变形温度计的建立

一个变质岩地区的研究离不开对该地区岩石的变质和变形的研究。迄今为止世界上的地质温度计都只能用来研究变质作用的温度,而不能研究变形作用的温度。我们发现斜长石菱切面角温度计是一个形变温度计,它可以用来研究变形作用的温度。这是世界上第一个变形     

试论台怀运动——五台山区五台群地质问题的新发现

本文从变形与变质发展演化的基本观点出发,在对五台群进行较为深入地研究之后。认为五台山区五台群中存在着一个十分重要的地质界面——角度不整合。代表着本区地质构造演化历史中一次重要的地壳运动。它导致五台群的解体。命名为台怀运动。其发生的时代为太古代末。这个界面分为上下两个部分。其下部的角闪岩相的片麻岩系属太古界,取名为繁峙群,其上部绿片岩相为五台群,属下元古界,并且指出这两个岩群的多期变形与多期变质的一般概貌。     

中国蓝闪片岩相的变质作用

本文论述了中国蓝闪片岩的分布、变质条件及其构造位置。中国的蓝闪片岩从中晚元古代开始,各变质期均有出现。根据矿物组合,可分为两类:第一类蓝闪片岩常含有高压矿物,如硬柱石、硬玉和文石以及蓝闪石、绿纤石、黑硬绿泥石、多硅白云母、红帘石等,属高压亚绿片岩相,称蓝闪—硬柱石片岩相,形成温度约250—350℃,压力大于500—800MPa,甚至可达1200MPa。此类蓝闪—硬柱石片岩相多代表海洋板块古消减带。第二类蓝闪片岩的常见矿物为蓝闪石、青铝闪石或镁钠闪石、黑硬绿泥石、红帘石和绿片岩相中的绿帘石、阳起石、绿泥石、白云母、有时还有黑云母、铁铝榴石和钠质辉石。形成温度约350—450℃,压力500—800MPa。此类蓝闪绿片岩相虽处于活动带,但与板块构造没有直接关系。我国西藏南部和内蒙温都尔庙属第一类,但大部分蓝闪片岩带属第二类。     

内蒙古头道桥地区蓝闪石片岩和相关变质岩石岩石学特征及其构造意义

内蒙古头道桥地区出露了一套经高压变质形成的岩石组合。本次研究通过岩相学和矿物化学分析,根据矿物组合的不同,识别出蓝片岩、绿片岩两种不同类型的岩石类型。其中,蓝片岩的矿物组合为角闪石（蓝闪石、蓝透闪石）+绿帘石+钠长石+绿泥石+石英+赤铁矿±多硅白云母±方解石±榍石;绿片岩的矿物组合为绿泥石+钠长石+石英±绿帘石±角闪石（阳起石、镁角闪石、蓝透闪石、冻蓝闪石等）±多硅白云母±赤铁矿。确定了蓝片岩的峰期变质级别为绿帘-蓝闪片岩相,峰期变质温度为400~600℃,压力为1.2~1.4 GPa。绿片岩的峰期变质级别为绿帘-角闪岩相。结合前人研究成果,认为蓝片岩和绿片岩的形成与额尔古纳地块和兴安地块的碰撞拼合有关。     

