Simultaneous flow of water and solutes through geological membranes—I. Experimental investigation

The relative retardation by geological membranes of cations and anions generally present in subsurface waters was investigated using a high pressure and high temperature ‘filtration cell’. The solutions were forced through different clays and a disaggregated shale subjected to compaction pressures up to 9500 psi and to temperatures from 20 to 70°C.The overall efficiences measured increased with increase of exchange capacity of the material used and with decrease in concentration of the input solution. The efficiency of a given membrane increased with increasing compaction pressure but decreased slightly at higher temperatures for solutions of the same ionic concentration.The results further show that geological membranes are specific for different dissolved species. The retardation sequences varied depending on the material used and on experimental conditions. The sequences for monovalent and divalent cations at laboratory temperatures were generally as follows: Li < Na < NH₃ < K < Rb < Cs Mg < Ca < Sr < Ba.The sequences for anions at room temperature were variable, but at 70°C, the sequence was: HCO₃ < I < B < SO₄ < Cl < Br.Monovalent cations contrary to some field data were generally retarded with respect to divalent cations. The differences in the filtration ratios among the divalent cations were smaller than those between the monovalent cations. The passage rate of B, HCO₃, I and NH₃ was greatly increased at 70°C.     

Seismic stratigraphy and sedimentation history of the East Mariana Basin,western Pacific

An interpretation of the seismic stratigraphy and sedimentation history of the East Mariana Basin has been made using recently collected seismic reflection and refraction data. This Mesozoic(?) age basin, between the Marshall Islands and the Mariana Trench, is subdivided into three regions. The central region with about 1000 m of sediment probably records Jurassic to Late Cretaceous sedimentation of a pelagic biogenic and clay-rich section overlain by a thick section of mainly Cenozoic carbonates shed from nearby volcanic platforms. A western region is characterized by a thinner sediment cover and a shallower acoustic basement with a similar sedimentation history except that the upper section is thinner as a consequence of fewer nearby volcanic highs. Extensive Late Cretaceous mid-plate volcanics apparently masks the lower section and forms acoustic basement. The shallower eastern region (east of 157.5°E) contains WNW-trending ridges which may be either fracture zones or high-amplitude abyssal hills. The sedimentation appears controlled by the same factors as in the other regions but the area was bypassed by most Cenozoic basin-filling turbidites because of its elevation.The isostatistically corrected basement depths between the three regions suggest that the crust in the east may be substantially younger than in the rest of the East Mariana Basin, perhaps Cretaceous in age. This requires the existence of a tectonic boundary within the basin.     

New alternatives for reference evapotranspiration estimation in West Africa using limited weather data and ancillary data supply strategies.

Accurate estimation of reference evapotranspiration (ET ₀ ) is essential for the computation of crop water requirements, irrigation scheduling, and water resources management. In this context, having a battery of alternative local calibrated ET ₀ estimation methods is of great interest for any irrigation advisory service. The development of irrigation advisory services will be a major breakthrough for West African agriculture. In the case of many West African countries, the high number of meteorological inputs required by the Penman-Monteith equation has been indicated as constraining. The present paper investigates for the first time in Ghana, the estimation ability of artificial intelligence-based models (Artificial Neural Networks (ANNs) and Gene Expression Programing (GEPs)), and ancillary/external approaches for modeling reference evapotranspiration (ET ₀ ) using limited weather data. According to the results of this study, GEPs have emerged as a very interesting alternative for ET ₀ estimation at all the locations of Ghana which have been evaluated in this study under different scenarios of meteorological data availability. The adoption of ancillary/external approaches has been also successful, moreover in the southern locations. The interesting results obtained in this study using GEPs and some ancillary approaches could be a reference for future studies about ET ₀ estimation in West Africa.     

Reducing Drift and Bias of a Global Ocean Model by Frequency-Dependent Nudging

Frequency-dependent nudging is applied to a coarse resolution (nominal 1°) global ocean model to suppress its drift and bias, and the impact of the nudging on the skill of the model is assessed. The nudging is applied to temperature and salinity in frequency bands centred on 0 and 1 cycles per year. As expected, the nudging significantly reduces the biases in the long-term mean and annual cycle of temperature, salinity, and sea level. By comparing the simulated (i) sea surface temperature with operational analyses based on observations, (ii) vertical profiles of temperature and salinity with observations made by Argo floats, and (iii) sea level with altimeter observations, it is shown that the skill of the model in simulating variability about the annual cycle is also improved. The potential benefit of applying frequency-dependent nudging to the ocean component of a coupled atmosphere–ocean model is discussed.     

Longitudinal Social Science Research in Natural Resource Communities: Lessons and Considerations

The majority of social science research is cross-sectional in nature, with data collected at a single point in time. However, social systems are dynamic and many of the variables of interest to social scientists may change over time. Longitudinal research methods enable data collection at two or more points in time among a population of interest to examine change in measured variables and influencing factors. Despite the opportunities it affords, longitudinal research is relatively uncommon in natural-resource-based social science research as compared to other fields (e.g., medical, criminal, education). We feel that the field of natural resource social science is ripe for a proliferation of longitudinal studies, now that a substantial body of cross-sectional data has been built. In the spirit of encouraging more of this type of research, we draw on our collective experiences in longitudinal studies to share lessons learned in research design, sampling, and data management.     

