火山热液型铅锌矿床岩石地球化学特征及预测指标

火山热液型铅锌矿床赋矿围岩、后期脉岩和蚀变岩石中成矿元素铅锌银含量高,矿体元素组合复杂,原生异常发育,并存在着原生分带现象。矿体前缘元素为I、Hg、As、Sb、B、Ba;近矿指示元素是Pb、Zn、Ag、Au、Cd、Mn、Cu;尾部或矿下指示元素为Cu、Mo、W、Sn。根据矿床指示元素的分布规律和原生晕的分带性,研制了判别矿床剥蚀程度和评价异常的地球化学指标,建立了该类矿床的地球化学找矿预测标志。     

西湖茶园茶叶铅污染铅同位素示踪

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。     

利用钻芯孔检测灌注桩钢筋笼长度的方法

根据充电法原理,结合模型桩试验,分析了钢筋笼周围的充电电场特征,结果表明钢筋笼的底端对应于电位梯度曲线的极小值点及电位曲线的拐点。以此研究结果为基础,提出了利用钻芯孔来检测成桩后钢筋笼长度的方法。某桥的应用表明,该方法简便、实用、可靠。     

北京郊区农田土壤中HCH残留调查及评价

北京郊区农田分析区的土壤样品中,均有不同程度的各种HCH异构体检出.在所测样品中,HCH异构体平均含量由高到低排序为σ-HCH、β-HCH、γ-HCH、α-HCH,而且在各个样品中γ-HCH都没有占据主导地位,说明在土壤中没有新的HCH进入.与商品HCH进行比较,w(α-HCH)和w(γ-HCH)明显下降,w(β-HCH)和w(σ-HCH)却相对上升了,分析得出异构体之间的降解转化速率由大到小排序为α-HCH、γ-HCH、σ-HCH、β-HCH.初步评价近年没有新的HCH来源污染本区,但仍有一定风险.     

东濮凹陷桥口构造沙三段储层成岩作用与孔隙演化

通过薄片观察、鉴定可知,桥口地区沙河街三段储集层砂岩成岩作用主要有压实作用、胶结作用、交代作用和溶蚀作用．孔隙以粒间溶孔、粒内溶孔和胶结物溶孔等次生溶孔为主．经粘土矿物X衍射分析,将成岩阶段划分为早成岩A、B期和晚成岩A1、A2、B期,早成岩A、B期的机械压实和胶结作用使原生孔隙大量丧失,晚成岩A1溶蚀作用对储层孔隙起重要改善作用,增加大量次生孔隙,晚成岩A2、B期方解石胶结物的胶结作用使砂岩次生孔隙大量减少．因此早期原牛孔隙的大量散失、晚期胶结作用使次生孔隙大量减少是造成本区砂岩低孔、低渗的主要原因．     

新疆与哈萨克斯坦寒武纪磷块岩资源

新疆和哈萨克斯坦寒武纪均为主要的磷矿成矿时代之一,但所形成的磷块岩资源量差别巨大．新疆寒武纪磷块岩矿层薄、矿石质量差、储量很少,哈萨克斯坦小卡拉套山寒武纪磷块岩矿层厚度大、矿石质量好、储量巨大．从实施“走出去”战略出发,邻国小卡拉套地区丰富的磷矿资源对于弥补新疆磷矿资源的严重不足具有重要意义．     

影响荧光光谱分析质量的因素

荧光光谱分析是油气化探中非常重要的一种分析方法,因此在地表样品的分析中,荧光光谱质量就显得尤其重要。消除影响因素,保证分析质量,是得到真实的地下油气信息的必要条件。通过实验研究,对影响荧光光谱分析质量的因素的进行探讨,除了在分析过程出现的影响因素外,样品的包装袋也是造成影响的重要因素。     

CSAMT法在松辽盆地伊胡塔地区嫩江组中的定位应用

上白垩统嫩江组不仅是松辽盆地南部重要的生油层系,而且在本区砂岩型铀成矿中也起着非常重要的作用。从ZK4孔的方法过井测深试验以及地电结构的对比分析入手,对探区内嫩江组的空间分布范围进行了分析研究,通过钻探施工,证实了CSAMT法应用的有效性。     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

Effect of Bacillus mucilaginosus on weathering of phosphorite and a preliminary analysis of bacterial proteins

The authors investigated the effect of Bacillus mucilaginosus on weathering of phosphorite. Analysis of different proteins was of significance in exploring the molecular biological mechanism in the bacterial weathering process. The concrete methods are described as follows： Mineral powder was put into liquid culture medium and B. mucilaginosus was incubated in the medium. The control （group） had no mineral powder in the medium. The treatments and controls were cultured simultaneously under the same condition. In a few days, the supernatant was filtrated, the main cations （Ca^2＋, Mg^2＋, Na^＋, Mn^2＋, Al^3＋, Fe^3＋, K^＋） were measured by ICP-OES, and the contents of water soluble phosphorus （Pws） and silicon （Siws） were determined by colorimetry. The residual solid was weighed on the filter paper, followed by digestion with concentrated HNO3. The concentrations of the main cations and Pws, Siws in the digest liquid were measured by using the method mentioned above. After the supernatant was centrifuged, the precipitation was used to analyze the protein differences between the treatment groups and the control groups by 2-dimentional gel electrophoresis （2-DE）. The experimental results showed that apatite and quartz were partially weathered, but kaolinite was dissolved completely. The population of bacteria increased when mineral powder was added in the liquid medium. Software analysis and comparison of the 2-DE pictures of bacterial proteins revealed 1134 visible protein spots in the treatment group, and 729 visible protein spots in the control group. To compare the bacterial protein expression contents of the treatment group with those of the control group, there were 496 different protein spots, including 214 protein spots which indicated that the protein contents increased, 75 protein spots were indicative of a decrease, and 207 proteins were newly synthesized. It is proposed that the increased bacterial contents may be related to some protein expression and activation after the