塔里木北缘及邻区海西期碱性岩岩石化学特征及其大地构造意义

塔里木地台北缘及邻区发育一套以正长岩、石英正长岩、霓辉正长岩、霓霞正长岩、碱性花岗岩类为代表，包括碱性辉长岩、碱长花岗岩、霓辉花岗岩、角闪正长岩、碱性辉石闪长岩、煌斑岩等类岩石在内的碱性侵入岩体．它们具有近东西向的带状分布特征．主体形成于海西期．相当于泥盆-二叠纪．钾钠含量较高，具有碱性岩类的岩石化学特征．构成一条碱性侵入岩带．其时空分布与北山-阿拉善地区的碱性岩带基本一致．该碱性岩带反映出在泥盆-二叠纪期间．塔里木地台北缘及邻区处于造山期后的拉张构造环境．     

新疆库鲁克塔格阔克塔格西碱性岩年代学、岩石地球化学特征及其地质意义

阔克塔格西碱性岩体出露于库鲁克塔格地块东段,兴地断裂南0.5km,呈椭圆状岩株产出,出露面积约17.5km2。岩体北部和西北部侵入于古元古界兴地塔格群中亚群大理岩、片岩及片麻岩之中,南部和东南部分别侵入于中元古代黑云母石英正长岩和黑云母角闪二长岩中。岩体从边部至中心可分为霓石钠长岩、霓石角闪正长岩和角闪正长岩3个岩相带。岩体边部内接触带形成ERR-Nb-Ta-Zr中型矿床。岩体锆石U-Pb年龄(LA-ICP-MS方法)为(224±2)Ma。岩石主要矿物为微斜长石和条纹长石,暗色矿物主要为钠铁闪石,具有碱性岩典型的富碱、低硅的特点。此外,富集轻稀土元素,负Eu异常,富集Nb、Ta、Th及Hf等高场强元素,亏损Sr、P及Ti不相容元素。Hf同位素特征显示岩浆源于富集岩石圈地幔。地球动力学背景属造山后的板内演化阶段。     

塔里木北缘波孜果尔碱性(花岗)岩铌-钽-锆-铷-稀土矿床钠铁闪石、霓石特征及意义

碱性造岩矿物能够记录碱性岩源区特征、岩浆演化以及晚期成矿的重要信息,是开展碱性岩成岩成矿研究的有效手段。波孜果尔碱性花岗岩型铌-钽-锆-铷-稀土矿床位于塔里木北缘-中亚南天山晚古生代造山带,是塔里木地块北缘铌成矿带中典型的碱性岩型矿床。本文通过对含矿岩体中的霓石和钠铁闪石开展矿物学研究,结合全岩成分揭示波孜果尔稀有-稀土金属矿床含矿岩体的岩石类型、演化特征、构造背景及成矿条件。研究发现,含矿碱性岩体由霓石钠铁闪石碱长花岗岩、霓石钠铁闪石石英碱长正长岩、霓石钠铁闪石碱长正长岩组成。不同岩相岩石均表现出相似的稀土和微量元素配分模式,以富集轻稀土元素和高场强元素,亏损大离子亲石元素和重稀土元素为特征,具有显著的负Eu异常,指示三种岩石类型是同源岩浆演化的产物。含矿岩体中的辉石为霓石-霓辉石,角闪石为钠铁闪石。霓石和钠铁闪石稀土和微量元素配分模式相似且含量都较低,富集重稀土、亏损轻稀土,具有显著的负Eu异常,并富集Zr、Hf等高场强元素,亏损Ba、Sr等大离子亲石元素。霓石和钠铁闪石微量元素特征指示三个岩相单元的演化程度由低到高依次为霓石钠铁闪石碱长花岗岩→霓石钠铁闪石石英碱长正长岩→霓石钠铁闪石碱长正长岩,且结晶分异作用控制了岩体的形成。同时,早期霓石钠铁闪石碱长花岗岩的钠铁闪石呈现Ce正异常,晚期岩相中则无异常,指示演化的早期阶段氧逸度较高,随着磁铁矿等氧化物的结晶熔体趋于还原。波孜果尔含矿岩体成矿元素除Rb外分布并不均匀,表现为演化早期的岩相富集Nb,而演化晚期的岩相更富集稀土和Zr。进一步研究发现,塔里木北缘碱性岩带发育的铌、稀土、钽、锆、铷、铀等稀有稀土金属矿化与地幔柱引起的幔源岩浆底侵有关,其构造背景可能为地幔柱对造山带的叠置。     

