Highly evolved juvenile granites with tetrad REE patterns: the Woduhe and Baerzhe granites from the Great Xing'an Mountains in NE China

In NE China, voluminous granitoids were emplaced in late Paleozoic and Mesozoic times. We report here Sr–Nd–O isotopic and elemental abundance data for two highly evolved granitic plutons, Woduhe and Baerzhe, from the Great Xing'an Mountains. They show a rather “juvenile” Sr–Nd isotopic signature and a spectacular tetrad effect in their REE distribution patterns as well as non-CHARAC (charge-and-radius-controlled) trace element behavior. The emplacement ages are constrained at 130±4 Ma for the Woduhe and 122±5 Ma for the Baerzhe granites by Rb–Sr and Sm–Nd isotope analyses. Both granites are also characterized by low but imprecise initial ⁸⁷Sr/⁸⁶Sr ratios of about 0.703. The Nd–Sr isotope data argue for their generation by melting of dominantly juvenile mantle component with subordinate recycled ancient crust. This is largely compatible with the general scenario for much of the Phanerozoic granitoids emplaced in the Central Asian Orogenic Belt. The parental magmas for both the Woduhe and Baerzhe granites have undergone extensive magmatic differentiation, during which intense interaction of the residual melts with aqueous hydrothermal fluids (probably rich in F and Cl) resulted in the non-CHARAC trace element behavior and the tetrad effect of REE distribution. Both the Woduhe and Baerzhe granites show the characteristic trace element patterns of rare-metal granites, but their absolute abundances differ by as much as two orders of magnitude. The oxygen isotope compositions of the two granites have been severely disturbed. Significant ¹⁸O depletion in feldspar, but not so much in quartz, suggests that the hydrothermal alteration took place in a temperature condition of 300–500 °C. This subsolidus hydrothermal alteration is decoupled from the late-stage magma–fluid interaction at higher temperatures. Despite the two distinct and intense events of “water–rock” interaction, the Rb–Sr and Sm–Nd geochronological systems seem to have maintained closed, hence, suggesting that the two events occurred shortly after the plutonic emplacements.     

Important crustal growth in the Phanerozoic: Isotopic evidence of granitoids from east-central Asia

The growth of the continental crust is generally believed to have been essentially completed in the Precambrian, and the amount of juvenile crust produced in the Phanerozoic is considered insignificant. Such idea of negligible growth in the Phanerozoic is now challenged by the revelation of very large volume of juvenile crust produced in the period of 500 to 100 Ma in several orogenic belts. While appreciable volumes of juvenile terranes in North America (Canadian Cordillera, Sierra Nevada and Peninsular Range, Appalachians) have been documented based on Nd isotopic data, the mass of new crust formed in the East-Central Asian Orogenic Belt (ECAOB), eastern part of the Altaid Tectonic Collage, appears to be much greater than the above terranes combined. New and published Nd-Sr isotope data indicate that the Phanerozoic granitoids from the southern belt of the ECAOB (Xinjiang-West Mongolia-Inner Mongolia-NE China) as well as from Mongolia and Transbaikalia were generated from sources dominated by a depleted mantle component. These granitoids represent a significant growth of juvenile crust in the Phanerozoic. Although most plutons in this huge orogenic belt belong to the calc-alkaline series, the ECAOB is also characterized by the emplacement of voluminous A-type granites. The origin of these rocks is probably multiple and is still widely debated. However, the isotopic data (Sr-Nd-O) and trace element abundance patterns of A-type granites from the ECAOB clearly indicate their mantle origin. The evolution of the ECAOB and the entire Altaid Collage is most likely related to successive accretion of arc complexes. However, the emplacement of a large volume of post-tectonic A-type granites requires another mechanism—probably through a series of processes including underplating of massive basaltic magma, partial melting of these basic rocks to produce granitic liquids, followed by extensive fractional crystallization. The proportion of juvenile to recycled, as well as that of arc-related to plume-generated, continental crust remains to be evaluated by more systematic dating and isotope tracer studies.     

