大兴安岭南段早白垩世早期后碰撞构造环境——来自林西县兰家营子辉长闪长岩的证据

对大兴安岭南段林西县以北兰家营子辉长闪长岩开展了系统的岩石学、锆石年代学和地球化学分析,以揭示该岩体的成因,并探讨大兴安岭南段早白垩世大地构造背景。锆石U-Pb定年结果表明,该岩体的形成时代为145.6±0.6 Ma,为早白垩世早期侵入体。地球化学分析结果表明,该岩体SiO2含量为53.38%~54.45%,K2O含量为1.34%~1.43%,Na2O含量为3.85%~4.05%,铝饱和指数A/CNK值介于0.8~0.9之间,属于钙碱性偏铝质岩浆岩。岩石的MgO和TFe2O3含量分别为5.44%~5.73%和7.53%~8.33%相应的Mg#值介于36.96~38.24之间,结合斜长石的环带和辉石的包橄结构,认为岩石是幔源原始岩浆经历分离结晶作用的产物。岩石相对富集Rb、Ba等大离子亲石元素,亏损Nb、Ta等高场强元素,锆石εHf(t)介于5.4~9.0之间指示岩浆起源于亏损的受俯冲流体交代过的岩石圈地幔。兰家营子辉长闪长岩与林西地区同时代A型花岗岩构成双峰式岩浆岩组合指示它们是伸展环境的产物。综合区域地质资料,认为大兴安岭南段早白垩世早期岩浆岩的形成与蒙古-鄂霍茨克洋闭合引起的碰撞后伸展背景有关。     

大兴安岭南段小乌兰沟正长花岗岩成因:锆石LA?ICP?MS U?Pb年代学、地球化学及Hf同位素的制约

大兴安岭南段西坡发育有大量晚侏罗世-早白垩世花岗岩,深入讨论岩石成因对该地区中生代地球动力学背景及其构造演化的研究具有重要地质意义.报道了小乌兰沟正长花岗岩的锆石LA?ICP?MS U?Pb年龄,全岩地球化学及锆石Hf同位素数据.小乌兰沟正长花岗岩的锆石206Pb/238U加权平均年龄为139.4±0.7 Ma,属早白垩世. 样品主量元素表现为富硅、富钾的高钾钙碱性系列岩石,A/CNK值介于1.00~1.11之间,属弱过铝质. 微量元素富集Rb、Th、U等大离子亲石元素（LILE）和轻稀土元素（LREE）,强烈亏损Ba、Sr、P、Ti等高场强元素（HFSE）,Eu负异常明显（δEu=0.007~0.009）,Zr+Nb+Ce+Y值基本小于350×10-6,含磁铁矿,未见原生白云母和碱性暗色矿物,属高分异I型花岗岩. 小乌兰沟正长花岗岩ε_Hf（t）值介于+5.5~+8.9之间,Hf同位素模式年龄t_DM2变化于700~947 Ma之间.结合区域研究,小乌兰沟正长花岗岩为上元古界变基性岩与中奥陶统变中性岩在低压、高温条件下发生部分熔融作用形成,是蒙古-鄂霍茨克洋闭合后伸展作用的产物.      

大兴安岭南段毛登高分异碱长花岗岩成岩时代与地球化学特征SCIEI北大核心CSCD

毛登矿床位于内蒙古锡林浩特境内,是大兴安岭南段典型的钼铋锡铜矿床,产于阿鲁包格山杂岩体晚阶段侵位的碱长花岗岩和花岗斑岩以及下-中二叠统大石寨组火山角砾岩中。本文以碱长花岗岩为主要研究对象,开展了岩石地球化学、Sr-Nd-Hf同位素、锆石U-Pb定年和微量元素地球化学研究,以探讨成岩时代、岩浆结晶的物理化学条件及其对成矿的制约。研究显示,碱长花岗岩锆石结晶年龄为140.5±0.8Ma,侵位于早白垩世。岩体高硅,富碱,贫钙、镁、铝,富集Rb、F、Th、Nd、Sm、Zr和Hf等元素,亏损Eu、Ba、Sr、P、Nb、Ti和轻稀土等元素,轻、重稀土分馏较小,具稀土四分组效应。碱长花岗岩锆石Ti温度为654~817℃,Ce^(4+)/Ce^(3+)值为0.1~19,岩浆氧逸度lg f(O 2)为-25.7~-18.6,表明原生岩浆为高温、低氧逸度的熔体。岩体具较高的εNd(t)值(-0.1~+2.9)和正的εHf(t)值(+4.0~+9.3)以及年轻的二阶段模式年龄(t Nd DM2=699~940Ma;t HfDM C=600~936Ma),表明岩浆源区来自含大量幔源组分的新生地壳的部分熔融。碱长花岗岩经历了高度分异演化和熔体-流体作用,具高F、低氧逸度特征,是毛登矿区钼、铋、锡、铜金属矿化形成的重要先决条件。     

