云南水头山铅锌矿床闪锌矿Rb-Sr定年及其地质意义

水头山铅锌矿床位于保山地块南端芦子园矿集区,区内以发育矽卡岩型和热液脉型两类铅锌矿化为特点.为查明铅锌多金属成矿作用过程,本文对水头山热液脉型铅锌矿床主成矿阶段的闪锌矿开展了Rb-Sr同位素组成测定,获得闪锌矿的Rb-Sr等时线年龄为135.8±4.2Ma(MSWD=1.70,n=6),结合区内其他矿床的成矿年龄,认为...     

湖南大义山矿田白沙子岭锡矿床Rb-Sr同位素等时线年龄及其地质意义

大义山矿田处于华南褶皱带南岭成矿带中段北缘,位于阳明山－大义山－上堡东西向基底断裂、攸县－宁远北东向基底断裂和郴州－邵阳北西向隐伏深断裂带的交汇部位,主要受大义山岩体控制,其中云英岩脉型锡矿为该矿田典型的成矿类型之一.对该矿田白沙子岭锡矿床云英岩脉型锡矿脉中的石英进行了流体包裹体Rb-Sr同位素测年及其地质意义的讨论.结果显示,矿脉中石英流体包裹体Rb-Sr同位素等时线年龄为160±1 Ma,属于南岭地区中生代160~150 Ma时段成矿高峰期产物;成矿与大义山岩体中侏罗世二长花岗岩具有密切的时间、空间和成因联系,为该期岩浆晚期热液成矿作用的产物;流体包裹体Rb-Sr同位素87Sr/86Sr初始比值为0.706 79±0.003 66,预示其成矿流体有幔源物质的参与,具有地壳和地幔混合流体的特征.      

Geochronology of igneous rocks at and near to the Nezhdaninka gold deposit, Yakutia, Russia: U-Pb, Rb-Sr, and Sm-Nd isotopic data

The intrusive rocks associated with the large Nezhdaninka gold deposit (Au > 470 t) hosted in the Permian carbonaceous terrigenous sequence have been dated on zircon and rock-forming minerals with precision U-Pb (ID-TIMS) and Rb-Sr methods. The lamprophyre of the dike complex that occurs in the ore field and spatially is related to gold mineralization has concordant U-Pb zircon age (121 ± 1 Ma) and the same isochron Rb-Sr age (121.0 ± 2.8 Ma). The concordant U-Pb zircon age of granodiorite that dominates in the Kurum pluton is 94 ± 1 Ma, whereas the Rb-Sr isochron age of various intrusive rocks from this pluton is 1–4 Ma younger. This difference is caused by long-term cooling of the Kurum pluton and later closure of Rb-Sr isotopic system of biotite (300–350°C) and other rock-forming minerals as compared with U-Pb isotopic system of zircon (～ 900°C). The Rb-Sr age of quartz diorite from the Gel’dy group of stocks (92.6 ± 0.8 Ma) coincides within uncertainty limits with the age of the Kurum pluton. Thus, the rocks pertaining to two epochs of magmatic activity, which developed in the South Verkhoyansk Foldbelt and divided by a time span of 25–28 Ma, are documented in the Nezhdaninka ore field. Taking into account that the age of gold mineralization is no less than 120 Ma, the data obtained allow us to specify the previously proposed formation model of the Nezhdaninka deposit. These data give grounds to rule out the Late Cretaceous Kurum pluton and the Gel’dy group of stocks from constituents of the ore-magmatic system, and to suggest that an Early Cretaceous deep-seated magma source existed beneath the deposit. Along with host terrigenous rocks, this magma source participated in the supply of matter to the hydrothermal system. The Nd, Sr, and Pb isotopic systematics of igneous rocks and ore mineralization in the Nezhdaninka ore field show that the Early and Late Cretaceous magma sources were formed in the Precambrian crust dated at ～1.8 Ga.     