兴蒙造山带正ε(Nd,t)值花岗岩的成因和大陆地壳生长

大陆地壳的生长速率和地壳生长的位置均是地球科学中的最基本的问题。现有的许多大陆地壳生长模式认为 ,90 %的大陆地壳生长于 18亿年以前 ,显生宙以来的地壳生长不到整个地壳的 10 % ,主要位于活动大陆边缘。近年来在兴蒙造山带发现大量具有新生地壳来源性质的花岗岩产生于 50 0～ 10 0Ma ,对上述传统看法提出了挑战。现有的Nd同位素资料表明 ,兴蒙造山带的显生宙花岗岩 ,不论形成于什么时代和什么构造背景 ,也不论属于何种成因类型 ,几乎都具有正ε(Nd ,t)值和年轻的Nd模式年龄tDM 。从西往东 ,随着时代逐渐变新ε(Nd ,t)值有逐渐降低的趋势。花岗岩的tDM同由蛇绿岩和岛弧杂岩记录的古亚洲洋扩张的时间基本一致。只有一些在新元古代微陆块上的花岗岩才显示负ε(Nd ,t)值和较老的tDM,反映了其源岩包括前寒武纪地壳同地幔来源物质的不同程度混合。兴蒙造山带的花岗岩具有地幔来源的ε(Nd ,t)值 ,说明这些花岗岩中有一部分 (例如加里东期和海西早期 )可能同板块俯冲作用有关 ,花岗岩的来源是被交代的地幔楔。而大面积的晚古生代—中生代花岗岩则可能是由 80 0～6 0 0Ma前俯冲的洋壳形成的新生大陆地壳在拉伸体制下部分熔融而成。如果情况是这样 ,显生宙就曾发生过大规模的地壳生长。板内岩浆活动 ,特别是     

A Jurassic garnet-bearing granitic pluton from NE China showing tetrad REE patterns

NE China is characterized by the massive distribution of Phanerozoic granitoids. Most of them are of I- and A-type granites, whereas S-type granites are rarely documented. The present work deals with the Dongqing pluton, a small granitic body emplaced in the southern Zhangguangcai Range. The pluton comprises a two-mica (±garnet) granite and a garnet-bearing muscovite granite; the latter occurs as veins in the former. The pluton shows a gradational contact with the surrounding host granites. Rb–Sr and Sm–Nd isotope analyses on whole-rocks and minerals reveal that the two types of granites were emplaced synchronously at about 160 Ma. The pluton was emplaced coeval with the surrounding I-type granitic pluton, and had a rapid cooling history. It is characterized by an initial Sr isotopic ratio of 0.706, slightly negative _Nd(T) values (−0.5 to −1.9) and young depleted-mantle model ages (970–1090 Ma). This suggests that the parent magma originated from partial melting of relatively juvenile crust, which is largely compatible with the general scenario for much of the Phanerozoic granitoids emplaced in the Central Asian Orogenic Belt.Geochemically, the granites of the Dongqing pluton are peraluminous, with a Shand Index (molar ratio A/CNK) of 1.0–1.1 for the two-mica granites and 1.2–1.3 for the garnet-bearing granites. All the garnet-bearing granites and some of the two-mica granites show tetrad REE patterns (=tetrad group), whereas most two-mica granites show normal granitic REE patterns (=normal group). The normal group granites exhibit depletion in Nb, Ta, P and Ti in spidergrams, and generally weak positive Eu anomalies in REE patterns. By contrast, the tetrad group granites manifest depletion in Ba, Nb, Ta, Sr, P, and Ti and significant negative Eu anomalies. The trace element data constrain the parental magmas to having undergone extensive magmatic differentiation. During their late stage magmatic evolution, intense interaction of residual melts with aqueous hydrothermal fluids resulted in the non-CHARAC (charge and radius controlled) trace element behavior and the tetrad effect in REE distribution patterns. This, in turn, leads to the invalidation of the commonly used tectonic discrimination criteria derived from trace element abundances of normal granites. In view of this and previous studies, we conclude that there were probably no S-type granites produced in NE China during the Phanerozoic. Consequently, weathered sedimentary material did not play an important role in the genesis of the strongly peraluminous granites in the Zhangguangcai Range.     

The 401–409 Ma Xiaodonggou granitic intrusion: implications for understanding the Devonian Tectonics of the Northwest China Altai orogen

Abstract

Palaeozoic granitoids in the Chinese Altai are important for understanding the evolution of the Central Asian Orogenic Belt (CAOB). The Xiaodonggou granitic intrusion, situated in the Chinese Altai (southern CAOB), is composed of two intrusive phases, medium-grained granite intruded by porphyritic granite. Zircon LA-ICP-MS U–Pb analyses of medium-grained granite and porphyritic granite yield ages of 409 ± 2 Ma and 400 ± 1 Ma, respectively, indicating that these formed in Early Devonian time. Medium-grained granite and porphyritic granite have similar geochemical features and Nd–Hf isotopic compositions. Arc-like geochemical characteristics (e.g. enrichment of LILEs and negative anomalies of Nb, Ta, Ti, and P) show that both phases are volcanic arc granites (VAGs). Geochemical and isotopic characteristics suggest that these magmas originated from melting older crust. Based on their near-zero or negative ε_Nd(t) values (?1.4to 0) and positive ε_Hf(t) values (+1.4 to +7.8), together with Nd model ages of 1.15–1.26 Ga and zircon Hf model ages of 0.90–1.30 Ga, we suggest that the Xiaodonggou granites were derived from a mixture of juvenile and old crustal components. Some other Devonian granitic intrusions were recently identi?ed in the Chinese Altai with ages between 416 and 375 Ma. These Devonian granites have similar geochemical characteristics and petrogenesis as Xiaodonggou granites. The formation of these Devonian granites was in response to subduction processes, suggesting that Chinese Altai was an active continental margin in Early Devonian time.     

