弱碱三元复合驱含油污泥的絮凝降水处理

采用絮凝剂,对油田污水处理过程产生的絮凝污泥进行处理,考察絮凝处理温度、pH值、处理时间等因素对污泥含水率的影响,以及部分水解聚丙烯酰胺(HPAM)和阳离子聚丙烯酰胺(CPAM)对絮凝含油污泥处理效果,评价KMnO4、FeCl3、Tsg、Yhg等4种絮凝助剂处理效果.结果表明/污泥含水率随处理温度和pH值的升高而先下降...     

新型抗高盐泡沫体系研发及性能评价

为克服高盐油藏常规起泡剂抗高盐性能差的缺点,通过复配及正交实验研发新型泡沫体系,最佳质量分数配方为0.40％羟磺基甜菜碱、0.04％十二醇与0.10％十二烷基二甲基苄基氯化铵.45～65℃下泡沫体系可应用于矿化度10～160 g/L;泡沫在含油质量分数为20.00％的静态条件下有较强的稳定性.阻力因子实验中,注入泡沫0...     

用膨润土处理含铅离子废水的研究

用膨润土对模拟含pb2 离子的废水进行了试验研究.结果表明:膨润土是一种有效的吸附剂.其在粒径范围为200-300目,温度30℃左右,用量每1L含铅废水(50mg/1)为3g,pH值在大于7中性至碱性,振荡时间为45min的实验条件下,对废水中Pb2 去除效率高于97%.     

污泥吸附剂制备的研究

为探索城市污泥资源化的途径,以城市污水处理厂的剩余污泥为原料,采用氯化锌活化法制备污泥吸附剂,考察了活化剂浓度、固液比、活化温度、活化时间4种因素对制备污泥吸附剂碘吸附值的影响,并对吸附剂进行了表征分析。实验结果表明:氯化锌浓度3mol/L、固液比1:2、活化温度550℃和活化时间40min为最佳制备条件,此条件下制得的污泥吸附剂碘吸附值为408.94mg/g,比表面积199.196m2/g,总孔体积为0.481cm3/g,微孔体积为0.089cm3/g,平均孔径为4.83nm。与商品活性炭相比,污泥吸附剂的碘吸附值和比表面积较小,孔径较宽,微孔所占比例较小,主要以过渡结构为主。     

5种除草剂对白鲢鱼种急性毒性试验

以白鲢(Hypophthalmicthysmolitris)为实验材料,研究常用除草剂对鱼类的毒性效应。结果表明:采用直线回归法求得的96hLC50值分别为:2,4_D丁酯0.185mg/L,可信限0.138~0.247mg/L;丁草胺0.080mg/L,可信限0.067~0.097mg/L;使它隆3.80mg/L,可信限2.68~5.40mg/L;艾割18.60mg/L,可信限14.80~23.32mg/L;嗪草酮108.80mg/L,可信限91.46~129.72mg/L。对鱼类安全浓度分别为0.019mg/L,0.38mg/L,0.008mg/L,1.86mg/Land10.88mg/L。     

4种重金属离子及其混合液对壶状臂尾轮虫的急性毒性试验

研究了铜、锌、镉、铅离子及其混合液对壶状臂尾轮虫(Brachionusurceus)的急性毒性影响,实验结果表明,Cu2+、Zn2+、Cd2+、Pb2+对壶状臂尾轮虫的24hLC50分别为83 .18μg/L、4 .27mg/L、7. 60mg/L、23 44mg/L,将4种离子按照质量比120∶20∶6∶1的比例配成混合金属溶液,其混合液对壶状臂尾轮虫的24hLC50为0 42mg/L。     

钻井泥浆和消油剂对合浦珠母贝稚贝的急性毒性试验

以合浦珠母贝稚贝为测试对象 ,比较了三种钻井泥浆和消油剂的 96h急性毒性效应。实验结果表明 ,钻井泥浆对合浦珠母贝稚贝的半致死浓度大于 10 5mg/ L;三种消油剂的半致死浓度分别为12 58mg/ L ,4 4 69mg/ L和 2 545mg/ L。     

