LA‐ICP‐MS Zircon U‐Pb Dating of Intermediate‐Acidic Intrusive Rocks and Molybdenite Re‐Os Dating from the Bangpu Mo (Cu) Deposit,Tibet and its Geological Implication

The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1?Ma (mean square of weighted deviates (MSWD) =9.5, n=8) and 60.60±0.31?Ma (MSWD=3.8, n=16), which belong to the late Cretaceous–early Paleocene in age. That means, they are products of an early tectonic-magmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19?Ma (MSWD=2.0, n=26) and 15.16±0.09?Ma (MSWD=3.9, n=5) separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2?Ma (MSWD=1.18, n=7) were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic–early Jurassic. Molybdenum (copper) ore-bodies produced in the monzogranite porphyry and copper (molybdenum) ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97–15.84?Ma, while isochron ages are 14.09±0.49?Ma (MSWD=26). The isochron ages of seven molybdenite from molybdenum (copper) ore with monzogranite porphyry type are 14.11±0.31?Ma (MSWD=5.2). There is great error in the isochron ages of four molybdenite from copper (molybdenum) ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2?Ma (MSWD=41), which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09?Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.     

西藏波龙斑岩铜金矿床的Re-Os同位素年龄及其地质意义

波龙斑岩铜金矿紧邻多不杂矿床,是多龙矿集区内新发现的一个超大型矿床。波龙矿床早期有两次成矿花岗闪长斑岩侵位,随后较晚期花岗斑岩侵位;地表广泛分布绢英岩化蚀变,深部发育钾化。本文对采于波龙斑岩型铜金矿床内石英-辉钼矿脉中的4件辉钼矿样品进行了Re-Os同位素测试,获得等时线年龄为119.4±1.3Ma (MSWD=0.63, n=4)。此年龄代表了波龙矿床的成矿年龄,与多不杂斑岩型铜金矿床的成矿年龄一致。波龙和多不杂斑岩型铜金矿床紧邻,并具有一致的成矿年龄,可能表明两个矿床的成矿受控于相同的构造-岩浆-成矿事件;斑岩铜矿具有成群分布的特征,波龙和多不杂斑岩铜金矿床的发现也暗示多龙矿集区具有找到其他大型斑岩铜金矿的潜力。     

Multiple and prolonged porphyry Cue Au mineralization and alteration events in the Halasu deposit,Chinese Altai,Xinjiang,northwestern China

The Halasu area is located in the southeastern margin of the Chinese Altai in Xinjiang, China. It is part of the Altaid orogenic collage where a number of porphyry-type Cue Moe Au deposits have been discovered in recent years. Geological mapping and drilling indicate the presence of various mineralized porphyritic intrusions in the Halasu Cue Au deposit, which is currently under exploration. Ue Pb dating of zircon crystals from four different mineralized porphyries reveals three significantly different ages of magmatic intrusion, i.e., ca. 372e382 Ma granodioritic porphyry and porphyritic granite, ca. 266 Ma quartz monzonitic porphyry, and ca. 216 Ma quartz dioritic porphyry. Ree Os dating of molybdenite from veinletdissemination ores in the granodioritic porphyry yields an age of mineralization of ca. 377 Ma, and Ar e Ar dating of K-feldspar from K-feldsparequartzechalcopyrite veins produces ages of ca. 269 and ca.198 Ma. The mineralization(and alteration) ages correspond broadly to the three episodes of magmatic intrusion, suggesting three overprinting porphyry mineralization events that are significantly separated in time. The first episode of porphyry intrusion and mineralization may be related to the magmatic arc being above a plate subduction zone, and the second was formed in a late-collisional environment during the closing of the Junggar Ocean, whereas the third episode of mineralization took place in the postcollisional stage. This case study suggests that in orogens where major porphyry deposits have been found in magmatic arc environments, the potential of discovering late- to post-collisional porphyry deposits cannot be neglected; conversely, in orogens where most porphyry deposits have late- to postcollisional ages, more attention should be paid to porphyries that were formed earlier in magmatic arc environments.     