黑龙江依兰地区蓝片岩相变质作用及其演化

依兰地区蓝片岩作为黑龙江杂岩的重要组成部分,其变质作用演化问题一直存在较大争议。本文通过对依兰地区蓝片岩的岩相学及矿物微区化学成分的研究,并运用PERPLE_X软件,在Na_2O-CaO-K_2O-MnO-FeO-MgO-Al_2O_3-SiO_2-H_2O-TiO_2-O(Fe_2O_3)(NCKMnFMASHTO)体系下对石榴石冻蓝闪石片岩(g-brs-wnc-act-phn-chl-ep-ab-stlp)、绿泥绿帘蓝闪石片岩(gl-brs-wnc-act-chl-ep-stlp)和白云母蓝闪石片岩(gl-wnc-phn-ab-ep-chl-sph)进行了相平衡模拟,并分别获得了500~525℃/1.14~1.2GPa、480℃/1.4GPa、450~500℃/0.95~1.2GPa峰期变质作用的温压条件,其峰期变质级别都达到了绿帘-蓝片岩相。结合前人发表的地球化学和年代学数据,建立了蓝片岩相岩石的顺时针变质演化P-T轨迹。研究区蓝片岩的形成标志着新生洋壳的俯冲作用,同时代表古亚洲洋构造域的结束和环太平洋构造域的开始。相平衡模拟中,P-T轨迹记录了峰期前温压条件递增的过程,温度峰期与压力峰期同时到达,说明蓝片岩相变质作用是在俯冲过程中实现的,而不是折返过程中达到的。减压阶段的轨迹近于平行追溯进变质轨迹,揭示与进变质过程相似的地热体制下(11～14℃/km),相对缓慢的抬升过程     

鄂北—豫南地区榴辉岩相岩石变质作用演化特征

鄂北－豫南地区榴辉岩相变质岩石类型多样，其野外产状和岩石化学特征反映了原地变质成因。根据区域地质及榴辉岩相变质岩石的野外产状，结合榴辉岩中石榴石绿辉石的Ｆｅ２＋－Ｍｇ互换温度计所计算出的峰期变质温度，将本区榴辉岩分为两类，一类为中温榴辉岩，产于晚太古界—早元古界大别群，为Ｂ类榴辉岩，由绿帘角闪岩相岩石进变质形成。榴辉岩相变质作用分为两阶段，首先为柯石英榴辉岩相阶段，其峰期变质条件为Ｔ＝６００℃～７００℃，Ｐ＝２．７～３．０ＧＰａ，然后近等温降压，出现蓝闪石等含水矿物，为蓝闪石榴辉岩相阶段，此时水活度在榴辉岩相变质过程中起着重要作用；另一类为低温榴辉岩，产于中元古界七角山组，为Ｃ类榴辉岩，由蓝片岩相岩石进变质形成，其峰期变质条件为Ｔ＝４９０℃～５６０℃，Ｐ＜１．５ＧＰａ。中温榴辉岩与低温榴辉岩具有不同的变质作用特征。最后讨论了本区高压变质带的成因演化。     

五台山腹地早前寒武纪变质岩中白云母的初步研究

五台山早前寒武纪变质岩中的白云母属二八面体的2M型多型变体,其中五台群中的白云母为富含绿鳞石分子的普通白云母,滹沱群为多硅白云母。通过对这些白云母化学成分和b_0值测定,确定五台群变质条件属中低压相系,滹沱群属中高压相系。五台群绿片岩相的变质压力为0.3—0.5 GPa,滹沱群为0.5—0.6 GPa。基于白云母成分和b_0值的研究,对划分变质级别、变质类型;确定变质作用期次;进行地层对比和构造分析等方面是可行的。     

陕甘川交界区碧口群的变质作用及其地质意义

碧口群由一套中晚元古代的变质双峰式火山岩及复理石型深积岩组成，其变质作用分为蓝片岩相和绿片岩相。据其野外分布及白云母ｂ０值的变化可分成Ａ、Ｂ、Ｃ三个变质带。蓝片岩相以钠质闪石＋绿帘石共生为特征，在Ａ带的大面积绿片岩中呈条带或残片状分布。对区内的角闪石、绿泥石、绿帘石及白云母等矿物及其间的交代关系研究表明蓝片岩和绿片岩并非同一物理化学条件下的产物。蓝片岩相的温度为３００－４００℃，压力为０．５－０．     

