西藏尕尔穷铜金矿床花岗岩类的地球化学特征及其地球动力学意义

尕尔穷铜金矿位于念青唐古拉板片与南羌塘板片之间的班公湖-怒江缝合带西段,区内花岗岩类形成于燕山晚期,主要为中酸性侵入岩,以岩基、岩株、岩枝、岩脉等形态产出。岩石具有较低的SiO2(52.92%～79.21%,多数集中在60%～65%,平均为63.64%)和较高的Al2O3(10.43%～16.49%,平均为15.23),高碱(ω(Na2O+K2O):4.86%～7.15%),ω(Na2O)/ω(K2O)比值变化较大(0.26～2.26),弱的负铕异常和负铈异常,相对富集不相容元素Rb、Th、K、Ce,而Ba、Ta、Nb、Ti亏损。这些特征表明花岗岩类是准铝质-弱过铝质钙碱性I型花岗岩,其源区物质可能是基性玄武质成分,形成于与板块俯冲有关的活动大陆边缘的陆缘弧环境,为深部地壳物质熔融后与幔源基性岩浆混合作用的产物。     

内蒙古天和永新生代玄武岩成因及其地质意义

天和永玄武岩为碧玄岩,至少可以划分出3种矿物共生组合类型。天和永玄武岩总体具有贫硅(w(SiO2)=43.97%～45.68%)、富碱(w(K2O+Na2O)=5.91%～7.65%)、富钾(w(K2O)=2.04%～2.89%)、高钛(w(TiO2)=2.18%～2.37%)、高Mg值(Mg#=68～76)的特征;稀土元素含量高(∑REE=(246.62～329.82)×10-6),稀土配分曲线呈右倾平滑直线,强烈富集轻稀土,轻重稀土强烈分馏((La/Yb)N>30),无明显的Eu(δEu=0.90～1.02)和Ce异常(δCe=0.96～1.00);强烈富集不相容元素,其中高场强元素(HFSE)Nb、Ta和Th出现峰值,具有近似OIB配分型式的特征;玄武岩富含相容元素Co((39.1～48.9)×10-6)、Ni((130～257)×10-6)、Cr((138～320)×10-6)。上述所有特征以及岩石结晶程度低、富含橄榄岩包体和少量捕虏晶、元素变异关系等均表明,天和永玄武岩是原生玄武岩质岩浆固结的产物。微量元素比值Ba/Rb(12～35)和碱金属的变化暗示源区可能遭受过流体的交代作用,源岩可能是富集的二辉橄榄岩。岩石成因模拟表明,形成天和永玄武岩的原生岩浆是在变压、部分熔融的条件下富集地幔源区岩石非实比熔融的产物,变压熔融柱穿切了Sp/Gt二辉橄榄岩相边界。岩浆形成于源区岩石的低度(约<5%)部分熔融,其中石榴石二辉橄榄岩部分熔融约为1%,尖晶石二辉橄榄岩部分熔融2%～5%。综合分析显示,源区部分熔融的触发机制是边际驱动的地幔对流,因而其形成深度大于东部的集宁玄武岩和汉诺坝玄武岩。     

江西崇义铁木里钨铁矿区内辉绿玢岩的年代学、地球化学特征及地质意义

华南地区中生代基性岩浆岩以拉斑玄武岩系列为主,碱性系列少见.江西崇义铁木里地区发育由碱性辉绿玢岩和A型花岗岩组成的双峰式侵入岩组合,对其中的辉绿玢岩开展了矿物学、年代学和地球化学研究.辉绿玢岩的斑晶矿物以次透辉石为主,少量为透辉石和普通辉石;基质中的斜长石为中长石（Ab=39.11%~43.30%）,角闪石为钛闪石.LA-ICP-MS锆石U-Pb定年结果表明辉绿玢岩的形成不早于136.6 Ma.岩石具有低SiO₂（41.73%~46.68%）、TiO₂（1.72%~1.94%）,富TFeO（7.64%~9.24%）、Al₂O₃（15.70%~17.22%）,全碱含量高（5.28%~6.60%）的特征,Mg#值为0.51~0.54,属于碱性玄武岩系列.轻重稀土元素之间、轻稀土元素内部分馏强（（La/Yb）_N=17.58~22.28,（La/Sm）_N=4.72~5.18）,Eu异常不明显（δEu=0.84~0.99）,显著富集大离子亲石元素,轻微富集高场强元素,过渡族元素含量较原始地幔偏低.Nd同位素表现为亏损特征（ε_Nd=+3.45）,（87Sr/86Sr）_i=0.707 5,（206Pb/204Pb）_i=18.769 6,（207Pb/204Pb）_i=15.733 7,（208Pb/204Pb）_i=39.110 0,显示OIB与EMII过渡特点.矿物成分、岩石地球化学、Nd同位素特征指示铁木里辉绿玢岩源自软流圈,部分熔融发生于石榴石稳定域,是软流圈地幔减压低程度熔融的产物,碱性玄武质岩浆与陆壳物质之间的同化混染作用较弱,岩浆演化过程中发生了单斜辉石、磷灰石和铁钛氧化物的分离结晶作用.华南内陆在白垩纪处于伸展拉张的应力状态,碱性玄武质岩石形成于岩石圈拉张和超壳深大断裂联合作用形成的板内伸展裂解（类裂谷）构造环境.      