四川锦屏山地区碱性杂岩锆石U-Pb年代学、地球化学特征及其地质意义

四川锦屏山地区碱性杂岩位于扬子地台西南缘,其岩体的主要岩石类型为霓石英碱正长岩、英碱正长岩、含萤石霓石钠闪-钠铁闪石碱性花岗岩、霓石(碱性)花岗斑岩、碱性伟晶岩脉。为确定该碱性杂岩的形成时代、成因及地质意义,对其进行了岩相学、LA-ICP-MS锆石U-Pb年龄及地球化学研究。结果表明,碱性杂岩中的锆石为岩浆成因,锆石~(206)Pb/~(238)U加权平均年龄为27.06±0.51Ma,侵入时代属于渐新世。该岩石具有富碱,高钾,贫镁、钙的岩石化学特征,属于碱性岩石系列。其稀土元素总量极高,轻、重稀土元素分馏明显,Eu异常不显著。微量元素相对富集Th、Zr、La、Nd等大离子亲石元素,亏损Nb、P、Ti等高场强元素的特征。综合以上数据、结合区域构造演化背景,说明该碱性杂岩为扬子地块插入到龙门山地壳的过程中,俯冲陆壳发生变质、脱水后形成的产物。     

安徽金寨响洪甸碱性侵入岩年代学、岩石地球化学及其意义

金寨响洪甸碱性侵入岩体分布在大别造山带东北缘的北淮阳地区,侵位于上元古界青白口系佛子岭群中。主要岩石类型为正长岩(似斑状正长岩)、碱性正长岩和霞石正长岩。正长岩的主要矿物为碱性长石及少量黑云母、普通辉石、绿钙闪石;碱性正长岩包含钾长石、角闪石、辉石和少量黑云母;霞石正长岩主要由碱性长石、霞石及少量绿钙闪石、普通辉石、次透辉石等矿物组成。化学成分上均具有偏铝质、富碱、高钾、贫钛的特点。富集大离子亲石元素K、Rb、U、Nd和轻稀土元素La、Ce、Pr、Nd、Sm,亏损高场强元素Nb、Ta、P、Ti,轻、重稀土元素比值及La/Nb、Ba/Nb值较高,呈弱的负铕异常。根据高精度同位素年代学测试结果,响洪甸碱性侵入岩成岩期次分为2期:早期霞石正长岩,LA-ICP-MS锆石U-Pb年龄为(135.1±0.7)Ma;晚期正长岩,SHRIMP锆石U-Pb年龄为(125.0±1)Ma和碱性正长岩,颗粒锆石U-Pb年龄为122.3 Ma。主体岩石似斑状正长岩的Hf同位素分析结果表明,其初始176Hf/177Hf比值为0.282 243~0.282 404,εHf(t)为-10.376~-16.602,结合该岩体的Sr-Nd同位素地球化学特征,推测响洪甸碱性侵入岩是富集地幔部分熔融的产物,其源区可能有部分陆壳物质的参与。其形成的构造背景为后碰撞的伸展环境。     