拉萨地块北部~90Ma斑岩型矿床年代学及成矿地质背景

近年来青藏高原多个大型—超大型斑岩Cu-Mo-Au矿床的发现已引起人们广泛的关注,现有研究显示这些含矿斑岩和斑岩型矿床的形成年龄主要集中在120～110Ma、～90Ma、54～45Ma和18～12Ma4个阶段,其中90Ma左右的斑岩型矿床的成矿地质背景仍存在很大争议。本文报道拉萨地块北部尼玛县拔拉扎斑岩型矿床含矿斑岩的LA-ICPMS锆石U-Pb定年以及辉钼矿Re-Os定年结果,并分析了该期的成矿地质背景。两件花岗闪长斑岩锆石206Pb/238U加权平均年龄分别为92.1±1.2Ma、93.8±1.2Ma,代表了岩浆的结晶时代;而辉钼矿Re-Os模式年龄为88.2～89.6Ma,代表了拔拉扎矿床的成矿年龄。依据区域地质资料,本文认为拉萨地块北部～90Ma岩浆活动和成矿作用既不可能是雅鲁藏布江结合带所代表的新特提斯洋平板俯冲或洋脊俯冲的产物,也不可能是班公湖-怒江洋盆南向俯冲消减直接的产物,而很可能是班公湖-怒江洋盆俯冲消减闭合之后碰撞过程的产物。因此本文认为拉萨地块中北部地区～90Ma的岩浆作用及其成矿作用是形成于碰撞的构造背景。     

Late Jurassic Cu-Mo Mineralization at the Zhashui-Shanyang District, South Qinling, China: Constraints from Re-Os Molybdenite and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry U-Pb Zircon Dating

The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism. Laser Ablation-Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb zircon dating of two granodiorite intrusions (Xiaohekou and Lengshuigou deposits) was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8?to 152.6±1.2?Ma, averaging 150.5 Ma, accompanied by a younger disturbance age of 144.3±1.7?Ma in the Lengshuigou intrusion, which is in excellent agreement with published sensitive high resolution ion micro-probe (SHRIMP) zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit. Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry, yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma. These mineralization ages overlap rock-forming ages of the host intrusions within the error range. This implies that the mineralization occurred in the Late Jurassic, which belongs to the tectonic phase B event of the Yanshan Movement, not Cretaceous as previously thought. Therefore, the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period, the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates, perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.     

内蒙古长山壕金矿区花岗岩同位素年代学研究及地质意义

长山壕金矿床是近年来在内蒙古中西段找到的一特大型金矿床。尽管金矿化在中元古界白云鄂博群变质沉积岩内呈层状、似层状和透镜状产出,但是与各类花岗岩类侵入岩具有密切空间分布关系。本次研究采用LA-ICP-MS方法分别对有关花岗岩类侵入岩进行了系统年代学研究,花岗斑岩和二长花岗斑岩样品的锆石U-Pb年龄值分别为290.9±2.8Ma (MSWD=1.4)和287.5±1.9Ma (MSWD=2.4);2件黑云母花岗岩样品的年龄值分别为267.9±1.2Ma (MSWD=0.95)和274.0±2.3Ma (MSWD=1.4)。根据上述同位素年龄数据,同时结合金矿区野外地质调查和岩(矿)相学证据,可以认为,长山壕金矿区花岗斑岩和二长花岗斑岩及相关金矿床的形成时间为早二叠世早期,并且遭受到早二叠世晚期-中二叠世早期构造-岩浆活动的叠加改造,矿区切穿含金矿脉黑云母花岗岩体的存在就是很好的例证。强烈的中酸性岩浆作用为金矿床的形成提供了动力、热力和物质来源,初步研究结果表明,长山壕金矿床是海西期构造-岩浆作用及相关流体活动的产物,属于与侵入岩有关的中温热液脉型金矿床。     

Age and Tectonic Setting of Mesothermal Magmatic Hydrothermal Vein‐Type Pb–Zn–(Ag) Mineralization in the Xiaohongshilazi Deposit,Central Jilin Province,Northeast China