新疆西南天山哈布腾苏河高压-超高压变质带中榴辉岩和蓝片岩的岩石学及变质演化

对西南天山哈布腾苏河一带出露的典型榴辉岩和蓝片岩进行了详细的岩相学、矿物化学和温压条件综合研究。榴辉岩可分为蓝闪石榴辉岩、钠云母榴辉岩、绿帘石榴辉岩和蓝闪石榴角闪岩(退变榴辉岩)4类,蓝片岩可分为含蓝闪石石榴白云母钠长片岩、石榴白云母蓝闪片岩和石榴白云母蓝闪石英片岩3类。新鲜榴辉岩主要矿物组合为石榴石+绿辉石+钠云母+绿帘石,退变榴辉岩则为石榴石+蓝闪石+角闪石;蓝片岩主要矿物组合为石榴石+蓝闪石+多硅白云母+钠云母+钠长石+石英。榴辉岩和蓝片岩中石榴石变斑晶均保存进变质生长环带,从核部到边部XMn和XFe降低,XMg和XCa升高,指示了升温进变质的演化过程。根据榴辉岩矿物共生组合、石榴石内部包体组合分布特征及传统地质温压计估算结果,确定榴辉岩经历了4阶段的变质演化:早期硬柱石蓝片岩相进变质阶段、峰期榴辉岩相变质阶段(t=543～579℃,p=1.5～1.6 GPa)、峰后绿帘蓝片岩相退变质阶段(t=～450℃,p1.0GPa)和晚期蓝闪绿片岩相退变质阶段(t400℃,p0.5 GPa)。利用p-T视剖面图计算的榴辉岩、蓝片岩峰期变质温压条件与传统地质温压计估算结果十分相近,其中榴辉岩的峰期变质条件t=520～550℃,p=1.7～1.9 GPa;蓝片岩峰期变质条件t=520～620℃,p=1.7～2.3 GPa。本文估算的榴辉岩峰期变质压力条件与前人根据柯石英的发现而认为研究区部分榴辉岩及其围岩曾经历超高压变质作用的认识明显相悖,原因可能如下:①后期退变质作用引起研究区榴辉岩全岩成分、矿物化学成分的调整,在采用Grt-Cpx-Phe温压计和以全岩成分为基础的相平衡模拟方法估算峰期温压条件时受到影响,从而使估算峰期压力条件普遍偏低;②西南天山的榴辉岩可能并非全都经历了超高压变质作用,高压、超高压榴辉岩可能分别代表了不同变基性岩块在不同俯冲深度变质的产物。     

关于大别山榴辉岩相变质作用

大别山产出的榴辉岩相岩石包括石榴橄榄岩、榴辉岩、榴云片岩、榴辉片麻岩、榴玉英岩和榴辉大理岩等不同系列,它们均分布于花岗质片麻岩中。矿物共生序列研究表明,榴辉岩相岩石经历了从绿帘角闪岩相、柯石英榴辉岩相、角闪榴辉岩相、绿帘角闪岩相到绿片岩相的演化过程。花岗质片麻岩及变质火山—沉积岩系并未经历超高压变质作用,但却与榴辉岩相岩石经历了同一期绿帘角闪岩相变质事件,证明二者在地壳范围内发生了构造合并     

糜棱岩化过程中矿物变形温度计

对有效确定中—低温下糜棱岩变形温度一直以来都没有比较理想的方法，而在研究韧性剪切带过程中对其变形温度的确定又常是必不可少的。根据近年来国际上对天然石英、长石、方解石等矿物变形的研究成果，总结了利用矿物变形指示变形温度的方法。在不同的温度条件下，长石与石英的变形方式具有阶段性，其变形与动态重结晶型式与温度具有明显的对应关系。石英变形中的滑移系及其C 轴组构图主要受变形温度的控制。低温变形中的方解石e 双晶纹形态也与温度呈密切的相关性。观测这些矿物变形的显微构造，可以很好地估计韧性剪切带糜棱岩化过程中的变形温度。     

Assessment of the Garnet-Clinopyroxene Thermometer

A thermometer based on the MgFe_?1 exchange equilibrium between garnet and clinopyroxene is formulated by using new experimental data measured at 600° to 950°C, 0.8 to 3.0 GPa, and f(O₂) defined by the fayalite-quartz-magnetite buffer in the basalt-H₂O system. The new formulation is T = 3820 / 1.828 + lnK_D (1 + a(2.2 ? p)), where T is temperature (K), P is pressure (GPa), KD is the Fe-Mg partition coefficient between garnet and clino-pyroxene, defined as KD = (Fe²+/Mg)garnet/(Fe²+/Mg) clinopyroxene, and a = 132/T. Application of the thermometer to rocks in amphibolite, granulite, and eclogite terranes yields temperatures that are in reasonable agreement with other well-calibrated thermometers and the experimental calibrations by Ellis and Green (1979) and Pattison and Newton (1989).     

