内蒙古维拉斯托矿区花岗岩类地球化学特征及其构造意义

维拉斯托铜多金属矿床是近年来在大兴安岭发现的大型银铜多金属矿床,为了深入讨论维拉斯托矿区花岗岩类的大地构造环境及其形成的动力学背景,通过系统观察和分析,讨论了维拉斯托矿区钻孔内出露的黑云母花岗岩、黑云母二长花岗岩以及石英闪长岩的岩石学及地球化学特征。黑云母花岗岩及黑云母二长花岗岩具高硅特征,A/NCK平均值为1.07,里特曼指数小于3.3,属于钙碱性系列;稀土总量较高,轻重稀土元素分馏强烈,中等Eu负异常;(⁸⁷Sr/⁸⁶Sr)t值为0.705 93~0.710 75,ε_Nd(t)值为-4.45~-0.63,具有高分异I型花岗岩特征。石英闪长岩的SiO2含量中等,准铝质,高镁(3.12%~7.58%),高Cr、Ni;稀土总量较低,轻重稀土元素分馏不明显,弱Eu负异常;(⁸⁷Sr/⁸⁶Sr)t值0.705 05~0.707 68,ε_Nd(t)值在-0.88 ~1.04,具有赞岐岩的元素组成特点。黑云母花岗岩及黑云母二长花岗岩主要来源于年轻陆壳的部分熔融,上侵过程经历较强烈的分异作用;石英闪长岩来源于俯冲流体/熔体或残余洋壳部分熔融对岩石圈地幔改造后的产物,岩浆演化后期并未经历强烈的地壳混染及分异作用。综合研究认为：维拉斯托矿区花岗岩类侵位于晚石炭世,形成于后碰撞环境。兴蒙造山带内大量出露晚石炭世-早二叠世的钙碱性高分异I型花岗岩及A型花岗岩,同时大量沉积学及地层古生物的证据均显示兴蒙造山带该时期已经进入陆内演化阶段。     

新疆西天山北达巴特斑岩型铜钼矿床铅同位素组成及成矿物质来源示踪

北达巴特斑岩型铜钼矿床位于西天山造山带北部。矿区钼矿化分布于流纹斑岩体内部,铜矿化受断裂构造控制,分布于流纹斑岩与地层的接触带附近。据矿物组合特征与交代关系,将成矿过程划分为3个阶段：早期石英—辉钼矿阶段,中期黄铁矿—黄铜矿—石英阶段,晚期萤石—黄铜矿阶段。对早阶段辉钼矿与晚阶段黄铜矿分别进行了Pb同位素分析。辉钼矿的²⁰⁸Pb/²⁰⁴Pb值为38.125～38.179,²⁰⁷Pb/²⁰⁴Pb值为15.570～15.575,²⁰⁶Pb/²⁰⁴Pb值为18.293～18.311,Pb同位素构造判别投点落在地壳和地幔范围内,有向造山带线靠近的趋势,指示成矿物质主要来源于地幔,流纹斑岩提供了主要的钼来源。黄铜矿²⁰⁸Pb/²⁰⁴Pb值为38.202～38.257,²⁰⁷Pb/²⁰⁴Pb值为15.581～15.621,²⁰⁶Pb/²⁰⁴     

青藏高原羌塘东部尕考查锐-西恰赛索闪长岩体特征及构造意义

尕考查锐-西恰赛索闪长岩体由黑云母石英闪长岩和不等粒辉长闪长岩组成,其单颗粒锆石U-Pb年龄为183 Ma,形成于早侏罗世.岩石富铝,属钙碱性系列.微量元素特征表现为：富集大离子亲石元素K、Rb、Ba及高场强元素Th,相对于其他相邻元素而言,Nb、Ta、P、Ti、Y略显亏损,（⁸⁷Sr/⁸⁶Sr）_i值为0.70424~0.70581,而ε_Nd（t）值为-0.6~+21.6,形成于岛弧环境.     