新疆阿尔泰东南缘哈拉乔拉镁铁质岩体地球化学特征与地质意义

哈拉乔拉镁铁质岩体位于新疆阿尔泰造山带东南缘, 主要岩石类型有辉长岩、辉长苏长岩、含长辉石岩、橄榄辉长岩和橄长岩.哈拉乔拉岩体具有低TiO₂(0.09%~1.28%)、低碱(Na₂O+K₂O=0.37%~0.78%)的特点, 属于拉斑玄武岩系列; 富集大离子亲石元素和轻稀土元素, 亏损高场强元素(Nb、Ta等), ε_Nd(t)为-2.62~-0.78, ε_Sr(t)为37.49~45.28.元素地球化学和Nd-Sr同位素组成表明, 岩浆源区为被消减板片交代改造过的富集型岩石圈地幔.原生岩浆为高镁拉斑玄武岩浆, 岩浆演化过程中主要发生了橄榄石、单斜辉石以及斜长石的分离结晶/堆晶, 后期有钛铁矿的析出.      

Permian High Ba-Sr Granitoids: Geochemistry, Age and Tectonic Implications of Erlangshan Pluton, Urad Zhongqi, Inner Mongolia

Abstract: Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemical characteristics reveal that the diorites belong to metaluminous, high-potassium calc-alkaline series, with chemical signatures of I-type granites. They are characterized by low SiO2 contents (56.63%–58.53%) and A/CNK (0.90–0.96), high Al2O3 contents (17.30%–17.96%) and Na2O/K2O ratios (1.20–1.70), enrichment in large ion lithophile elements (LILE, e.g., Ba=556–915 ppm, Sr=463–595 ppm), and relative depletion in high field strength elements (HFSE, e.g., Nb, Ta, Ti) in primitive mantle-normalized spidergram, and right-declined rare earth element patterns with slightly negative Eu anomalies (d?Eu=0.72–0.90). They have Sr/Y ratios (20–25) evidently less than Kebu Pluton (49–75) to its east. Sensitive high resolution ion micro-probe U-Pb zircon dating of the diorites has yielded an intrusive age of 270±8?Ma. This leads us to conclude that Erlangshan diorites were formed by mixing between the middle or lower crustal-derived magma and minor mantle-derived mafic magma, followed by fractional crystallization, which was trigged by crustal extension and fault activity in post-collisional setting.     

鲁西金岭地区含矿闪长岩体成因:来自锆石U-Pb年代学和地球化学证据

鲁西金岭闪长岩位于华北克拉通东南部,主要由辉石闪长岩-黑云母闪长岩组成。LA-ICP-MS锆石U-Pb定年测定闪长岩侵位年龄为(129.17±0.96)和(130.15±0.65)Ma,属于早白垩世岩浆活动的产物。闪长岩SiO2和K_2O的质量分数较低,MgO、Na_2O、Fe_2O_3、MgO和Al_2O_3的质量分数较高,Mg#为58.00~70.00。Na_2O/K_2O为1.08~2.96,相对富钠高铝,其里特曼指数为1.95~2.96,具有钙碱性系列的岩浆演化趋势。金岭闪长岩w(Ni)为99.00×10~(-6)~237.00×10~(-6),w(Cr)为270.00×10~(-6)~600.00×10~(-6),w(Co)为19.00×10~(-6)~44.00×10~(-6),表明其具有幔源岩浆的属性。稀土元素球粒陨石标准化曲线表明样品具有富集轻稀土元素(LREE),亏损重稀土元素(HREE)以及弱Eu(δEu为0.91~1.12)异常的特征。所有样品富集大离子亲石元素(Ba、K、Sr)和高场强元素Nd,亏损高场强元素Rb、Nb、Ta、Zr。样品中约2.5Ga古老锆石的存在证明岩浆源区受到古老下地壳物质的混染作用。鲁西金岭地区闪长岩应形成于太平洋板块俯冲后后撤引起的伸展环境,其岩浆源区是富集地幔起源的基性岩浆底侵华北古老下地壳并与下地壳熔融形成的壳源酸性岩浆混合过程的产物。     

