不同涂层的二氧化铅电极催化性能的比较

研究了热分解法和电沉积法制备二氧化铅电极的工艺,通过对苯酚的电解和生成羟基自由基的量,比较了两种方法制得的电极的催化性能,并比较了采用电沉积法制备电极时掺杂铋或镧对电极的催化性能的影响。实验结果表明,这4种电极都具有良好的电催化性能,并且明显降低了槽电压,且对苯酚的降解均符合一级反应动力学,电沉积法制得的电极的催化性能优于热分解法制得的电极,掺镧的电极优于无掺杂和掺铋的电极。     

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen…     

波包传播诊断的理论基础和计算方法

文中提出了一种新的利用实际观测资料研究波包传播的诊断方法 (WPD) ,并通过理想资料和实际资料的计算证明了该方法的可用性和广泛性     

博格达山晚石炭纪造山活动的变形地质记录

主要由钙碱性火山岩、火山碎屑岩组成的博格达古岛弧是天山缝合造山带的重要组成部分 ,是一个发育较成熟的山链 ,其演化经历了晚古生代的韧性剪切收缩 ;中生代伸展调整及新生代再造山过程。晚古生代的造山活动在博格达山有很好的地质记录 ,并以显著的韧性剪切变形带的形成和发育同造山的褶皱构造为特点。剪切变形带内同构造的石英脉中的锆石U PbSHRIMP测年结果与山链中花岗岩、辉长岩年龄颇为一致 (311～ 316Ma) ,这个年龄反映在结束洋盆散聚、碰撞焊接的晚华力西期造山过程中 ,博格达古岛弧内存在一次虽不甚强烈 ,但又较为明显的构造岩浆事件 ,其成因可能与引起石炭纪大规模裂陆式喷发的深部断裂构造重新活动有关。     

用TRMM资料研究江淮、华南降水的微波特性

热带测雨卫星TRMM (Tropical Rainfall Measuring Mission) 于1997年11月发射成功, 其首次携带了空载雷达, 有关资料已在网上对公众发布。利用热带测雨卫星上的微波成像仪TMI (TRMM Microw ave Imager) 资料以及其和测雨雷达TRMM/PR (Precipitation Radar) 资料联合反演的地面瞬时降水产品, 采用散射指数 (Is) 法从理论上探讨了我国江淮、华南降水尤其是暴雨的微波特性, 其中I_s表达式通过江淮、华南晴空TMI资料统计回归得到。以联合反演的地面瞬时降水产品为真值, 用面积相当法对14个降水个例求I_s降水阈值, 研究了阈值和降水面积以及85.5 GHz垂直通道最低亮温的关系, 并寻求了I_s和降水的相关特征。研究表明:I_s降水阈值随降水面积的增大或85.5 GHz垂直通道最低亮温的降低有增高的趋势; I_s与强对流性降水瞬时雨强对应很好, I_s≥60 K是一个好的暴雨指标。最后进行了初步的雨强反演试验研究, 由于TMI资料分辨率的提高以及时空配合较好的真值, 反演的地面瞬时降水与真值相关效果大大提高。     

Impacts of topography and land degradation on the sea breeze over eastern Spain

Summary A three-dimensional non-hydrostatic atmospheric model RAMS, version3b, is used to examine the impact of complex topography on the sea breeze under heterogeneous and degradation land use characteristics. In the study, it is shown that topography plays an important role in the sea-breeze circulation by aligning the sea breeze front to the coastline and locating the convergence zones close to the mountain range. When the sea breeze is coupled with the upslope wind, the sea-breeze circulation is strengthened by the topography.Sensitivity analyses are carried out to determine the influence of vegetation and soil moisture, i.e., land surface modifications, to this thermally driven flow. Land degradation results in an enhanced sea-breeze circulation which is characterized by a stronger onshore flow, a stronger return current, a larger updraft velocity associated with the sea-breeze front and further inland penetration. Other important features are a deeper sea-breeze depth, a larger downdraft velocity behind the sea-breeze front, and a longer offshore extent. The results also show how land changes modify the sea breeze temporal evolution resulting in an earlier onset and later end. The study stresses the convenience of using three-dimensional models with detailed land surface information to model the sea breeze in complex terrain where land use is rapidly modified.Received February 25, 2002; accepted October 7, 2002 Published online April 10, 2003     

近地层相似理论适用的分析研究

利用实测的脉动场与平均场同步梯度观测资料研究近地层相似理论的适用性。结果表明：理论的核心——近地层为常数通量层的近似假设在有植被陆面上是基本不成立的。Ｗ′Ｔ′随高度明显减小；摩擦速度ｕ＊在３０ｍ高度范围内可增大２４％左右。用相似理论关系式（或称作廓线通量法）得到的通量值只代表某高度层以下的平均值     

胶东招掖郭家岭型花岗岩锆石年代学及其Pb同位素特征

采用SHRIMP测年技术，精确地测定了郭家岭型花岗岩年龄为130-126Ma，主要金矿化在126-120Ma之间，郭家岭型花岗岩与金矿化关系最密切。岩体Pb同位素组成反映了本区所处构造背景。     

辽东湾北部浅海区泥沙输送及其沉积特征

根据实测资料，本文定量分析了辽东湾北部泥沙输送及其分布，并对辽河三角洲沉积区划作了初步讨论。研究表明本区泥沙以纵向搬运为特征。双台子河以西来沙和辽河西水道入海泥沙是区域东部拦门沙体和浅滩发育的主导因素。汛季大潮期，泥沙自西向东运移落淤在河口及毗邻浅水域；小潮期，泥沙除向东扩散外，大部泥沙向海方搬运。调查区可划分六个现代沉积作用区，即潮坪沉积区、辽河水下三角洲细粒沉积区、河口沙洲沉积区、波浪潮流冲蚀沉积区、河口冲积沉积区以及潮汐水道沉积区。     

Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.