中条山涑水杂岩中TTG片麻岩的锆石Hf同位素特征及其形成环境

中条山前寒武纪涑水杂岩主要由西姚和寨子英云闪长质-奥长花岗质-花岗闪长质(TTG)片麻岩、横岭关和北峪钙碱性花岗质岩石组成。SHRIMP锆石U-Pb年代学研究表明,西姚石英闪长质片麻岩~(207)Pb/~(206)Pb加权平均年龄为2536±8Ma,是新太古代的产物;西姚和寨子TTG片麻岩及横岭关和北峪钙碱性花岗质岩石岩浆锆石Hf同位素组成ε_(Hf)(t)全为正值,且在t-ε_(Hf)(t)图解上,落在2.6～3.1Ga地壳演化线范围内。北峪钙碱性花岗质岩石中三个继承锆石核的~(207)Pb/~(206)Pb加权平均年龄为2633±84Ma,其锆石ε_(Hf)(t)值为-2.0～ 5.6。前寒武纪涑水杂岩中花岗质岩石的SHRIMP锆石U-Pb年代学和锆石Hf同位素特征揭示它们最可能形成于新太古代到古元古代,岩浆主要来源于约2650Ma初生地壳的部分熔融,并有更古老的地壳物质的加入。     

华北克拉通新太古代早期构造热事件的响应:来自左权地区ca.2.7Ga TTG片麻岩的证据

新太古代早期是全球地质历史上一个重要的地壳生长时期,世界众多克拉通中广泛存在2. 7Ga左右的岩浆年龄记录。华北克拉通最主要的岩浆事件发生在新太古代晚期,这与世界其他克拉通广泛存在～2. 7Ga的构造热事件明显不同。但全岩Nd和锆石Hf同位素研究表明,华北克拉通～2. 5Ga的岩石主体来自于中太古代晚期-新太古代早期大陆物质的重熔或再造。因此,厘定～2. 7Ga地质事件在华北克拉通的空间分布对深入理解新太古代地壳形成与演化具有重要科学意义。华北克拉通已识别出的～2. 7Ga的花岗质岩石主要分布在胶东、鲁西、武川、赞皇和太华等少数杂岩区,中部带的恒山、阜平和中条杂岩中亦有零星出露。左权变质杂岩位于中部带中南段,赞皇杂岩西南,初步地球化学和锆石年代学研究表明,该地区有多种岩石类型记录了～2. 7Ga的年龄信息,包括副片麻岩、长英质浅色体、磁铁矿角闪片麻岩和TTG片麻岩。其中,TTG片麻岩的原岩为英云闪长岩,锆石发育明显的核边结构,核部具有清晰的岩浆环带,两个不同LA-ICP-MS实验室获得的不一致线上交点年龄分别为2727±14Ma和2731±12Ma,代表了TTG岩浆岩的结晶年龄。同时,左权变质岩石中较好地保存了新太古代晚期的岩浆和变质年龄记录,推测其所代表的构造热事件与华北克拉通～2. 5Ga所经历的大规模幔源岩浆的底侵作用有关。     

华北克拉通阜平杂岩新太古代-古元古代多期地质事件及其构造性质

本文收集了阜平杂岩新太古代早期-古元古代晚期基底岩石的岩石地球化学、锆石U-Pb年代学、同位素地球化学和变质作用资料,以期对阜平杂岩早寒武纪演化历史进行初步总结.阜平新太古代早期~2.7 Ga片麻岩原岩为英云闪长岩,具有TTG质片麻岩的地球化学特征;其锆石ε_Hf（t）具有较高的正值（+5.44~+7.50）,单阶段模式年龄为2 745~2 824 Ma,表明新太古代早期为阜平杂岩强烈的地壳生长时期.新太古代晚期片麻岩的时代集中于2 543~2 484 Ma,主要岩石类型为英云闪长岩-奥长花岗岩-花岗闪长岩（TTG）,同时区域内还存在二长花岗岩.TTG质片麻岩的ε_Nd（t）值为-1.64~+0.96,单阶段模式年龄为2.76~3.04 Ga;锆石ε_Hf（t）值为-1.9~+7.91,单阶段和两阶段模式年龄分别为2 546~2 888 Ma和2 548~3 119 Ma.这些TTG岩石主要为新太古代早期岩石的部分熔融,并有少量中太古代地壳物质参与.近于同期具有岛弧性质的辉长岩和变质作用暗示阜平杂岩新太古代晚期可能经历了俯冲和弧-陆或陆-陆碰撞.古元古代中期（2.1~2.0 Ga）阜平地区花岗质岩浆活动强烈.该阶段花岗岩具有A型花岗岩特征,与同期的火山-沉积岩系形成于华北克拉通古元古代中期伸展的陆内裂谷环境中.阜平杂岩中基性麻粒岩包体记录的变质作用时代为1.89~1.85 Ga,并具有顺时针演化的P-T轨迹,其代表了古元古代晚期裂谷闭合的陆内造山过程,表明华北最终克拉通化.      

