Sediment disturbance off the Tagus Estuary, Western Portugal: chronic contamination, sewage outfall operation and runoff events

Sediment disturbance patterns in the coastal area off the Tagus Estuary (Portugal) have been assessed using a set of combined techniques. The potential sources of disturbance in the area include chronic contamination of the fine sediments originating from the estuary, a local input from a long-sea sewage outfall and occasional high runoff episodes following torrential rain. The Sediment Quality Triad approach, combining environmental chemistry (namely organic contaminants), macrofaunal benthic communities and laboratory sediment toxicity assays, was performed on sediment samples from 20 sites. The samples were collected before the outfall commenced operation and four years after commissioning, in order to evaluate the relative magnitudes of the three potential sources of disturbance. The sediment contamination created by the estuary was identified as the most important cause of reduced sediment quality, as disturbance in all three components of the Sediment Quality Triad were only found in a site located near the estuary.     

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.     

Agricultural land use dynamics in the Brazilian Amazon based on remote sensing and census data

The potential impact of deforestation in the Brazilian Amazon on greenhouse gas emissions to the atmosphere calls for policies that take account of changes in forest cover. Although much research has focused on the location and effects of deforestation, little is known about the distribution and reasons for the agricultural uses that replace forest cover. We used Landsat TM-based deforestation and agricultural census data to generate maps of the distribution and proportion of four major agricultural land uses throughout the Brazilian Amazon in 1997 and 2007. We built linear and spatial regression models to assess the determinant factors of deforestation and those major agricultural land uses - pasture, temporary agriculture and permanent agriculture - for the states of Pará, Rondônia, and Mato Grosso. The data include 30 determinant factors that were grouped into two years (1996 and 2006) and in four categories: accessibility to markets, public policies, agrarian structure, and environment. We found an overall expansion of the total agricultural area between 1997 and 2007, and notable differences between the states of Pará, Rondônia, and Mato Grosso in land use changes during this period. Regression models for deforestation and pasture indicated that determinant factors such as distance to roads were more influential in 1997 than in 2007. The number of settled families played an important role in the deforestation and pasture, the effect was stronger in 2007 than 1997. Indigenous lands were significant in preventing deforestation in high-pressure areas in 2007. For temporary and permanent agricultures, our results show that in 1997 the effect of small farms was stronger than in 2007. The mapped land use time series and the models explain empirically the effects of land use changes across the region over one decade.     

A new design of the LAPS land surface scheme for use over and through heterogeneous and non-heterogeneous surfaces: Numerical simulations and tests

Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

Effect of growth on active biomonitoring with terrestrial mosses

The effects of growth of autoirrigated, shaded transplants of Pseudoscleropodium purum on the quantification of tissue concentrations of Cd, Cu, Hg, V and Zn, were investigated in 4 exposure periods, each of 56 days, at 7 sampling sites (contaminated and uncontaminated). Concentrations of the elements in the basal portions of the moss shoots were compared with the concentrations in the portions of the shoots that grew during the exposure period. Mercury and V were present at lower concentrations in the new portions of the shoots than in the basal portions, whereas the opposite was true for Cd, Cu and Zn. The magnitude of error introduced by growth was not negligible, and in some cases was higher than 40%, relative to the results obtained by analysis of the whole shoot. Devitalization of moss prior to its use as transplant material is recommended to avoid growth of the plant during the exposure period.     

A numerical study of the orbits of second species of the planar circular RTBP

We present a numerical study of the set of orbits of the planar circular restricted three body problem which undergo consecutive close encounters with the small primary, or orbits of second species. The value of the Jacobi constant is fixed, and we restrict the study to consecutive close encounters which occur within a maximal time interval. With these restrictions, the full set of orbits of second species is found numerically from the intersections of the stable and unstable manifolds of the collision singularity on the surface of section that corresponds to passage through the pericentre. A ‘skeleton’ of this set of curves can be computed from the solutions of the two-body problem. The set of intersection points found in this limit corresponds to the S-arcs and T-arcs of Hénon’s classification which verify the energy and time constraints, and can be used to construct an alphabet to describe the orbits of second species. We give numerical evidence for the existence of a shift on this alphabet that describes all the orbits with infinitely many close encounters with the small primary, and sketch a proof of the symbolic dynamics. In particular, we find periodic orbits that combine S-type and T-type quasi-homoclinic arcs.     

Euro-Cordex Regional Projection Models: What Kind of Agreement for Europe?

Mathematical Geosciences - EURO-CORDEX is an international initiative which provides regional climate projections based on multiple dynamical and empirical–statistical downscaling models. The...     

A concerted research effort to advance the hydrological understanding of tropical páramos

Páramos, a neotropical alpine grassland-peatland biome of the northern Andes and Central America, play an essential role in regional and global cycles of water, carbon, and nutrients. They act as water towers, delivering water and ecosystem services from the high mountains down to the Pacific, Caribbean, and Amazon regions. Páramos are also widely recognized as a biodiversity and climate change hot spots, yet they are threatened by anthropogenic activities and environmental changes. Despite their importance for water security and carbon storage, and their vulnerability to human activities, only three decades ago, páramos were severely understudied. Increasing awareness of the need for hydrological evidence to guide sustainable management of páramos prompted action for generating data and for filling long-standing knowledge gaps. This has led to a remarkably successful increase in scientific knowledge, induced by a strong interaction between the scientific, policy, and (local) management communities. A combination of well-established and innovative approaches has been applied to data collection, processing, and analysis. In this review, we provide a short overview of the historical development of research and state of knowledge of the hydrometeorology, flux dynamics, anthropogenic impacts, and the influence of extreme events in páramos. We then present emerging technologies for hydrology and water resources research and management applied to páramos. We discuss how converging science and policy efforts have leveraged traditional and new observational techniques to generate an evidence base that can support the sustainable management of páramos. We conclude that this co-evolution of science and policy was able to successfully cover different spatial and temporal scales. Lastly, we outline future research directions to showcase how sustainable long-term data collection can foster the responsible conservation of páramos water towers.     

Locality Attributes and Networks Serving to Reveal Amazonian Urbanization beyond the Cities

Beyond the Amazonian cities, distinct spatial units arranged in networks compose an extended urban space, usually invisible to government agencies and public polities. This article empirically reveals this space by studying the localities’ characteristics and connections. In southwestern Pará, Brazil, 236 communities were sampled using field expeditions. Variables related to the locality organization, history, health and education services, urban infrastructure, and land use were explored in a fuzzy cluster analysis. Local production and consumption flows were considered in the locality network analysis. The fuzzy analysis allowed identifying a hierarchy of localities for which the geographical location influences the spatial distribution patterns of five groups. On the other hand, consumption and production networks identified different locality's articulations, with persistent dependence on cities. These results characterize extensive urbanization at the local level and highlights the participation of the local populations configuring the Amazonian territory.