钻井泥浆和消油剂对合浦珠母贝稚贝的急性毒性试验

以合浦珠母贝稚贝为测试对象，比较了三种钻井泥浆和消油剂的96h急性毒性效应。实验结果表明，钻井泥浆对合浦珠母贝稚的半致死浓度大于10^5mg/L；三种消油剂的半致死浓度分别为1258mg/L,4469mg/L和2545mg/L。     

滨海含水层胶体絮凝导致地层损害的实验研究

滨海含水层地层损害是指淡水驱替咸水过程中,释放后的黏土胶体发生絮凝沉降,导致地层孔隙被堵塞,引起含水介质的渗透性降低的现象。该文通过絮凝沉降实验和定流速砂柱实验,分析不同离子强度和阳离子价态(一价、二价)对胶体絮凝沉降的影响,结果表明:NaCl作为电解质时,絮凝发生的离子强度范围在0.032~0.034 mol/L之间,絮凝时间从82 min减少至39 min;而电解质为CaCl 2,离子强度为0.006 mol/L时,胶体的絮凝时间仅需6 min;钙钠比越高,黏粒絮凝发生的越快。砂柱实验结果显示,含水介质渗透性会随着电解质溶液的离子强度增加和阳离子价态的升高快速降低。当电解质为NaCl,离子强度分别为0.054 mol/L和0.017 mol/L时,含水介质渗透性降低20%所需时间分别为15 min和50 min;当电解质为CaCl2,离子强度为0.011 mol/L时,含水介质渗透性降低20%仅需5 min。因为高离子强度和高价阳离子可以加速胶体絮凝,多孔介质的孔吼更容易发生堵塞,研究成果对降低滨海含水层的地层损害有一定的实际应用价值。     

CYF-0.2型油水分离器的台架试验

对CYF-0.2型油水分离器进行了台架试验,并对其分离效果的影响因素进行了分析。结果表明:该油水分离器的分离效果为10mg/L以下,满足国家规定的排放标准(15mg/L);水的流速、温度、压力以及水中污油的种类等是影响油水分离器分离效果的主要因素。     

Seasonal dynamics of nitrogen and phosphorus in water and sediment of a multi-level ditch system in Sanjiang Plain,Northeast China

The multi-level ditch system developed in the Sanjiang Plain, Northeast China has sped up water drainage process hence transferred more pollutants from farmlands into the rivers of this region. Understanding the seasonal dynamics of nitrogen (N) and phosphorus (P) transportation in the ditch system and the role of different ditch size is thus crucial for water pollution control of the rivers in the Sanjiang Plain. In this study, an investigation was conducted in the Nongjiang watershed of the Sanjiang Plain to study the nutrient variation and the correlation between water and sediments in the ditch system in terms of ditch level. Water and sediments samples were collected in each ditch level in growing season at regular intervals (once per month), and TN, NO₃ ⁻N, NH₄ ⁺-N, TP, and PO₄ ³⁻-P were analyzed. The results show that nutrient contents in water were higher in June and July, especially in July, the contents of TN and TP were 3.21 mg/L and 0.84 mg/L in field ditch, 4.04 mg/L and 1.06 mg/L in lateral ditch, 2.46 mg/L and 0.70 mg/L in branch ditch, 1.92 mg/L and 0.63 mg/L in main ditch, respectively. In August and September, the nutrient contents in the water were relatively lower. The peak value of nutrient in ditch water had been moving from the field ditch to the main ditch over time, showing a remarkable impact of ditch system on river water environment. The nutrient transfer in ditch sediments could only be found in rainfall season. Nutrient contents in ditch sediment had effect on that in ditch water, but nutrients in ditch water and sediments had different origination. Ditch management in terms of the key factors is hence very important for protecting river water environment.     