Timing of formation of the Hongdonggou Pb-Zn polymetallic ore deposit,Henan Province,China: Evidence from Rb-Sr isotopic dating of sphalerites

The Hongdonggou Pb-Zn polymetallic ore deposit,located in the southwestern part of the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore mineralization in Henan Province,China,is an important part of the East Qinling metallogenic belt.The orebodies in the deposit,which are vein,bedded and lenticular,are mainly hosted in the syenite porphyry,and formed within the carbonate and clastic rocks of the Yuku and Qiumugou formations partially.The genesis of the deposit has previously been argued to be of hydrothermal-vein type or of skarn-hydrothermal type.In this study,we report the results of Rb-Sr isotopic dating based on sphalerites from the main orebody of the Hongdonggou Pb-Zn polymetallic ore deposit,which yield an isochron age of 135.7 ± 3.2 Ma,constraining the timing of mineralization as early Cretaceous.The age is close to those reported for the Pb-Zn deposits in the Luanchuan ore belt.The(~(87)Sr/~(86)Sr),values of the sphalerites(0.71127 + 0.00010) are lower than that of terrigenous silicates(0.720) and higher than the mantle(0.707),suggesting that the metallogenic components were mainly derived through crust-mantle mixing.Combining the results from this study with those from previous work,we propose that the Hongdonggou Pb-Zn polymetallic ore deposit is a hydrothermal-vein deposit associated with the early Cretaceous tectonothermal event,and the mineralization is controlled by NWand near EW-trending faults in the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore concentration belt.     

相山铀矿田西部地区深部多金属矿化成矿年代与成矿流体演化:Rb-Sr同位素体系的制约

江西相山铀矿田科学深钻3号孔在深部-700 m发现大量铅锌多金属矿化脉,垂向上呈"上铀下多金属"的分布特征。本文选取深部多金属矿脉主成矿阶段(S3)自形闪锌矿样品6件和不同阶段的毒砂、黄铁矿、方铅矿、方解石等样品12件,以及围岩全岩样品17件,进行了Rb、Sr同位素组成研究。结果表明:(1)由闪锌矿Rb-Sr等时线法确定的相山铀矿田深部多金属矿化形成于121. 0±3. 5Ma,与围岩火山岩存在较大时差,可能与晚于围岩的深部次火山有关。根据穿插关系,多金属矿化略晚于碱性交代铀矿化,但明显早于酸性交代铀矿化;(2)多金属矿化脉体中金属矿物的Rb和Sr含量分别介于0. 041×10~(-6)～1. 38×10-6和2. 35×10-6～23. 11×10-6之间,Sr同位素初始比值(87Sr/86Sr)i变化较大,介于0. 706114～0. 718814之间,平均值为0. 713579,暗示相山铀矿田深部多金属矿化的成矿物质主要来源于地壳。初始流体Sr同位素值(0. 718665)明显高于成矿时赋矿围岩(流纹英安岩为0. 714581,碎斑流纹岩为0. 714417)的Sr同位素组成,表明多金属成矿流体和物质并非来自围岩火山岩;(3)由早到晚阶段的(87Sr/86Sr)i呈明显降低的演化趋势,表明成矿流体演化过程中受到大气降水的不断稀释作用。相山矿田的铀矿和深部多金属矿化同形成于华南中生代板内伸展构造背景。     

Rb-Sr isotope systematics in metamorphic rocks,Kongsberg sector,south Norway

Rb-Sr isotope data are presented for gneisses, migmatite neosome material and granitic and gabbroic intrusive rocks from the southern part of the Kongsberg sector, south Norway. The maximum age of the crust in this area appears to be ～1.6 AE. Two metamorphic episodes at ～1.5–1.6 AE and at ～1.1–1.2 AE are recognized. Initial ⁸⁷Sr/⁸⁶Sr ratios for the granitic rocks give evidence for reworking of sialic crust and indicate that approximately 1.6 AE old crust repeatedly acted as a source for granitic magmas for a timespan of ～0.5 AE.     

Isotopic Geochronology of the Late Paleozoic Kanggur Gold Deposit of East Tianshan Mountains, Xinjiang, NW China