中祁连西段黑沟梁子花岗岩的锆石U-Pb同位素年龄及成因

黑沟粱子花岗岩岩体为中祁连山带两段野马南山巨量花岗岩的一部分,出露于野马山南北缘,岩性为黑云母二长花岗岩。δ值、NK／A值、A／NCK值、Eu负异常、δEu值、ACF图解、⁸⁷Sr/⁸⁶Sr比值、εS_r、¹⁴⁷Sm／¹⁴⁴Nd比值、²⁰⁷Pb/²⁰⁴Pb比值、ENd值等岩石化学和同位素特征表明黑沟粱子花岗岩属钙碱性过铝质岩系,浆来源于地壳物质的重熔,具S型花岗岩特点。通过对黑沟梁子花岗岩的颗粒级锆石U-Pb同位素测年,获得²⁰⁶Pb/²³⁸U表面年龄统计权重平均值为(444±17)Ma。w(Nb)-w(Y)和w(Rb)一w(Y+Nd)图和R₁-R₂图解上两个样点均落入同碰撞花岗岩区,结合前人研究成果可以确定该岩体形成于板块碰撞阶段。该岩体的锆石U-Pb年龄的确定和成因的探讨对于深入研究祁连造山带的构造演化提供了一条重要的地质信息。     

湘东北栗山铅锌铜矿床二长花岗岩岩石成因及其氧逸度对成矿的指示意义

栗山铅锌铜矿床位于江南造山带多金属成矿带中段,是湘东北地区近几年发现的一大型矿床。本文对矿区内的黑云母二长花岗岩和二云母二长花岗岩进行了岩石地球化学、Sr-Nd同位素和黑云母矿物成分研究。岩石地球化学特征显示,两种二长花岗岩均属于高钾钙碱性系列。其中,黑云母二长花岗岩属于正常S型花岗岩,富集Rb、Th、K大离子亲石元素,亏损Ba、Nb、Ta、Sr、P、Ti高场强元素,有弱的Eu负异常,源区岩石为变质杂砂岩;二云母二长花岗岩属于分异的S型花岗岩,富集Rb、Th、U、K大离子亲石元素,亏损Ba、Nb、Sr、P、Ti高场强元素,Eu负异常大于前者,源区岩石为变泥质岩和少量变质杂砂岩。黑云母二长花岗岩的(⁸⁷Sr/⁸⁶Sr)_i值在0.7143～0.7159之间,ε_Nd(t)值介于-9.4～-8.5,两阶段模式年龄t_DM2变化范围为1631～1703 Ma;二云母二长花岗岩的(⁸⁷Sr/⁸⁶Sr)_i值在0.7156～0.7...     

云南金平铜厂金矿床地质特征和成矿物质来源

铜厂金矿床位于哀牢山造山带金平古生代盖层构造单元的中南部.金矿化分布于奥陶系下统复理石碎屑岩和志留系中-上统白云岩之间的北西走向断裂破碎带中.含金矿物主要为自然金和银金矿,附着于黏土矿物或赋存于石英、黄铁矿、毒砂裂隙和胶结物的颗粒间.矿石为细脉状、浸染状和团块状构造.围岩蚀变为碳酸盐化、硅化、绢云母化等.金矿石黄铁矿δ³⁴S为0.337‰~3.113‰,²⁰⁸Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁶Pb/²⁰⁴Pb分别为39.3814~40.1504、15.7093~15.7727和19.002~19.5492.矿区石英正长斑岩δ³⁴S为-1.118‰~-0.161‰,²⁰⁸Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁶Pb/²⁰⁴Pb分别是39.0817~39.2278、15.653~15.6805和18.8186~18.8612.金矿石黄铁矿的硫不是来源于石英正长斑岩,铅来源于上地壳.石英正长斑岩铅为上地壳和下地壳或上地幔混合来源铅.金矿床可能是在新生代岩浆-构造作用晚期,断裂构造中循环的热液汲取上地壳沉积围岩中的金等成矿物质形成的含矿流体,在断裂构造带压力和温度较低部位通过充填和交代作用形成的.     

