华北克拉通南缘下汤地区古元古代构造热事件——地球化学特征、锆石SHRIMP U-Pb定年和Hf同位素研究

本文报道了华北克拉通南缘鲁山县下汤地区早前寒武纪变质基底岩石的地球化学、锆石定年和Hf同位素组成。上太华岩群两个变质沉积岩样品的变质锆石年龄为1.91~1.93 Ga,由于变质作用强烈改造,碎屑锆石真正的形成年龄难以确定。碎屑锆石ε_(Hf)(t)和t_(DMW(CC))(Hf)分别为-0.26~10.41和2244~2958 Ma。一个变质辉长闪长岩样品的捕获锆石年龄为2.32 Ga,变质锆石年龄为1.93 Ga。捕获锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-1.79~2.22和2695~2940 Ma。两个片麻状奥长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.30~1.30和2481~2764 Ma。一个片麻状正长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.67~2.40和2415~2788 Ma。结合地球化学和前人研究结果,可得出如下结论:(1)上太华岩群形成时代形成于古元古代早期;(2)进一步支持了该区存在约2.3 Ga岩浆作用的认识;(3)发现广泛分布的1.91~1.93 Ga壳源奥长花岗岩和正长花岗岩;(4)确定1.91~1.94 Ga变质作用在该区广泛发育。     

内蒙古大青山地区早前寒武纪变质岩的锆石Hf同位素组成和稀土模式

本文报道了内蒙古大青山地区早前寒武纪变质岩石的锆石Hf同位素和稀土组成。两个古元古代晚期（1.9～2.1 Ga）变质碎屑沉积岩样品中碎屑锆石的(n(176Hf)/n(177Hf))c、tDM1(Hf)和tDM2(Hf)分别为0.281079～0.281502、2548～3000 Ma、2612～3153 Ma和0.280916～0.281451、2533～2717 Ma、2600～3404 Ma; 一个古元古代早期（2.37 Ga）变质辉长岩样品中岩浆锆石的εHf(t)和tDM1(Hf)分别为1.50～6.68和2449～2647 Ma,表明大青山及邻区在新太古代晚期—古元古代早期存在强烈的构造岩浆热事件,既有地幔添加又有壳内再循环作用。三个样品的边部变质锆石εHf(t)、tDM1(Hf)和tDM2(Hf)分别为-9.49～3.91、2201～2686 Ma、2285～2887 Ma;-7.29～-2.42、2350～2540 Ma、2499～2740 Ma和-5.46～-0.53、2319～2507 Ma、2443～2687 Ma,Th/U比值普遍小于01。与核部锆石相比,边部变质锆石tDM2(Hf)变小,Th/U比值和稀土含量降低,但稀土模式十分类似。研究表明,变质锆石增生边的形成及其Hf同位素、稀土和U—Th组成受核部锆石和变质作用的双重制约。变质增生边的形成至少部分与核部锆石溶解以后的再结晶有关,变质流体起了重要作用。     

华北地台南缘张士英岩体的锆石SHRIMP U-Pb测年、Hf同位素组成及其地质意义

张士英岩体位于华北地台南缘,岩石类型包括钾长花岗岩、似斑状花岗岩和石英斑岩脉,其中只在钾长花岗岩中发育有暗色岩石包体,在包体和寄主岩中发育反映岩浆混合作用的岩石结构。钾长花岗岩、似斑状花岗岩和石英斑岩脉的SHRIMP锆石U-Pb年龄分别为107.3±2.4Ma、106.7±2.5Ma和101±3Ma。锆石Hf同位素分析结果显示,钾长花岗岩的锆石εHf(t)为-15.96～-20.80,单阶段模式年龄(tDM1)为1396～1643Ma,两阶段模式年龄(tDM2)为1880～2018Ma;似斑状花岗岩的锆石εHf(t)为-18.97～-22.18,tDM1为1512～1640Ma,tDM2为1925～2080Ma;除了一粒年龄为2.6Ga的锆石具有εHf(t)为-0.71、tDM1为2943Ma和tDM2为3036Ma的组成,石英斑岩的锆石εHf(t)为-23.41～-27.95,tDM1为1678～1896Ma,tDM2为2144～2330Ma。这些数据暗示,除了存在少量太古宙地壳物质的贡献外,张士英岩体的物质来源可能主要为1.9～2.3Ga期间形成的新生地壳,但也不排除古老地壳与富集地幔源混合的可能。综合分析前人研究成果表明,在太平洋板块俯冲方向发生转变的过程中,先存断裂带发生拉张。张士英岩体与中国东部同期岩浆活动一起可能形成于这种受断裂带控制的伸展环境。     

