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1.
报道了塔里木库鲁克塔格地区新元古代晚期花岗闪长岩和钾长花岗岩的锆石U-Pb年龄和Hf同位素组成。花岗闪长岩锆石U-Pb谐和年龄为630.1±1.3Ma,钾长花岗岩锆石U-Pb谐和年龄为630.6±1.3Ma。Hf同位素组成表明,这2种岩石主要来自古老(中)基性地壳的重熔,可能有部分地幔物质的加入。结合已有的研究表明,650~615Ma期间的岩浆活动代表了塔里木地块新元古代最晚期的岩浆活动,是Rodinia超大陆解体过程中的产物,与泛非造山事件无关。塔里木地块自新元古代中期到早寒武世,持续接受了被动大陆边缘沉积,表明在这一时期塔里木为冈瓦那大陆之外独立的大陆块体,或是位于冈瓦那大陆最边缘的稳定大陆块体。  相似文献   

2.
通过对藏南隆子-古堆一带广泛发育近东西走向的中基性脉岩较系统的地质年代学和岩石地球化学研究,3个基性脉岩的SHRIMP锆石U-Pb年龄为133~140.9Ma,代表了辉长岩的结晶年龄,而中性脉岩的SHRIMP锆石U-Pb年龄130±1.7Ma代表了闪长岩的结晶年龄。表明中基性脉岩属于钙碱性-碱性系列,总体富Ti O2,平均含量为3.08,LREE富集,轻重稀土分异较为明显,LILE略为富集,HFSE亏损不明显,属被动大陆边缘构造环境,可能代表了早白垩世新特提斯洋扩张引起喜马拉雅被动大陆边缘一侧裂解的产物。  相似文献   

3.
呼斯特岩体是新疆西天山博罗科努岛弧带上的一个与矽卡岩成矿有关的复式杂岩体,由二长花岗岩、花岗闪长岩、正长花岗岩、花岗细晶岩、闪长玢岩、辉长岩和中基性包体等组成。本文对该岩体不同岩相岩石开展了岩石学、锆石LAICP-MS U-Pb同位素定年和Hf同位素研究,探讨岩石成因及构造意义。锆石U-Pb定年结果表明,正长花岗岩、闪长玢岩、花岗闪长岩和二长花岗岩加权平均年龄分别为380.2±4.6Ma、372.8±5.9Ma、367.7±4.5Ma和366.2±4.5Ma,岩体侵位时代为晚泥盆世,在大约15Myr期间,至少发生了3~4次岩浆侵入。在地球化学组成上,除辉长岩外,岩体为准铝质-弱过铝质、高钾钙碱性-低钾(拉斑)系列的I型花岗岩,轻重稀土分馏明显,具Eu负异常;富集Th、U,亏损Ba、P和高场强元素(如Nb、Ta、Zr、Ti),为晚古生代北天山洋向南俯冲于伊犁地块背景下岩浆活动的产物。二长花岗岩锆石Hf同位素组成较为均一,εHf(t)值为1.3~3.0,二阶段Hf模式年龄为1171~1280Ma,远大于成岩年龄,说明原始岩浆从地幔分异后经历了较长时间的地壳滞留。研究认为,高钾中酸性岩(花岗岩、闪长玢岩和中基性包体)由元古代新生基性下地壳部分熔融而成,伴有受俯冲沉积物熔体交代的幔源岩浆混合。低钾花岗闪长岩高Sr、低Y和Yb,属O型埃达克岩,与同源的辉长岩一起由俯冲的大洋板片部分熔融形成,源岩为低钾的拉斑玄武岩。  相似文献   

4.
内蒙古乌兰浩特地区太平山嘎查岩体主要岩石类型为黑云母二长花岗岩。所测得的LA-ICP-MS锆石U-Pb年龄分别为127.4 Ma和125.6 Ma,属于早白垩世。太平山嘎查岩体的地球化学特征表明岩体属于弱过铝质、高钾钙碱性系列的高分异I型花岗岩。样品(P9-48-1)的锆石Hf同位素组成显示黑云母二长花岗岩的ε_(Hf)(t)=+8.60±0.57,两阶段亏损地幔模式年龄为511~748 Ma,说明其岩浆源区主要为新元古代—显生宙期间从亏损地幔新增生地壳的部分熔融。太平山嘎查岩体应形成于伸展构造体制,该伸展构造体制的产生可能与古太平洋板块向欧亚大陆下的俯冲有关。  相似文献   