西藏冈底斯中段晚侏罗世许如错花岗岩成因：锆石U-Pb年龄、地球化学及Sr-Nd-Pb-Hf同位素证据

西藏冈底斯中段晚侏罗世许如错花岗岩的岩石成因对理解特提斯洋演化具有重要的意义。本次系统研究了许如错地区似斑状黑云母二长花岗岩的岩石学、锆石U-Pb年代学、锆石Lu-Hf同位素、全岩元素地球化学和Sr-Nd-Pb同位素。许如错花岗岩的锆石U-Pb年龄为152.3±0.7 Ma,形成于晚侏罗世。SiO₂和Al₂O₃质量分数较高,平均值分别为71.3%和14.2%,铝饱和指数（A/CNK）较高（1.10～1.23）,属于强过铝质高钾钙碱性系列岩石;富集大离子亲石元素（Rb, Th和K）、轻稀土元素和Pb等;亏损高场强元素（Nb, Ta, Ti和P）,重稀土元素,Eu, Sr和Ba等。锆石εHf（t）值（-12.5～-16.9）、全岩⁸⁷Sr/⁸⁶Sr_（t）初始值（0.715～0.717）、εNd（t）值（-14.2～-14.5）和Pb同位素初始值(²⁰⁸Pb/²⁰⁴Pb_（t）,²⁰⁷     

西准噶尔包古图含矿岩体矿物学特征及意义

西准噶尔包古图铜金矿带位于达拉布特岛弧南部,包古图地区的一些小型斑岩体与铜金矿化关系非常密切,其岩性以闪长岩和石英闪长岩为主.矿物学研究发现,本区斑岩体中角闪石具镁角闪石成分特征,黑云母属镁质黑云母,斜长石为中长石.矿物化学成分显示含矿斑岩的成岩物质主要来源于地幔,并有少量地壳物质加入.本区岩石类型属钙碱性花岗岩类,与俯冲作用有关,是相对高温(800℃)和较高氧逸度条件下的产物.据含矿岩体矿物化学成分估算,包古图含矿岩体的形成压力范围在230～390 MPa.     

冀北大滩盆地钾玄岩系列的厘定、岩石成因及与铀成矿关系

大滩盆地位于华北克拉通北缘隆起带和沽源—红山子铀成矿带西南段,盆地内五里营铀矿点赋存在义县期(早白垩世晚期)二长斑岩中。二长斑岩全岩为高钾、富碱、低钛、贫铁,富集轻稀土元素和大离子亲石元素,无明显Eu负异常,具有碱性系列和钙碱性系列的特征,属典型的钾玄岩系列;[n(⁸⁷Sr)/n(⁸⁶Sr)]_i为0.707290～0.707399(平均值为0.707343),[n(¹⁴³Nd)/n(¹⁴⁴Nd)]_i为0.511849～0.511895(平均值为0.511876),ε_Nd(t)值变化范围是-12.38～-11.49,[n(²⁰⁶Pb)/n(²⁰⁴Pb)]_i为17.236～17.343(平均值17.296),[n(²⁰⁷Pb)/n(²⁰⁴Pb)]_i为15.407～15.428(平均值为15.416),[n(<...     

安徽金寨县沙坪沟钼矿成矿岩体矿物学特征及其成岩成矿意义

安徽金寨县沙坪沟钼矿成矿岩体主要包括二长花岗斑岩、正长斑岩及花岗斑岩,主要矿物组成为石英、钾长石、斜长石、黑云母。本文利用电子探针技术对主要矿物的矿物学特征进行了研究,结果表明,岩石中斜长石为钠长石;钾长石以条纹长石为主;黑云母属于镁质黑云母,富Mg、Al、K,贫Ca,MF值变化于0.65~0.72之间。黑云母化学成分显示本区岩体为I型花岗岩,属于造山带钙碱性花岗岩类,其成岩物质具壳幔混合的特点。黑云母矿物温压计计算结果显示,岩体固结温度约500~580℃,氧逸度变化范围是10-14~10-15.8,其含铁指数对寻找钼矿具较好的指示意义。     