冀东地区新太古代晚期的岩浆事件与地壳增生:来自岩石地球化学和锆石年龄及Hf同位素的制约

在华北克拉通东部冀东的遵化-迁西-迁安地区广泛分布有新太古代晚期的斜长角闪岩(基性火山岩)、TTG片麻岩和紫苏闪长岩/紫苏花岗岩。锆石U-Pb同位素测定表明,该区的斜长角闪岩、TTG片麻岩和紫苏闪长岩/紫苏花岗岩几乎同时形成于2529±30Ma到2555±14Ma期间。这是华北克拉通新太古代晚期一次重要的岩浆事件,并紧随有2.5Ga左右的麻粒岩相变质作用。阴极发光图像显示,TTG片麻岩和紫苏闪长岩/紫苏花岗岩中一些锆石的核部为灰黑色,具杉树叶结构或无内部结构,意味着这些锆石核部的U-Th-Pb同位素体系在变质作用期间受到了干扰或重置,因此岩浆锆石核部的207Pb/206Pb加权平均年龄通常被解释为代表岩浆事件最年轻的年龄。新太古代晚期TTG片麻岩和紫苏闪长岩/紫苏花岗岩的岩浆锆石具有正的εHf(t)值(-0.08~9.49),计算的tDM1(Hf)模式年龄介于2572~2896Ma之间,峰值年龄为2.72Ga。这表明,TTG片麻岩和紫苏闪长岩/紫苏花岗岩的母岩浆是从亏损地幔源分异出来的,且2.7Ga是研究区和华北克拉通最重要的一次地壳增生事件。地球化学和岩石成因研究表明,本区的TTG片麻岩和紫苏闪长岩/紫苏花岗岩是由来自新生地壳基性岩石部分熔融形成的岩浆通过结晶分离形成的,其中角闪石是主要的分离相矿物。地幔柱模式更有利于解释本区TTG片麻岩和紫苏闪长岩/紫苏花岗岩的成因以及冀东地区的许多其他地质特征。     

华北克拉通南缘豫西下汤地区2.3 Ga岩浆作用和1.94 Ga变质作用

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成。岩石呈包体形式存在于中元古代花岗岩中。片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30Ga;岩石高SiO2和K2O,低ΣFeO、MgO和CaO,具稀土总量较高(ΣREE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu*=0.76)的稀土模式;εNd(t)(t=2.30Ga)=-0.75;tDM(Nd)=2.66Ga。黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25Ga;岩石低SiO2和MgO,高Al2O3和P2O5,具稀土总量高(ΣREE=373.4×10-6)、轻重稀土分离不强[(La/Yb)n=9.4]及较强负铕异常(Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25Ga)=-1.21;tDM(Nd)=2.75Ga。片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94Ga变质锆石年龄。片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30Ga)=-6.71～0.38,tDM1(Hf)=2627～2910Ma,tDM2(CC)(Hf)=2823～3255Ma。黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25Ga)=-19.58～-1.73,tDM1(Hf)=2664～3360Ma,tDM2(CC)(Hf)=2968～4011Ma。结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在一规模较大的约2.3Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的>2.7Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史。     