Some progress on understanding the Phanerozoic granitoids in China

There are large volumes of the Phanerozoic granitoid rocks in China and neighboring areas. In recent years, numerous new and precise U-Pb zircon ages have been published for these granitoids, and define many important magmatic events, such as ca. 500 Ma granitoid events in the West Junggar, Altai orogens in the NW China, and Qinling orogen in the central China. These ages accurately constrain the time of important Early Paleozoic, Late Paleozoic, Early Mesozoic and Late Mesozoic magmatic events of the northern, central, western, southern and eastern orogenic Mountains in China. There occur various types of granitoids in China, such as calc-alkaline granite, alkali granite, highly-fractionated granite, leucogranite, adakite, and rapakivi granite. Rapakivi granites are not only typical Proterozoic as in the North China Craton, but were also emplaced during Paleozoic and Mesozoic in the Kunlun-Qinling orogen, a part of the China Central Orogenic Belt (CCOB). Nd-Hf isotopic tracing and mapping show that granitoids in the southern Central Asian Orogenic Belt (CAOB) in China (or the Northern China Orogenic Belt) are characterized predominantly by juvenile sources. The juvenile crust in this orogenic domain accounts for over 50% by area, distinguishing it from other orogenic belts in the world, and those in central (e.g., Qinling), southwestern and eastern China. Based on a large amount of new age data, a preliminary granitoid and granitoid-tectonic maps of China have been preliminarily compiled, and an evolutionary framework of Phanerozoic granitoids in China and neighboring areas has been established from the view of assembly and breakup of continental blocks. Research ideas on granitoid tectonics has also been proposed and discussed.     

Highly fractionated I-type granites in NE China (I): geochronology and petrogenesis

Northeastern (NE) China is the easternmost part of the Central Asian Orogenic Belt (CAOB), which is celebrated for its accretionary tectonics and the world's most important juvenile crust production in the Phanerozoic era. Abundant granitoids occur in the Great Xing'an, Lesser Xing'an and Zhangguangcai Ranges in NE China. This paper presents partial results of a series of studies on the granitoids from this region, aiming to understand their role in the building of new continental crust in eastern Asia. Three composite granite plutons (Xinhuatun, Lamashan and Yiershi) were chosen for geochemical and isotopic study in order to determine their emplacement ages and petrogenesis. Petrographically, they range from granodiorite (minor), monzogranite, syenogranite to alkali-feldspar granite. Quartz and perthitic feldspar are principal phases, accompanied by minor amounts of plagioclase, biotite (<5%) and other accessory minerals. In addition, many contain abundant miarolitic cavities which suggest that they were emplaced at shallow levels with extensive fractional crystallization. Geochemically, the granites are silica-rich, peraluminous and have high contents of alkalis. They invariably show enrichment in light rare earth elements (LREE) and significant negative Eu anomalies. All the granitic rocks demonstrate the characteristic negative anomalies in Ba, Nb, Sr, P, Eu, and Ti, and a positive anomaly in Pb in the spidergram.

The emplacement of the Xinhuatun pluton took place at 184±4 Ma as revealed by zircon SHRIMP U–Pb data. This is also supported by the slightly younger Rb–Sr whole-rock (WR) isochron age of 173±3 Ma. A whole-rock (WR) Rb–Sr isochron age of 154±3 Ma was obtained for the Lamashan pluton, which is interpreted as close to the time of emplacement. The Yiershi pluton was intruded at about 140 Ma as evidenced by a zircon U–Pb age of 137±2 Ma and WR Rb–Sr isochron age of 143±5 Ma. Biotite-WR Rb–Sr isochrons and ⁴⁰Ar/³⁹Ar ages of feldspars allow us to estimate the cooling rate of each pluton.

Geochemical data suggest that the rocks are highly fractionated I-type granites. Fractionation of biotite and feldspars was the principal process of magmatic differentiation and responsible for major element variation. Rb, Sr and Ba concentrations were controlled by feldspar separation, whereas REE elements were fractionated by accessory minerals, such as apatite, allanite and monazite.     

