四川盆地西缘长兴期海绵生物礁的发现及其地质意义

在四川盆地西缘首次发现较大规模的晚二叠世长兴期海绵礁,造礁生物主要由钙质海绵的Peronidella cf.regulara和Grossotubenella irregulara组成。该生物礁的发现对于四川盆地的油气勘探和古地理恢复具有重要意义。     

川东北地区不同构造带地层水化学特征与油气保存的关系

判断油气藏保存条件的优劣,除了盖层和断层封闭性之外,还有油气水的化学特征,如地层水的交替或油气散失。通过对川东北地区地层水的水型、矿化度、水性系数等参数的综合分析认为,川东北宣汉—达县地区与通江—南江—巴中地区的地层水具有矿化度高和氯镁系数越大,变质系数、脱硫系数和碳酸盐平衡系数就越小的特点。矿化度、水性系数及水型的变化具有很好的一致性,表明该区存在有利于油气保存的水文地质条件。     

四川盆地北部长兴组生物礁地震响应特征与分布规律

井下钻探结果和地震资料表明四川盆地北部上二叠统长兴组生物礁发育,通过对典型井长兴组岩性与电性资料的分析,明确了生物礁的岩性与储层发育特征。根据井下生物礁及围岩岩性与电性资料并结合过井地震剖面反射波的几何特征,建立台地边缘生物礁的地震正演数值模型,通过对比生物礁模型地震正演记录与实际生物礁地震剖面,建立针对研究区台地边缘生物礁的地震响应特征模式。依据生物礁的地震响应特征对该地区连片二、三维地震测线开展地震相分析,通过已有钻井地震相与沉积相对应关系分析,指出了长兴组生物礁在该地区的分布规律。四川北部地区地震相与沉积相带具有良好的对应关系,存在环台棚-海盆相的台地前缘斜坡-台地边缘生物礁相-开阔台地相沉积体系,地震剖面上生物礁的外部形态呈丘状或透镜状,内部为杂乱反射特征;礁盖白云岩具有亮点反射特征,生物礁底界面出现上凸或者下凹反射现象,生物礁的上部地层具有披覆反射结构,四川盆地北部地区长兴组台地边缘生物礁相在台棚-海盆相东、西两侧沿北西向呈条带状展布,分布面积大于2000km~2,生物礁气藏勘探潜力巨大。     

华南二叠系生物礁的地层学意义初探

笔者于1982年研究湘甫上二叠统剖面时,发现郴县华塘乡三合、桐木桥、太排冲长兴组发育生物礁,具有明显岩隆地貌,南北线状断续延伸,长达40公里。礁体由浅灰色块状礁灰岩组成,造架生物为串管海绵;粘结生物有古石孔藻、管壳石;附礁生物有腕足类、有孔虫、钙藻等。二叠系生物礁遍及华南,空间分布不连续,时间延伸从西南往东北,层位渐趋抬高。因生物组合相似,岩石类型及基本层序可以对比。华南二叠系生物礁具有穿时性,持续性,还具有三度空间地层体的客观物质单位—组的性质。     

四川盆地东北部飞仙关组层序地层与储层分布

四川盆地东北部飞仙关组层序界面主要有水下间断不整合面及暴露侵蚀不整合面等两类界面，相当于Peter Vail的Ⅱ类层序界面。通过对南江桥亭及PG2井等典型剖面解剖，将飞仙关组划分为两个沉积层序，厘清层序与储层的关系：储层主要位于三级层序高水位体系域中，其中，第一层序的高水位体系域发育浅滩鲕粒白云岩储层，其构成了川东北地区飞仙关组储层主体，第二层序高水位体系域发育浅滩相鲕粒灰岩储层。建立飞仙关组层序地层格架，对储层二维空间分布进行预测认为，浅滩鲕粒白云岩储层主要分布于PG2井-宣汉渡口立石河之间，浅滩鲕粒灰岩储层主要分布于南江桥亭及CP82井等地。浅滩鲕粒白云岩储层分布广，区域上分布于通江-开县局限台地及其西侧，浅滩鲕粒灰岩储层主要分布在通南巴地区及东部城口-万源一带。     