西藏查孜地区中新世正长岩的锆石U-Pb年代学、地球化学及岩石成因

查孜正长岩体是拉萨地块中段新发现的中新世钾质-超钾质侵入岩,岩性主要为中粗粒石英角闪正长岩和斑状石英正长岩,有暗色包体发育.对两种正长岩进行了岩石学、锆石U-Pb年代学和地球化学研究.结果显示,两种岩石的锆石U-Pb年龄分别为10.37±0.24 Ma、11.06±0.39 Ma,代表它们形成于中新世,是拉萨地块后碰撞岩浆作用的产物.查孜正长岩具有相对高钾（K₂O=6.75%~7.39%）、低镁（MgO=1.44%~2.97%）的特征,K₂O/Na₂O>1,属钾质岩;具有与超钾质岩石相似的微量元素特征,强烈富集Rb、Th、U、K等大离子亲石元素（LILE）和轻稀土元素（LREE）,相对亏损Nb、Ta、Zr、Hf、Ti、P等高场强元素（HFSE）和重稀土元素（HREE）,但Cr（22.7×10-6~64.6×10-6）、Ni（18.9×10-6~46.6×10-6）含量明显偏低.其中,斑状石英正长岩的SiO₂含量相对较高,但MgO、K₂O、Cr、Ni、REE和Y等元素含量比石英角闪正长岩的低.综合分析认为,查孜正长岩主要形成于岩浆混合作用,是富集岩石圈地幔部分熔融形成的超钾质岩浆与地壳物质部分熔融形成的酸性岩浆混合的结果,两种岩石的地球化学差异主要是岩浆混合的程度和比例不同导致的;它的形成可能与岩石圈地幔的减薄作用有关.      

Variation in the geochemistry of mantle sources for tholeiitic and calc-alkaline mafic magmas,Western Sunda volcanic arc,Indonesia

Quaternary lavas of the normal island-arc basalt—andesite—dacite association in the islands of Java and Bali range from those belonging to tholeiitic series over Benioff-zone depths of ～ 150 km to high-K calc-alkaline series over Benioff-zone depths of 250 km. More abundant and diverse calc-alkaline lavas are found over intermediate Benioff-zone depths. On average, basaltic lavas become slightly more alkaline (largely due to increased K contents) with increasing depth to the Benioff zone. Levels of incompatible minor and trace elements (K, Rb, Cs, Ba, Nb, U, Th, light REE) show a corresponding increase of almost an order of magnitude.Low average Mg-numbers (～ 0.52) and Ni and Cr abundances (15–25 and 35–60 ppm, respectively) of basaltic lavas suggest that few lavas representing primary mantle-derived magma compositions are present. Calculated primary basaltic magma compositions for most tholeiitic and calc-alkaline volcanic centres are olivine tholeiites with 15–30% ol. The single high-K calc-alkaline centre considered yielded transitional alkali olivine basalt—basanite primary magma compositions. These calculated magma compositions suggest that the percentage of mantle melting decreases with increasing depth to the Benioff zone (from >25 to <10%), while the corresponding depth of magma separation increases from ～ 30 to 60 km.Calculation of REE patterns for basaltic magmas on the basis of peridotitic mantle sources with spinel lherzolite, amphibole lherzolite or garnet lherzolite mineralogy, and model REE levels of twice chondritic abundances, indicates that change in the conditions of magma genesis alone cannot explain the observed change in light-REE abundances of basaltic lavas with increasing depth to the Benioff zone. Complementary calculations of the REE levels of mantle sources required to yield the average tholeiitic, calc-alkaline and high-K calc-alkaline basaltic magma indicate that light-REE abundances must increase from 2–3 to 7–8 times chondrites with increasing depth to the Benioff zone. The percentages of mantle melting favoured on REE evidence are lower than those indicated by major-element considerations.The observed variation in incompatible element geochemistry of mantle magma sources is thought to be related directly or indirectly to dehydration and partial-melting processes affecting subducted oceanic crust. The possible nature of this relationship is discussed.     