四川锦屏山地区碱性杂岩锆石U-Pb年代学、地球化学特征及其地质意义

四川锦屏山地区碱性杂岩位于扬子地台西南缘,其岩体的主要岩石类型为霓石英碱正长岩、英碱正长岩、含萤石霓石钠闪-钠铁闪石碱性花岗岩、霓石(碱性)花岗斑岩、碱性伟晶岩脉。为确定该碱性杂岩的形成时代、成因及地质意义,对其进行了岩相学、LA-ICP-MS锆石U-Pb年龄及地球化学研究。结果表明,碱性杂岩中的锆石为岩浆成因,锆石⁽²⁰⁶⁾Pb/(206)Pb/⁽²³⁸⁾U加权平均年龄为27.06±0.51Ma,侵入时代属于渐新世。该岩石具有富碱,高钾,贫镁、钙的岩石化学特征,属于碱性岩石系列。其稀土元素总量极高,轻、重稀土元素分馏明显,Eu异常不显著。微量元素相对富集Th、Zr、La、Nd等大离子亲石元素,亏损Nb、P、Ti等高场强元素的特征。综合以上数据、结合区域构造演化背景,说明该碱性杂岩为扬子地块插入到龙门山地壳的过程中,俯冲陆壳发生变质、脱水后形成的产物。     

山西临县紫金山碱性杂岩体SHRIMP锆石U-Pb年龄、地球化学和Sr-Nd-Hf同位素研究

山西临县紫金山碱性杂岩体位于华北克拉通内鄂尔多斯盆地东缘,为汾河富碱侵入岩带中最典型的碱性岩体。岩体主要岩石类型为二长岩、辉石正长岩、霓霞钛辉岩、暗霞正长岩、霞石正长岩、假白榴石斑岩和粗面斑岩。依据SHRIMP锆石U-Pb定年结果,结合前人的测年数据,确定岩体形成于138.7~125.0 Ma,系早白垩世碱性岩浆事件的产物。该套岩石高钾、富碱、贫钙和镁,属于碱性岩石系列。稀土元素总量高,轻、重稀土元素分馏明显,Eu异常不显著。微量元素富集LREE和Rb、Ba、K、Sr等大离子亲石元素,亏损HREE和Th、U、Nb、Ta、Ti等高场强元素。同位素分析结果显示全岩ISr为0.704 228~0.706 313,εNd(t)变化于-12.3~-0.5之间。锆石的εHf(t)为-20.2~-16.4,二阶段模式年龄tDM2为2.22~2.46 Ga。推测紫金山碱性杂岩体形成于华北克拉通中生代构造体制转折后的伸展背景下,因构造体制转换产生的强大应力作用导致吕梁地区软流圈多次上涌,随后软流圈、岩石圈地幔和下地壳物质部分熔融产生的岩浆发生多次不同比例的混合,所形成的各期混合岩浆分批上侵定位在地壳浅部环境,从而形成紫金山碱性杂岩体。汾河富碱侵入岩带形成时间集中于138.7~125.0 Ma,是华北克拉通中西部岩石圈破坏事件的岩浆活动证据,其与华北克拉通东部地区几乎同时发生岩石圈减薄作用。因构造体制转换产生强大应力作用导致构造薄弱地区软流圈上涌,进而引起大规模的壳-幔岩浆相互作用,可能为华北克拉通中西部地区中生代破坏的主要原因,并且由北至南壳幔岩浆相互作用中幔源岩浆逐渐减少。     

河北矾山杂岩体中单斜辉石的研究

1 岩相学及主量元素地球化学特征 矾山杂岩体位于河北省涿鹿县境内,岩体大致呈椭圆状,长约6 km,宽约5 km.岩石包括单斜辉石岩、黑云母辉石正长岩、辉石正长岩、碱性长石正长岩及细粒辉石正长岩.     

熊耳群火山岩系的上限年龄及其地质意义

元古宙伸展构造环境产出的壳幔型熊耳群火山岩系 ,具有向碱性演化的趋势。晚期有石英正长斑岩、霓辉正长岩、正长辉长岩产出 ,赋存在熊耳群中上部。应用单锆石U Pb法测定年龄 ,石英正长斑岩谐和年龄为 ( 1731± 2 9)Ma ,霓辉正长岩、正长辉长岩上交点年龄分别为( 1644± 14)Ma、( 1750± 65)Ma。1650～ 170 0Ma是碱性岩浆活动热构造事件的标志 ,石英正长斑岩被中元古代晚期的高山河组不整合覆盖 ,故以 1650～ 170 0Ma作为熊耳群的上限。1650～ 170 0Ma热构造事件是华北地块重大地质事件 ,有可能是进一步划分中元古代重要的年龄界限。     