Abstract: The Kanggur gold deposit lies in East Tianshan mountains, eastern section of Central Asia orogenic belt. The gold mineralization occurs on the northern margin of the Aqishan‐Yamansu Paleozoic island arc in the Tarim Plate. It was hosted mainly in Middle‐Lower Carboniferous calc‐alkaline volcanic rocks, and controlled by the distributions of syn‐tectonic intrusions and ductile shear zones. In order to determine ore‐forming age of the Kanggur deposit, samples were collected from ores, wall rocks, altered rocks and intrusions. The dating methods include Rb‐Sr isochron and Sm‐Nd isochron, and secondly ⁴⁰Ar/³⁹Ar age spectrum, U‐Pb and Pb‐Pb methods. Based on the mineral assemblage and crosscutting relationship of ore veins, five mineralization stages are identified. This result is confirmed by isotope geochronologic data. The first stage featuring formation of pyrite‐bearing phyllic rock, is mineralogically represented by pyrite, sericite and quartz with poor native gold. The Rb‐Sr isochron age of this stage is 2905 Ma. The second stage represents the main ore‐forming stage and is characterized by native gold–quartz–pyrite–magnetite–chlorite assemblage. Magnetite and pyrite of this stage are dated by Sm‐Nd isochron at 290.47.2 Ma and fluid inclusion in quartz is dated by Rb‐Sr isochron at 282.35 Ma. The third mineralization stage features native gold–quartz–pyrite vein. In the fourth stage, Au‐bearing polymetallic sulfide‐quartz veins formed. Fluid inclusions in quartz are dated by Rb‐Sr isochron method at 25821 Ma. The fifth stage is composed of sulfide‐free quartz–carbonate veins with Rb‐Sr age of 2547 Ma. The first and second stages are related to ductile‐brittle deformation of shear zones, and are named dynamo‐metamorphic hydrothermal period. The third to fifth stages related to intrusive processes of tonalite and brittle fracturing of the shear zones, are called magmato‐hydrothermal mineralization period. The Rb‐Sr isochron age of 2905 Ma of the altered andesite in the Kanggur mine area may reflect timing of regional ductile shear zone. The Rb‐Sr isochron age of 28216 Ma of the quartz‐syenite porphyry and the zircon U‐Pb age of 2757 Ma of tonalite in the north of Kanggur gold mine area are consistent with the age of gold mineralization (290‐254 Ma). This correspondence indicates that the tonalite and subvolcanic rocks may have been related to gold mineralization. The Rb–Sr, Sm‐Nd and U‐Pb ages and regional geology support the hypothesis that the Kanggur gold deposit was formed during collisional orogenesis process in Late Variscan.     

Characteristic Features of Tin–iron–copper Mineralization in the Anle-Huanggangliang Mining Area, Inner Mongolia, China

Abstract: The Anle Sn‐Cu and Huanggangliang Fe‐Sn deposits have been exploited in the Linxi district, which is located 165 km northwest of Chifeng City in northern China. In this study the formation mechanisms of the tin deposits in the Anle and Huanggangliang mining area were investigated to understand the mechanisms of tin mineralization in northern China. The veins of the Anle deposit are divided into cassiterite–quartz–chlorite veins, chalcopyrite‐bearing quartz veins, cassi–terite–chalcopyrite–bearing quartz veins and sphalerite‐quartz veins. The sequence of mineralization is tin mineralization (stage I), copper mineralization (stage II), and lead‐zinc mineralization (stage III). The Huanggangliang tin deposit consists of magnetite skarn orebodies and many cassiterite‐bearing feldspar–fluorite veins and veinlets cutting the magnetite orebodies. The fluid inclusions in quartz and fluorite in ores from the Anle and Huanggangliang tin deposits are divided into two‐phase fluid inclusions, vapor‐rich fluid inclusions and poly‐phase fluid inclusions. The final homogenization temperatures of fluid inclusions of quartz in the ores of the Anle deposit and fluorite of tin‐bearing feldspar veins in the Huanggangliang tin deposit range from 195 to 425C and from 215 to 450C, respectively. The fluids responsible for the Anle and Huanggangliang tin deposits were of very high temperature and NaCl‐rich ones containing K, Ca, Al, Si, Ti, Fe and Cl in addition to ore metals such as Sn and Cu. The temperature and chemical composition of fluid in fluid inclusions of igneous rocks in the mining area are very similar to those of fluid in fluid inclusions in the ores of these deposits. The fluid for these ore deposits had a close relation with the fluid coexisting with melt of Late Jurassic granitic rocks in this mining area. Salinities of fluid inclusions from these ore deposits and granitic rocks in the mining area were estimated to range from 35 to 50 wt % NaCl equivalent. Based on arsenopy‐rite geothermometry and fluid inclusion studies, a fluid containing 40 wt% NaCl (eq.) could be formed by phase separation of fluid having 6 wt% NaCl (eq.) at a temperature of 420 to 500C and a pressure of 0.3 to 0.4 kb. The temperatures and pressures presented above indicate an NaCl‐rich magmatic fluid derived from granitic melt that had intruded into a shallow level of crust caused the Sn–Fe–Cu mineralization of the mining area. The geological relationship between these ore deposits and granitic bodies around the ore deposits, and the similarity of fluids forming these ore deposits and coexisting with granitic melt, suggest that these ore deposits were formed by the activity of fluid derived from granitic melt in Late Jurassic age.     