The Xiaohongshilazi deposit located in central Jilin Province, Northeast China, is a newly discovered and medium‐scale Pb–Zn–(Ag) deposit with ore reserves of 34,968 t Pb, 100,150 t Zn, and 158 t Ag. Two‐stage mineralization has been identified in this deposit. Stratiform volcanic‐associated massive sulfide (VMS) Pb–Zn mineralization interbedding with the marine volcanic rocks of the Late Carboniferous–Early Permian Daheshen Formation was controlled by the premineralization E–W‐trending faults. Vein‐type Pb–Zn–(Ag) mineralization occurs within or parallel to the granodiorite and diorite porphyries controlled by the major‐mineralization N–S‐trending faults that cut the stratiform mineralization and volcanic rocks. To constrain the age of vein‐type Pb–Zn–(Ag) mineralization and determine the relationship between mineralization and magmatism, we conducted LA–ICP–MS U–Pb dating on zircon from the ore‐bearing granodiorite and diorite porphyries and Rb–Sr dating on metal sulfide. Granodiorite and diorite porphyries yield zircon U–Pb weighted‐mean ²⁰⁶Pb/²³⁸U ages of 203.6 ± 1.8 Ma (Mean Standard Weighted Deviation [MSWD] = 1.8) and 225.6 ± 5.1 Ma (MSWD = 2.3), respectively. Sulfides from four vein‐type ore samples yield a Rb–Sr isochron age of 195 ± 17 Ma (MSWD = 4.0). These results indicate a temporal relationship between the granodiorite porphyry and vein‐type Pb–Zn–(Ag) mineralization. The granodiorite associated with vein‐type mineralization has high SiO₂ (68.99–70.49 wt.%) and Na₂O (3.9–4.2 wt.%; Na₂O/K₂O = 1.07–1.10) concentrations, and A/CNK values of 0.95–1.04; consequently, the intrusion is classified as a high‐K, calc‐alkaline, metaluminous I‐type granite. The granodiorite porphyry is enriched in large‐ion lithophile elements (e.g. Rb, Th, U, and K) and light REE and is depleted in high‐field‐strength elements (e.g. Nb, Ta, P, and Ti) and heavy REE, indicating that it represents a subduction‐related rock that formed at an active continental margin. Furthermore, the granodiorite porphyry has Mg# values of 31–34, indicating a lower crustal source. Based on petrological and geochemical features, we infer that the ore‐bearing granodiorite porphyry was derived from the partial melting of the lower crust. In summary, mineralization characteristics, cross‐cutting relationships, geochronological data, and regional tectonic evolution indicate that the region was the site of VMS Pb–Zn mineralization that produced stratiform orebodies within the Late Carboniferous–Early Permian marine volcanic rocks of the Daheshen Formation, followed by mesothermal magmatic hydrothermal vein‐type Pb–Zn–(Ag) mineralization associated with granodiorite porphyry induced by the initial subduction of the Paleo‐Pacific Plate beneath the Eurasia Plate during the Late Triassic–Early Jurassic.     

鄂东鸡冠嘴矿区成矿岩体锆石SHRIMP U-Pb定年及其意义

鄂东鸡冠嘴铜金(铁)矿床位于阳新岩体西北端,与铜绿山铜金矿床毗邻。矿区成矿岩体主要岩性为石英正长闪长玢岩、石英闪长岩、闪长岩和安山玢岩。其中石英正长闪长玢岩与成矿关系密切。在前人矿床地质特征研究基础上,笔者对成矿岩体进行了锆石SHRIMP U-Pb定年,获得石英正长闪长玢岩和闪长岩的年龄为146±2Ma(95%可信度,MSWD=1.3)和132±4Ma(95%可信度,MSWD=3)。测定结果表明,区内石英正长闪长玢岩和闪长岩分属燕山早期和燕山晚期岩浆活动的产物。鉴于矿体在空间上主要赋存于岩体内外接触带及层间破碎带中,推测成矿作用应略晚于石英正长闪长玢岩(146±2Ma)而早于闪长岩侵位的时间(132±4Ma),这与前人获得长江中下游铜铁金成矿带代表性矿床的辉钼矿Re-Os模式年龄分布在134.7～143Ma的研究结果一致。     

