泌阳凹陷核三下亚段砂岩成岩作用及储集性

泌阳凹陷东部核三下亚段砂岩储层由辨状河三角洲成因的长石砂岩及岩屑长石砂岩组成。主要成岩作用包括压实、石英和长石次生加大、晶粒状方解石胶结、溶解、自生绿泥石等，演化程度已达到晚成岩Ｂ亚期。成岩作用使砂岩原生孔隙体系发生强烈变化。各种成岩作用对储集性有不同影响，孔隙度的减少主要与压实及碳酸盐胶结作用有关；石英和长石次生加大及自生粘土衬边经常使喉道堵塞，对渗透率危害较大；溶解作用形成的次生孔隙及喉道对砂     

东营凹陷沙四段碳酸盐岩成岩作用研究

论文通过对济阳坳陷东营凹陷碳酸盐岩储层成岩作用分析,在碳酸盐储集岩中识别出了9种成岩作用,进行了成岩阶段的划分,结合成岩作用、孔隙演化和孔隙充填,建立了不同成岩期的成岩作用类型、孔隙演变及其它们间的相互关系,提出了6种成岩相.研究认为不同的成岩相对储层建设性起着不同的作用,白云岩化作用、溶蚀作用、去白云石化作用、构造破裂作用和流体充注作用对优质储层的形成与破坏起着非常重要的控制作用.研究成果对于陆相碳酸盐岩成岩作用的研究具有一定的参考价值.     

饶阳凹陷古近系成岩作用特征

通过26口井岩石薄片和铸体薄片的镜下观察及14口井扫描电镜等资料的分析,对饶阳凹陷古近系碎屑岩储层的岩石学特征、成岩作用及成岩相进行了研究。研究区储层砂岩的成分成熟度和结构成熟度均较低,岩石类型以长石砂岩和岩屑长石砂岩为主,磨圆中等,多呈次棱-次圆状,分选中等偏差。成岩作用主要有压实作用、胶结作用、交代蚀变作用、溶解作用等。中深部储层的成岩相组合可划分为胶结-溶解成岩相、胶结成岩相、压实-胶结成岩相、胶结-溶解-交代成岩相4种类型。     

箕状断陷湖盆缓坡带层序地层格架内成岩特征研究——以东营凹陷南部缓坡带沙河街组为例

东营凹陷在沙河街组沉积期为北陡南缓的箕状断陷湖盆。通过钻井岩心、测井、薄片及扫描电镜分析,在断陷湖盆的南缓坡带古近系沙河街组中识别出了冲积扇、河流、三角洲和湖？白沉积体系,以及滨浅湖砂坝和缓坡远端浊积扇沉积相。建立了东营凹陷南部缓坡带层序地层格架及层序演化模式。在此基础上,详细研究了层序地层格架内的成岩作用特征。层序地层格架内主要成岩作用类型有压实作用、压溶作用、溶解作用等,成岩阶段为早成岩A、B期,晚成岩A、B期。层序地层格架内发育了碳酸盐胶结、石英次生加大、高岭石胶结和泥岩压实四种成岩相。     

喀什凹陷白垩纪碎屑岩中流体包裹体研究

本文在成岩作用研究的基础上，对喀什凹陷白垩纪碎屑岩中的流体包裹体作了初步研究。通过包裹体的显微测温及包裹体的再平衡研究，得到碎屑岩的成岩温度及其经历的最大古地温，并利用包裹体资料对油气的运移及演化作了初步评价     

东营凹陷古近系砂岩成岩作用与孔隙演化

东营凹陷是重要的油气富集区，在古近系地层发育湖相水下扇沉积、滨浅湖沉积和三角洲沉积等砂岩。砂岩的成岩作用及孔隙演化对储层的储集性能有重要影响。在对大量薄片和岩心进行分析的基础上，运用扫描电镜和X衍射粘土分析等手段，对东营凹陷砂岩储层的成岩作用和孔隙演化进行了研究。研究结果表明，该区压实作用、胶结作用使砂岩孔隙度降低，不稳定矿物的溶蚀作用和碳酸盐胶结物的溶解作用导致孔隙度增大。根据有机质的演化及粘土矿物的变化序列，在不同的构造单元，砂岩成岩作用和孔隙演化随埋深具有明显的规律性，可划分出原生孔隙带、原生次生孔隙带和次生孔隙带3个孔隙演化带，存在着较有利的次生孔隙发育带。     