太行山木吉村斑岩铜(钼)矿床岩石地球化学、Sr-Nd-Pb同位素特征及其地质意义

木吉村斑岩铜(钼)矿床位于太行山北段涞源杂岩体的腰部,是太行山构造-岩浆-成矿带的一个重要矿床。在野外调研的基础上,对木吉村斑岩铜(钼)矿床含矿岩体进行了系统的岩石学、地球化学和Sr-Nd-Pb同位素研究。结果表明：木吉村矿床的含矿岩体闪长玢岩为高钾钙碱性I型侵入岩,具有较高的SiO₂、Al₂O₃、Sr含量和Sr/Y比值以及(La/Yb)_N,较低的Yb、Y的特征;稀土元素配分曲线呈右倾趋势,轻稀土相对富集,轻重稀土分异明显,具微弱的正Eu异常;微量元素蛛网图中富集大离子亲石元素Ba、K、U、Sr,亏损高场强元素Nb、Ta、P、Ti,总体显示出与埃达克岩相似的地球化学特征。闪长玢岩的I_Sr为0.705 386~0.706 838,ε_Nd(t)为-16.7~-14.9,²⁰⁸Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb、²⁰⁶Pb/²⁰⁴Pb的平均值分别为36.614、15.226、16.545,与木吉村矿床矿石中的硫化物铅同位素数值基本一致,Sr-Nd-Pb同位素共同表明其岩浆形成可能与有深源基性物质参与的古老下地壳部分熔融有关。结合研究区地质背景,认为木吉村含矿岩体可能主要来自古老下地壳的部分熔融,并受到幔源物质的混染作用。     

松辽盆地徐家围子断陷营城组粗面岩成因与隐爆机制

松辽盆地徐家围子断陷营城组火山岩中含有粗面质岩石,是深层天然气重要储层之一。岩心、钻井及地震资料研究表明,粗面岩具有高位喷发、低位充填的特征,在火山口附近厚度大,远离火山口厚度小。粗面岩主量、微量及同位素地球化学显示其属于钾玄岩系列,富集稀土元素,强不相容元素Rb、Ba、Th、U质量分数较高。粗面岩的(⁸⁷Sr/⁸⁶Sr)_i=0.704 321~0.705 395,ε_Nd(t)为正值（3.36 ~ 3.83）,Pb同位素比值相对集中,(²⁰⁶Pb/²⁰⁴Pb)_i、(²⁰⁷Pb/²⁰⁴Pb)_i、(²⁰⁸Pb/²⁰⁴Pb)_i平均值分别为18.43、15.51和38.23。研究表明,粗面质岩浆由区域年轻地壳组分部分熔融形成,经历了一定程度的分离结晶作用,地壳混染作用不显著。粗面质岩浆多期次喷发后形成粗面岩,热液气体不断聚集发生隐蔽爆破形成角砾,未固结的角砾被岩浆期后热液“胶结”,形成隐爆角砾岩,构成了粗面质岩石重要的储层类型。     

Geochemistry of the Rio Espinharas hybrid complex, northeastern Brazil

The Rio Espinharas pluton, northeastern Brazil, belongs to the shoshonitic series and consists mainly of syenogranite, quartz–monzonite and porphyritic quartz–monzonite, but diorite, quartz–monzodiorite, quartz–syenite and microsyenogranite also occur containing microgranular enclaves, except for the diorite. Most variation diagrams of rocks, amphiboles, biotites and allanites show linear trends, but K, Zr, Sr and Ba of rocks display curved scattered trends. The rocks ranging from diorite to syenogranite define a pseudo-errorchron and have similar REE patterns. Syenogranite and microsyenogranite are derived from two distinct pulses of granite magma with initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7083±0.0003 and 0.7104±0.0007, respectively. Modelling of major and trace elements shows that the syenogranite evolved by fractional crystallization of plagioclase, microcline, edenite, biotite and titanite, whereas quartz–monzonite, porphyritic quartz–monzonite, quartz–monzodiorite and quartz–syenite resulted from simple mixing between an upper mantle-derived dioritic magma and the upper crust-derived syenogranite magma. Dioritic enclaves are globules of a mafic magma from the upper mantle.     

Modeling of subduction components in the Genesis of the Meso-Cenozoic igneous rocks from the South Shetland Arc, Antarctica