Chronology and Geochemistry of Mesozoic Volcanic Rocks in the Linjiang Area, Jilin Province and their Tectonic Implications

Zircon U-Pb ages and geochemical analytical results are presented for the volcanic rocks of the Naozhigou, Ergulazi, and Sidaogou Formations in the Linjiang area, southeastern Jilin Province to constrain the nature of magma source and their tectonic settings. The Naozhigou Formation is composed mainly of andesite and rhyolite and its weighted mean 206Pb/238U age for 13 zircon grains is 2224±1 Ma. The Ergulazi Formation consists of basaltic andesite, basaltic trachyandesite, and andesite, and six grains give a weighted mean 206Pb/238U age of 131±4 Ma. The Sidaogou Formation consists mainly of trachyandesite and rhyolite, and six zircon grains yield a weighted mean 206Pb/238U age of113±4 Ma. The volcanic rocks have SiO2=60.24%-77.46%, MgO=0.36%-1.29% (Mg#=0.32-0.40) for the Naozhigou Formation, SiO2=51.60%-59.32 %, MgO=3.70 %-5.54% (Mg#=0.50-0.60) for the Ergulazi Formation, and SiO2=58.28%-76.32%, MgO=0.07%-1.20% (Mg#=0.14-0.46) for the Sidaogou Formation. The trace element analytical results indicate that these volcanic rocks are characterized by enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), relative depletion in heavy rare earth elements (HREEs) and high field strength elements (HFSEs, Nb, Ta, and Ti), and negative Eu anomalies. Compared with the primitive mantle, the Mesozoic volcanic rocks in the Linjiang area have relatively high initial 87Sr/86Sr ratios (0.7053-0.7083) and low eNd(t) values (-8.38 to -2.43), and display an EMII trend. The late Triassic magma for the Naozhigou Formation could be derived from partial melting of a newly accretional crust with the minor involvement of the North China Craton basement and formed under an extensional environment after the collision of the Yangtze Craton and the North China Craton. The Early Cretaceous volcanic rocks for the Ergulazi and Sidaogou Formations could be formed under the tectonic setting of an active continental margin related to the westward snbduction of the Izanagi plate.     

新疆阿吾拉勒山西段下二叠统陆相火山岩岩石地球化学特征、成因及构造背景

新疆阿吾拉勒山西段是伊犁石炭-二叠纪裂谷的重要组成部分,本文对该区下二叠统典型的双峰式玄武岩-流纹岩组合进行了系统的岩相学和岩石地球化学研究。岩石整体高Na2O、高Al2O3、低TiO2、富碱。玄武岩富集大离子亲石元素Ba、K、LREE和P,亏损高场强元素Th、U、Ta、Nb。粗面斑岩和流纹斑岩富集大离子亲石元素Rb、K、LREE、高场强元素Th、Zr、Hf,亏损Ta、Nb、Sr、Ti和P。玄武安山玢岩的蛛网图与粗面斑岩和流纹斑岩较为一致,但少量元素的特征与玄武岩相似。玄武岩浆来源于弱亏损地幔,并受到了下地壳物质的混染,而玄武安山玢岩、粗面斑岩和流纹斑岩则可能来源于地壳物质的部分熔融。双峰式火山岩的形成可能与上地幔玄武岩浆的底侵作用有关。裂谷演化导致的陆相火山活动持续到早二叠世晚期达到顶峰,中二叠世以后,构造环境由拉伸转为挤压,裂谷演化趋于终止。该区石炭纪末-早二叠世的裂谷活动与整个天山地区晚古生代的构造演化背景具有一致性。     

Lamprophyre or Lamproite Dyke in the SW Tarim Block?--Discussion on the Petrogenesis of These Rocks and Their Source Region