小兴安岭-张广才岭地区晚古生代至中生代花岗岩的成因及其地质意义

中国东北地区显生宙花岗岩的成因一直是中亚造山带东段研究的热点之一,尤其是小兴安岭-张广才岭地区的花岗岩其成因及形成的大地构造背景一直存在较大争议。本文新获得小兴安岭-张广才岭铁力和依兰地区的二长花岗岩LA-ICP-MS锆石U-Pb年龄分别为188±1 Ma和257±3 Ma。地球化学数据显示,两地区的二长花岗岩均为Ⅰ型花岗岩并且富集大离子亲石元素(Th和U等)和轻稀土元素,亏损高场强元素(Nb和Ta等)和重稀土元素具有弧岩浆岩的地球化学特征。锆石Hf同位素数据显示,铁力地区二长花岗岩的岩浆源区可能来自于中新元古代的下地壳部分熔融。综合前人在小兴安岭-张广才岭地区已发表的花岗岩类岩石的地质年代学和地球化学数据,初步推测小兴安岭-张广才岭地区在晚古生代至中生代期间处于活动大陆边缘环境。同时,小兴安岭-张广才岭地区晚古生代至中生代的岩浆岩具有自东向西形成时代逐渐变年轻的趋势,这可能是由于东侧的牡丹江洋在晚古生代至中生代期间俯冲角度逐渐变缓造成的。     

南秦岭勉略带北光头山花岗岩体群的成因及其构造意义

南秦岭勉略带北部花岗岩体从闪长岩到花岗闪长岩和花岗岩变化,反映了钙碱性岩岩石组合特征,矿物组成以长石、石英、黑云母和少量角闪石为主,副矿物有锆石、磷灰石、磁铁矿和榍石,岩石化学上它们相对高K、Sr,Zr／Y比值较高,富集LEE和LILE,贫化HFSE,与后碰撞富钾钙碱性I型花岗岩特征一致。此外,它们明显亏损Nb、Ta,低Y、Yb和有较高的 LaN／YbN和Sr／Y比值,多数岩体发育淬冷岩浆结构的暗色闪长质微粒包体,包体与寄主花岗岩的稀土及微量元素存在明显差异,证明它们是地壳增厚背景下,可能由下部地壳拆沉作用导致的分别来自幔源和下部地壳熔融的二元岩浆混合演化的产物。个别高分异岩体的Fetot／Mg比值高、明显亏损Sr、Ba、Ti、P,呈现了向强分异A型花岗岩过渡的后碰撞富钾过铝偏碱性花岗岩特征。因此,结合西部岩体形成年代早于东部岩体分析,西部形成时代较早偏中基性的含有大量闪长质微粒包体的岩体代表了早期下部地壳拆沉作用的发生,东部形成较晚分异程度高的高钾钙碱性Ⅰ型花岗岩体的出现指示了南、北两大陆块碰撞汇聚后向伸展的转折,而更晚期高度分异的姜家坪富钾花岗岩体的出现则表明秦岭造山带已进入主碰撞结束期的伸展拉张演化阶段,并预示了新的板内演化期的到来。     

Geochemical and isotope data from the Acatlán Volcanic Field, western Trans-Mexican Volcanic Belt: Origin and evolution

The Quaternary Acatlán Volcanic Field (AVF) is located at the western edge of the Trans-Mexican Volcanic Belt (TMVB). This region is related to the subduction of the Pacific Cocos and Rivera plates beneath the North American plate since the late Miocene. AVF rocks are products of Pleistocene volcanic activity and include lava flows, domes, erupted basaltic andesite, trachyandesite, trachydacite, and rhyolite of calc–alkaline affinity. Most rocks show depletion in high field-strength elements and enrichment in large ion lithophile elements and light rare earth elements as is typical for magmas in subduction-related volcanic arcs. ⁸⁷Sr/⁸⁶Sr values range from 0.70361 to 0.70412, while Nd values vary from +2.3 to +5.2. Sr–Nd isotopic data plot along the mantle array. On the other hand, lead isotope compositions (²⁰⁶Pb/²⁰⁴Pb=18.62–18.75, ²⁰⁷Pb/²⁰⁴Pb=15.57–15.64, and ²⁰⁸Pb/²⁰⁴Pb=38.37–38.67) give evidence for combined influences of the upper mantle, fluxes derived from subducted sediments, and the upper continental crust involved in magma genesis at AVF. Additionally δ¹⁸O whole rock analyses range from +6.35‰ in black pumice to +10.9‰ in white pumice of the Acatlán Ignimbrite. A fairly good correlation is displayed between Sr as well as O isotopes and SiO₂ emphasizing the effects of crustal contamination. Compositional and isotopic data suggest that the different AVF series derived from distinct parental magmas, which were generated by partial melting of a heterogeneous mantle source.     