川中——川南过渡带上三叠统香溪群储层成岩作用的定量评价与成岩相

成岩作用目前还处于定性描述阶段，为定量描述成岩作用对储层物性的影响，笔者提出了压实系数、胶结系数、溶蚀系数及成岩系数概念，它们分别表征压实作用、胶结作用、溶蚀作用及成岩综合效应引起的储层孔隙度变化。沉积物在成岩演化过程中发生的主要成岩变化及基产物叫成岩相，成岩相变化可形成透镜状成岩储渗体，它是香溪群透镜状油气藏形成的原因。     

珠江口盆地砂岩疏松主控因素分析——以恩平凹陷M油田新近系韩江组地层为例

珠江口盆地恩平凹陷新近系浅层砂岩存在疏松现象，开发过程中出砂问题严重，为油田高效开采带来了很大的困难.通过对恩平凹陷M油田韩江组地层的沉积成因、成岩作用及油气充注期次的研究，揭示了砂岩疏松的主要控制因素，为后续根据属性情况进行井位调整等生产措施奠定了基础.研究结果表明，韩江组砂岩疏松的控因有3方面：一是研究区韩江组属于三角洲前缘沉积环境，粒度细，泥质含量高，不利于胶结成岩；二是成岩程度弱，属于早成岩A期，胶结程度弱；三是油气充注严重抑制了成岩作用.     

河南东濮凹陷深层储层分析

从砂岩岩石学特征、砂体类型、成岩作用、孔隙特征、储层类型及储层发育的控制因素等诸方面对河南东濮凹陷深层储层进行了分析。东濮凹陷深层 (沙三3 -4 亚段 )岩性以粉砂、细砂岩为主 ,成分成熟度中等 ,结构成熟度较高 ,成岩作用强烈 ,碳酸盐胶结和长石的溶蚀是最主要的成岩事件。深层砂岩经历了 5个成岩阶段。砂岩孔隙度明显受深度控制 ,深层砂岩发育 4种类型的孔隙 ,以残余溶蚀孔隙为主。深层储层可划分为常规储层和非常规致密储层。深层储层主要受成岩作用、砂体类型、地层压力及油气藏形成的控制。     

乌石凹陷流沙港组成岩作用及其孔隙演化

通过铸体薄片鉴定、X射线衍射、扫描电镜以及镜煤等多种实验手段对乌石凹陷流沙港组砂岩成岩作用及孔隙演化做了详细研究.结果表明:乌石凹陷流沙港组二段、三段岩石类型主要为石英砂岩,少量长石石英砂岩,粒级分选中等偏差.砂岩的成岩强度均已达到中成岩阶段A期.孔隙类型以原生粒间孔和次生溶蚀孔隙为主,压实作用、胶结作用等减少原生粒间孔隙,溶蚀作用产生大量的次生溶孔,改善储集层物性.     

Hydraulic conductivity of shallow sandy aquifers: Effects of sedimentologic and diagenetic differences

The relationship between values of hydraulic conductivity determined from grain-size methods,K _gr, and those from pumping-test methods,K _pt, have been evaluated statistically using data from recent and older sandy materials. It is shown that both methods generally give the same values only in recent sediments that have not been subjected to significant diagenetic alteration and give variable results in older and diagenetically altered sediments. The ratioK _pt/K_gr appears to vary, probably in response to the degree of diagenetic alteration. It is further found that methods incorporating the effects of grain size (d1O or d50) and sorting could give betterK values than those incorporating the effect of grain-size only and, thus, suggest the joint inclusion of both parameters in the grain-size determination of permeability.     

松辽盆地构造演化及成盆动力学探讨

松辽盆地晚侏罗世以来的构造演化经历了10个阶段:缓慢裂陷和快速坳陷—加速裂陷和快速坳陷—减速裂陷和慢速坳陷—慢速裂陷和快速坳陷—加速裂陷和加速坳陷—减速裂陷和减速坳陷—裂陷、坳陷终止和缓慢反转—快速反转和快速差异坳陷—慢速反转和慢速差异坳陷—反转停止和坳陷终止。构造发育演化的结果形成了“下断中坳上隆顶平”的盆地结构。“中坳”部分沉积的可容纳空间,54%来源于盆地基底的长期伸展坳陷;“上隆”部分沉积的可容纳空间,31%来源于盆地基底的受压坳陷。构造作用的转换起因于东部区域应力场的转变。     

Kinetic Modeling of Diagenesis of Eogene Lacustrine Sandstone Reservoirs in the Jianghan Basin,Southeastern China