达县-宣汉地区长兴组-飞仙关组礁滩相特征及其对储层的制约

通过对普光2井、普光6井和毛坝3井等钻井资料以及地震剖面的详细研究,可知长兴组—飞仙关组生物礁相在地震剖面上,形态为透镜状,具有透镜体、中强变振幅、杂乱影像特征。岩性为灰色障积海绵礁灰岩、灰色障积海绵礁白云岩、灰色骨架海绵礁灰岩、灰色骨架海绵礁白云岩等组成。滩相在地震剖面上表现为透镜体、中强变振幅、不连续影像特征,其岩性主要为浅灰色厚块状亮晶鲕粒白云岩、亮晶含砾鲕粒白云岩、亮晶含豆粒鲕粒白云岩、亮晶生屑白云岩及亮晶砂屑白云岩等。两者在空间上相伴生,沿着台地边缘分布,形成台地边缘礁滩相带,该相带控制了达县—宣汉地区储层的岩性、储集性及其空间分布。     

银额盆地哈日凹陷Y井油气地球化学特征与油气源对比

Y井是银额盆地哈日凹陷施钻的第一口揭示二叠系厚度较大的参数钻井,于二叠系试获天然气9.15×104m3/d(无阻流量),并产少量凝析油。在对Y井天然气及凝析油组分、同位素,以及凝析油生物标志化合物等分析的基础上,探讨了天然气和凝析油成因类型。结果表明,天然气为油型(腐泥型)凝析油伴生气,凝析油为高成熟腐泥型,生烃母质以水生生物为主,烃源岩演化进入高成熟阶段。将Y井凝析油与哈日凹陷周缘杭乌拉剖面出露的下二叠统埋汗哈达组烃源岩生物标志化合物特征进行对比,二者具有良好的亲缘关系,Y井凝析油及天然气源于二叠系,进一步证实了银额盆地石炭系—二叠系良好的油气资源前景。     

四川盆地东部中二叠统茅口组台内藻礁沉积特征

四川盆地东部月005-H1井发现了中二叠统茅口组三段中发育的小型台内藻礁。岩心分析表明,该生物礁以藻格架灰岩为主,造礁生物以叶状藻为主、见少量苔藓虫,含虫筳类、非虫筳有孔虫、腕足类、双壳类、海百合、棘皮类等附礁生物,藻片之间沉积有灰泥和少量生物碎屑。礁体纵向上发育两个较为完整的旋回,每个旋回发育四个成礁阶段,单个旋回厚度约1.5 m,每个旋回发育四个礁阶段,并可划分出礁基、礁核、礁盖(基)等亚相类型。认为该生物礁的形成与峨眉地裂运动引起的基底正断活动有关,形成于"堑—垒"构造格局的浅水型碳酸盐岩断隆之上。推测该类藻礁灰岩可能与茅口组古风化壳岩溶型储层关系密切。     

川东北地区石炭系成岩作用及储集性

川东北石炭系为一套蒸发性局限海潮坪沉积 ,仅残存中石炭统黄龙组。残厚在通江—南江—巴中地区为2 0 -m左右 ,且分布零星 ;开县—大竹—垫江一带为主要分布区 ,达县地区最厚 ,局部可达 70 -m。岩性主要为含粒屑微—粉晶白云岩、角砾状白云岩、膏岩及泥晶灰岩等。经历了白云石化、重结晶、溶蚀等成岩作用和构造作用 ,地层的溶蚀孔、晶间孔和裂缝发育 ,其储集性能得到了较大改善 ,成为川东北乃至川东地区碳酸盐岩地层中最重要的一套储集层。孔隙度大于 3%的储层分布范围也在开县—大竹—垫江构造上 ,呈北东向展布。宣汉以北 ,主要是由于双石庙、通江—南江—巴中地区石炭系地层变薄 ,因而储集性能较差。高产的沙罐坪气藏预示本区石炭系具良好的油气远景。     

川东黄龙场构造上二叠统长兴组生物礁特征与潜伏礁预测

通过黄龙场4口上二叠统长兴组钻井岩心剖面和其他井相关资料的详细研究,证实黄龙1井、4井有生物礁, 黄龙3井、5井无生物礁;生物礁由海绵障积岩组成,属于台地边缘礁。针对礁与非礁地层物性差异小,非均质性强, 多解性问题突出的特点,运用地质、测井和地震相结合的预测方法,确定了黄龙1井区的生物礁气藏发育边界,并发现了黄龙5井西侧生物礁气藏,为川东生物礁预测提供了一种实用的方法。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.