内蒙古多伦中酸性侵入岩岩石地球化学特征及构造环境分析

内蒙古多伦县北部分布四个中酸性岩体,其岩石类型为:二长花岗岩、石英正长岩、石英正长斑岩和石英二长斑岩,出露面积0.5~12.4km~2不等,产状为岩株。同位素测龄成果显示二长花岗岩形成年龄为143.8±1.2 Ma,属晚侏罗世晚期(J_3);石英二长斑岩形成年龄为138.4±0.6Ma,属早白垩世早期(K_1)。岩石系列为高钾、钙碱性系列。据岩石地球化学特征推断:研究区内的四个岩体具同源特征,是岩浆同源演变的产物,岩浆来源为中下地壳。结合岩石Q-Ab-Or-H_2O相图,岩浆结晶温度接近750~800℃。二长花岗岩形成于大陆碰撞地球动力学环境即陆内造山构造环境;石英正长岩、石英正长斑岩、石英二长斑岩形成于造山后期构造环境。研究区在晚侏罗世晚期陆内碰撞造山运动已经结束而转入造山后期构造环境,至早白垩世早期大规模双峰式火山岩的喷发标志着研究区全面进入陆内造山后的裂谷阶段或者陆内伸展运动阶段。     

西昆仑塔什库尔干苦子干碱性杂岩体的成因及其构造意义

苦子干碱性杂岩体是塔什库尔干新生代碱性岩带的主要组成之一,主要由霓辉正长岩、石英霓辉正长岩和碱性花岗岩组成。霓辉正长岩、石英霓辉正长岩和碱性花岗岩的SiO2含量差别较大,分别为50．26％～54．11％、59．74％～60．43oA、69．59％～72．13％;霓辉正长岩与石英霓辉正长岩的里特曼指数相近,分别为7．83～10．97、8．51～9．05,明显不同于碱性花岗岩（2．49～3．71）。这3种碱性岩石都表现出富集轻稀土,以及K、Rb、Sr、Ba等大离子亲石元素（LILE）,亏损Nb、Ta、Ti等高场强元素（HFSE）的特征。其中异常高的Sr、Ba和∑REE含量暗示可能还有富集地幔物质的加入。利用原位锆石LA—ICP—MS同位素测试方法,获得石英霓辉正长岩和碱性花岗岩的锆石U—Pb年龄分别为10．9±0．1Ma和11．9土0．4Ma,代表了岩石的结晶年龄;石英霓辉正长岩锆石εHf（t）值为-9．78～3．24,碱性花岗岩中锆石εHf（t）值为-13．54～5．78,均显示岩浆源区具有壳幔混合的特点。依据这些资料,并结合区域地质研究的综合分析,笔者初步提出西昆仑塔什库尔干苦子干碱性杂岩体的形成是由于青藏高原在～25Ma期间主体拆沉作用发生后,造成软流圈物质向北逃逸,并受到北面塔里木克拉通岩石圈山根阻挡而上涌,进而发生壳幔混合作用的产物。因此,该杂岩体是青藏高原大规模拆沉后浆活动的远程效应,且标志着研究区在～11Ma期间已处于伸展构造背景。     