华北克拉通东北部新太古代晚期地壳生长:来自板石沟表壳岩年代学和Hf同位素的证据

对板石沟表壳岩中的斜长角闪岩和角闪片岩进行了锆石U-Pb年代学、地球化学以及Hf同位素分析,以探讨华北克拉通东北部新太古代晚期的构造环境和地壳演化。板石沟表壳岩主要岩石类型包括斜长角闪岩、斜长片麻岩、角闪片岩和磁铁石英岩,LA-ICP-MS锆石U-Pb测年显示斜长角闪岩(BA-1)岩浆锆石形成于2548±11Ma,绿帘角闪片岩(BA-6)岩浆锆石形成于2548±23Ma,代表了表壳岩的形成时代,在绿帘角闪片岩中识别出3颗年龄为2754±80Ma~2710±92Ma的捕获锆石,表明板石沟地区可能存在新太古代早期岩浆事件。斜长角闪岩和角闪片岩的原岩为玄武质火山岩,微量元素特征指示其形成于岛弧环境。Hf同位素分析结果显示斜长角闪岩εHf(t)为正值(0.29~8.89),单阶段模式年龄(tDM1)分布在2877~2469Ma之间,绿帘角闪片岩多具正的εHf(t)值(-0.78~8.03),tDM1介于2871~2544Ma,表明岩浆主要来源于亏损地幔,伴随少量古老地壳物质的再造,部分tDM1与207Pb/206Pb年龄相近,并同时具有高εHf(t)值的锆石反映板石沟地区新太古代晚期(2550Ma)发生过地壳增生事件。结合其他地区表壳岩研究成果,认为华北克拉通可能存在新太古代吉-辽-冀弧陆碰撞造山带,板石沟地区属于该造山带的一部分。     

蚌埠隆起区中生代花岗岩的岩石成因：锆石Hf同位素的证据

对蚌埠隆起区中生代不同时期的花岗岩中6个岩体的锆石LA-MC-ICP MS原位Hf同位素的研究,据此限定它们的岩浆源区和重建华北克拉通东南部的构造格架。结果表明,中生代不同时期的花岗岩中岩浆锆石的初始Hf同位素组成(ε_(Hf)(t))可以分成两组:第一组的女山(130Ma)和西庐山花岗岩(130Ma)的ε_(Hf)(t)值分别为-18.4和-16.1;第二组的曹山(110Ma)、锥山二长花岗岩(110Ma)和蚂蚁山花岗岩(110Ma)以及淮光花岗闪长岩(130Ma)的ε_(Hf)(t)值分别为-22.3、-23.1和-21.1以及-28.1,这些岩浆锆石低的ε_(Hf)(t)值表明它们可能来源于古老的大陆下地壳。女山和西庐山岩体中早古生代—新元古代继承锆石具有低的ε_(Hf)(t)值(-2.3～-7.7)和1.52Ga～1.79Ga的Hf同位素两阶段模式年龄,表明它们的岩浆源区主要以扬子克拉通下地壳物质为主。曹山、锥山和蚂蚁山以及淮光岩体中岩浆锆石的Hf同位素两阶段模式年龄为1.89Ga～2.58Ga,结合淮光岩体中古元古代继承锆石和3400Ma捕获锆石中低的ε_(Hf)(t)值(-5.7～-6.8,-0.6、-0.9)和古老的Hf同位素两阶段模式年龄(2.44Ga～2.80Ga,3.7Ga),表明它们主要来源于华北克拉通下地壳物质的部分熔融。淮光和女山岩体中古元古代—新太古宙继承锆石中正的ε_(Hf)(t)值(0.3～6.7)以及高的ε_(Hf)(t)值(16.9～21.7)的存在,暗示形成这些古老继承锆石的初始物质中有幔源物质的涉入。蚌埠隆起区深部地壳中扬子克拉通基底物质的存在暗示扬子克拉通可能沿着郯庐断裂带向西或北西方向俯冲于华北克拉通之下。     

2.3 Ga Magmatism and 1.94 Ga Metamorphism in the Xiatang Area,Southern Margin of the North China Craton——Evidence from Whole-rock Geochemistry and Zircon Geochronology and Hf Isotope

