid up to a height of 50–80 m. At higher levels deviations from the measurements progressively occur. For applied use an extension to the wind profile in the surface layer is formulated for the entire boundary layer, with emphasis on the lowest 200–300 m and considering only wind speeds above 3 m s?1 at 10 m height. The friction velocity is taken to decrease linearly through the boundary layer. The wind profile length scale is composed of three component length scales. In the surface layer the first length scale is taken to increase linearly with height with a stability correction following Monin-Obukhov similarity. Above the surface layer the second length scale (L MBL ) becomes independent of height but not of stability, and at the top of the boundary layer the third length scale is assumed to be negligible. A simple model for the combined length scale that controls the wind profile and its stability dependence is formulated by inverse summation. Based on these assumptions the wind profile for the entire boundary layer is derived. A parameterization of L MBL is formulated using the geostrophic drag law, which relates friction velocity and geostrophic wind. The empirical parameterization of the resistance law functions A and B in the geostrophic drag law is uncertain, making it impractical. Therefore an expression for the length scale, L MBL , for applied use is suggested, based on measurements from the two sites.  相似文献   

10.
The mean flow profile within and above a tall canopy is well known to violate the standard boundary-layer flux–gradient relationships. Here we present a theory for the flow profile that is comprised of a canopy model coupled to a modified surface-layer model. The coupling between the two components and the modifications to the surface-layer profiles are formulated through the mixing layer analogy for the flow at a canopy top. This analogy provides an additional length scale—the vorticity thickness—upon which the flow just above the canopy, within the so-called roughness sublayer, depends. A natural form for the vertical profiles within the roughness sublayer follows that overcomes problems with many earlier forms in the literature. Predictions of the mean flow profiles are shown to match observations over a range of canopy types and stabilities. The unified theory predicts that key parameters, such as the displacement height and roughness length, have a significant dependence on the boundary-layer stability. Assuming one of these parameters a priori leads to the incorrect variation with stability of the others and incorrect predictions of the mean wind speed profile. The roughness sublayer has a greater impact on the mean wind speed in stable than unstable conditions. The presence of a roughness sublayer also allows the surface to exert a greater drag on the boundary layer for an equivalent value of the near-surface wind speed than would otherwise occur. This characteristic would alter predictions of the evolution of the boundary layer and surface states if included within numerical weather prediction models.  相似文献   

11.
Wind speed was measured at a height of 1 cm above the ground and at several other heights in and above a canopy of tall fescue grass (Festuca arundinacea) using single hot-wire and triple hot-film anemometers. The plant area density in the canopy was concentrated close to the ground, with 75% of the plant area standing belowz=15 cm, wherez is height above the ground. The frequency distributions of horizontal wind speeds,s, were sharply skewed towards positive values at all measurement heights, but were most highly skewed near the ground where the coefficient of skewness ranged from 1.6 to 2.9. Above mid-canopy height, the frequency distribution ofs was described reasonably well by a Gumbel extreme value distribution. Average wind speed,S, decreased exponentially with depth into the canopy with an exponential scale length of abouth/2.8, whereh is the height of the canopy. Atz=1 cm, the value ofS was about 11% of the surface-layeru *. The standard deviation of the fluctuations of the vertical and horizontal components of the wind speed also decreased exponentially with depth inside the canopy with a scale length of abouth/2.5.Inside the canopy, the Eulerian integral time scales for the vertical ( w ) and horizontal ( u ) components of wind speed were about 0.1 s and 1.0 s, respectively, and were approximately constant with height. Above the canopy, these time scales increased sharply and, atz=2.25h, w and u were approximately 1.0 and 3.0s, respectively. Turbulence length scales in the vertical and downwind directions, u and w ·U, respectively, were approximately 1 cm for heights between 1 to 10 cm above the ground inside the canopy, while atz=2.25h, they were about 55 cm and 277 cm. Relatively quiescent periods (lulls) in the air close to the ground were interrupted frequently by gusts. The frequency of occurrence of gusts appears to be correlated with the value of the local shear near the top of the canopy.  相似文献   

12.
Using a mountain meadow as a case study it is the objective of the present paper todevelop a simple parameterisation for the within-canopy variation of the phytoelementdrag (Cd) and sheltering (Pm) coefficients required for Massman's model of momentum transfer by vegetation. A constant ratio between Cd and Pm is found to overestimate wind speed in the upper canopy and underestimate it in the lower canopy.Two simple parameterisations of Cd/Pm as a function of the plant area density and the cumulative plant area index are developed, using values optimised by least-squares regression between measured and predicted within-canopy wind speeds. A validation with independently measured data indicates that both parameterisations work reliably for simulating wind speed in the investigated meadow. Model predictions of the normalised zero-plane displacement height and the momentum roughness length fall only partly within the range of values given in literature, which may be explained by the accumulation of plantmatter close to the soil surface specific for the investigated canopies. The seasonal course of the normalised zero-plane displacement height and the momentum roughness length are discussed in terms of the seasonal variation of the amount and density of plant matter.  相似文献   