抚顺南部早前寒武纪变质杂岩的地质事件序列

抚顺南部早前寒武纪变质杂岩是华北克拉通北缘辽北-吉南早前寒武纪变质地块的一个重要组成部分,主要由浑南群石棚子组角闪岩相变质火山岩、火山碎屑岩及相伴生的沉积岩等表壳岩系和侵位于其中的石英闪长质片麻岩、英云闪长质-奥长花岗质-花岗闪长质(TTG)片麻岩和花岗闪长岩-二长花岗岩-钾长花岗岩岩石组合组成。LA-ICP-MS锆石U-Pb同位素分析结果显示,侵位于表壳岩中的石英闪长质片麻岩样品12LN39-3的岩浆结晶年龄为2571±7Ma,指示存在老于该年龄的表壳岩系。英云闪长质片麻岩样品12LN04-1和奥长花岗质片麻岩样品13LB49-3的岩浆结晶年龄分别为2544±4Ma和2550±10Ma,记录了一期重要的英云闪长质-奥长花岗质片麻岩侵位事件。斜长角闪岩(样品12LN25-2)的岩浆结晶的最小年龄为2530±5Ma,指示另一火山喷发阶段。晚期钾长花岗岩样品12LN01-1和奥长花岗质片麻岩样品12LN27-1分别侵位于2522±4Ma和2518±23Ma,说明它们的岩浆作用发生于同一时期。而采自于晚期未变形侵入体的石英闪长岩样品12LN30-2的岩浆结晶年龄为2496±18Ma,与上述表壳岩和深成侵入体的主要变质作用(2510~2470Ma)同期发生。这些年代学结果表明,抚顺南部地区新太古代大规模的铁镁质火山喷发作用在大于2571±7Ma已经发生,紧接着2571±7Ma发生石英闪长质岩浆侵位,在2550±10Ma~2544±4Ma之间发生英云闪长质-奥长花岗质岩浆侵位。接下来铁镁质火山再度喷发(~2530±5Ma),随后为钾长花岗岩和奥长花岗质岩浆的侵位(2522±4Ma~2518±23Ma)。晚期为角闪岩相变质作用时期(2510~2470Ma),伴随一定规模的石英闪长岩侵位。     

内蒙古武川西乌兰不浪地区早前寒武纪变质基底锆石SHRIMP定年及Hf同位素组成

本文报道了华北克拉通西部武川西乌兰不浪地区太古宙变质基底的锆石SHRIMP年龄和Hf同位素组成。一个片麻状奥长花岗岩样品的锆石具核边结构,核部岩浆锆石和边部变质锆石的207Pb/206Pb加权平均年龄分别为2692±17Ma和2528±16Ma。对9个样品进行了锆石Hf同位素分析。新太古代早期(2692～2697Ma)片麻状奥长花岗岩(2个样品)的岩浆锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为4.78～8.83、2646～2780Ma和2632～2845Ma;新太古代二辉麻粒岩(2个样品)中的捕获锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为-2.30～8.62、2543～2954Ma和2529～3189Ma;新太古代变质深成岩(4个样品)的岩浆锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为-2.60～8.09、2529～2880Ma和2538～3089Ma;古元古代蓝晶石榴长英质片麻岩(1个样品)的碎屑锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为1.52～6.59、2432～2774Ma和2498～2925Ma。结合前人研究结果,可得出如下结论和认识:1)该区存在新太古代早期片麻状奥长花岗岩,太古宙岩石在新太古代晚期普遍遭受高级变质作用影响;2)新太古代早期为该区地壳形成主要时期,新太古代晚期则主要表现为陆壳物质再循环;3)作为阴山地块的典型代表,固阳-武川地区与华北克拉通东部太古宙基底十分类似,可能表明华北克拉通在新太古代晚期已成为统一的整体。     