福建石狮白垩纪花岗岩与中基性脉岩的年代学与地球化学

在我国华南地区广泛发育了白垩纪岩浆活动,形成了大面积的花岗岩和多期侵位的中基性和酸性脉岩。其中中基性脉岩被认为是华南白垩纪多期伸展作用的标志之一。本文对采自福建沿海石狮地区的石狮和东埔两地的花岗岩和侵入的中基性脉岩进行了锆石U-Pb年代学和Hf同位素以及岩石元素地球化学研究。石狮地区的花岗岩和花岗闪长岩为中钾-高钾钙碱性、弱过铝质岩石,2个锆石U-Pb年龄分别为105.3±1.0Ma和105.1±0.5Ma,2个花岗岩的锆石εHf(t)为-0.9~+2.0;侵入的脉岩为辉绿岩和闪长岩,属于准铝质中钾-高钾钙碱性岩石,2个闪长岩的锆石U-Pb年龄分别89.5±1.5Ma和96.1±1.2Ma,脉岩的εHf(t)为+1.3~+5.0。石狮地区花岗岩和脉岩显示轻重稀土中等分馏和弱的Eu异常,花岗岩稀土总量明显低于脉岩,岩石大离子亲石元素富集、高场强元素亏损,显示岛弧岩浆岩的地球化学特征;微量元素判别(Ta/Hf-Th/Hf,Zr-Zr/Y)表明石狮地区的岩脉产于大陆边缘裂谷环境或板内构造环境,脉岩应是古太平洋俯冲的大陆边缘背景之上,俯冲结束后转入大陆边缘伸展作用的标志。福建沿海厦门-石狮-晋江地区的伸展作用发生在87~96Ma,与华南区域上多期伸展作用中~90Ma的伸展作用吻合。     

中条山地区涑水杂岩新太古代烟庄正长花岗岩年龄及成因:对华北克拉通地壳演化的制约

太古宙末期钾质花岗岩的广泛发育是陆壳成熟和稳定化的重要标志，对了解早期陆壳的形成与演化具有重要的意义.发育于华北克拉通南缘中条山地区涑水杂岩中的烟庄正长花岗岩的形成年龄和成因还没有被很好地限定，构造背景还存在争议.对烟庄花岗岩进行了锆石U-Pb年代学和Hf同位素以及全岩地球化学和Nd同位素研究.烟庄花岗岩锆石SHRIMP U-Pb年龄为2 515±7 Ma.岩石具有高硅(SiO₂=73.05%~74.85%)、高钾(K₂O=4.46%~5.86%)、富碱(ALK=8.32%~9.36%)、贫钙(CaO=0.55%~0.98%)、低TFeO*(0.73%~1.28%)和MgO(0.31%~0.52%)的特征，A/CNK=1.01~1.04，为弱过铝质的钾玄系列.稀土总量变化较大(ΣREE=63.80×10-6~250.02×10-6))，轻重稀土元素分异明显((La/Yb)_N=25.44~92.87)，Eu异常变化较大(Eu/Eu*=0.47~0.79).岩石低Sr、Ba，富集Rb、Th、U等元素，亏损Nb、Zr、Y、Yb、Cr、Co、Ni等元素，具有较高的Rb/Sr、Rb/Ba和Sr/Yb比值以及较低Sm/Nd和Nd/Th比值，具有高分异I型花岗岩的特征.烟庄花岗岩具有0附近的全岩ε_Nd(t)值，岩浆锆石具有正的ε_Hf(t)值(2.85~3.66)，两阶段Hf模式年龄为2 258~2 883 Ma，多数在2 600~2 883 Ma之间.结合其他方面研究，烟庄花岗岩具有同碰撞和后碰撞花岗岩的特征，推测为新生地壳在由挤压向伸展转换的构造背景下部分熔融所形成，可能有少量地幔物质添加.这期钾质花岗岩的形成，标志着华北克拉通太古宙末期强烈岩浆活动的结束以及稳定陆壳的形成.      