朝鲜半岛北部定州与铁山稀土矿相关碱性岩和花岗岩的岩石学和SIMS锆石U-Pb年代学特征研究

朝鲜半岛北侧的狼林地块是中朝克拉通的重要组成部分,狼林地块具有与辽南地块以及辽吉活动带类似的早前寒武纪岩石组成、变质和变形特征。我们在分布有稀土矿的朝鲜定州-铁山一带(狼林地块西北部),采集了与稀土矿密切相关的碱性岩(粗粒正长岩和萤石化霓辉正长岩)和花岗岩(似斑状花岗岩)样品。岩石样品的岩相学观察表明,定州与铁山地区的碱性岩和花岗岩并不显示明显的岩浆期之后的热液蚀变特征。SIMS锆石U-Pb定年结果显示粗粒正长岩的岩浆结晶年龄为1865±6Ma,萤石化霓辉正长岩的岩浆结晶年龄为1868±8Ma,铁山地区的四件似斑状花岗岩的年龄结果分别为1871±13 Ma、1866±8 Ma、1872±6 Ma和1873±7 Ma,这些年龄值一方面代表了岩浆活动时代,另一方面可能也代表了朝鲜定州和铁山稀土矿的成矿时代。狼林地块的这些碱性岩与花岗岩的时代与华北克拉通辽吉活动带以及狼林地块其它地区的高级变质作用同期,并且在辽南地块,也有类似碱性岩的报道。综合现有的证据表明,辽吉活动带、辽南地块以及狼林地块在古元古代可能属于同一个大型构造带,并且这个构造带(或者构造带的一部分)当时处于伸展的构造背景。通过全面对比野外观测结果、岩石的岩相结构、岩浆结晶时代可知,朝鲜定州和铁山一带的稀土矿与中朝克拉通的世界级稀土矿——白云鄂博,在岩石组合、稀土矿物组成、岩石蚀变特征、成矿时代等方面存在较大的区别。关于这一稀土矿的具体稀土矿物组成、矿床成因以及储量等众多问题,未来还需要进行大量的工作。     

阿尔金山东端余石山铌钽矿区霓辉正长岩的LA-ICP-MS定年及对成矿时代的制约

余石山铌钽矿床是近年来发现的一大型矿床,位于阿尔金造山带之红柳沟-拉配泉蛇绿构造混杂岩带、祁连造山带、欧龙布鲁克微陆块的结合部位。对矿区进行成矿背景研究时发现,矿区赋矿地层主要为长城系熬油沟组,岩性组合为变质火山岩及大理岩,穿插有霓辉正长岩体,其中发育细粒烧绿石与霓辉石等富铌钽矿物。并对霓辉正长岩进行锆石LA-ICP-MS年代学测定,结果表明霓辉石正长岩成岩年龄为(776.8±2.5)Ma,成矿与成岩年龄相近或稍晚,表明该霓辉正长岩和铌钽矿床可能形成于南华纪Rodinia超大陆裂解时所产生的大陆边缘裂谷构造环境。     

Nature and timing of the Solonker suture of the Central Asian Orogenic Belt: insights from geochronology and geochemistry of basic intrusions in the Xilin Gol Complex,Inner Mongolia,China

The Solonker suture zone of the Central Asian Orogenic Belt (CAOB) records the final closure of the Paleo-Asian Ocean. The nature and timing of final collision along the Solonker suture has long been controversial, partly because of an incomplete record of isotopic ages and differing interpretations of the geological environments of key tectonic units. The Xilin Gol Complex, consisting of strongly deformed gneisses, schists and amphibolites, is such a key tectonic unit within the CAOB. Lenticular or quasi-lamellar amphibolites are dispersed throughout the complex, intercalated with biotite–plagioclase gneiss. Both rock types experienced amphibolite-facies metamorphism. The protolith of the amphibolite is a basic rock that intruded into the biotite–plagioclase gneiss at 319 ± 4 Ma based on LA-ICPMS zircon U–Pb dating. The basic intrusion was sourced from a modified magma that experienced crystal fractionation and was admixed with slab-derived fluids. The slab-derived fluids, which formed during Early Paleozoic oceanic subduction along the north-dipping Sonidzuoqi–Xilinhot subduction zone, mixed with the magma source and produced subduction-related geochemical signatures superimposed on volcanic arc chemistry. After Early Paleozoic oceanic subduction and arc-continent collision, a transient stage of extension occurred between 313 and 280 Ma in the Sonidzuoqi–Xilinhot area. Deformation and recrystallization during the switch from compression to extension and reheating by the later magmatic intrusions reset the isotope systems of minerals in the Xilin Gol Complex, recorded by a 312.2 ± 1.5 Ma biotite ⁴⁰Ar/³⁹Ar age from biotite–plagioclase gneiss, a 309 ± 12 Ma zircon intercept age and a 307.5 ± 3.5 Ma hornblende ⁴⁰Ar/³⁹Ar age from amphibolites in the complex. There was an arc/forearc-related marine basin at the southern margin of the Xilin Gol Complex during the Permian. The closure of the oceanic basin led to Late Paleozoic–Middle Triassic north-dipping subduction beneath the Xilin Gol Complex and induced the amphibolite-facies metamorphism of the complex. The final suturing of the Solonker zone occurred from 269 to 231 Ma. This latest amphibolite-facies metamorphism with pressures of 0.31–0.39 GPa and temperatures of 620–660 °C was recorded at 263.4 ± 1.4 Ma to the Xilin Gol Complex, as indicated by the hornblende ⁴⁰Ar/³⁹Ar age from the amphibolites, as well as several zircon ages of 260 ± 3–231 ± 3 Ma. The Xilin Gol Complex documented the progressive accretion of a single, long-lived subduction system at the southern margin of the south Mongolian microcontinent from the Early Paleozoic (~452 Ma) to Middle Triassic (~231 Ma). The CAOB shows protracted collision prior to final suturing.     

