2008年奥运会期间北京地区大气O3浓度模拟分析

利用空气质量模式系统RAMS-CMAQ模拟分析了2008年8月北京及周边地区近地面O3浓度的时空变化。分析结果表明,模式系统可以较好地模拟污染物以及气象要素的变化特征和区域分布情况;奥运会期间的污染控制对O3浓度的降低有明显的作用,但是在一些有利的气象条件下,O3易达到较高浓度:8月2日、24日14时(北京时间)左右O3浓度都在0.22mg.m-3以上,其中2日北京地区处于辐合的弱风场中,风速为1.5～2.5m.s-1,24日则是处于自南向北的有输送作用的风场中,风速为3.5～6.5m.s-1;污染控制对北京周边地区的效果要好于北京市区。     

苹果套袋栽培中的气象条件与管理措施

苹果套袋初期,高温易发生果实日灼现象,果实膨大期适温为20-27℃,成熟采收期为13-20℃;花芽分化期土壤保持最大含水量的60%为宜,果实膨大期需水量350 mm左右,成熟期连阴雨天气影响果实着色和采收;日照时数多,光照强,光质好,利于花芽分化、果实糖分积累和着色.摘袋时间因品质不同而异,应在阴天或多云天摘袋;若晴天摘袋,宜在10-14时进行.     

Experimental evidence for eukaryotic fossil preservation: Onion skin cells in silica solution

Research on the origin of eukaryotes often focuses on the exceptional preservation found in silicified Precambrian fossils. Nuclei like subcellular structures in well-preserved fossil becomes confusion and arguments, which focus on whether the partial degradation of prokaryotes produces artifacts that resemble a ‘nucleus’, or fossilized nuclei of eukaryotes. In order to understand the mechanisms of silicification and identify the fossilized subcellular and microstructures in rocks, a series of laboratory controlled experiments were performed for simulating the silicification process. The effects of different silica solutions in eukaryote fossilization were studied in our experiments by exposing onion skin cells (epidermis) to silica solutions. Onion skin provides a good experimental model because of its well characterized cellular structures which are easily observed. The designed experiments revealed that the possibility of onion cell preserved as a “fossil” with nuclear structures, the first week fossilization, or mineralization as rapid as 1 week is important. And the experiment also revealed interactions between silica and the onion skin cell wall surface functional groups were weak. The preservation of nuclei in the onion skin model was due to precipitation in highly supersaturated silica solutions rather than simply the high silica concentration. When the silica gel precipitates slowly at low supersaturation states, the nuclei were not well preserved, but the rapid precipitation at high supersaturated silica conditions preserved nuclear structures. A better understanding of the processes involved in onion skin fossilization will further contribute to issues concerning the silicification of other eukaryotic materials.     

海藻中类胡萝卜素的提取及含量测定

许多研究已经表明，类胡萝卜素是分布最广泛、最重要的一类光辅助合成色素。类胡萝卜素具有多种生物学功能：作为化学保护剂可抵抗由植物自身叶绿素的光敏氧化作用引起的有害作用，给人体补充β-胡萝卜素可有效降低心血管疾病和癌症的发生概率，高摄入富含类胡萝卜素的饮食和降低白内障发生的危险之间有重要联系(Bendich，1993)。海藻中含有丰富的类胡萝卜素，从结构类型说，通常可以分为三类：胡萝卜素、叶黄素和类胡萝卜素酸。海藻中还含有多种特有的类胡萝卜素，如褐藻黄素、甲藻黄素、硅藻黄素等。直到目前为止，海藻中类胡萝卜素的组成与生理学功能尚没有明确的结论，因而对我国丰富的海藻资源中的类胡萝卜素进行较为系统和全面的化学及生物活性研究已成为摆在我们面前的一个重要课题。本研究选取我国青岛海滨三类大型经济海藻——红、绿、褐藻中资源量丰富的代表性种类作为实验材料，较系统地测定了其中类胡萝卜素的含量，并运用经典的柱层析法对各类胡萝卜素组分进行了分离，通过薄层分析和可见光谱扫描对各分离组分进行了定性、定量分析。     