长江中游沿岸地下水中铵氮与磷的共存规律及其控制因素

长江中游平原区面临着一系列严重的地质环境问题，其中地下水铵氮和磷的问题十分突出，但目前对于二者共存规律的认识还十分薄弱。以长江中游沿岸故道区为典型研究区，对采集的地下水样品进行了水文地球化学分析，并综合运用因子分析和随机森林模型探讨了铵氮和磷的赋存规律。结果表明:地下水整体处于还原环境中，NH₄-N的质量浓度为0.03~71.0 mg/L（均值9.92 mg/L），P的质量浓度为0.02~3.38 mg/L（均值0.51 mg/L）。地下水中高浓度的铵氮与磷均主要为天然成因，但铵氮与磷的迁移富集过程存在差异:铵氮的迁移富集与含氮有机质矿化过程密切相关；磷的迁移富集与铁氧化物或氢氧化物的还原性溶解密切相关，而含磷有机质矿化是磷富集的次要过程。Eh很低的地下水环境易产生高浓度铵氮的地下水，相对中等的还原环境会产生高浓度的磷但通常不会伴生高浓度的铵氮；当地下水中S2-，DOC，I均处于相对较高的浓度水平时会伴生大量的铵氮，而磷的浓度在很大程度上受控于Fe2+浓度；当DOC，I和Fe2+浓度都高时，通常会出现铵氮和磷浓度都较高的现象。      

红海湾底质硫化物的分布和变化

根据南海区半封闭型海湾规模化养殖技术研究的需要,对红海湾底质硫化物进行了研究。用碘量法分析的结果表明：红海湾底质中硫化物含量的区域分布极不均匀,呈北部河口区＞虾池＞鱼湾＞中部＞南部自然水域＞礁滩区的特点。虾池、鱼的硫化物含量清淤前分别为清淤后的8.4、3．6倍;湾南部硫化物含量春季明显高于夏季,其余区域的两季差异不明显。46份样品中约13％、28％分别超过国内外评价标准,超标测站位于河口和清淤前的虾池、鱼。礁滩护养增殖区、南部自然水域、湾中部牡蛎养殖区和清淤后的虾池、鱼尚未见硫化物的污染。     

基于空间填充曲线排列码划分的并行缓冲区算法

缓冲区计算是地理信息系统空间分析的基本功能之一。在矢量缓冲区研究方面,以往大多聚焦缓冲区生成算法,这些优化方法在单机计算环境中针对大规模空间数量数据的计算效率提升是有限的,因而需要并行环境下的改进方法来进一步破解计算瓶颈。本文基于Map Reduce计算模型和分布式内存计算框架,提出了一种基于空间填充曲线排列码划分的并行缓冲区分析算法(SPBM),基于空间填充曲线编码进行数据排序和范围划分,对跨越网格的数据采用近似切分方法,在考虑负载均衡的前提下对任务并行分解,之后按照给定深度的"树状"方式进行结果合并。本文在单机和集群两种环境下利用实际道路网等数据进行了实验。同等环境下,相较于目前流行的GIS软件——QGIS和Post GIS计算性能提升明显,相较于现有其他并行优化方法效率提升超过50%。这样的优化分析方法对于GIS中其他矢量分析算法的并行算法也具有一定的借鉴意义。     

复杂环境下基于GPS+BDS-3的PPP/INS/ODO组合导航性能分析

针对复杂环境下单一导航定位技术存在精度低、可靠性和完整性差的问题,提出一种GPS+BDS-3的PPP/INS/ODO组合导航方案.采用GPS+BDS-3双系统观测数据,推导无电离层组合PPP模型,进一步给出PPP/INS/ODO组合模型并分析时间异步及杆臂误差的处理策略,结合里程计测速信息和非完整性约束信息,提高组合导...     

The Influences of Mg~(2+), Ca~(2+) and Mg ~(2+)/Ca ~ (2+) Ratio in Mixed Seawater on the Emergence Rate of Penaeus japonicus Postlarva

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苯酚和十二烷基苯磺酸钠对奥尼罗非鱼的急性毒性及安全评价

用苯酚和十二烷基苯磺酸钠对奥尼罗非鱼进行急性毒性实验,以评价其在水环境中对奥尼罗非鱼的影响。研究表明:苯酚对奥尼罗非鱼的24、48、96 h的LC50分别为40.33、34.23、28.07 mg/L,十二烷基苯磺酸钠分别为10.06、9.14、8.48 mg/L;苯酚对奥尼罗非鱼SC及最大容许浓度MPC分别为2.807、0.281 mg/L,十二烷基苯磺酸钠对奥尼罗非鱼SC为0.848 mg/L,最大容许浓度MPC为0.085 mg/L。     