中国大气降水的氧同位素温标

中国北部中 高纬度地区大气降水δ1 8O与地面气温的相关性与中国其他地区不同 ,前者是正相关 ,后者是负相关。海口与香港的年均δ1 8O 温度系数为 - 0 .42‰ /℃ ,二者都属于热带季风型气候。高纬度地区年均δ1 8O 温度系数与月均系数相近 ,约为 0 .4‰ ℃ ,例如 ,兰州 0 .35‰ ℃ ,张掖 0 .46‰ ℃ ,乌鲁木齐 0 .42‰ ℃。中纬度地区石家庄月均δ1 8O 温度系数 (0 .11‰ ℃ )小于年均δ1 8O 温度系数 (0 .34‰ ℃ )。华北平原古大气降水δ1 8O 古地面气温系数为 0 .36‰ ℃ ,与石家庄现代大气降水年均δ1 8O 现代年均地面气温系数相近。因此 ,中国中高纬度地区大气降水的年均δ1 8O 温度系数 ,可用作氧同位素温标再造当地古气温。     

Monazite-Xenotime-Garnet Equilibrium in Metapelites and a New Monazite-Garnet Thermometer

Prograde suites of pelitic rocks were examined with electronmicroprobe and laser ablation inductively coupled plasma massspectrometry to determine the systematics of element partitioningbetween coexisting monazite, xenotime, and garnet. Monazitegrains that grew in equilibrium with xenotime are enriched inY and Dy compared with monazite that grew in xenotime-absentassemblages. Y and heavy rare earth element contents of monazitecoexisting with xenotime increase with rising temperature. Monazite–xenotimeY–Gd and Y–Dy partitioning is systematic withina metamorphic grade, and increases slightly with increasingmetamorphic grade, suggesting that monazite–xenotime pairsapproached partitioning equilibrium. Garnet and monazite inboth xenotime-bearing and xenotime-absent assemblages show astrong ( R² = 0·94) systematic relationship between inversetemperature and ln(K_Eq) for the net-transfer equilibrium YAG+ OH-Ap + (25/4)Qtz = (5/4)Grs + (5/4)An + 3YPO₄-Mnz + 1/2H₂O,suggesting that garnet and monazite crystallized in compositionalequilibrium. The following temperature–K_Eq relationshipfor the equilibrium above has been derived:      

金红石Zr温度计在苏鲁-大别榴辉岩研究中的应用：问题讨论

金红石Zr含量温度计在苏鲁-大别超高压榴辉岩中的应用普遍得出了比峰期变质温度明显偏低的温度值。通过对比国内外的研究,并结合岩相学的分析,认为除了超高压可能使金红石对Zr的容纳度降低外,较强的退变质和流体作用下的扩散丢失是造成金红石Zr含量降低的主要原因。同一样品不同金红石颗粒之间Zr含量和温度的显著差别说明金红石与共存锆石和石英之间的Zr配分平衡已受到退变质作用的破坏且未能达到再平衡,金红石Zr含量温度代表的是每个颗粒受不同程度退变质和扩散影响后的某个缓冲状态,其平均温度的地质意义很难界定。只有将金红石的赋存状态、岩相学分析等研究与数据本身的均匀性分析结合起来进行综合判断,才有可能对金红石Zr温度计给出合理解释。     

An Improved Set of a--X Parameters for Fe--Mg--Ca Garnets and Refinements of the Orthopyroxene-Garnet Thermometer and the Orthopyroxene--Garnet--Plagioclase--Quartz Barometer