西藏雄梅铜矿区含矿斑岩与非含矿斑岩成因对比研究

西藏雄梅铜矿床是近年来在班公湖_怒江成矿带中段新发现的一处斑岩铜矿床,该矿床的发现使得班公湖_怒江成矿带真正具备了"带"的概念,大大地拓宽了找矿远景。文章通过对雄梅铜矿区斑岩体的LA_ICP_MS锆石U_Pb定年,发现矿区存在2套斑岩:一套是前人测定的年龄为106.7 Ma的含矿斑岩;另一套是本文测定的非含矿斑岩,3个年龄分别是(121.8±2.3)Ma(MSWD=0.32)、(122.8±2.1)Ma(MSWD=1.16)、(121.5±2.5)Ma(MSWD=0.54)。两套斑岩的岩性虽然都是花岗闪长斑岩,但非含矿斑岩比含矿斑岩含有更多的钾长石,矿化强度大大减弱。岩石地球化学分析结果表明,两套斑岩虽然都富集大离子亲石元素(LILE)Rb、Ba、Th、U、K、Pb,亏损高场强元素(HFSE)Nb、Ta、Ti,具有碰撞后岩浆作用的共同特征,但在岩浆源区和成因上显示出明显的差异。含矿斑岩和非含矿斑岩均属于强过铝质S型花岗岩,然而前者源区组成为杂砂岩,后者源区则以泥质岩为主。岩浆分异过程中,含矿斑岩受斜长石和钾长石的分离结晶控制,非含矿斑岩则受钾长石和黑云母的分离结晶控制。     

新疆伊吾琼河坝地区铜、金矿成矿时代及其找矿前景

文章采用高分辨率、高灵敏度离子探针(SHRIMP)和Rb-Sr等时线定年技术,对新疆伊吾琼河坝地区的云英山斑岩铜矿和淖毛湖北山金矿床的岩体和矿体进行了年代学研究,获得云英山斑岩铜矿区内斜长花岗斑岩体SHRIMP锆石U-Pb年龄为(411.7±7.1)Ma(95%置信度,MSWD=3.0),该矿床的含矿石英脉石英矿物Rb-Sr等时线年龄为(357±15)Ma(95%置信度,MSWD=0.16);淖毛湖北山金矿含矿石英脉中石英矿物Rb-Sr等时线年龄为(346±10)Ma(95%置信度,MSWD=0.19).测定结果显示,该区斑岩型铜矿和破碎带蚀变岩型金矿的形成时间为晚泥盆世-早石炭世,表明云英山式斑岩型铜金矿和淖毛湖式金矿成矿作用与泥盆纪-石炭纪汇聚阶段的火山-次火山岩浆活动有关,也意味着在琼河坝地区具有寻找与火山作用有关的铜、金多金属矿的潜力.     

西藏冈底斯南部陆陆碰撞早期成矿作用分析

冈底斯带南部发育有大量的斑岩铜钼矿床和矽卡岩型铜铅锌多金属矿床,形成了斑岩铜矿带和多金属矿带.前人的研究表明,成矿带内的矿床形成年代大都小于30Ma,处于碰撞后期伸展构造环境.本文对冈底斯带中南部的甲龙矽卡岩型铁矿、撒当金银矿床(点)和多底沟矽卡岩型钼矿床(点)开展了年代学研究,结果显示:甲龙铁矿黑云母二长花岗斑岩的锆石LA-ICP-MS U-Pb年龄为61.1 ±0.4Ma,MSWD=0.94;撒当赋矿安山岩锆石LA-ICP-MS U-Pb年龄为62.6±0.5Ma,MSWD=1.51;多底沟钼矿床(点)3件辉钼矿Re-Os模式年龄为64.3±0.8Ma ～ 69.2±3.3Ma,加权平均模式年龄为66.7±6.4Ma(MSWD=8.1).三个矿床(点)的同位素年龄表明成岩成矿事件和印度-欧亚板块陆陆碰撞早期构造岩浆事件有关.结合前人工作,我们提出冈底斯中南部发生了大规模与陆陆碰撞早期岩浆事件有关的成矿作用,形成了大面积分布的矿床,具有良好的找矿前景,应引起更多关注.     