Quantification of methane fluxes from hydrocarbon seeps to the ocean and atmosphere: Development of an <Emphasis Type="Italic">in situ</Emphasis> and online gas flux measuring system

Natural hydrocarbon seeps in the marine environment are important contributors to greenhouse gases in the atmosphere. Such gases include methane, which plays a significant role in global carbon cycling and climate change. To accurately quantify the methane flux from hydrocarbon seeps on the seafloor, a specialized in situ and online gas flux measuring (GFM) device was designed to obtain high-resolution time course gas fluxes using the process of equal volume exchange. The device consists of a 1.0-m diameter, 0.9-m tall, inverted conical tent and a GFM instrument that contains a solenoid valve, level transducer, and gas collection chamber. Rising gas bubbles from seeps were measured by laboratory-calibrated GFM instruments attached to the top of the tent. According to the experimental data, the optimal anti-shake time interval was 5 s. The measurement range of the device was 0–15 L min^?1, and the relative error was ± 1.0%. The device was initially deployed at an active seep site in the Lingtou Promontory seep field in South China Sea. The amount of gas released from a single gas vent was 30.5 m³ during the measurement period, and the gas flow rate ranged from 22 to 72 L h^?1, depending on tidal period, and was strongly negatively correlated with water depth. The measurement results strongly suggest that oceanic tides and swells had a significant forcing effect on gas flux. Low flow rates were associated with high tides and vice versa. The changes in gas volume escaping from the seafloor seeps could be attributed to the hydrostatic pressure induced by water depth. Our findings suggest that in the marine environment, especially in the shallow shelf area, sea level variation may play an important role in controlling methane release into the ocean. Such releases probably also affect atmospheric methane levels.     

中国近地面PM2.5浓度与排放的时空分布及其关联分析

PM_2.5是威胁人体健康的主要大气污染物之一。大量研究关注近地面PM_2.5浓度的监测及其时空分布,但目前针对PM_2.5排放及其与近地面浓度之间的关联研究较为缺乏。本文通过2000—2014年近地面PM_2.5浓度格网数据和PM_2.5排放格网数据,采用长时间序列分析法对PM_2.5浓度和PM_2.5排放从定性和定量两个角度进行时空变化趋势对比研究,并进一步结合标准差椭圆法和趋势分析法,分析了我国近地面PM_2.5浓度和PM_2.5排放的时空变化特征及其关联。结果表明,从总体时间序列趋势上,近地面PM_2.5浓度和PM_2.5排放之间在空间分布上基本呈现一致性,集中在胡焕庸线以东的人口密集区,但在时间上,PM_2.5浓度和排放之间存在动态变化时间差。且PM_2.5浓度的变化更为明显,2000—2007年高于35 μg/m³的国土面积占比增加了14.26%,2007—2014年减少了2.84%;从标准差椭圆分析来看,PM_2.5浓度椭圆和排放椭圆在覆盖面积和方位角上与人口和经济分布吻合,但前者面积更大,长轴更接近于东西方向,二者存在约17°差异,而两类椭圆的中心位置随时间变化呈现出较一致的轨迹特征并呈现出滞后特点;此外,受大气扩散、点源排放等因素影响,PM_2.5浓度变化趋势与排放变化趋势在胡焕庸线以东并不完全一致,部分区域排放呈降低趋势而浓度则反而呈升高趋势。因此,从全国层面来看,减排政策对浓度降低在时间上虽存在滞后,但边际效益显著,并已显露成效;而从局地来看,受地形、气象条件和大气化学过程等复杂影响,二者的变化在空间上仍会存在差异,有待进一步深入研究;从防控措施来看,在继续加强落实本地减排政策的同时,应考虑污染物的扩散迁移规律,加强联防联控,有效改善空气质量。