An internally consistent set of activity-composition relationsfor Fe-Mg-Ca garnets constrained from calorimetric and phaseequilibrium experiments provides the basis for refining theorthopyroxene-garnet thermometer and the orthopyroxene-garnet-plagioclase-quartzbarometer based on the equilibria FeSiO₃ + 1/3Mg₃Al₂Si₃O₁₂ = MgSiO₃ + 1/3Fe₃Al₂Si₃O₁₂ (A) Mg₂Si₂O₆ + CaAl₂Si₂O₈ = 2/3 Mg₃Al₂Si₃O₁₂ + 1/3 Ca₃Al₂Si₃O₁₂+ SiO₂ (B) Fe₂Si₂O₆ + CaAl₂Si₂O₈ = 2/3 Fe₃Al₂Si₃O₁₂ + 1/3 Ca₃Al₂Si₃O₁₂+ SiO₂. (C) The major modification arises from better constrained valuesof mixing parameters for the pyrope-almandine binary. Thermodynamicanalysis of reversed experimental data on Fe-Mg partioning betweenorthopyroxene and garnet (Kawasaki & Matsui, 1983; Lee &Ganguly, 1988), when combined with the enthalpy of solutiondata for the pyrope-almandine binary (Geiger et al.t 1987),yields and AGIT of the exchange reaction as cal in the temperaturerange 1248–1573 K. The retrieved data, combined with the known thermochemical parametersfor the pyrope-grossular and almandine-grossular binaries andcomplementary phase equilibrium data, have been used to estimatetemperatures from equilibrium (A) and pressures from equilibria(B) and (C). The geothermometer registers temperatures higherby 70–100C than those obtained from Harley's (1984) formulationand 20–40?C lower than those from Lee & Ganguly's(1988) formulation for granulite grade rocks; the scatter inestimated temperatures for all areas is lower when comparedwith the other two formulations. The estimated pressures from(B) and (C) are reasonable for granulite grade rocks in thepressure range 3.0–12.0 kb and agree, in most cases, within? 1000'b. The smaller scatter in the computed temperatures and convergenceof calculated pressure values support the claim that the formulationspresented here represent improved versions of the orthopyroxene-garnetgeothermometer and the orthopyroxene-garnet-plagioclase-quartzgeobarometer.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

Inter-regional correlation of transgressions and regressions in the Cretaceous period

Well investigated platforms have been selected in each continent, and the history of Cretaceous transgressions and regressions there is concisely reviewed from the available evidence. The factual records have been summarized into a diagram and the timing of the events correlated between distant as well as adjoining areas.On a global scale, major transgressions were stepwise enlarged in space and time from the Neocomian, via Aptian-Albian, to the Late Cretaceous, and the post-Cretaceous regression was very remarkable. Minor cycles of transgression-regression were not always synchronous between different areas. Some of them were, however, nearly synchronous between the areas facing the same ocean.Tectono-eustasy may have been the main cause of the phenomena of transgression-regression, but certain kinds of other tectonic movements which affected even the so-called stable platforms were also responsible for the phenomena. The combined effects of various causes may have been unusual in the Cretaceous, since it was a period of global tectonic activity. The slowing down of this activity followed by readjustments may have been the cause of the global regression at the end of the Cretaceous.     

The lamprophyres of Afyon stratovolcano,western Anatolia,Turkey: description and genesis

The Afyon stratovolcano exhibits lamprophyric rocks, emplaced as hydrovolcanic products, aphanitic lava flows and dyke intrusions, during the final stages of volcanic activity. Most of the Afyon volcanics belong to the silica-saturated alkaline suite, as potassic trachyandesites and trachytes, while the products of the latest activity are lamproitic lamprophyres (jumillite, orendite, verite, fitztroyite) and alkaline lamprophyres (campto-sannaite, sannaite, hyalo-monchiquite, analcime–monchiquite). Afyon lamprophyres exhibit LILE and Zr enrichments, related to mantle metasomatism.