大兴安岭南段晚中生代侵入岩时空分布及主脊与东坡岩体特征对比

通过岩相学、地球化学、锆石U-Pb年代学对位于大兴安岭主脊上的马勒根坝岩体、朝阳沟岩体和大兴安岭东坡区域的野猪沟岩体、布敦化岩体的4个不同花岗岩岩体的岩石类型、主量和微量元素特征、年代学及构造背景进行对比分析,讨论了研究区在晚侏罗世—早白垩世的岩浆活动及地质背景。LA-ICP-MS锆石U-Pb年龄显示:主脊朝阳沟岩体和东坡布敦化岩体年龄分别为(154±1) Ma和(154.1±1.6) Ma,属于晚侏罗世岩体,主脊马勒根坝岩体和东坡野猪沟岩体年龄分别为(144.62±0.74) Ma和(140.2±2.7) Ma,属于早白垩世岩体。岩相学和地球化学特征显示:主脊岩体为高钾钙碱性-准铝质-过铝质花岗岩岩体,东坡岩体为钙碱性-高钾钙碱性-准铝质-弱过铝质TTG型岩体;主脊比东坡岩体更加亏损Ba、Nb、Sr、P、Ti、Eu元素,为高分异I型花岗岩,东坡岩体为正常的I型花岗岩。结合区域地质资料分析,认为在晚侏罗世—早白垩世伊泽奈崎板块NNW向俯冲和蒙古—鄂霍次克洋闭合共同作用于大兴安岭南段地区,在大兴安岭主脊形成断裂带,导致幔源岩浆上涌底侵下地壳而形成沿断裂带分布的花岗岩体;主脊处于碰撞向伸展环境过渡的时期,东坡区域此时应处于俯冲时期。     

内蒙古乌兰浩特地区二长花岗岩年代学、岩石成因及其构造环境

内蒙古乌兰浩特地区太平山嘎查岩体主要岩石类型为黑云母二长花岗岩。所测得的LA-ICP-MS锆石U-Pb年龄分别为127.4 Ma和125.6 Ma,属于早白垩世。太平山嘎查岩体的地球化学特征表明岩体属于弱过铝质、高钾钙碱性系列的高分异I型花岗岩。样品(P9-48-1)的锆石Hf同位素组成显示黑云母二长花岗岩的ε_(Hf)(t)=+8.60±0.57,两阶段亏损地幔模式年龄为511~748 Ma,说明其岩浆源区主要为新元古代—显生宙期间从亏损地幔新增生地壳的部分熔融。太平山嘎查岩体应形成于伸展构造体制,该伸展构造体制的产生可能与古太平洋板块向欧亚大陆下的俯冲有关。     