内蒙古固阳地区角闪石等矿物分离结晶形成的新太古代TTG片麻岩——来自元素地球化学和热力学模拟的证据

内蒙古固阳地区存在大量的新太古代末期(石英)闪长质-英云闪长质-奥长花岗质-花岗闪长质(DTTG)片麻岩组合。LA-ICP-MS锆石U-Pb同位素测年得到了石英闪长质片麻岩和英云闪长质片麻岩的结晶年龄分别为(2 504±11)和(2 514±7)Ma,在石英闪长质片麻岩中同时得到了约2.6 Ga的继承锆石年龄。这些石英闪长质(D)片麻岩具有相对较低的w(SiO₂)(62.08%～62.62%)和Sr/Y值(23.3～39.8),w(MgO)(2.08%～3.06%)和w(TFe₂O₃)(5.43%～6.01%)相对较高,不具有或具有弱的Eu负异常(Eu/Eu^*为0.91～0.98),轻、重稀土元素分异相对不明显((La/Yb)_N为7.59～21.60),显示岛弧钙碱性岩石的地球化学特征。结合其锆石Hf同位素组成,本文认为其形成于相对低压较浅层次古老下地壳的部分熔融,同时有幔源熔体的加入。固阳新太古代末期英云闪长质-奥长花岗质(TT)片麻岩则显示较高的w(SiO₂     

华北克拉通~2.5Ga地壳再造事件：来自中条山TTG质片麻岩的证据

华北克拉通中部中条山区涑水杂岩是华北克拉通新太古代TTG质片麻岩地体之一。为了探讨华北克拉通新太古代构造-岩浆事件的性质及早前寒武纪地壳的形成和演化,选择涑水杂岩中TTG质岩石进行研究。研究表明这套TTG质岩石富Na、高Al、Sr,低Y、Cr、Ni含量。稀土元素配分曲线右倾,富Rb、Ba等大离子亲石元素,强烈亏损Nb、Ta等高场强元素。LA-ICP-MS锆石U-Pb定年结果表明,这套TTG质片麻岩形成于2553～2561Ma,属新太古代晚期产物。锆石Lu-Hf同位素分析结果显示εHf(t)为正值,两阶段模式年龄集中在2.7～2.8Ga。结合涑水杂岩中TTG质片麻岩的岩石地球化学特征,认为这套TTG片麻岩可能主要来自2.7～2.8Ga的下地壳镁铁质岩石在新太古代晚期的部分熔融,可能有少量的地幔物质加入。考虑同期发育大量花岗质岩石的事实,说明新太古代晚期在华北克拉通中部并不存在大规模的俯冲作用,华北克拉通在新太古代晚期已经基本成型。结合前人研究成果和本文锆石Lu-Hf同位素分析结果,提出中条山区～2.5Ga岩浆事件代表一期重要的陆壳再造事件。     

鲁西地区新太古代中期岩浆活动——新甫山与上港等岩体锆石SHRIMPU—Pb定年的证据

新甫山、上港岩体分布于鲁西新太古代早期泰山岩群和英云闪长质片麻岩、条带状英云闪长质片麻岩组成的古陆核的东北部。主要岩性为片麻状花岗闪长岩及片麻状奥长花岗岩。根据新的锆石SHRIMPU—Pb定年结果,片麻状花岗闪长岩形成年龄为（2613±12）Ma,片麻状奥长花岗岩形成年龄为（26234±9）Ma,为新太古代中期形成。在泰山桃花峪一下港之间出露的条带状英云闪长质片麻岩中奥长花岗质脉体锆石U—Pb年龄在2660～2600Ma。该期岩体是新太古代早期英云闪长质片麻岩发生变质作用与重熔岩浆作用的产物。     