辽宁赛马霓霞正长岩黑云母地球化学特征、40Ar-39Ar年龄及其地质意义

黑云母不仅是理想的40Ar-39Ar年代学定年矿物,其化学组成还可用来指示母岩浆物理化学条件、岩浆源区及分异演化程度、成矿潜力和成岩构造环境.本文对辽宁赛马碱性杂岩体中分布最为广泛的霓霞正长岩中的黑云母开展系统电子探针分析和40Ar-39Ar定年,结合pMELTS软件对前人全岩主量元素分析数据开展了平衡结晶计算,探讨了母岩浆物理化学性质、演化过程和成岩构造背景.电子探针分析结果表明赛马霓霞正长岩黑云母具有高铁高钛特征,属铁质黑云母.根据黑云母主量元素含量及比值估算黑云母结晶温度为770~800℃,lgf_O2介于-16~-14,而pMELTS平衡结晶计算结果表明整个霓霞正长岩岩浆体系于1 300℃以上便已开始结晶,且随温度降低氧逸度呈现不断降低的趋势,这种较高温度和持续降低的氧逸度环境不利于岩浆热液的分异,使得碱金属（Na）、挥发分及铀钍稀有元素保留在岩浆房内并在后期钠质岩浆（异霞正长岩）结晶分异过程中富集成矿.部分黑云母发育完好的振荡环带,且核部较幔部具有更高的TiO₂、Na₂O含量和更低的SiO₂含量和Fe3+/（Fe3++Fe2+）比值,也进一步证实黑云母结晶后残余岩浆具有更低氧逸度和更高Na含量.赛马碱性岩是华北克拉通北缘近东西向碱性岩带的一部分,本文获得其黑云母40Ar-39Ar年龄为222 Ma左右,形成于古亚洲洋闭合之后的后碰撞伸展构造背景.      

The Thermal History of the Huangmeijian Granite Intrusion in Anhiii and Its Relation to Mineralization: Isotopic Evidence

Abstract Whole—rock Rb—Sr, zircon U—Pb and hornblende, biotite and K—feldspar K—Ar ages are used to reconstruct the cooling history of the Huangmeijian intrusion in the Anqing—Lujiang quartz—syenite belt in Anhui. Oxygen isotope geothermometry of mineral pairs demonstrates that diffusion is a dominant factor controlling the closure of isotopic systems. Assuming the cooling of the intrusion is synchronous with a dicrease in local geothermal gradients, an emplacement depth of about 8 km and the magma crystallization temperature of 800 ± 50°C are estimated. The Huangmeijian intrusion experienced a rapid cooling process and uplifted after its emplacement and crystallization at 133 Ma B.P. with a cooling rate of 34.5°C / Ma and an uplifting rate of 0.35 mm/ a. The intrusion was rising until it rested at a depth of 3 km at a temperature of 300 ± 50°C about 14 Ma later. Then the intrusion was in slow cooling and uplifting with a cooling rate of 4.4°C / Ma and an uplifting rate of 0.04 mm/ a. U—Pb dating of pitchblende is done for the hydrothermal uranium deposit formed in the contact zone of the Huangmeijian intrusion. The result shows that the mineralization age is close to the closing time of the K—Ar system in biotite. The fluid inclusion thermometry indicates that the mineralization temperature is in agreement with the closure temperature of the biotite K—Ar system. This suggests a close relationship between the slow cooling of the intrusion and the hydrothermal uranium mineralization process.     