Petrogenesis of mafic microgranular enclaves (MMEs) in the oligocene-miocene granitoid plutons from northwest Anatolia,Turkey

Mafic microgranular enclaves (MMEs) in host granitoids can provide important constraints on the deep magmatic processes. The Oligocene-Miocene granitoid plutons of the NW Anatolia contain abundant MMEs. This paper presents new hornblende Ar-Ar ages and whole-rock chemical and Sr-Nd isotope data of the MMEs from these granitic rocks. Petrographically, the MMEs are finer-grained than their host granites and contain the same minerals as their host rocks (amphibole + plagioclase + biotite + quartz + K-feldspar), but in different proportions. The Ar-Ar ages of the MMEs range from 27.9 ± 0.09 Ma to 19.3 ± 0.01 Ma and are within error of their respective host granitoids. The MMEs are metaluminous and calc-alkaline, similar to I-type granites. The Sr-Nd isotopes of MMEs are 0.7057 to 0.7101 for ⁸⁷Sr/⁸⁶Sr and 0.5123 to 0.5125 for ¹⁴³Nd/¹⁴⁴Nd, and are similar to their respective host granitoids. These lithological, petrochemical and isotopic characteristics suggest that the MMEs in this present study represent chilled early formed cogenetic hydrous magmas produced during a period of post-collisional lithospheric extension in NW Anatolia. The parental magma for MMEs and host granitoids might be derived from partial melting of underplated mafic materials in a normally thickened lower crust in a post-collisional extensional environment beneath the NW Anatolia. Delamination or convective removal of lithospheric mantle generated asthenospheric upwelling, providing heat and magma to induce hydrous re-melting of underplated mafic materials in the lower crust.     

Source regions of granites and their links to tectonic environment: examples from the western United States

This review, in honor of Ilmari Haapala's retirement, reflects on lessons learned from studies of three granitic systems in western North America: (1) Mesoproterozoic samples from west Texas and east New Mexico; (2) Laramide granitic systems associated with porphyry-copper deposits in Arizona; and (3) granites of the Colorado Mineral Belt. The studies elucidate relationships amongst tectonic setting, source material, and magma chemistry.

Mesoproterozoic basement samples are from two different felsic suites with distinct elemental and isotopic compositions. The first suite, the “plutonic province”, is dominantly magnesian, calc-alkalic to alkali-calcic, and metaluminous. It has low K₂O/Na₂O and Rb/Sr, and Nd model ages of 1.56 to 1.40 Ga. The second suite, the “Panhandle igneous complex”, is magnesian, metaluminous, alkalic, and is part of the Mesoproterozoic belt of magmatism that extends from Finland to southwestern United States. Samples from the Panhandle igneous complex demonstrate three episodes of magmatism: the first pulse was intrusion of quartz monzonite at 1380 to 1370 Ma; the second was comagmatic epizonal granite and rhyolite at 1360 to 1350 Ma. Both of these rock types are high-K to slightly ultra-high-K. The third pulse at 1338 to 1330 Ma was intrusion of ultra-high-K quartz syenite. Nd model ages (1.94 to 1.52 Ga) are distinct from those of the “plutonic province” and systematically older than crystallization ages, implying a substantial crustal input to the magmas.

At the Sierrita porphyry-copper deposit in the Mazatzal Province of southeastern Arizona, trace element, Sr, and Nd isotopic compositions were determined for a suite of andesitic and rhyolitic rocks (67 Ma) intruded by granodiorite and granite. Isotopic composition and chemical evolution are well correlated throughout the suite. Andesite has the least negative initial ε_Nd (−4.3) and lowest ⁸⁷Sr/⁸⁶Sr_i (0.7069). It is also the oldest and chemically most primitive, having low concentrations of Rb, SiO₂, and high concentrations of transition elements. These parameters change through the system to the youngest unit (granite), which has the most negative ε_Nd (−8.5), the highest ⁸⁷Sr/⁸⁶Sr_i (0.7092), and is chemically most evolved. Correlation between chemical and Nd isotopic evolution probably resulted from a continuous process of progressive assimilation, in which mafic magmas invade and incorporate continental crust. Deposits in Arizona with ε_Nd values more negative than the −8.5 of Sierrita lie in the older Yavapai province in the northwestern part of the state. The difference in the most negative epsilon Nd implies that Nd isotopic signature is sensitive to the age of the Precambrian domain.

The granites from the Colorado Mineral Belt were emplaced during the transition from Laramide convergence to mid-Tertiary extension. Three different groups of granites are recognized. The first is Laramide and was formed during assimilation-fractional crystallization involving lower crustal mafic source materials; the second and third groups are mid-Tertiary and represent intracrustal melting of heterogeneous sources. This change in source regions and melt regimes in transition from convergence to extension is fundamental to the Mesozoic and Cenozoic evolution of western North America.     