鲁西栗杭地区新太古代地质剖面的解剖:野外研究和SHRIMP U-Pb锆石定年

以往对鲁西新太古代地质研究主要是区域性的,对于露头尺度上的深入研究还不多见.本文对鲁西泰山栗杭地区的地质剖面进行了详细的野外地质和锆石SHRIMP年代学研究.岩石十分新鲜,类型多种多样,现象丰富且复杂.条带状英云闪长质片麻岩和细粒英云闪长质片麻岩的岩浆锆石年龄分别为2.62 Ga和2.63 Ga,可解释为岩石的形成时代.另一条带状英云闪长质片麻岩的岩浆锆石和变质锆石年龄相近,均为~2.57 Ga,其地质意义需进一步工作来确定.奥长花岗质岩脉的形成时代为2.60 Ga.闪长质片麻岩侵入条带状英云闪长质片麻岩和奥长花岗质岩脉,岩浆锆石年龄为2.52 Ga,存在2.66~2.69 Ga外来锆石.研究表明,泰山地区存在不同时代（~2.7 Ga和~2.6 Ga）英云闪长质片麻岩,仅根据野外特征难以相互区别.该剖面所记录的岩浆构造热事件是鲁西地区新太古代地质演化的缩影,但缺失~2.7 Ga TTG岩石记录.      

北大别早白垩纪花岗岩类的Sm-Nd和锆石Hf同位素及其构造意义

大别造山带产出两期早白垩纪造山后花岗岩类:早期(≈132Ma)变形的角闪石英二长岩和斑状二长花岗岩具高钾的类埃达克岩的地球化学特征,形成于增厚地壳(>50km)的下地壳部分熔融;晚期(≈128Ma)未变形的花岗岩包括细粒二长花岗岩和钾长花岗(斑)岩,属于正常安山岩-英安岩-流纹岩系列岩石,它们形成于相对薄的地壳(<35km)的下地壳部分熔融。早期变形的花岗岩类中,角闪石英二长岩的(~(87)Sr/~(86)Sr)_i=0.7066～0.7076,ε_(Nd)(t)=-20.3～-27.8,类似于扬子下地壳基性麻粒岩的Sr-Nd同位素特征,其中白垩纪岩浆锆石(≈132Ma)Hf同位素初始比值(ε_(Hf)(t))和两阶段Hf模式年龄(t_(DM2))分别为-29.30.5和303065Ma;我们认为角闪石英二长岩源于锆石Hf模式年龄约3.0Ga的基性下地壳部分熔融。早期斑状二长花岗岩的(~(87)Sr/~(86)Sr)_i=0.7078～0.7083,ε_(Nd)(t)=-15.8～-20.0,类似于北大别英云闪长质-花岗质片麻岩的Sr-Nd同位素特征,其白垩纪岩浆锆石(≈132Ma)的ε_(Hf)(t)和t_(DM2)分别为-24.80.5和274434Ma。我们认为宽状二长花岗岩源于约2.7Ga的中酸性下地壳部分熔融。晚期未变形的花岗岩的(~(87)Sr/~(86)Sr)_i=0.7069～0.7105,ε_(Nd)(t)=-16.4～-22.1,类似于北大别英云闪长质-花岗质片麻岩的Sr-Nd同位素特征;其白垩纪岩浆锆石(≈128Ma)的ε_(Hf)(t)具有较大的变化范围(-25.2～7.4),主要峰值为-22.5±0.5,次要峰值为-16.3±0.7,并有少量正的ε_(Hf)(t)值5.8～7.4,与ε_(Hf)(t)值对应的t_(DM2)分别为2600±40Ma、2211±68Ma和743±130Ma。我们认为晚期未变形的花岗岩源于锆石Hf模式年龄约2.6～2.2Ga的中酸性下地壳部分熔融,源区夹杂新元古代新生的陆壳。在大别造山带垮塌之前(>132Ma),增厚地壳(>50km)的下地壳存在双层结构:锆石Hf模式年龄约为3.0Ga的基性下地壳基底和约2.7Ga的中酸性(英云闪长质-花岗质)上部下地壳.在大别造山带伸展垮塌的晚期阶段(≈128Ma),减薄的下地壳(<35km)主要为锆石Hf模式年龄约2.6～2.2Ga的中酸性(英云闪长质-花岗质)岩石,并夹杂少量新元古代Rodinia超大陆裂解时形成的新生陆壳。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.