Isotope data and trace elements concentrations are presented for volcanic and plutonic rocks from the Livingston, Greenwich, Robert, King George and Ardley islands (South Shetland arc, Antarctica). These islands were formed during subduction of the Phoenix Plate under the Antarctica Plate from Cretaceous to Tertiary. Isotopically (⁸⁷Sr/⁸⁶Sr)_o ratios vary from 0.7033 to 0.7046 and (¹⁴³Nd/¹⁴⁴Nd)_o ratios from 0.5127 to 0.5129. εNd values vary from +2.71 to +7.30 that indicate asthenospheric mantle source for the analysed samples. ²⁰⁸Pb/²⁰⁴Pb ratios vary from 38.12 to 38.70, ²⁰⁷Pb/²⁰⁴Pb ratios are between 15.49 and 15.68, and ²⁰⁶Pb/²⁰⁴Pb from 18.28 to 18.81. The South Shetland rocks are thought to be derived from a depleted MORB mantle source (DMM) modified by mixtures of two enriched mantle components such as slab-derived melts and/or fluids and small fractions of oceanic sediment (EM I and EM II). The isotopic compositions of the subduction component can be explained by mixing between at least 4 wt.% of sediment and 96 wt.% of melts and/or fluids derived from altered MORB.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Isotopic equilibrium/disequilibrium in granites, metasedimentary rocks and migmatites (Damara orogen, Namibia)—a consequence of polymetamorphism and melting

The overwhelming part of the continental crust in the high-grade part of the Damara orogen of Namibia consists of S-type granites, metasedimentary rocks and migmatites. At Oetmoed (central Damara orogen) two different S-type granites occur. Their negative ε_Nd values (− 3.3 to − 5.9), moderately high initial ⁸⁷Sr/⁸⁶Sr ratios (0.714–0.731), moderately high ²⁰⁶Pb/²⁰⁴Pb (18.21–18.70) and ²⁰⁸Pb/²⁰⁴Pb (37.74–37.89) isotope ratios suggest that they originated by melting of mainly mid-Proterozoic metasedimentary material. Metasedimentary country rocks have initial ε_Nd of − 4.2 to − 5.6, initial ⁸⁷Sr/⁸⁶Sr of 0.718–0.725, ²⁰⁶Pb/²⁰⁴Pb ratios of 18.32–18.69 and ²⁰⁸Pb/²⁰⁴Pb ratios of 37.91–38.45 compatible with their variation in Rb/Sr, U/Pb and Th/Pb ratios. Some migmatites and residual metasedimentary xenoliths tend to have more variable ε_Nd values (initial ε_Nd: − 4.2 to − 7.1), initial Sr isotope ratios (⁸⁷Sr/⁸⁶Sr: 0.708–0.735) and less radiogenic ²⁰⁶Pb/²⁰⁴Pb (18.22–18.53) and ²⁰⁸Pb/²⁰⁴Pb (37.78–38.10) isotope compositions than the metasedimentary rocks. On a Rb–Sr isochron plot the metasedimentary rocks and various migmatites plot on a straight line that corresponds to an age of c. 550 Ma which is interpreted to indicate major fractionation of the Rb–Sr system at that time. However, initial ⁸⁷Sr/⁸⁶Sr ratios of the melanosomes of the stromatic migmatites (calculated for their U–Pb monazite and Sm–Nd garnet ages of c. 510 Ma) are more radiogenic (⁸⁷Sr/⁸⁶Sr: 0.725) than those obtained on their corresponding leucosomes (⁸⁷Sr/⁸⁶Sr: 0.718) implying disequilibrium conditions during migmatization that have not lead to complete homogenization of the Rb–Sr system. However, the leucosomes have similar Nd isotope characteristics than the inferred residues (melanosomes) indicating the robustness of the Sm–Nd isotope system during high-grade metamorphism and melting. On a Rb–Sr isochron plot residual metasedimentary xenoliths show residual slopes of c. 66 Ma (calculated for an U–Pb monazite age of 470 Ma) again indicating major fractionation of Rb/Sr at c. 540 Ma. However, at 540 Ma, these xenoliths have unradiogenic Sr isotope compositions of c. 0.7052, indicating depleted metasedimentary sources at depth. Based on the distinct Pb isotope composition of the metasedimentary rocks and S-type granites, metasedimentary rocks similar to the country rocks are unlikely sources for the S-type granites. Moreover, a combination of Sr, Nd, Pb and O isotopes favours a three-component mixing model (metasedimentary rocks, altered volcanogenic material, meta-igneous crust) that may explain the isotopic variabilty of the granites. The mid-crustal origin of the different types of granite emphasises the importance of recycling and reprocessing of pre-existing differentiated material and precludes a direct mantle contribution during the petrogenesis of the orogenic granites in the central Damara orogen of Namibia.     