华北克拉通南缘卢氏多金属矿集区硫化物Rb-Sr定年及地质意义

华北克拉通南缘秦岭成矿带发育大量金矿、钼矿及铅锌多金属矿床。卢氏多金属矿集区位于东秦岭成矿带,主要矿床有夜长坪钼钨矿、八宝山铁铜矿、楼房银铜矿、柳关铅锌矿等。其中楼房银铜矿为热液脉状多金属矿床,矿床赋存于太华群角闪斜长片麻岩中,矿体受构造蚀变破碎带控制,矿床中划分出两个成矿阶段:石英-黄铁矿-黄铜矿组合和石英-黄铁矿-方铅矿-闪锌矿-方解石组合,其中前者是铜成矿阶段,后者为铅锌成矿阶段。柳关铅锌矿为矽卡岩矿床,矿体产于官道口群白云岩与花岗斑岩岩体或隐爆角砾岩接触矽卡岩化带内,矿床划分出两个成矿阶段:透辉石-透闪石-阳起石-石榴石-磁铁矿组合和方铅矿-闪锌矿-黄铁矿-绿帘石-蛇纹石-石英-方解石组合,前者为磁铁矿成矿阶段,后者是铅锌成矿阶段。金属硫化物定年结果表明,楼房银铜矿黄铜矿Rb-Sr等时线年龄为127. 8±3. 1Ma(2σ,MSWD=1. 1),初始87Rb/86Sr为0. 710998±0. 000068;柳关铅锌矿黄铁矿Rb-Sr等时线年龄为124. 8±1. 6Ma(2σ,MSWD=1. 4),初始87Rb/86Sr为0. 711074±0. 000064。研究表明卢氏多金属矿集区内热液多金属矿床形成于早白垩世,其形成与区内早白垩世岩浆活动有关。综合区域地质研究,区内多金属矿床形成于早白垩世与克拉通破坏有关的构造环境。     

Metallogenetic Mechanism and Timing of Late Superimposing Fluid Mineralization in the Dongguashan Diplogenetic Stratified Copper Deposit,Anhui Province

1 Introduction The region of the middle-lower reach of the Yangtze River is an important mineralized belt of Fe, Cu, Au, S and other elements, with a series of sedimentary-hydrothermal diplogenetic mineral deposits (Xu and Zhu, 1978; Liu et al., 1984; Gu and Xu, 1986; Gu et al., 1993, 2000; Zhai et al., 1992). Some geologists thought that the Carboniferous massive sulfide exhalative sediment was the basis of the late diplogenetic mineralization (Gu and Xu, 1986; Gu et al., 1993, 2000); o…     

The Yermakovsky beryllium deposit,Western Transbaikal region,Russia: Geochronology of igneous rocks

The sequence of rock and ore formation at the Yermakovsky beryllium deposit is established on the basis of geological relationships and Rb-Sr and U-Pb isotopic dating. The Rb-Sr age of amphibolitefacies regional metamorphism is determined for quartz-biotite-plagioclase schist (266 ± 18 Ma) and dolomitized limestone (271 ± 12 Ma) of the Zun-Morino Formation. The U-Pb zircon age of premineral gabbro is 332 ± 1 Ma. The Rb-Sr age of gabbro is somewhat younger (316 ± 8.3 Ma), probably owing to the effect of Hercynian metamorphism on sedimentary rocks of the Zun-Morino Formation and gabbroic intrusion that cuts through it. The U-Pb zircon age of gneissose granite of the Tsagan Complex at the Yermakovsky deposit is 316 ± 2 Ma, i.e., close to the age of metamorphism superimposed on gabbro rocks. The U-Pb zircon age of preore granitic dikes, estimated at 325 ± 3 and 333 ± 10 Ma, is close to the age of gabbro. The Ar/Ar age of amphibole from a granitic dike (302.5 ± 0.9 Ma) probably displays a later closure of this isotopic system or the effect of superimposed processes. The Rb-Sr age of alkali syenite intrusion is 227 ± 1.9 Ma. The U-Pb zircon age of alkali leucogranite stock pertaining to the Lesser Kunalei Complex is 226 ± 1 Ma, while the Rb-Sr age of beryllium ore is 225.9 ± 1.2 Ma. These data indicate that beryllium ore mineralization is closely related in space and time to igneous rocks of the Lesser Kunalei Complex dated at 224 ± 5 Ma and varying from gabbro to alkali granite in composition. Thus, the preore Hercynian magmatism at the Yermakovsky deposit took place ∼330 Ma ago and was completed by metamorphism dated at 271–266 Ma. The ore-forming magmatism and beryllium ore mineralization are dated at 224 ± 5 Ma. Postore magmatic activity is scarce and probably correlated with tectonic melange of host rocks.     