桂中坳陷环江凹陷上古生界海相页岩储层孔隙结构和分形特征研究

通过有机地化分析、全岩X衍射矿物分析、甲烷等温吸附及低压氮气吸附实验,本文对桂中坳陷环江凹陷上古生界页岩样品的孔隙结构及分形特征进行了研究.结果表明:研究区页岩总有机碳含量(TOC)平均为2.40%,热成熟度(Ro)平均为2.65%,处于过成熟演化阶段.页岩主要的矿物组成为石英和黏土.页岩的比表面积平均为5.86 m2/g,孔容平均为0.014 9 mL/g,平均孔径为11.2 nm.页岩中发育大量的中孔,主要呈两端开口的圆筒形孔或四边开放的平行板状孔.页岩中TOC含量和石英含量越多,微-中孔越发育、比表面积和孔容越大,而平均孔径则变小.通过Frenkel-Halsey-Hill (FHH)模型和氮气吸附实验数据计算得到孔隙表面分形维数D1(平均为2.428 4)和孔隙结构分形维数D2(平均为2.622 2),对应的相对压力(P/P0)分别是0~ 0.45和0.45 ~ 0.99.分形维数D1、D2随着比表面积、孔容的增加而增加,而平均孔径随着前者的增加而减小.分形维数D1、D2、TOC含量、石英含量和甲烷吸附量之间呈现较好的正相关性,但随着黏土矿物含量的增多而减小.分形维数D1与Langmuir压力存在弱负相关性,分形维数D2随Langmuir压力增大有变大的趋势.桂中坳陷西北部页岩分形维数越大,孔隙结构越复杂,其对天然气的吸附和存储能力越强.     

Corporate social responsibility,green credit,and corporate performance: an empirical analysis based on the mining,power, and steel industries of China

Natural Hazards - From the perspective of corporate social responsibility and environmental risk management, green credit will have an important impact on corporate performance. The influence of...     

高效优化非分裂PML边界二阶标量波方程数值模拟方法

卷积完全匹配层（convolution perfectly matched layer,CPML）吸收边界是一种高效处理波动方程数值模拟中人工边界反射波的方法。本文基于传统的一阶系统CPML吸收边界条件推广并推导了新的二阶系统CPML边界条件（NCPML）。与常规二阶系统CPML边界条件不同,新边界条件推导的核心思想是在复数-频率域中忽略部分衰减因子空间变化特性,避免其在时间域产生复杂卷积算子,然后反变换至时间域得到基于CPML吸收条件的二阶标量波方程,并应用于二阶标量波方程数值模拟。均匀介质模型测试验证了NCPML吸收条件在内存使用上相对于常规二阶系统CPML与SPML（split PML）吸收条件更少。在对人工边界反射的吸收效果上,NCPML稍逊色于常规二阶系统CPML,但二者均相对于SPML优势明显。最后通过层状模型和Marmousi模型测试验证了NCPML的稳定性及其在效率上的优势。     

Assessment of PPP integer ambiguity resolution using GPS,GLONASS and BeiDou (IGSO,MEO) constellations

Although integer ambiguity resolution (IAR) can improve positioning accuracy considerably and shorten the convergence time of precise point positioning (PPP), it requires an initialization time of over 30 min. With the full operation of GLONASS globally and BDS in the Asia–Pacific region, it is necessary to assess the PPP–IAR performance by simultaneous fixing of GPS, GLONASS, and BDS ambiguities. This study proposed a GPS + GLONASS + BDS combined PPP–IAR strategy and processed PPP–IAR kinematically and statically using one week of data collected at 20 static stations. The undifferenced wide- and narrow-lane fractional cycle biases for GPS, GLONASS, and BDS were estimated using a regional network, and undifferenced PPP ambiguity resolution was performed to assess the contribution of multi-GNSSs. Generally, over 99% of a posteriori residuals of wide-lane ambiguities were within ±0.25 cycles for both GPS and BDS, while the value was 91.5% for GLONASS. Over 96% of narrow-lane residuals were within ±0.15 cycles for GPS, GLONASS, and BDS. For kinematic PPP with a 10-min observation time, only 16.2% of all cases could be fixed with GPS alone. However, adding GLONASS improved the percentage considerably to 75.9%, and it reached 90.0% when using GPS + GLONASS + BDS. Not all epochs could be fixed with a correct set of ambiguities; therefore, we defined the ratio of the number of epochs with correctly fixed ambiguities to the number of all fixed epochs as the correct fixing rate (CFR). Because partial ambiguity fixing was used, when more than five ambiguities were fixed correctly, we considered the epoch correctly fixed. For the small ratio criteria of 2.0, the CFR improved considerably from 51.7% for GPS alone, to 98.3% when using GPS + GLONASS + BDS combined solutions.