13.
Prediction of windthrow risk to individual or groups of retained trees in harvested stands requires an improved understanding of canopy airflow dynamics. Large-eddy simulations were used to simulate wind-tunnel experiments in two and three dimensions to compare with observations for model validation and to address parameter space considerations for the design of subsequent retention pattern experiments. The three-dimensional simulations were similar to the observed wind-tunnel data for the statistical profiles for but there were greater differences in skewness and kurtosis. These results were obtained using a common leaf-area drag formulation without either skin friction or speed dependent drag that enables scaling with U 0 (ambient wind speed) and h (height of the canopy). This scaling results in a single non-dimensional parameter h/h c where h c (x, y, z) is the momentum range resulting from the canopy drag. The validity of the model scaling was tested using two-dimensional simulations. The irrotational component of the flow (potential flow) was found to be important when defining vertical domain limitations and has significant implications for time dependent flow (i.e. turbulent conditions) when considering retention pattern design. The sudden onset of drag associated with the isolated stand presents some unexpected challenges. The horizontal scales of the shearing instabilities were simulated in two dimensions and found to range between 2h for early times to 7h for later times. The early-time horizontal scales are in the range of logical retention pattern scales and as such need to be taken into account as part of the parameter space, i.e. a range of retention pattern lengths need consideration.  相似文献   

14.
Wind speed profiles above a forest canopy relate to scalar exchange between the forest canopy and the atmosphere. Many studies have reported that vertical wind speed profiles above a relatively flat forest can be classified by a stability index developed assuming wind flow above a flat plane. However, can such a stability index be used to classify vertical wind speed profiles observed above a sloping forest at nighttime, where drainage flow often occurs? This paper examines the use of the bulk Richardson number to classify wind speed profiles observed above a sloping forest at nighttime. Wind speed profiles above a sloping forest were classified by the bulk Richardson number Ri B . Use of Ri B distinguished between drainage flow, shear flow, and transitional flow from drainage flow to shear flow. These results suggest that Ri B is useful to interpret nighttime CO2 and energy fluxes above a sloping forest. Through clear observational evidence, we also show that the reference height should be high enough to avoid drainage-flow effects when calculating Ri B .  相似文献   

15.
Wind and temperature profiles and surface radiation temperature were measured over barley during two observation periods in Estonia. The calculated displacement height (d) could be taken as 3/4 and 2/3 of the canopy height (h) for a dense and a moderate canopy respectively. The roughness length for wind speed was best approximated with the relation z0u = 0.3(h - d). The excess resistance to heat exchange kB-1 was the most doubtful parameter, but it was concluded that kB-1 = 2 is a good estimate for the time being.  相似文献   

16.
Forced convection in a quasi-steady atmospheric boundary layer is investigated based on a large-eddy simulation (LES) model. The performed simulations show that in the upper portion of the mixed layer the dimensionless (in terms of mixed layer scales) vertical gradients of temperature, humidity, and wind velocity depend on the dimensionless height z/z i and the Reech number Rn. The peak values of variances and covariances at the top of the mixed layer, scaled in terms of the interfacial scales, are functions of the interfacial Richardson number Ri. As a result expressions for the entrainment rates, in the case when the interfacial layer has a finite depth, and a condition for the presence of moistening or drying regimes in the mixed layer, are derived. Profiles of dimensionless scalar moments in the mixed layer are proposed to be expressed in terms of two empirical similarity functions F m and F i , dependent on dimensionless height z/z i , and the interfacial Richardson number Ri. The obtained similarity expressions adequately approximate the LES profiles of scalar statistics, and properly represent the impact of stability, shear, and entrainment. They are also consistent with the parameterization proposed for free convection in the first part of this paper.  相似文献   

17.
In the first part of this study, results of a computational fluid dynamics simulation over an array of cubes have been validated against a set of wind-tunnel measurements. In Part II, such numerical results are used to investigate spatially-averaged properties of the flow and passive tracer dispersion that are of interest for high resolution urban mesoscale modelling (e.g. non resolved obstacle approaches). The results show that vertical profiles of mean horizontal wind are linear within the canopy and logarithmic above. The drag coefficient, derived from the numerical results using the classical formula for the drag force, is height dependent (it decreases with height). However, a modification of the formula is proposed (accounting for subgrid velocity scales) that makes the drag coefficient constant with height. Results also show that the dispersive fluxes are similar in magnitude to the turbulent fluxes, and that they play a very important role within the canopy. Vertical profiles of turbulent length scales (to be used in kl closure schemes, where k is the turbulent kinetic energy and l a turbulent length scale) are also derived. Finally the distribution of the values around the mean over the reference volumes are analysed for wind and tracer concentrations.  相似文献   