西天山晚石炭世岩浆混合花岗岩的确定及其地质意义——来自玉奇布拉克和乌图精河岩体的LA-ICP-MS锆石U-Pb年龄和岩石地球化学证据

西天山博罗科努地区的玉奇布拉克和乌图精河岩体中发育大量暗色闪长质包体,包体发育矿物相互包裹的嵌晶及岩浆冷凝矿物不平衡结构,同时出现淬冷形成的针状磷灰石,指示岩体形成过程经历了二元岩浆的混合作用。包体较寄主花岗岩有明显低的SiO_2、K_2O,高CaO、FeO~T和MgO,但二者的微量元素高度一致,相对富集Rb、Th、U、K等LILE,贫HFSE,亏损Sr、Nb、Ta、P和Ti等元素,为二元岩浆混合作用所致。经LA-ICP-MS锆石U-Pb定年,两个岩体寄主花岗岩和包体分别获得301 Ma、308 Ma和303 Ma、298 Ma的形成年龄,指示同期不同源岩浆活动并存。寄主花岗岩的ε_(Hf)(t)值分别为+4.20~+8.33和+4.97~+7.0;Hf陆壳模式年龄T C_(DM)为782~1045 Ma和863~998 Ma,揭示它们主要源自新元古代早期陆壳物质。包体的εHf(t)值分别为+2.75~+6.41和+4.63~+7.92,与区域上同期基性岩脉正的εHf(t)和εNd(t)值相当。结合区域上同期花岗岩类高ε_(Hf)(t)和ε_(Nd)(t)、中等n(~(87)Sr)/n(~(86)Sr)推断,该期花岗岩是新元古代早期陆壳物质部分熔融的岩浆与被消减带组分改造的略亏损岩石圈地幔岩浆混合作用的结果,并构成由晚石炭世高钾钙碱性花岗岩向早二叠世富钾花岗岩/或A型花岗岩转换的岩浆演化系列,表明晚石炭世—早二叠世期间西天山造山带转入后碰撞晚期向伸展转化的构造环境。陆壳伸展导致幔源基性岩浆上侵,诱发陆壳部分熔融产生壳源岩浆,二者混合形成晚古生代以来西天山最为广泛的花岗岩浆活动,成为区内一次重要的地壳垂向增生事件。     

马达加斯加Maevatanana金矿区花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义

马达加斯加中部Maevatanana、Andriamena和Beforona三条绿岩带共有上百处铬、镍、铁、金等金属矿点。对位于马达加斯加中北部绿岩带的Maevatanana西南部花岗岩体进行主量元素、微量元素、锆石LA-MC-ICP-MS U-Pb定年及Lu-Hf同位素分析。岩体主要由黑云母二长花岗岩构成,为准铝质到弱过铝质的高钾钙碱性系列花岗岩,富集Rb、Ba、K等大离子亲石元素(LILE),亏损Nb、Ta、Ti等高场强元素(HFSE),其稀土元素总量为∑REE=92.02×10-6,A/CNK=1.01。其内锆石LA-MCICP-MS U-Pb的年龄为739~767Ma,即中新元古代,其εHf(t)均为负值,揭示该矿区花岗岩体源区为陆壳。其中岩浆锆石和继承锆石的Hf同位素二阶段模式年龄相近,表明花岗岩源岩的形成时期和基底黑云角闪斜长片麻岩的原岩一致。地球化学性质显示花岗岩体为I型花岗岩,与埃达克岩类似。综合数据认为岩体形成于中-新元古代(824~720Ma)Rodinia超大陆裂解,伴随Mozambique洋闭合Tanzanian克拉通与印度Dharwar克拉通汇聚背景下的陆缘弧岩浆活动。     

内蒙古扎鲁特旗二长花岗岩LA-ICP-MS锆石U-Pb年龄、岩石地球化学特征及地质意义

本文对内蒙古扎鲁特旗二长花岗岩体开展岩相学、LA-ICP-MS锆石U-Pb年代学及地球化学研究,探讨岩体的形成时代、成因及地质意义。研究表明,二长花岗岩中的锆石U-Pb加权年龄分别为124±1 Ma和126±1 Ma,侵入时代为早白垩世。二长花岗岩中SiO_2含量为69.45%～73.64%,Na_2O和K_2O含量分别为3.16%～4.62%、3.78%～4.37%;铝饱和指数A/CNK介于1.00～1.25之间,属于高钾钙碱性过铝质高分异的I型花岗岩。同时,微量元素中K、Ba、Rb等大离子亲石元素以及Zr、Th、U、Hf等不相容元素呈现富集状态,P、Ti、Nb、Ta等高场强元素则亏损严重。结合区域构造演化背景,本文认为大兴安岭南段扎鲁特旗地区的伸展作用应主要与蒙古—鄂霍茨克造山带的伸展垮塌作用有关。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

Composition,formation conditions,and genesis of the Talatui gold deposit,the Eastern Transbaikal Region,Russia

The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag₂Te) and matildite (AgBiS₂). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...