火山-侵入杂岩带的成岩-成矿专属性

成岩成矿关系问题,特别是成矿作用与岩浆活动的专属性问题,一直是矿床学研究中的重要课题。粤东地区热液脉状锡、钨（多金属）矿床产于中生代花岗质火山岩、次火山岩和侵入岩组成的火山侵入杂岩带中,成岩年龄与成矿年龄一致,但矿床地质、矿床矿物流体包裹体和同位素地球化学没有相对标准来区分这些来源于岩浆作用不同阶段、不同产出状态岩浆岩的成矿物质特征,使得人们对于区内矿床成因的认识不一。文中运用稀土元素地球化学方法,着重探讨和对比了矿床矿石、蚀变岩石及与成矿有关的岩浆岩的稀土元素特征和配分型式,并进一步根据在不同压力条件下Ｃｌ－在熔体和热液间的分配系数实验数据和不同压力条件下热液与相应熔体平衡时的稀土元素分配系数实验结果,分别计算了厚婆坳锡矿床和莲花山钨矿床与矿区有关岩浆岩熔体平衡的热液中的稀土元素浓度并制出配分型式,再与矿床矿石及矿石矿物稀土元素配分型式比较,从而确定成矿与侵入阶段的花岗岩岩浆活动关系密切。区内矿床为岩浆热液矿床。研究结果表明,稀土元素作为热液流体来源的示踪剂能有效地确定火山侵入杂岩带的成岩成矿专属性。     

江西德兴铜厂斑岩铜矿床岩石学特征及岩浆演化与成矿的关系

江西德兴铜矿曾引起我国地质学者极大的关注,并进行过广泛的调查研究,其中许多研究成果集中综合于《德兴斑岩铜矿》这一专著中。但对赋矿岩石特征、岩浆活动与成矿作用的关系上,尚需要深入的研究和探讨。     

河南省栾川县西沟铅锌银矿床单矿物铷-锶同位素组成特征

河南栾川西沟铅锌银矿床位于华北克拉通南缘栾川断裂北侧,为赋存于中-晚元古代浅变质碳酸盐建造中的层控矿床,被认为是晚元古代的热水沉积型矿床.从成矿早阶段至晚阶段,矿物共生组合依次为;细粒黄铁矿、粗粒黄铁矿-闪锌矿-白云石-石英组合、多金属硫化物-白云石-石英组合、黄铁矿-石英-碳酸盐组合.本文对其矿石硫化物和黑云母进行了单颗粒矿物Rb-Sr同位素分析和研究.1件赋矿钙质二云片岩样品的5个黑云母颗粒样品给出Rb-Sr等时线年龄为366.0±10Ma,代表赋矿围岩的区域变质年龄.由于黄铁矿-碳酸盐细脉切穿了钙质二云片岩的片理,闪锌矿细脉切穿大理岩条带,矿体未遭受区域变质作用,可推断矿化发生于366Ma之后.考虑到区域内的构造变形事件和大规模花岗岩类侵入和成矿作用的年龄数据集中在156～134Ma,峰值在138 Ma左右,认为西沟铅锌银矿床形成于晚侏罗世-早白垩世.5件成矿早阶段细粒黄铁矿具有较低的I_(Sr-138Ma0值(按138Ma计算的锶同位素初始比值),变化范围为0.7100～0.7151,平均0.7127,该值略高于晚侏罗-早白垩斑岩类和花岗岩基,明显低于太古代太华群变质基底、中元古代熊耳群安山质火山盖层和中-晚元古代栾川群和官道口群的片岩地层,但与赋矿围岩栾川群大理岩地层接近,表明碳酸盐地层变质脱水和晚侏罗-早白垩岩浆岩均有可能为早阶段成矿提供成矿流体.相比之下,主成矿阶段硫化物则更加富含放射成因锶;14个主成矿阶段粗粒黄铁矿测点的I_(Sr-138Ma)值范围为0.7152～0.7344,平均0.7247,13个闪锌矿测点的I_(Sr-138Ma)值范围为0.7108～0.7398,平均0.7283,这些硫化物I_(Sr-138Ma)值接近于或低于太古宙太华群、中元古代熊耳群和中-晚元古代官道口群和栾川群,表明这些地层的锶都有可能混入成矿流体.因此,上述研究表明成矿早阶段流体主要为壳源岩石的变质脱水流体或燕山期岩浆热液,而在主成矿阶段,通过水岩相互作用与浅源循环的大气水或建造水的混入,浅部盖层栾川群地层的成分较多地加入了成矿系统.     