5.
西天山哈勒尕提含矿花岗岩体位于准噶尔和伊犁地块间的西天山构造带内,其中赋含矽卡岩型铁铜矿床。岩体由闪长岩、花岗闪长岩和二长花岗岩组成。二长花岗岩LA-ICP-MS锆石U-Pb年龄为(357.9±1.3)Ma,时代为晚泥盆世。岩石地球化学特征表明,闪长岩和花岗闪长岩属贫钾富钠准铝质的I型花岗岩,二长花岗岩类则属贫钠富钾的过铝质S型花岗岩。岩相接触关系、地球化学特征表明,其不是同源岩浆分异结晶的产物,应源于长英质-基性麻粒岩相下地壳的分层熔融和先后侵入形成的。结合区域演化历史,西天山哈勒尕提含矿花岗岩体形成于大陆边缘弧环境,地幔动力学为靠俯冲带陆一侧的地幔上隆引起下地壳局部熔融和有少量地幔物质加入的模式。  相似文献   

6.
杨帆  姜艳艳  陈井胜  韩兴 《岩石学报》2022,(8):2467-2488
本文对华北克拉通北缘中段赤峰撰山子矿区二长闪长岩、花岗(斑)岩等进行了岩相学、地球化学、锆石U-Pb定年以及Hf同位素研究,以期对古亚洲洋演化形成制约。锆石U-Pb定年显示,二长闪长岩和花岗岩形成于早石炭世(341.0±2.2Ma、324.1±4.3Ma),花岗斑岩形成于晚二叠世(252.8±3.2Ma、252.0±1.5Ma)。岩石地球化学及Hf同位素表明,二长闪长岩为高钾钙碱性I型花岗岩,形成于火山弧环境,其源区可能是俯冲板片脱水交代的地幔楔部分熔融产生玄武质岩浆上涌,导致新生地壳物质的部分熔融,并有部分玄武质岩浆加入形成的产物;花岗岩及花岗斑岩均为高钾钙碱性A型花岗岩,花岗岩形成于火山弧环境,花岗斑岩形成于造山后伸展环境,二者皆为新生地壳部分熔融的产物。综合前人研究认为,早石炭世-晚二叠世,研究区经历了古亚洲洋俯冲、弧-陆碰撞以及造山后伸展等阶段。  相似文献   

7.
为了解晚古生代西伯利亚板块南缘增生造山过程中的岩浆活动特征及其对贺根山洋盆闭合时间的制约,对东乌旗巴彦都兰闪长岩、二长花岗岩岩相学、锆石U-Pb年代学、锆石Hf同位素和岩石地球化学进行了研究,并讨论了岩石成因和构造环境。闪长岩、二长花岗岩锆石U-Pb同位素年龄依次为(319.8±0.9)Ma、(300.8±1.7)Ma,分别侵位于晚石炭世、早二叠世地层。闪长岩以正的锆石εHf(t)(13.5~17.1)为特征,具有年轻的锆石地壳模式年龄(tDMc)(335~466 Ma),明显富集Rb、K等大离子亲石元素(LILE),亏损Ba、Sr,相对亏损Ta、Nb和Ti等高场强元素(HFSE),为洋壳俯冲阶段,地幔楔混入并与年轻洋壳部分熔融形成。二长花岗岩以高钾、富碱、弱过铝质为特征,富集部分大离子亲石元素(LREE、Rb、K等);Zr弱负异常、Hf弱正异常,亏损Sr、Nb、Ta、P、Ti,显示后造山花岗岩特征。二长花岗岩形成于伸展构造环境,是贺根山洋盆闭合后后造山阶段的产物,为洋壳俯冲形成的先成地壳部分熔融而成。  相似文献   