青海野马泉铁锌矿床二长花岗岩锆石U-Pb和金云母Ar-Ar测年及地质意义

青海野马泉铁锌矿床地处祁漫塔格山与柴达木盆地之间的盆山结合部位,是矽卡岩型铁锌多金属矿床。矿体均呈隐伏?半隐伏状产出、具多期次强烈岩浆活动叠加等特征。长期以来,有关野马泉铁锌多金属矿床的成矿岩体和成矿时代众说纷纭,制约了对该矿床成因机制的认识及进一步的矿产勘查工作。本文基于详细的野外实地调查和矿床地质特征解剖,开展了成岩成矿年龄精测,探讨了成矿构造环境。铁锌矿体产于二长花岗岩与围岩地层的外接触带,发育石榴子石、透辉石、金云母、绿帘石等矽卡岩化作用。利用LA-ICP-MS锆石U-Pb法,获得成矿二长花岗岩的年龄为229.5±2.2 Ma(n=22,MSWD=1.3);采用Ar-Ar分步升温法获得与磁铁矿共生的金云母坪年龄为222.0±1.3 Ma(MSWD=0.41)、等时线年龄为222.4±2.5 Ma(MSWD=1.4),证实野马泉铁锌多金属矿床形成于晚三叠世,成矿岩体属过铝质、高钾钙碱性系列,为I-A过渡型花岗岩,具有高SiO_2,高K_2O/Na_2O,低P_2O_5,低Sr高Yb的特点。结合区域其他多金属矿床最新成岩成矿年代学数据,认为野马泉矿床形成于东昆仑地区海西?印支造山旋回晚期、由碰撞向后碰撞转换的地质构造环境。     

粤北大宝山多金属矿床LA-ICP-MS锆石U-Pb和辉钼矿Re-Os定年及其地质意义

对粤北大宝山多金属矿床次英安斑岩(样品ZK5803)中锆石LA-ICP-MS U-Pb定年结果为(174.6±1.5)Ma(MSWD=0.7),与矿区花岗闪长斑岩的形成年龄基本一致;3个斑岩型和矽卡岩型钼钨矿石辉钼矿Re-Os模式年龄为(163.2±2.3)Ma(样品CD-30)、(165.2±2.4)Ma(样品DB-18)和(163.4±2.4)Ma(样品CD-38),与层状铜铅锌矿中辉钼矿Re-Os模式年龄(164.7±3.0)Ma基本一致;上述4个样品给出的加权平均年龄为(164.0±2.5)Ma(MSWD=0.16);该成矿年龄与南岭地区其他钼多金属矿床形成时间一致,同属于华南地区中生代第二阶段成矿作用。矿床地质特征、流体包裹体氢氧同位素(δ18O=-3.75‰～7.0‰,δD=-50.7‰～-56.1‰)和矿石硫化物硫同位素(δ34S=-2.00‰～3.00‰)资料表明,该矿床为与矿区次英安斑岩和花岗闪长斑岩有成因联系的岩浆期后热液矿床。矿区各类矿床应为同一期成矿事件的产物,不同于前人认为的存在加里东期海底喷流沉积和燕山期叠加成矿,或燕山期两期成岩成矿的观点。结合岩石微量元素图解和前人研究结果,推测其成矿动力学背景为南岭地区后造山伸展环境。     

Re–Os and U–Pb geochronology of porphyry Mo deposits in central Jilin Province: Mo ore-forming stages in northeast China