The mineralogical, petrological and geochemical studies on Keliyang (克里阳) potassic dykes have been carried out to understand their rock types, the petrogenesis and the nature of their mantle sources. They are potassic lamprophyre, not lamproites as the previous researchers believed. In this study, the whole-rock major and trace element compositions of another 6 lamproite dykes recently discovered are reported. Major elements were determined by X-ray fluorescence spectrometry (XRF) techniques, while REE and trace elements were determined by inductively coupled plasma mass spectrometry (ICP-MS). They can be classified into phlogopite-diopside lamprophyre, leucite-diopside lamprophyre and granular carbonatite-bearing diopside lamprophyre on the basis of their mineral components. They are all characterized by relatively low SiO2 (41.31% -44. 84%), TiO2 (0.75% -0.86%) and high MgO (7.30%-11.33%), K2O (4.01%-6.01%) concentrations with K2O/Na2O ratios of 2. 77-12.49. In addition, they display enrichment in large-ion iithophile elements (LILEs, e. g., Rb, Sr,Ba) and LREE, but a relative depletion in high-field-strength elements (HFSEs, e.g. , Nb, Ta, Zr, Hf and Ti). They display similar chondrite-normalized REE patterns with slight negative Eu anomalies (δEu=0.64-0. 82), and high initial 87Sr/86Sr ratios, which resemble those of high K/Ti and low-Ti potassic magmas formed in subduction-related settings. Consequently, we suggest that the parental magma was generated by partial melting of the phlogopite-amphibole- bearing garnet lherzolite within the lithospheric mantle that might have been metasomatized by a potassium-bearing fluid released from a subduction oceanic crust.     

北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的岩石成因及其构造意义

文中研究了北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的年代学、地球化学和Sr-Nd同位素组成。毛藏寺岩体主要岩石类型为花岗闪长岩。锆石U Pb定年获得花岗闪长岩岩浆结晶年龄为（424±4） Ma。花岗闪长岩具有高的Mg#（约55）,K2O/Na2O=0.77~0.91,A/CNK=0.92~0.94,表明岩石属准铝质。在微量元素组成上,花岗闪长岩富集LILE、亏损HFSE,轻重稀土分异明显［(La/Yb)N=16.9~19.5］,具有弱的Eu负异常（Eu/Eu*=0.75~0.83）;花岗闪长岩具有ISr=0.706 3~0.706 5,εNd(t) =-1.5~-1.1,TDM=1.10~1.16 Ga。这些地球化学特征和Sr Nd同位素组成表明,花岗闪长岩岩浆源区为基性下地壳变玄武质岩石,但在成岩过程中有少量幔源物质的加入。黄羊河岩体主要由钾长花岗岩组成,其岩浆结晶年龄为（402±4） Ma。岩石富碱（K2O+Na2O=6.91‰~7.66%）,K2O/Na2O>1,A/CNK=0.97~1.05。钾长花岗岩富集LILE及HFSE,轻重稀土元素分馏中等［(La/Yb)N =10.6~17.8］,并具有明显的负Eu异常（Eu/Eu*=0.43~0.68）,表明钾长花岗岩具有铝质A型花岗岩的地球化学特征。钾长花岗岩具有ISr=0.710 3~0.711 3,εNd(t)=-6.7~-6.0,TDM=1.46~1.55 Ga,反映岩浆主要来自地壳中长英质物质的部分熔融。冷龙岭地区花岗岩类的岩石成因及其岩浆演化揭示了北祁连山造山带从加里东早期的挤压构造体制向加里东晚期的伸展构造体制的演化。这些花岗岩类形成于碰撞后构造背景,岩浆的产生可能与俯冲的北祁连洋板片的断离作用有密切联系。     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

Primitive basalts and andesites from the Mt. Shasta region,N. California: products of varying melt fraction and water content

Quaternary volcanism in the Mt. Shasta region has produced primitive magmas [Mg/(Mg+Fe^*)>0.7, MgO>8 wt% and Ni>150 ppm] ranging in composition from high-alumina basalt to andesite and these record variable extents ofmelting in their mantle source. Trace and major element chemical variations, petrologic evidence and the results of phase equilibrium studies are consistent with variations in H₂O content in the mantle source as the primary control on the differences in extent of melting. High-SiO₂, high-MgO (SiO₂=52% and MgO=11 wt%) basaltic andesites resemble hydrous melts (H₂O=3 to 5 wt%) in equilibrium with a depleted harzburgite residue. These magmas represent depletion of the mantle source by 20 to 30 wt% melting. High-SiO₂, high-MgO (SiO₂=58% and MgO=9 wt%) andesites are produced by higher degrees of melting and contain evidence for higher H₂O contents (H₂O=6 wt%). High-alumina basalts (SiO₂=48.5% and Al₂O₃=17 wt%) represent nearly anhydrous low degree partial melts (from 6 to 10% depletion) of a mantle source that has been only slightly enriched by a fluid component derived from the subducted slab. The temperatures and pressures of last equilibration with upper mantle are 1200°C and 1300°C for the basaltic andesite and basaltic magmas, respectively. A model is developed that satisfies the petrologic temperature constraints and involves magma generation whereby a heterogeneous distribution of H₂O in the mantle results in the production of a spectrum of mantle melts ranging from wet (calc-alkaline) to dry (tholeiitic).     