鄂东南地区鄂城岩体的时代、成因及其对成矿作用的指示

鄂城岩体位于鄂东南地区的最北部,是鄂东南地区的六大岩体之一.在该岩体的南缘接触带上产出了长江中下游地区最大的矽卡岩型铁矿床——程潮铁矿床.众多研究表明,程潮铁矿化与鄂城杂岩体的岩浆演化密切相关,然而目前对于成矿作用究竟是与花岗质岩还是闪长质岩有关仍存在争议.通过对鄂城杂岩体开展系统的锆石U-Pb年代学、元素地球化学和Sr-Nd-Hf同位素研究,结果表明该岩体主要由花岗岩、石英二长岩、花岗斑岩以及小面积的闪长岩组成,最早侵位于140±1 Ma（中粒闪长岩）,之后依次侵位形成了细粒闪长岩（132±2 Ma）、花岗斑岩（130±2 Ma）、花岗岩（中细粒花岗岩129±2 Ma,中粒花岗岩129±1 Ma）和石英二长岩（129±1 Ma）.根据全岩地球化学特征,鄂城杂岩体的岩石组成大致可以分为两组:（1）花岗岩类,包括花岗岩、花岗斑岩和角闪石英二长岩,钾质,具有高SiO₂,低TiO₂、FeO_t、MnO、MgO含量等特征;（2）闪长岩类,包括中、细粒闪长岩,钠质,具有低SiO₂,高TiO₂、FeO_t、MnO、MgO含量等特征.这些岩石均富集轻稀土元素（LREE）和大离子亲石元素（LILE,如Rb、Th等）,亏损高场强元素（HFSE,如Nb、P、Ti）等,且花岗岩类具明显的负Eu异常,而闪长岩类则无此特征.在同位素组成方面,鄂城花岗岩类具有较负的全岩ε_Nd（t）值（-11.7~-10.1）和锆石ε_Hf（t）值（-22.91~-9.83）,闪长岩类则具有稍高的全岩ε_Nd（t）值（-7.6）和锆石ε_Hf（t）值（-12.04~-4.69）.元素和同位素地球化学特征共同表明,鄂城花岗岩类属于高分异Ⅰ型花岗岩,且主要来源于古元古代基底物质的部分熔融作用,源区可能有少量幔源物质的加入;闪长岩类主要来源于富集岩石圈地幔,且经历了一定的分离结晶作用.年代学结果显示,鄂城花岗岩类和细粒闪长岩的侵位时间均与程潮铁矿床的主成矿期吻合.结合野外接触关系以及前人的研究,程潮铁矿化可能与上述两类岩石均密切相关.从整个鄂东南地区的成矿作用来看,随着岩浆源区壳源物质贡献的增大以及岩浆分异程度的增加,岩浆作用与铁矿化的关系也更加密切.      

Geochemical and Sr–Nd–Pb isotopic compositions of the Eocene Dölek and Sariçiçek Plutons, Eastern Turkey: Implications for magma interaction in the genesis of high-K calc-alkaline granitoids in a post-collision extensional setting