Central Jilin Province lies along the eastern edge of the Xing–Meng orogenic belt of northeast China. At least 10 Mo deposits have been discovered in this area, making it the second-richest concentration of Mo resources in China. To better understand the formation and distribution of porphyry Mo deposits in the area, we investigated the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of mineralization. Our new geochronological data show the following: the Jidetun Mo deposit yields molybdenite Re–Os model ages of 164.6–167.1 Ma, an isochron age of 168 ± 2.5 Ma, and a weighted mean model age of 165.9 ± 1.2 Ma; the Houdaomu Mo deposit yields molybdenite Re–Os model ages of 167.4–167.7 Ma, an isochron age of 168 ± 13 Ma, and a weighted mean model age of 167.5 ± 1.2 Ma; and the Chang’anpu Mo deposit yields a zircon U–Pb age for granodiorite porphyry of 166.9 ± 1.5 Ma (N = 16). These new age data, combined with existing molybdenite Re–Os dates, show that intense porphyry Mo mineralization was coeval with magmatism during the Middle Jurassic (167.8 ± 0.4 Ma, r > 0.999). The geotectonic mechanisms responsible for Mo mineralization were probably related to subduction of the Palaeo-Pacific plate beneath the Eurasian continent. Combining published molybdenite Re–Os and zircon U–Pb ages for northeast China, the Mo deposits are shown to have been formed during multiple events coinciding with periods of magmatic activity. We identified three phases of mineralization, two of which had several stages: the Caledonian (485–480 Ma); the Indosinian comprising the Early–Middle Triassic (248–236 Ma) and Late Triassic (226–208 Ma) stages; and the Yanshanian phase comprising the Early–Middle Jurassic (202–165 Ma), Late Jurassic–early Early Cretaceous (154–129 Ma), and Early Cretaceous (114–111 Ma) stages. Although Mo deposits formed during each phase/stage, most of the mineralization occurred during the Early–Middle Jurassic.     

内蒙古大井矿区及外围岩浆岩锆石U-Pb年龄及其对成矿时间的约束

大井是内蒙古东部地区的一处大型铜银锡多金属矿床,矿体呈脉状产出在二叠系林西组地层中,受NW或NWW向断裂控制。本文对大井矿区及其外围主要侵入岩体和火山岩开展了年代学和地球化学研究。LA-MC-ICP-MS锆石测年结果表明,大井矿区内靠近1号矿脉产出的2件霏细岩脉样品的锆石年龄分别为170.7±1.4Ma(MSWD=1.9)和170.7±1.1Ma(MSWD=1.3);矿区外围马鞍子黑云母二长花岗岩体的锆石年龄为279.7±1.3Ma(MSWD=0.74);唐家营子附近安山玢岩脉的锆石年龄为252.0±1.8Ma(MSWD=1.6);大四段村似斑状黑云母二长花岗岩体的锆石年龄为242.8±1.7Ma(MSWD=1.7);采自大坝南部的流纹质晶屑熔结凝灰岩、流纹质火山角砾熔岩和晶屑凝灰岩的锆石年龄分别为143.5±0.7Ma(MSWD=0.38),144.3±0.7Ma(MSWD=1.2)和145.3±1.0Ma(MSWD=2.5);小城子村南部石英斑岩脉的锆石年龄为146.1±0.9Ma(MSWD=1.7),安山玢岩脉的锆石年龄133.2±0.7Ma(MSWD=0.96)。反映本区至少存在四期岩浆活动,分别是海西晚期、印支早期、燕山早期和燕山中期。岩石地球化学分析结果表明,大井矿区及外围主要侵入岩(黑云母二长花岗岩、似斑状黑云母二长花岗岩、霏细岩、安山玢岩和石英斑岩)均为富SiO₂、富碱、准铝的钙碱性岩石,在SiO₂-K₂O图解上均落入"高钾钙碱系列"区。所有的岩石样品具有轻稀土分异明显、富集大离子亲石元素(LILE)的特征,其中Ba、Nb、Sr、P、Ti相对亏损,而Rb、Th、K、Ce、Nd、Hf、Sm、Y 和Yb相对富集。侵入岩和火山岩的年代学与岩石地球化学特征表明,马鞍子黑云母二长花岗岩和大四段村似斑状黑云母二长花岗岩的侵位可能与古亚洲洋的碰撞闭合有关,形成于挤压的构造环境;燕山早期侵入岩在本区并不发育,其形成环境还有待进一步查明,可能与西伯利亚板块和蒙古-华北板块之间的鄂霍茨克洋消亡及后碰撞造山有关;而燕山晚期大规模的侵入-火山喷发活动可能是由岩石圈减薄,区域大规模伸展所引起。根据本文对矿区内及外围侵入岩与火山岩的年代学研究,结合矿区地质和前人研究成果,认为大井铜银锡矿床的成矿主要与晚侏罗世-早白垩世岩浆活动(146~133Ma)有关,是区域伸展构造背景下岩浆活动的产物。     