Late Jurassic granitoids in the Xilamulun Mo belt,Northeastern China: geochronology,geochemistry, and tectonic implications

ABSTRACT

The Xilamulun Mo belt of Northeastern China, located in the southeastern segment of the Central Asia Orogenic Belt (CAOB), is composed of large deposits of porphyry Mo and quartz-vein-type Mo, which are related to Mesozoic granitoids. Previous studies led to the conclusion that all granitoids in the region formed during the Cretaceous and Triassic, but our new laser ablation inductively coupled plasma mass spectrometry U–Pb zircon dating of magmatic zircons from five samples of four mineralized plutons (Nailingou, Longtoushan, and Hashitu granites and Erbadi and Hashitu granite porphyries) reveals that these range in age from 143.8 ± 1.2 to 149.5 ± 1.0 Ma. These granites show post-collisional (A-type) geochemical characteristics (e.g. enrichment in total alkali, LILE, and LREE and depletion in Eu, Ba, P, and Nb). The Erbadi, Longtoushan, Hashitu, and Longtoushan granitoids exhibit moderately positive Hf isotopic compositions (ε_Hf(t) = ?0.3 to 10.2), indicating that granitic magmas may reflect mixtures of mantle melts and continental crust. These mineralized granites were all emplaced along a major fault over a time span of ~6 million years during the Late Jurassic. We conclude that igneous activity and mineralization resulted from the rollback of the subducted Palaeo-Pacific plate beneath Eurasia. Confirming that the Late Jurassic granitic intrusives are related to the Mo mineralization is useful for understanding the Mesozoic tectonic evolution of the Xilamulun Mo belt and also has significant implications for the regional exploration of ores.     

Geochemistry,U–Pb geochronology,Sm–Nd and O isotopes of ca. 50 Ma long Ediacaran High-K Syn-Collisional Magmatism in the Pernambuco Alagoas Domain,Borborema Province,NE Brazil

The Pernambuco Alagoas (PEAL) domain shows the major occurrence of granitic batholiths of the Borborema Province, NE Brazil, with Archean to Neoproterozoic range of Nd T_DM model ages, giving clues on the role of granites during the Brasiliano orogeny. SHRIMP U/Pb zircon geochronological data for seven granitic intrusions of the PEAL domain divide the studied granitoids into three groups: 1) early-to syn-collision granitoids with crystallization ages ca. 635 Ma (Serra do Catú pluton), 2) syn-collision granitoids with crystallization ages 610–618 Ma (Santana do Ipanema, Água Branca, Mata Grande and Correntes plutons) and 3) late-to post-collision granitoids with ages of ca. 590 Ma (Águas Belas, and Cachoeirinha plutons). The intrusions of group 1 and 2, except the Mata Grande and Correntes plutons, show Nd T_DM model ages ranging from 1.2 to 1.5 Ga, while the granitoids from group 3, and Mata Grande Pluton and Correntes plutons have Nd T_DM model ages ranging from 1.7 to 2.2 Ga. The studied granitoids with ages <600 Ma are high-K, calc-alkaline, shoshonitic and those with ages <600 Ma are transitional high-K calc-alkaline to alkaline. The volcanic arc signatures associated with the Paleoproterozoic Nd T_DM model ages are interpreted as inherited from the source rocks. The oldest ages and lower Nd T_DM model ages are recorded from granitoids intruded in the southwest part of the PEAL domain, suggesting that these intrusions are associated with slab-tearing during convergence between the PEAL and the Sergipano domains. Zircon oxygen isotopic data in some of the studied plutons, together with the available Nd isotopic data suggest that the Brasiliano orogeny strongly reworked older crust, of either Paleoproterozoic or Tonian ages. The studied granitoids are coeval with calc-alkaline granitoids of the Transversal Zone and Sergipano domains and rare high-K calc-alkaline granitoids from the Transversal Zone domain. Such large volumes of high-K granitoids with crystallization ages older than 600 Ma are not recorded in the Transversal Zone domains, suggesting that at least between 600 and 650 Ma, the granitic magmatism of these two areas were distinct. However, the studied granitoids (630–580 Ma) located in the north part of the PEAL domain, north of the Palmares shear zone are coeval with granitoids of similar geochemical compositions in the Transversal Zone domain. It suggests that the southeastern part of the Transversal Zone and the northern part of the PEAL domains belonged to the same crustal block during the Brasiliano/Pan-African orogeny.     

Magma sources for Mesozoic anorogenic granites of the White Mountain magma series,New England,USA