In the Tuoshi oilfield,located in the Cenozoic Jianghan Basin of southeastern China ,there have been found hydrocarbon reservoirs hosted in lacustrine sandstones of the Eogene Xingouzui Formation.The main diagenetic features identified in these sandstones include the dissolution of detrital K-feldspar and albite grains,the precipitation of quartz as overgrowths and /or cements ,and the precipitation and /or transformation of clay minerals.These diagenetic features were interpreted to have occurred in early,intermediate and late stages,based on the burial depth.The kinetics of fluid-mineral reactions and the concentrations of aqueous species au each stage of diagenesis were simulated numerically for these lacustrine sandstones,using a quasi-sta-tionary state approximation that incorporates simultaneous chemical reactions in a time-space continuum.During the early diagenetic stage,pore fluid was weakly acidic,which resulted in dissolution of K-feldspar and albite and,therefore,led to the release of K^ ,Na^ ,Al^3 and SiO2(aq) into the diagenetic fluid.The increased K^ ,Na^ ,Al^3 and SiO2(aq) concentrations in the diagenetic fluid caused the precipitation of quartz,kaolinite and illite.At the beginning of the intermediate diagenetic stage the concentration of H^ was built up due to the decomposition of organic matter,which was responsible for further dissolution of K-feldspar and albite and pre-cipitation of quartz,kaolinite,and illite.During the late diagenetic stage,the pore fluid was weakly alkaline,K-feldspar became stable and was precipitated with quartz and clay minerals.When the burial depth was greater than 3000 m,the pore fluids became supersaturated with respect to allbite,but undersaturated with respect to quartz,resulting in the precipitation of albite and the dissolution of quartz.The diagenetic reactions forecasted in the numerical modeling closely matched the diagenet-ic features identified by petrographic examination, and therefore,can help us to gain a better understanding of the diagenetic processes and associated porosity evolution in sandstone reservoirs.     

Thermal equations of state of dioctahedral micas on the join muscovite–paragonite

 Powder diffraction measurements at simultaneous high pressure and temperature on samples of 2M1 polytype of muscovite (Ms) and paragonite (Pg) were performed at the beamline ID30 of ESRF (Grenoble), using the Paris-Edinburgh cell. The bulk moduli of Ms, calculated from the least-squares fitting of V–P data on each isotherm using a second-order Birch–Murnaghan EoS, were: 57.0(6), 55.1(7), 51.1(7) and 48.9(5) GPa on the isotherms at 298, 573, 723 and 873 K, respectively. The value of (∂K _T /∂T) was −0.0146(2) GPa K⁻¹. The thermal expansion coefficient α varied from 35.7(3) × 10⁻⁶ K⁻¹ at P ambient to 20.1(3) × 10⁻⁶ K⁻¹ at P = 4 GPa [(∂α/∂P) _T = −3.9(1) × 10⁻⁶ GPa⁻¹ K⁻¹]. The corresponding values for Pg on the isotherms at 298, 723 and 823 K were: bulk moduli 59.9(5), 55.7(6) and 53.8(7) GPa, (∂K _T /∂T) −0.0109(1) GPa K⁻¹. The thermal expansion coefficient α varied from 44.1(2) × 10⁻⁶ K⁻¹ at P ambient to 32.5(2) × 10⁻⁶ K⁻¹ at P = 4 GPa [(∂α/∂P) _T = −2.9(1) × 10⁻⁶ GPa⁻¹ K⁻¹]. Thermoelastic coefficients showed that Pg is stiffer than Ms; Ms softens more rapidly than Pg upon heating; thermal expansion is greater and its variation with pressure is smaller in Pg than in Ms. Received: 28 January 2002 / Accepted: 5 April 2002     

Therm odynamics of Diagenetic Fluid and Fluid／Mineral Reactions in the Eogene Xingouzui Formation,Oil Field T,Jianghan Basin

This study focuses on the thermodynamics of diagenetic fluid from the Eogene Xingouzui Formation which represents the most important reservoir in Field Oil T in the Jianghan Basin. The measured homogenization temperatures (110–139 °C) of fluid inclusions in diagenetic minerals fell within the range of 67 –155 °C at the middle diagenetic stage. The pressure of diagenetic fluid is estimated at 10.2 –56 MPa. The activity of ions in the fluid shows a tendency of Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ > Fe³⁺ > Fe²⁺ for cations, and HCO ₃ ⁻ > SO ₄ ²⁻ > F⁻ > Cl⁻ > CO ₃ ²⁻ for anions. For the gaseous facies, there is a tendency of CO₂> CO> H₂S> CH₄> H₂. According to the thermodynamic calculations, the pH and Eh of the fluid are 5.86–6.47 and −0.73–−0.64V, respectively. As a result of the interaction between such a diagenetic fluid and minerals in the sediments, feldspars were dissolved or alterated by other minerals. The clay mineral kaolinite was instable and hence was replaced by illite and chloritoid. This project was jointly funded by the National Natural Science Foundation of China (49133080) and the Open Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences.     