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成.岩石呈包体形式存在于中元古代花岗岩中.片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30 Ga;岩石高SiO2和K2O,低∑FeO、MgO和CaO,具稀土总量较高(∑REE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu(*)=0.76)的稀土模式;εNd(t)(t=2.30 Ga)=-0.75; tDM(Nd) =2.66 Ga.黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25 Ga;岩石低SiO2 和MgO,高Al2O3和P2O5,具稀土总量高(∑REE=373.4×10-6)、轻重稀土分离不强[ (La/Yb)n=9.4]及较强负铕异常( Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25 Ga)=-1.21;tDM(Nd) =2.75 Ga.片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94 Ga变质锆石年龄.片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30 Ga)=-6.71～0.38,tDMI(Hf) =2627 ～2910 Ma,tDM2(CC)(Hf)=2823 ～ 3255 Ma.黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25 Ga)=-19.58～ -1.73,tDM1 (Hf) =2664～3360 Ma,tDM2(CC)(Hf)=2968 ～4011 Ma.结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在—规模较大的约2.3 Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的＞2.7 Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史.     

鞍山地区铁架山花岗岩及表壳岩的锆石SHRIMP年代学和Hf同位素组成

辽宁鞍山中太古代铁架山花岗岩是华北克拉通时代最古老、分布范围最大的富钾质花岗岩。具相对高钾(4.77～5.75%)低钠(3.16～3.52%)、强烈负铕负钡异常(Eu/Eu*=0.40～0.51,Ba/Ba*=0.15～0.26)的组成特征,且高t_(DM)(Nd) (3.42～3.38Ga),低ε_(Nd)(t)(-3.61～-2.51)。花岗岩样品A9837和A0433岩浆锆石年龄分别为2992±10Ma和2983±10Ma。结合前人定年结果,可把铁架山花岗岩主体形成时代限制在2.96～2.99Ga之间。另一花岗岩样品A9825岩浆锆石年龄为2914±4Ma,可能代表了铁架山花岗岩形成后局部深熔作用的时代。首次在铁架山花岗岩中获得残余锆石年龄,其最大达3759Ma。2个花岗岩样品(A9837,A9825)岩浆锆石的t_(DM)(Hf)和ε_(Hf)(t)分别为3.48～3.32Ga和-7.85～-2.29.残余锆石的t_(DM)(Hf)和ε_(Hf)(t)分别为3.89～3.47Ga和-19.5～-6.2。这些资料为铁架山花岗岩形成于古老陆壳物质再循环提供了直接证据。存在于铁架山花岗岩中的表壳岩主要为变质沉积岩,其地球化学组成特征与铁架山花岗岩类似。3个变质沉积岩样品(A9819,A0435,A0436)的碎屑锆石年龄大都为～3.0Ga,其中2个样品(A0435,A0436)的碎屑锆石ε_(Hf)(t)和t_(DM)(Hf)分别为-9.93～-2.29和3672～3297Ma,与铁架山花岗岩中的岩浆锆石类似。表明这些变质沉积岩形成于铁架山花岗岩之后,而不是以前认为的那样为铁架山花岗岩中的包体。     

华北克拉通南缘太古宙地壳生长和再造:登封地区五指岭组碎屑锆石U-Pb-Hf同位素制约

对登封地区嵩山群五指岭组二云石英片岩和石英岩中碎屑锆石进行了LA-ICP-MS U-Pb年代学和原位Hf同位素分析,为探讨华北克拉通南缘太古宙地壳生长和再造提供了制约。结果显示,碎屑锆石多数呈自形–半自形,发育振荡生长环带,结合相对高的Th/U比值(0.07~1.87),暗示它们多数为岩浆成因。二云石英片岩和石英岩中碎屑锆石具有类似的年龄和Hf同位素组成,它们的207Pb/206Pb谐和年龄分别介于2879~2027 Ma和3346~1903 Ma之间,峰期年龄分别为2524 Ma和2528 Ma。~2.5 Ga锆石的εHf(t)值多数为正值,介于+0.10~+9.22之间,tDM2C变化于3028~2453 Ma之间,4颗碎屑锆石的εHf(t)值为负值,变化于-1.68~-0.03之间,tDM2C介于3132~3032 Ma之间。根据上述结果并结合相邻地区的相关研究资料,表明嵩山群沉积于古元古代晚期,五指岭组中碎屑锆石的物源主要为华北克拉通南缘~2.5 Ga具有新生地壳属性的结晶基底物质。华北克拉通南缘存在中–新太古代时期的地壳生长,同时发育中太古代古老地壳物质的再造。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...