The magma sources for granitic intrusions related to the Mesozoic White Mountain magma series in northern New England, USA, are addressed relying principally upon Nd isotopes. Many of these anorogenic complexes lack significant volumes of exposed mafic lithologies and have been suspected of representing crustal melts. Sm–Nd and Rb–Sr isotope systematics are used to evaluate magma sources for 18 felsic plutons with ages ranging from about 120 to 230 Ma. The possibility of crustal sources is further examined with analyses of representative older crust including Paleozoic granitoids which serve as probes of the lower crust in the region. Multiple samples from two representative intrusions are used to address intrapluton initial isotopic heterogeneities and document significant yet restricted variations (<1 in _Nd). Overall, Mesozoic granite plutons range in _Nd [T] from +4.2 to -2.3, with most +2 to 0, and in initial ⁸⁷Sr/⁸⁶Sr from 0.7031 to 0.709. The isotopic variations are roughly inversely correlated but are not obviously related to geologic, geographic, or age differences. Older igneous and metamorphic crust of the region has much lower Nd isotope ratios with the most radiogenic Paleozoic granitoid at _Nd [180 Ma] of -2.8. These data suggest mid-Proterozoic separation of the crust in central northern New England. Moreover, the bulk of the Mesozoic granites cannot be explained as crustal melts but must have large mantle components. The ranges of Nd and Sr isotopes are attributed to incorporation of crust by magmas derived from midly depleted mantle sources. Crustal input may reflect either magma mixing of crustal and mantle melts or crustal assimilation which is the favored interpretation. The results indicate production of anorogenic granites from mantle-derived mafic magmas.     

西准噶尔克拉玛依岩体的成因:年代学、岩石学和地球化学证据

西准噶尔地区克拉玛依岩体主要由闪长岩和花岗岩组成,锆石SHRIMP法给出的岩体结晶年龄为(315.5±2.8)Ma,为晚石炭世侵入岩.克拉玛依岩体具岛弧岩石的元素地球化学特征:总体上岩石富钠.A/CNK=0.57～0.84,富集LREE,(La/Yb)N=4.7～6.1,Eu显示弱负异常(δEu=0.76～0.91),...     

Geochemical constraints on the origin of bimodal magmatism at the Okinawa Trough, an incipient back-arc basin

The magmatism at the axial zone of the middle Okinawa Trough, a young continental back-arc basin, comprises a bimodal basaltic–rhyolitic suite, accompanied by minor intermediate rocks. We report major and trace element and Sr–Nd isotopic data for the intermediate to silicic suites, to provide constraints on their petrogenesis. The rhyolites, recovered as lava and pumice, fall into three geochemical groups (type 1, 2, and 3 rhyolites). Type 1 rhyolites have ⁸⁷Sr/⁸⁶Sr (0.7040–0.7042) and ¹⁴³Nd/¹⁴⁴Nd (0.5128–0.5129) identical to those of associated basalts, and are characterized by highly fractionated REE patterns. Petrogenesis of type 1 rhyolites is explicable in terms of fractional crystallization of the associated basalt. In contrast, type 2 rhyolites and andesite have slightly higher ⁸⁷Sr/⁸⁶Sr (0.7044–0.7047) but similar ¹⁴³Nd/¹⁴⁴Nd (0.5128) compared to those of the basalts. The compositions of type 2 rhyolite and andesite can be explained by assimilation and fractional crystallization (AFC) processes of the basalt magma; quantitative analysis suggests assimilation/fractional crystallization (M_a/M_c) ratios of ≤0.05. Hybrid andesite generated by mixing of evolved basalt and type 1 rhyolite is also present. We emphasize that mechanical extension in this part of the Okinawa Trough involves gabbroic lower crust that resulted from fractionation of mantle-derived basaltic magmas. Type 3 rhyolite occurs only as pumice, which makes its derivation questionable. This rhyolite has major and trace element compositions and Sr–Nd isotopic ratios, which suggests that it may be derived from volcanic activity on the southern Ryukyu volcanic front, and arrived in the Okinawa Trough by drifting on the Kuroshio Current.     

Sources of Phanerozoic granitoids in the transect Bayanhongor–Ulaan Baatar, Mongolia: geochemical and Nd isotopic evidence, and implications for Phanerozoic crustal growth

The Central Asian Orogenic Belt (CAOB) is renowned for massive generation of juvenile crust in the Phanerozoic. Mongolia is the heartland of the CAOB and it has been subject to numerous investigations, particularly in metallogenesis and tectonic evolution. We present new petrographic, geochemical and Sr–Nd isotopic analyses on Phanerozoic granitoids emplaced in west-central Mongolia. The data are used to delineate their source characteristics and to discuss implications for the Phanerozoic crustal growth in Central Asia. Our samples come from a transect from Bayanhongor to Ulaan Baatar, including three tectonic units: the Baydrag cratonic block (late Archean to middle Proterozoic), the Eo-Cambrian Bayanhongor ophiolite complex and the Hangay–Hentey Basin of controversial origin. The intrusive granitoids have ages ranging from ca. 540 to 120 Ma. The majority of the samples are slightly peraluminous and can be classified as granite (s.s.), including monzogranite, syenogranite and alkali feldspar granite. Most of the rocks have initial ⁸⁷Sr/⁸⁶Sr ratios between 0.705 and 0.707. Late Paleozoic to Mesozoic granitoids (≤250 Ma) are characterized by near-zero _Nd(T) values (0 to −2), whereas older granitoids show lower _Nd(T) values (−1.5 to −7). The data confirm the earlier observation of Kovalenko et al. [Geochemistry International 34 (1996) 628] who showed that granitoids emplaced outside of the Pre-Riphean basement rocks are characterized by juvenile positive _Nd(T) values, whereas those within the Pre-Riphean domain and the Baydrag cratonic block, as for the present case, show a significant effect of ‘contamination’ by Precambrian basement rocks. Nevertheless, mass balance calculation suggests that the granitoids were derived from sources composed of at least 80% juvenile mantle-derived component. Despite our small set of new data, the present study reinforces the general scenario of massive juvenile crust production in the CAOB with limited influence of old microcontinents in the genesis of Phanerozoic granitoids.     