陕西洛南县石家湾钼矿Re-Os同位素年龄及地质意义

陕西石家湾钼矿床位于东秦岭成矿带西段黄龙铺地区,钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化,属斑岩型矿床.在矿床中选取不同矿化类型的辉钼矿样品,进行了Re～Os同位素定年,获得模式年龄变化范围为143.1±2.1～145.1±2.2 Ma之间,其加权平均年龄(144.0±1.1 Ma,MSWD=0.91)、等时线年龄(145.4±2.1 Ma,MSWD=0.83)与石家湾斑岩体的成岩年龄(141.4±0.6Ma)相近,说明成岩成矿作用发生在晚侏罗世一早白垩世.综合辉钼矿中Re的含量、硫同位素以及相关岩体的源区特征等多方面证据认为,石家湾斑岩型钼矿的成矿物质主要来自于下地壳,并混有少量幔源成分.     

西藏曲水县达布斑岩铜(钼)矿床成岩成矿年代学研究

本文采用锆石LA-ICP-MS微区U-Pb测年技术,对冈底斯成矿带东段曲水县达布斑岩Cu(Mo)矿床北部达布矿区含矿斑岩体、南部显角囊含矿花岗闪长斑岩岩体进行了年代学研究,通过对3件岩体样品中单颗粒锆石的分析,达布主矿体花岗闪长斑岩样品206Pb/238U年龄加权平均值为16.5±0.05Ma(n=15,MSWD=3),达布主含矿体二长花岗斑岩样品年龄为16.1±0.13Ma(n=15,MSWD=1.03),南部显角囊矿体花岗闪长斑岩年龄为16.2±0.04Ma(n=13,MSWD=0.0064)。对达布矿床斑岩Cu(Mo)矿床主矿体中4件辉钼矿样品,显角囊矿体中6件辉钼矿样品,分别进行了Re-Os同位素测试,等时线年龄分别为14.6±0.50Ma(MSWD=0.35,主矿体)、14.8±0.23Ma(MSWD=1.3,显角囊)。结合前人研究以及本次测年结果认为:1)达布斑岩铜(钼)矿床岩体侵位的年龄应限定在16Ma左右,成矿时代为14Ma左右,成矿时间差小于0.86Ma,与区域上"成矿瞬时发生"的成矿规律是一致的;2)矿床产出于印度-亚洲大陆板块后碰撞伸展环境。     

Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China

The Tongcun Mo porphyry deposit in northwest Zhejiang is hosted in three porphyry units: Huangbaikeng, Songjiazhuang, and Tongcun, from southwest to northeast. U–Pb zircon ages of 162?±?3.0 Ma for the Huangbaikeng porphyry, 159.9?±?3.0 Ma for the Songjiazhuang porphyry, and 167.6–155.6 Ma for the Tongcun porphyry indicate that these intrusions formed during the Jurassic and are most likely associated with the northwestward subduction of the Izanagi Plate. Trace element compositions of zircons from the Tongcun deposit constrain the oxygen fugacity (fO₂) of the magma using zircon Ce anomalies and Ti-in-zircon temperatures. The average magmatic fO₂ for the porphyries in the Tongcun deposit is fayalite–magnetite–quartz (FMQ)?+?2.7, which is similar to the Shapinggou (FMQ?+?3.2) and Dabaoshan (FMQ?+?3.5) Mo porphyry deposits, but much higher than that of the reduced Cretaceous ore-barren Shangjieshou porphyry (FMQ-1.1) around 8 km away from the Tongcun deposit. The distinct difference in magmatic oxygen fugacity between the Jurassic and Cretaceous porphyries may help to explain the absence of Mo porphyry mineralization in northwest Zhejiang during the Cretaceous.     