The major and trace elements and Sr–Nd–Pb isotopes of the host rocks and the mafic microgranular enclaves (MME) gathered from the Dölek and Sariçiçek plutons, Eastern Turkey, were studied to understand the underlying petrogenesis and geodynamic setting. The plutons were emplaced at  43 Ma at shallow depths ( 5 to 9 km) as estimated from Al-in hornblende geobarometry. The host rocks consist of a variety of rock types ranging from diorite to granite (SiO₂ = 56.98–72.67 wt.%; Mg# = 36.8–50.0) populated by MMEs of gabbroic diorite to monzodiorite in composition (SiO₂ = 53.21–60.94 wt.%; Mg# = 44.4–53.5). All the rocks show a high-K calc-alkaline differentiation trend. Chondrite-normalized REE patterns are moderately fractionated and relatively flat [(La/Yb)_N = 5.11 to 8.51]. They display small negative Eu anomalies (Eu/Eu = 0.62 to 0.88), with enrichment of LILE and depletion of HFSE. Initial Nd–Sr isotopic compositions for the host rocks are ε_Nd(43 Ma) = − 0.6 to 0.8 and mostly I_Sr = 0.70482–0.70548. The Nd model ages (T_DM) vary from 0.84 to 0.99 Ga. The Pb isotopic ratios are (²⁰⁶Pb/²⁰⁴Pb) = 18.60–18.65, (²⁰⁷Pb/²⁰⁴Pb) = 15.61–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.69–38.85. Compared with the host rocks, the MMEs are relatively homogeneous in isotopic composition, with I_Sr ranging from 0.70485 to 0.70517, ε_Nd(43 Ma) − 0.1 to 0.8 and with Pb isotopic ratios of (²⁰⁶Pb/²⁰⁴Pb) = 18.58–18.64, (²⁰⁷Pb/²⁰⁴Pb) = 15.60–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.64–38.77. The MMEs have T_DM ranging from 0.86 to 1.36 Ga. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data, in conjunction with the geodynamic evidence, suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, probably triggered by the upwelling of the asthenophere, and interacted with a crustal melt that originated from the dehydration melting of the mafic lower crust at deep crustal levels. Modeling based on the Sr–Nd isotope data indicates that  77–83% of the subcontinental lithospheric mantle involved in the genesis. Consequently, the interaction process played an important role in the genesis of the hybrid granitoid bodies, which subsequently underwent a fractional crystallization process along with minor amounts of crustal assimilation, en route to the upper crustal levels generating a wide variety of rock types ranging from diorite to granite in an extensional regime.     

安徽省铜陵桂山铜铅锌矿C-H-O-S-Pb 同位素地球化学特征及其意义

安徽铜陵桂山铜铅锌矿床是铜陵矿集区沙滩脚矿田内近年来新发现的以铜矿为主,伴生铅锌矿的中小型多金属矿床,该矿床的矿体主要赋存于三叠系南陵湖组灰岩与青山花岗闪长斑岩体接触带附近及花岗闪长斑岩体内。本文在对该矿床地质特征的研究基础上,对代表性（岩）矿石进行碳、氢、氧、硫、铅同位素研究分析,据此约束该矿床的成矿流体和成矿物质来源。研究成果显示, 桂山铜铅锌矿床中方解石样品中δ¹³C_V-PDB 值为−3.2‰～2.0‰ 间,δ¹⁸O_V-SMOW 为8.3‰～15.2‰ 间,石英流体包裹体水的δD_V-SMOW 为−112.6‰～−6.8‰,δ¹⁸O_V-SMOW 为10.5‰～14.7‰,矿石中硫化物δ³⁴S值变化范围为−0.9‰～4.1‰,具塔式分布特征,矿石铅中的²⁰⁶Pb /²⁰⁴Pb 比值为18.409～18.585,²⁰⁷Pb /²⁰⁴Pb 比值为15.588～15.703,²⁰⁸Pb /²⁰⁴Pb 比值为38.483～38.843,以上指示了桂山铜铅锌矿床的成矿流体主要来源于岩浆水,并有大气降水的加入。分异成矿流体的岩浆可能来源于地幔,且伴有上地壳物质混入的特点。岩浆-地幔的溶解作用,伴有地层中碳质的混入。     

内蒙古东乌旗阿尔哈达铅-锌-银矿床硫和铅同位素研究

阿尔哈达铅-锌-银矿床是近年来在内蒙古东乌珠穆沁旗境内发现的一处大型铅-锌-银矿床,其产出环境和形成机理为国内外矿床学家所关注。对该矿床代表性岩（矿）石样品进行了硫和铅同位素分析,并对其变化规律和成因意义进行了讨论。研究结果表明,围岩和矿石中硫化物δ³⁴S值变化范围为1.2‰～8.6‰,具有混源硫特征。根据共生硫化物对所确定的温度表明,该矿床的形成可划分为高温和中-低温两个阶段。17件矿石硫化物样品²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb比值变化范围分别为18.153~18.431,15.370~15.602和37.653~38.213,其平均值分别为18.271、15.464和37.873;3件围岩硫化物样品²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb比值变化范围分别为18.281~18.293,15.470~15.484和37.874~37.909,平均值分别为18.288、15.477和37.893。硫和铅同位素研究结果表明,阿尔哈达铅-锌-银矿床成矿物质分别来自泥盆系火山-沉积岩和印支期花岗岩。