Geology,geochemistry and genesis of the Makou magnetite-apatite deposit in the Luzong volcanic basin,Middle-Lower Yangtze River Valley Metallogenic Belt,Eastern China

The Middle-Lower Yangtze River Valley Metallogenic Belt (MLYB) is located on the northern margin of the Yangtze Plate (Eastern China). Ore deposits in the belt are mainly clustered in seven ore districts, and are closely associated with Mesozoic intermediate-felsic magmatic rock. Among the seven ore districts, the Luzong and Ningwu districts host large-scale iron resources in volcanic basins. The Makou magnetite-apatite deposit in the southern Luzong Basin was previously interpreted to be related to a quartz syenite porphyry. In this study, we conducted field geological studies and determined the age and geochemistry of the Makou intrusive rocks. Petrography and electron probe micro analysis (EPMA) indicated that the Makou ore-hosting rocks have intense albite alteration. The wallrock alteration is spatially restricted, and comprises albite alteration (Stage I), magnetite mineralization (Stage II), quartz-sulfide alteration (Stage III) and carbonate alteration (Stage IV) stages. Fluid inclusions in syn-mineralization apatite homogenized at 252.2–322.6 °C, which slightly lower than is typical for magnetite-apatite deposits in the region. Field study revealed that the quartz syenite porphyry at Makou disrupted the orebodies along clear-cut intrusive contacts, and that the quartz syenite porphyry does not contain iron mineralization, suggesting it has no direct genetic relationship with the iron mineralization. The ore-hosting albitite and ore-forming biotite diorite have LA-ICP-MS zircon U-Pb ages of 129.6 ± 1.2 Ma and 131.2 ± 3.3 Ma, respectively, and the iron mineralization was dated by mass spectrometer phlogopite ⁴⁰Ar-³⁹Ar at 130.76 ± 0.77 Ma. We propose that the Makou magnetite-apatite deposit is genetically related to the biotite diorite, rather than to the quartz syenite porphyry in the mine pit. The biotite diorite closely resembles intrusions related to magnetite-apatite deposits elsewhere in the region.     

陕西小秦岭华阳川韧性剪切带的特征 及其区域构造意义

陕西小秦岭华阳川韧性剪切带发育在新太古界太华群之中,野外调研和显微构造观察结果表明,该韧性剪切带是由构造片岩、眼球状片麻岩组成的深层次韧性剪切带,具有逆冲兼左行走滑的斜冲特征。对韧性剪切带构造片岩黑云母进行^40Ar／^39Ar同位素定年,获得坪年龄为419M±0．6Ma,反等时线年龄为417Ma±0．8Ma。认为华阳川韧性剪切带及其相应的小秦岭区域主导构造变形是发生于419Ma左右的秦岭加里东事件的结果。     

Isotopic Geochronology of the Xianghongdian Alkaline Complex, Northern Margin of the Dabie Mountains, China

To the north of the Qinling-Dabie orogen there exists a Mesozoic (K1) granite-syenite belt called the Beihuaiyang granite-syenite belt, in which the Xianghongdian alkaline complex outcrops in the Devonian Foziling schist and also intruded into the slightly earlier volcanic rocks. This alkaline complex is composed of syenite, alkaline syenite and nepheline syenite, but the nepheline syenite occurs inside the alkaline syenite in the pod-like, irregular, lenticular or layered shape. Researches on the petrogenesis of the alkaline complex and the relationship between the alkaline syenite and the nepheline syenite must rely on precise isotopic ages. Previous researches have reported iso-topic dating results merely by the 40Ar/39Ar method on hornblende and biotite separated from the alkaline syenite and nepheline syenite. In view of this, the authors have made fairly detailed isotopic geochronological studies of the alkaline syenite and nepheline syenite by using Rb-Sr isochron for the whole rock and minerals,