8.
辽西-辽南地区新太古代花岗质岩石的锆石LA-ICP-MS U-Pb年代学和微量元素及全岩地球化学和锆石Hf同位素研究为探讨华北克拉通东北部前寒武纪地壳生长和演化提供了制约。结果表明,辽西地区钓鱼台二长花岗岩和辽南地区城子坦片麻状石英闪长岩、安波花岗质片麻岩中锆石均发育岩浆生长环带,结合相对高的Th/U比值(0.24~1.75)和锆石稀土元素特征,暗示它们均为岩浆锆石。定年结果显示,钓鱼台二长花岗岩、城子坦片麻状石英闪长岩和安波花岗质片麻岩的原岩分别形成于2519±9Ma、2505±10Ma和2519±11Ma,即它们均形成于新太古代晚期。辽西-辽南地区新太古代花岗质岩石均具有高SiO2(61.85%~73.38%)、低MgO(0.36%~2.83%)、富Na2O+K2O(7.64%~10.86%)的特征,为准铝质-弱过铝质的高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素,发育弱的Eu负异常和Sr、P、Ti的亏损。岩浆锆石均具有正的εHf(t)值,介于0.4~5.9之间,tDM1变化于2595~2798Ma之间,峰值年龄为2740Ma,与华北克拉通最重要的一次地壳增生事件相一致。辽西-辽南地区新太古代花岗质岩石形成于板块俯冲的弧构造环境下新增生下地壳物质的部分熔融。  相似文献   

9.
班公湖-怒江缝合带西段出露大量中酸性侵入岩,为特提斯洋俯冲、拉萨地块与羌塘地块碰撞造山过程中岩浆响应的重要组成部分。本文对该缝合带西段阿翁错地区的闪长岩、花岗闪长岩和花岗岩进行了详细的岩石地球化学和锆石U-Pb年代学研究。锆石LA-ICP-MS U-Pb定年结果表明闪长岩、花岗闪长岩、花岗岩成岩年龄分别为119.3±1.8 Ma、114.7±1.4 Ma和103.2±1.3 Ma。岩石地球化学特征显示中酸性侵入岩属高钾钙碱性系列,具准铝质-弱过铝质I型花岗岩特征;其LREE分馏程度较高,而HREE近于平坦,存在Eu负异常;富集Rb、La等大离子亲石元素和Th、Zr、Hf等高场强元素,亏损Nb、Ta、P、Ti等高场强元素,具有岛弧岩浆岩的特征。研究结果表明在早白垩世晚期(103.0±1.3 Ma)班公湖-怒江特提斯洋壳仍在向北俯冲于南羌塘地块之下,随着俯冲深度增加,大洋板片发生大规模脱水,释放的流体交代地幔楔并引发其部分熔融,产生的幔源岩浆向上运移,与下地壳物质不同比例混合形成了闪长岩和花岗闪长岩;而花岗岩主要由古老下地壳物质部分熔融形成,并有少量地幔物质的参与。  相似文献   

10.
基于详细的野外调查,对四川新龙地区不同类型侵入岩进行了岩石学、地球化学和锆石U-Pb同位素测年,探讨其岩石成因及构造背景。研究表明,古隆巴花岗闪长岩和日果闪长岩同属准铝质系列,具有低硅碱、高铁镁特征,中等的稀土元素总量及明显的Nb、Ta负异常,属于I型花岗岩,为俯冲期岩浆活动产物,获得日果闪长岩锆石U-Pb年龄为217.1±0.8 Ma,形成时代为晚三叠世。日里隆巴花岗闪长岩和花岗岩属于过铝质系列,具有高硅碱、低铁镁及弱的Nb、Ta负异常,均属于S型花岗岩,但后者经历了更高程度的分异,分别为碰撞期和后碰撞期岩浆活动的产物,获得日里隆巴花岗闪长岩锆石U-Pb年龄为203.6±0.5Ma,形成时代为晚三叠世末。结合区域资料认为,晚三叠世甘孜-理塘洋盆大规模向西俯冲,少量的弧岩浆岩就位于被动大陆边缘雅江残余盆地;晚三叠世末期,由于洋板块的消亡发生弧-陆碰撞,地壳发生部分熔融,形成强过铝质花岗岩。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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