Magnetic susceptibility of the rock matrix related to magnetic fabric studies

Non-ferromagnetic minerals constitute what is called the rock matrix, whose susceptibility (K₁) is directly accessible using only high magnetic fields. Measurements on minerals and a wide range of rock types show that K₁ is mainly due to paramagnetism and hardly exceeds 10⁻³ SI, with an anisotropy degree (P) less than 1.35. Different methods to estimate the role of the matrix component in low-field susceptibility (K) and its anisotropy include petrological and chemical analysis, evolution of P vs K, low temperature studies and comparison of K with remanent magnetizations.     

Pressure–volume–temperature equation of state of andradite and grossular, by high-pressure and -temperature powder diffraction

 The thermoelastic parameters of natural andradite and grossular have been investigated by high-pressure and -temperature synchrotron X-ray powder diffraction, at ESRF, on the ID30 beamline. The P–V–T data have been fitted by Birch-Murnaghan-like EOSs, using both the approximated and the general form. We have obtained for andradite K ₀=158.0(±1.5) GPa, (dK/dT )₀=−0.020(3) GPa K⁻¹ and α₀=31.6(2) 10⁻⁶ K⁻¹, and for grossular K ₀=168.2(±1.7) GPa, (dK/dT)₀=−0.016(3) GPa K⁻¹ and α₀=27.8(2) 10⁻⁶ K⁻¹. Comparisons between the present issues and thermoelastic properties of garnets earlier determined are carried out. Received: 7 July 2000 / Accepted: 20 October 2000     

Vertical diffuse attenuation coefficient (Kd) based optical classification of IRS-P3 MOS-B satellite ocean colour data

The optical classification of the different water types provides vital input for studies related to primary productivity, water clarity and determination of euphotic depth. Image data of the IRSP3 MOS-B, for Path 90 of 27th February, 1998 was used for deriving vertical diffuse attenuation coefficient (K_d) and an optical classification based onK _d values was performed. An atmospheric correction scheme was used for retrieving water leaving radiances in blue and green channels of 412, 443, 490 and 550 nm. The upwelling radiances from 443 nm and 550 nm spectral channels were used for computation of vertical diffuse attenuation coefficientK _d at 490 nm. The waters off the Gujarat coast were classified into different water types based on Jerlov classification scheme. The oceanic water type IA (K _d range 0.035-0.040m^-1), type IB (0.042-0.065 m^-1), type II (0.07-0.1m^-1) and type III (0.115-0.14m^-1) were identified. For the coastal waters along Gujarat coast and Gulf of Kachchh, K_d(490) values ranged between 0.15 m^-1 and 0.35 m^-1. The depth of 1% of surface light for water type IA, IB, II and III corresponds to 88, 68, 58 and 34 meters respectively. Classification of oceanic and coastal waters based onK _d is useful in understanding the light transmission characteristics for sub-marine navigation and under-water imaging.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

海拉尔盆地乌尔逊-贝尔坳陷隆起带类型及对油气成藏控制作用

海拉尔盆地为典型的小型断陷湖盆,具有"下断上凹"的二元结构,"洼槽控油、隆起带控油"特征明显。本文在系统研究构造演化特征的基础上,分析了不同类型隆起带形成演化历史及对油气的控制作用。研究表明,海拉尔盆地构造演化历经了5个阶段:即铜钵庙组山间盆地、南一段和南二段被动裂陷盆地、南三段和南四段主动裂陷盆地、大磨拐河组-伊敏组断-坳转化盆地和青元岗组坳陷盆地。经历了3期强烈变形和2期强烈改造,被动裂陷的走滑作用导致反向断层及其下盘翘倾隆起,形成"长期淋滤造储、近洼不整合输导、反向断层遮挡" 的成藏有利条件,最终成为被动裂陷层序有利油气富集区带。主动裂陷伸展作用形成小型滚动背斜和中央隆起带,小型滚动背斜带形成"小而肥"构造油藏,而中央隆起带形成典型的复式油气聚集带。南屯组沉积末期构造反转,导致部分中央背斜带隆升剥蚀,断裂切割破碎,进而导致大气水下渗淋滤,有效改造基岩潜山储层,成为基岩潜山油藏的富集带。伊敏组沉积末期,形成正反转断层和反转期活动的正断层两种调整型断层,将早期聚集在断陷构造层的油气调整到大磨拐河组,聚集在反转构造及其边部,形成次生油气聚集带。