西藏甲玛超大型铜矿区斑岩脉成岩时代及其与成矿的关系

甲玛铜多金属矿是冈底斯成矿带上资源储量达到超大型规模的又一个重要矿床,2010年7月已正式投产。产于矽卡岩、斑岩和角岩中的辉钼矿Re-Os定年已表明甲玛矿床的铜钼成矿时代集中于17~14Ma,而成岩时代的研究相对较少,尤其是矿区及外围大量出露的近南北向展布的斑岩脉。本文选取矿区铅山上52号平硐内的2件弱矿化斑岩脉样品,花岗斑岩(JM52-0)和花岗闪长斑岩(JM52-46.7),首次开展斑岩脉的锆石SHRIMP U-Pb定年,获得的²⁰⁶Pb/²³⁸U-²⁰⁷Pb/²³⁵U协和年龄分别为14.2±0.2Ma和14.1±0.3Ma,代表了甲玛矿区地表出露的近南北向展布的斑岩脉侵位时岩浆锆石的结晶年龄。斑岩脉的成岩时代与区域上与近南北向正断层系统及裂谷裂陷带有关的冈底斯含矿斑岩侵位时代(18~12Ma)一致。甲玛的成岩成矿时代显示了成岩作用与成矿作用基本同期,且与冈底斯成矿带东段主要斑岩型-矽卡岩型铜多金属矿床的成岩成矿时代基本一致,成矿高峰集中在17~14Ma之间,指示了冈底斯在中新世的岩浆构造活动事件,而且表明了甲玛铜钼矿化与岩浆热液的成因联系。     

Rb-Sr Dating of Pyrite and Quartz Fluid Inclusions and Origin of Ore-forming Materials of the Jinshan Gold Deposit,Northeast Jiangxi Province,South China

The Jinshan gold deposit is located in the Northeast Jiangxi province,South China,which related to the ductile shear zone.It contains two ore types,i.e.the alteration-type ore and the goldbearing quartz vein ore.Rb-Sr age dating is applied to both gold-bearing pyrite in the alteration-type ore and fluid inclusion in the gold-bearing quartz vein to make clear the time of the gold mineralization of the Jinshan deposit.Analytical results of this study yielded that the age of the alteration-type ore bodies is about 838±110Ma,with an initial 87Sr/86Sr value of 0.7045±0.0020.However,the age of the gold-bearing quartz vein-type ore is about 379±49Ma,and the initial 87Sr/86Sr is 0.7138±0.0011.Based on the age data from this work and many previous studies,the authors consider that the Jinshan gold deposit is a product of multi-staged mineralization,which may include the Jinninian,Caledonian,Hercynian,and Yanshanian Periods.Among them,the Jinninian Period and the Hercynian Period might be the two most important ore-forming periods for Jinshan deposit.The Jinninian Period is the main stage for the formation of alteration-type ore bodies,while the Hercynian Period is the major time for ore bodies of gold-bearing quartz vein type.The initial values of the 87Sr/86Sr from this study,as well as the previous isotope and trace element studies,indicate that the ore-forming materials mainly derived from the metamorphic wall rocks,and the ore-forming fluids mainly originated from the deep metamorphic water.     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