18.
This study investigates the organised motion near the canopy-atmosphere interface of a moderately dense spruce forest in heterogeneous, complex terrain. Wind direction is used to assess differences in topography and surface properties. Observations were obtained at several heights above and within the canopy using sonic anemometers and fast-response gas analysers over the course of several weeks. Analysed variables include the three-dimensional wind vector, the sonic temperature, and the concentration of carbon dioxide. Wavelet analysis was used to extract the organised motion from time series and to derive its temporal scales. Spectral Fourier analysis was deployed to compute power spectra and phase spectra. Profiles of temporal scales of ramp-like coherent structures in the vertical and longitudinal wind components showed a reversed variation with height and were of similar size within the canopy. Temporal scales of scalar fields were comparable to those of the longitudinal wind component suggesting that the lateral scalar transport dominates. The existence of a – 1 power law in the longitudinal power spectra was confirmed for a few cases only, with a majority showing a clear 5/3 decay. The variation of effective scales of organised motion in the longitudinal velocity and temperature were found to vary with atmospheric stability, suggesting that both Kelvin-Helmholtz instabilities and attached eddies dominate the flow with increasing convectional forcing. The canopy mixing-layer analogy was observed to be applicable for ramp-like coherent structures in the vertical wind component for selected wind directions only. Departures from the prediction of m = Λ w L s −1 = 8–10 (where Λ w is the streamwise spacing of coherent structures in the vertical wind w and L s is a canopy shear length scale) were caused by smaller shear length scales associated with large-scale changes in the terrain as well as the vertical structure of the canopy. The occurrence of linear gravity waves was related to a rise in local topography and can therefore be referred to as mountain-type gravity waves. Temporal scales of wave motion and ramp-like coherent structures were observed to be comparable.  相似文献   

19.
Based on the momentum flux–wind profile relationship of the Monin–Obukhov Similarity (MOS) theory, the observational data from the urban boundary layer field campaign in Nanjing are used to calculate the friction velocity ( $ {u_*} $ ) at the top of the urban canopy and the calculated results are evaluated. The urban surface roughness parameters (the roughness length z 0 and zero-plane displacement height z d) are estimated with the Ba method (Bottema’s morphological method). Two different regimes are employed for the calculations. In the homogeneous approach, z 0 and z d are averagely derived from the surface elements in the whole study area; while in the heterogeneous approach, z 0 and z d are locally derived from the surface elements in the corresponding upwind fetches (or source areas). The calculated friction velocities are compared to the measurement data. The results show that the calculated friction velocities from the heterogeneous approach are in better agreement with the observed values than those from the homogeneous approach are. This study implies that the local roughness parameters can properly represent the dynamical heterogeneity of urban surface, and its application can significantly improve the performance of parameterizations based on the MOS theory in the urban roughness sublayer.  相似文献   

20.
The Regional Atmospheric Modeling System (RAMS)-based Forest Large-Eddy Simulation (RAFLES), developed and evaluated here, is used to explore the effects of three-dimensional canopy heterogeneity, at the individual tree scale, on the statistical properties of turbulence most pertinent to mass and momentum transfer. In RAFLES, the canopy interacts with air by exerting a drag force, by restricting the open volume and apertures available for flow (i.e. finite porosity), and by acting as a heterogeneous source of heat and moisture. The first and second statistical moments of the velocity and flux profiles computed by RAFLES are compared with turbulent velocity and scalar flux measurements collected during spring and winter days. The observations were made at a meteorological tower situated within a southern hardwood canopy at the Duke Forest site, near Durham, North Carolina, U.S.A. Each of the days analyzed is characterized by distinct regimes of atmospheric stability and canopy foliage distribution conditions. RAFLES results agreed with the 30-min averaged flow statistics profiles measured at this single tower. Following this intercomparison, two case studies are numerically considered representing end-members of foliage and midday atmospheric stability conditions: one representing the winter season with strong winds above a sparse canopy and a slightly unstable boundary layer; the other representing the spring season with a dense canopy, calm conditions, and a strongly convective boundary layer. In each case, results from the control canopy, simulating the observed heterogeneous canopy structure at the Duke Forest hardwood stand, are compared with a test case that also includes heterogeneity commensurate in scale to tree-fall gaps. The effects of such tree-scale canopy heterogeneity on the flow are explored at three levels pertinent to biosphere-atmosphere exchange. The first level (zero-dimensional) considers the effects of such heterogeneity on the common representation of the canopy via length scales such as the zero-plane displacement, the aerodynamic roughness length, the surface-layer depth, and the eddy-penetration depth. The second level (one-dimensional) considers the normalized horizontally-averaged profiles of the first and second moments of the flow to assess how tree-scale heterogeneities disturb the entire planar-averaged profiles from their canonical (and well-studied planar-homogeneous) values inside the canopy and in the surface layer. The third level (three-dimensional) considers the effects of such tree-scale heterogeneities on the spatial variability of the ejection-sweep cycle and its propagation to momentum and mass fluxes. From these comparisons, it is shown that such microscale heterogeneity leads to increased spatial correlations between attributes of the ejection-sweep cycle and measures of canopy heterogeneity, resulting in correlated spatial heterogeneity in fluxes. This heterogeneity persisted up to four times the mean height of the canopy (h c ) for some variables. Interestingly, this estimate is in agreement with the working definition of the thickness of the canopy roughness sublayer (2h c –5h c ).  相似文献   

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