Combined interpretation of radar, hydraulic, and tracer data from a fractured-rock aquifer near Mirror Lake, New Hampshire, USA

An integrated interpretation of field experimental cross-hole radar, tracer, and hydraulic data demonstrates the value of combining time-lapse geophysical monitoring with conventional hydrologic measurements for improved characterization of a fractured-rock aquifer. Time-lapse difference-attenuation radar tomography was conducted during saline tracer experiments at the US Geological Survey Fractured Rock Hydrology Research Site near Mirror Lake, Grafton County, New Hampshire, USA. The presence of electrically conductive saline tracer effectively illuminates permeable fractures or pathways for geophysical imaging. The geophysical results guide the construction of three-dimensional numerical models of ground-water flow and solute transport. In an effort to explore alternative explanations for the tracer and tomographic data, a suite of conceptual models involving heterogeneous hydraulic conductivity fields and rate-limited mass transfer are considered. Calibration data include tracer concentrations, the arrival time of peak concentration at the outlet, and steady-state hydraulic head. Results from the coupled inversion procedure suggest that much of the tracer mass migrated outside the three tomographic image planes, and that solute is likely transported by two pathways through the system. This work provides basic and site-specific insights into the control of permeability heterogeneity on ground-water flow and solute transport in fractured rock.

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Resumen Una interpretación integrada de radar experimental de campo transversal a pozos, trazadores, y datos hidráulicos demuestra el valor de combinar el monitoreo geofísico realizado en periodos de tiempo con mediciones hidrológicas convencionales en la caracterización mejorada de un acuífero rocoso fracturado. Se llevó a cabo tomografía de radar por periodos de tiempo y diferencia de atenuación durante un experimento con trazadores salinos en el sitio de investigación hidrológica de roca fracturada del Servicio Geológico de Estados Unidos cerca del Lago Espejo, Condado Grafton, New Hampshire, USA. La presencia del trazador salino eléctricamente conductivo refleja efectivamente fracturas permeables o trayectorias para imágenes geofísicas. Los resultados geofísicos orientan la construcción de modelos numéricos tri-dimensionales de flujo de agua subterránea y transporte de solutos. En un esfuerzo por explorar explicaciones alternativas para los datos tomográficos y trazadores se considera un conjunto de modelos conceptuales que involucran campos de conductividad hidráulica heterogéneos y transferencias de masa de ritmo limitado. La calibración de datos incluye concentraciones de trazadores, el tiempo de llegada de la concentración pico en la salida, y presión hidráulica en régimen permanente. Los resultados del procedimiento de acoplamiento invertido sugieren que mucho de la masa del trazador migró fuera de los tres planos de imagen tomográfica, y que el soluto es probablemente transportado por dos trayectorias a través del sistema. Este trabajo aporta ideas básicas y específicas del sitio en relación con el control de la heterogeneidad de permeabilidades en el flujo de agua subterránea y transporte de solutos en rocas fracturadas.

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Résumé Une interprétation intégrée détudes de terrain (radar entre puits, traçages, données hydrauliques) démontre la valeur de la combinaison entre la géophysique des temps finis et les mesures hydrologiques conventionnelles pour une interprétation améliorée dun aquifère de roche fracturée. La tomographie au radar a été mise en uvre durant un traçage artificiel au sel au site de recherche sur lhydrologie des roches fracturées du Service Géologique des US, à proximité du Lac Mirror, Conté de Grafton, Nouvel Hampshire, USA. La présence du traceur électriquement conducteur met en relief, grâce à la géophysique, la présence de fractures ou découlements préférentiels. Les résultats de la géophysique ont permis la construction de modèle hydrogéologique tri-dimensionnel des écoulements et du transport de soluté. Dans loptique dexplorer des interprétations alternatives des données de traçage et de tomographie, différents modèles conceptuels sont utilisés concernant lhétérogénéité des conductivités hydrauliques et des taux limités de transferts de solutés. Les données du calibrage incluent les données de concentration du traceur, le temps darrivée du pic de restitution et les données piézométriques en régime permanent. Les résultats de la procédure dinversion couplée suggèrent quune quantité très importante du traceur migre au delà de la fenêtre de visualisation des tomographies, et que le soluté est transporté via deux voies découlement préférentiel. Ce travail apporte des connaissances de base et spécifiques au site concernant la distribution de la perméabilité dans laquifère et le transport de soluté dans les roches fracturées.

     

Late Middle Pleistocene deposits at Norton Farm on the West Sussex coastal plain,southern England

The coastal plain of West Sussex, southern England, is internationally important because of the sequence of discrete high‐sea‐level events preserved at various elevations across it. New evidence is presented from a site at Norton Farm, near Chichester, on the Lower Coastal Plain, where Pleistocene marine sands, fining upwards into silts, occur between 5.3 m and 9.1 m OD. The sequence reflects a regressive tendency at the transition from an interglacial to a cold stage. The marine sands have yielded foraminifera, ostracods and molluscs that indicate a declining marine influence through the sequence, culminating in a tidal mudflat, strongly weathered in places. Cool‐climate foraminifera (including Elphidium clavatum, Cassidulina reniformis and Elphidium albiumbilicatum) and ostracods have been recovered from the marine sands. Some species with an apparent preference for warmer water conditions, however, are also present. Freshwater taxa washed into the terminal marine sediments include some cold climate indicators, such as Pisidium stewarti and P. obtusale lapponicum. Additional evidence for cool climatic conditions during the deposition of the upper part of the marine sequence is provided by the lack of tree taxa in the pollen record and by features of the micromorphology. The marine sediments probably began accumulating during OIS 7, a conclusion based on their elevation, on amino acid ratios from shells, but especially on vertebrate evidence, particularly the presence of a small form of horse, together with a large, distinctive, form of northern vole (Microtus oeconomus). The occurrence of cool climate indicators in these marine sediments may demonstrate a lag between the climatic deterioration and the expected glacio‐eustatic fall in relative sea‐level. This evidence appears to support the conclusions drawn from the study of coral terraces in Barbados. Such a scenario would provide the conditions necessary for the emplacement of the large erratic boulders reported from the Lower Coastal Plain of West Sussex. Copyright © 2000 John Wiley & Sons, Ltd.