张家口高家庄多金属矿床成矿时代厘定及其地质意义

太行山北东向构造-岩浆岩带中发育有多个燕山期酸性岩体,目前已发现的多金属及贵金属矿床与燕山期岩体有着密切的成因联系。本文对分布于大河南岩体北西侧的高家庄多金属矿床采用硫化物Rb-Sr法进行了同位素定年,(144.5±1.4)Ma等时线测年结果与采用锆石U-Pb法确定的大河南岩体形成时代接近;此外,矿床硫化物的初始锶同位素比值为0.7122~0.7123,显示成矿物质来源以壳源为主。这与大河南岩体主要为陆壳物质部分熔融形成的认识相一致,即高家庄多金属矿床在成矿物质来源上与大河南岩体的形成与演化之间具有密切的成因联系。大河南岩体的形成时限与区内多金属矿床形成时限与中国东部第二次大规模成矿期一致,此时区内地球动力学环境正处于主应力场由近南北向转换到近东西向的构造体制大转折时期。在此独特的成矿背景下,深熔作用形成的花岗质岩浆沿NNE向与原EW向断裂交汇处侵位。花岗质岩浆高侵位但未发生喷发作用,使挥发组分和成矿元素得以保存,从而为大规模成矿作用提供了必须的热、流体、挥发组分和成矿元素。     

贵州五指山特大型铅锌矿床闪锌矿的Rb-Sr定年及其地质意义

贵州五指山铅锌矿床为近年新勘探出的特大型铅锌矿床,其成矿时代不明,成因类型及控矿因素争议较大。本文测定的该矿床那雍枝矿段闪锌矿的Rb-Sr等时线年龄,为458. 2±2. 9Ma (MSWD=1. 07,n=5),初始~(87)Sr/~(86)Sr=0. 713823±0. 000010,表明矿床的成矿时代为中奥陶世晚期至晚奥陶世早期,晚于赋矿地层沉积时代。结合矿床地球化学及矿床地质特征,认为五指山铅锌矿床为典型的后生矿床,成因类型属密西西比河谷型(MVT)铅锌矿床。五指山铅锌矿床的形成与加里东构造运动紧密相关,与黔中隆起构造事件对应。基底断层构造及破碎带是成矿作用的内在控制因素,而加里东期华夏地块与扬子陆块之间的碰撞造山运动,即都匀运动及广西运动是五指山特大型铅锌矿床成矿作用的外因。     

云南保山金厂河铁铜铅锌多金属矿床Rb-Sr等时线测年及其地质意义

金厂河铁铜铅锌多金属矿床位于保山地块北部、NS向保山-施甸复背斜与NNW向澜沧江断裂锐角交汇部位的南部。矿体呈层状、似层状产于寒武系核桃坪组金厂河背斜的层间裂隙中,受NW向、NE向断裂交汇处的控制。选取闪锌矿及其共生的方铅矿、黄铜矿、石英样品,应用Rb-Sr同位素测年方法,获得闪锌矿等时线年龄为（118.9±5.9） Ma,闪锌矿+方铅矿等时线年龄为（119.3±1.7） Ma,闪锌矿+黄铜矿等时线年龄为（120.3±5.1） Ma,闪锌矿+石英等时线年龄为（117.0±2.4） Ma,闪锌矿+方铅矿+石英等时线年龄为（118.7±1.5） Ma,闪锌矿+方铅矿+黄铜矿等时线年龄为（119.6±1.6） Ma,闪锌矿+方铅矿+黄铜矿+石英等时线年龄为（118.9±1.4） Ma。Rb-Sr定年结果表明,金厂河铁铜铅锌多金属矿床的成矿时代为117~120 Ma,为早白垩世。热液矿物组合的 （⁸⁷Sr/⁸⁶Sr）_i平均值为0.713?885,与保山地块内志本山岩体的（⁸⁷Sr/⁸⁶Sr）_i值接近,指示其成矿物质主要来源于地壳,成矿作用与保山地块内燕山晚期花岗岩岩浆活动有关,结合矿区重力负异常特点,推测矿区内存在隐伏的中-酸性岩体。通过地球动力学背景探讨,认为该矿床的形成可能是对中特提斯洋闭合过程中腾冲地块与保山地块碰撞造山作用的响应,与地块内部受碰撞影响而导致地壳深熔所产生的岩浆作用有关。