赣北阳储岭斑岩型钨钼矿床成矿岩体副矿物U-Pb年龄精确厘定

赣北阳储岭大型斑岩型钨钼矿床地处江南造山带东部九岭-障公山隆起带,是江南钨矿带典型的斑岩型白钨矿矿床。钨钼矿体主要发育于二长花岗斑岩内,少量发育于花岗闪长岩和爆破角砾岩中。矿体以脉状、网脉状、似层状、透镜状、星点状产出。前人针对阳储岭矿床已开展全岩Rb-Sr法、全岩K-Ar法、锆石U-Pb法、辉钼矿Re-Os法等诸多定年工作,但因“过剩Ar”的存在、后期热事件扰动和高U花岗岩中锆石发生蜕晶化等原因,导致成岩年龄结果及解释仍存在争议。文章选取与成矿相关的二长花岗斑岩开展了独居石和金红石原位LA-ICPMS U-Pb同位素定年分析,以精确厘定成矿岩体的侵位年龄。研究表明,独居石年龄为（146.06±0.61）Ma(MSWD=10.2),金红石年龄为（150.20±2.60）Ma(MSWD=1.13)。此外,独居石是开展高U成钨岩体定年的有力对象,独居石年龄与前人发表的高精度辉钼矿Re-Os年龄在误差范围内相一致,独居石年龄可更准确地代表矿床的成矿岩体年龄。阳储岭矿床所处的江南钨矿带内的矿床形成时代主要可分为中侏罗世（约162 Ma）、晚侏罗世（150～135 Ma）和早白垩世（135～12...     

U–Pb and Re–Os geochronology and geodynamic setting of the Dabaoshan polymetallic deposit, northern Guangdong Province, South China

The Dabaoshan polymetallic deposit in northern Guangdong Province contains iron, copper, lead, zinc, molybdenum, tungsten and sulfur mineral resources. Porphyry-type Mo(W) and skarn-type Mo-W mineralization occurs along the internal and external contact zones of the granodioritic porphyry, respectively. LA-ICP-MS U–Pb dating of zircons from two granodioritic porphyry samples yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 175.8 ± 1.5 Ma (MSWD = 0.037) and 175.0 ± 1.7 Ma (MSWD = 0.41). They can be pooled together to yield a combined weighted age of 175.4 ± 1.6 Ma (MSWD = 0.26), which is interpreted as the emplacement age of the granodioritic porphyry. Re–Os dating of three molybdenite samples from porphyry and skarn ores yielded consistent model ages of 163.2 ± 2.3 Ma to 165.2 ± 2.4 Ma, with a weighted mean of 163.9 ± 1.3 Ma (MSWD = 0.81), which is the age of Mo–W mineralization. These ages are consistent with the molybdenite Re–Os model age (164.7 ± 3 Ma) measured by Mao et al. (2004a) for the stratiform Cu–Pb–Zn orebody, and they can yield a weighted mean of 164.0 ± 2.5 Ma (MSWD = 0.16). This implies that Mo–W and Cu–Pb–Zn mineralization in the Dabaoshan polymetallic deposit are the products of one mineralization event. The mineralization in the deposit coincides closely with that of Mo-polymetallic mineralization (164–149 Ma) elsewhere in the Nanling region, comprising an important polymetallic metallogenic belt of south China, and corresponds to the second episode of Mesozoic metallogenesis in South China. Combined with previous studies, we suggest that the Dabaoshan polymetallic deposit is related to post-collisional lithosphere extension in the Nanling region of South China. Geological data and Pb isotopic evolution diagrams, together with stable isotopic data of fluid inclusions (δ¹⁸O = − 3.75–7.0‰, δD = − 50.7 to − 56.1‰) and ore sulfides (δ³⁴S = − 2–3‰), suggest a genetic relationship between the Dabaoshan polymetallic deposit, the granodioritic porphyry and the dacitic porphyry. These data, combined with the Re content (64.7 to 102.4 ppm) of molybdenite, indicate that the ore-forming components were derived from mixed crustal and mantle sources.