Mantle and Crustal Sources in the Genesis of Late-Hercynian Granitoids (NW Portugal): Geochemical and Sr-Nd Isotopic Constraints

Large volumes of granitoids were emplaced in the Hercynian Central Iberian Zone during the last ductile deformation phase (D3, 300-320 Ma). The biotite-rich granitoids are the most abundant: (1) syn-D3 granodiorites-monzogranites (313-319 Ma) with calc-alkaline and aluminopotassic affinities; (2) late-D3 granodiorites-monzogranites (306-311 Ma), related to subalkaline and aluminopotassic series. These granitoids are associated with coeval gabbro-norite to granodiorite bodies and/or mafic microgranular enclaves. Both granitoids and basic-intermediate rocks show petrological, geochemical and isotopic evidence of interaction between felsic and mafic magmas.The mantle-derived melts, represented by shoshonitic gabbro-norites, were probably derived from an enriched and isotopically homogeneous source (Sr_i = 0.7049 to 0.7053, e_Nd = -2.1 to -2.5). In some syn- and late-D3 plutons there are evidences of essentially crustal granites, represented by moderately peraluminous monzogranites of aluminopotassic affinity. They have similar Nd model ages (1.4 Ga) but different isotopic compositions (Sr_i = 0.7089 to 0.7106, e_Nd = -5.6 to -6.8), revealing a heterogeneous crust. Potential protoliths are metasedimentary (immature sediments) and/or felsic meta-igneous lower crust materials. Large amounts of hybrid magmas were generated by the interaction of these coeval mantle- and crust-derived liquids, giving rise to slightly peraluminous monzogranites/granodiorites of calc-alkaline and subalkaline affinities, which display more depleted isotopic compositions than the crustal end-members (Sr_i = 0.7064 to 0.7085, e_Nd = -4.4 to -6.2). Petrogenetic processes involving mingling and/or mixing and fractional crystallization (at variable degrees) in multiple reservoirs are suggested.A major crustal growth event occurred in late-Hercynian times (∼305-320 Ma) related to the input of juvenile mantle magmas and leading to the genesis of composite calc-alkaline and subalkaline plutons, largely represented in the Central Iberian Zone.     

Mixing of asthenospheric and lithospheric mantle-derived basalt magmas as shown by along-arc variation in Sr and Nd isotopic compositions of Early Miocene basalts from back-arc margin of the NE Japan arc

We report trace element and Sr–Nd isotopic compositions of Early Miocene (22–18 Ma) basaltic rocks distributed along the back-arc margin of the NE Japan arc over 500 km. These rocks are divided into higher TiO₂ (> 1.5 wt.%; referred to as HT) and lower TiO₂ (< 1.5 wt.%; LT) basalts. HT basalt has higher Na₂O + K₂O, HFSE and LREE, Zr/Y, and La/Yb compared to LT basalt. Both suite rocks show a wide range in Sr and Nd isotopic compositions (initial ⁸⁷Sr/⁸⁶Sr (SrI) = 0.70389 to 0.70631, initial ¹⁴³Nd/¹⁴⁴Nd(NdI) = 0.51248 to 0.51285). There is no any systematic variation amongst the studied Early Miocene basaltic rocks in terms of Sr–Nd isotope or Na₂O + K₂O and K₂O abundances, across three volcanic zones from the eastern through transitional to western volcanic zone, but we can identify gradual increases in SrI and decreases in NdI from north to south along the back-arc margin of the NE Japan arc. Based on high field strength element, REE, and Sr–Nd isotope data, Early Miocene basaltic rocks of the NE Japan back-arc margin represent mixing of the asthenospheric mantle-derived basalt magma with two types of basaltic magmas, HT and LT basaltic magmas, derived by different degrees of partial melting of the subcontinental lithospheric mantle composed of garnet-absent lherzolite, with a gradual decrease in the proportion of asthenospheric mantle-derived magma from north to south. These mantle events might have occurred in association with rifting of the Eurasian continental arc during the pre-opening stage of the Japan Sea.