Heat-producing elements in the lunar mantle: Insights from ion microprobe analyses of lunar pyroclastic glasses

We provide new estimates for the abundance of heat-producing elements in the lunar mantle by using SIMS techniques to measure the concentrations of thorium and samarium in lunar pyroclastic glasses. Lunar pyroclastic glasses are utilized in this study because they represent quenched products of near-primary melts from the lunar mantle and as such, they provide compositional information about the mantle itself. Thorium and samarium were measured because: (1) Th is not significantly fractionated from Sm during partial melting of the pyroclastic glass source regions, which are dominated by olivine and pyroxene. Therefore, the Th/Sm ratios that we measure in the pyroclastic glasses reflect the Th/Sm ratio of the pyroclastic glass source regions. (2) Strong correlations between Th, U, and K on the Moon allow us to use measured Th concentrations to estimate the concentrations of U and K in the pyroclastic glasses. (3) Th, Sm, U, and K are radioactive elements and as such, their concentrations can be used to investigate heat production in the lunar mantle.The results from this study show that the lunar mantle is heterogeneous with respect to heat-producing elements and that there is evidence for mixing of a KREEP component into the source regions of some of the pyroclastic glasses. Because the source regions for many of the glasses are deep (?400 km), we propose that a KREEP component was transported to the deep lunar mantle. KREEP enriched sources produce 138% more heat than sources that do not contain KREEP and therefore, could have provided a source of heat for extended periods of nearside basaltic magmatism. Data from this study, in conjunction with models for the fractional crystallization of a lunar magma ocean, are used to show that the average lunar mantle contains 0.15 ppm Th, 0.54 ppm Sm, 0.039 ppm U, and 212 ppm K. This is a greater enrichment in radiogenic elements than some earlier estimates, suggesting a more prolonged impact of radiogenic heat on nearside basaltic volcanism.     

Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.     

黑龙江三道湾子金矿床火山岩-次火山岩年代学、地球化学和地质意义

三道湾子金矿床位于小兴安岭北麓,是典型的以碲金化合物为主的矿床,为了限定其成矿时代和厘定其成矿地质背景,笔者对同成矿地质体火山岩和成矿期后的玄武粗安玢岩的单颗粒锆石U-Pb年龄和元素地球化学进行测定,获得同成矿地质体粗面英安斑岩及玄武粗安玢岩的~(206)Pb/~(238)U年龄加权平均值分别为(124.2±0.9)Ma(MSWD=0.5,n=18)和(118.9±2.3)Ma(MSWD=0.5,n=6);赋矿围岩为玄武粗安岩与同成矿地质体粗面英安斑岩,Si O2含量为52.75%~62.30%,K_2O和Na_2O含量分别为2.02%~2.85%和3.96%~4.24%。里特曼指数(δ)在0.85~3.67之间,属于钙碱性到高钾钙碱性岩系特征;成矿期后脉岩玄武粗安玢岩,SiO_2含量为51.53%~52.32%,K_2O含量为2.30%~2.36%,Na_2O含量为3.78%~4.14%,里特曼指数(δ)在4.05~4.86之间;微量和稀土元素均显示富集大离子亲石元素(Cs、K、Rb、Ba、LREE等),相对亏损高场强元素(Nb、Ta、Zr、Hf等)和HREE,特别是强烈亏损Th、U和Nb、Ta的特征,与岛弧钙碱性玄武岩相似。研究揭示了该矿床形成于早白垩世(124~119 Ma)或晚中生代造山后伸展构造环境,成矿热动源可能是交代大洋性质的岩石圈地幔。     

鄂尔多斯地块北部中、新生代玄武岩地球化学特征及其地质意义

通过对分布于鄂尔多斯地块北部杭锦旗与和林格尔玄武岩地球化学特征的研究,探讨了该区中、新生代岩浆源区的组成、变化及其所反映的地质意义。杭锦旗与和林格尔分别有早白垩世(Ar-Ar年龄为126.2Ma)和晚中新世(Ar-Ar年龄为6.4Ma)玄武岩分布。杭锦旗早白垩世玄武岩的SiO2(46.93%～47.93%)较低而碱含量较高(K2O+Na2O为5.75%～6.21%),组合指数σ为6.7～8.0,K2O(Na2O-2),属于碱性系列的钾质粗面玄武岩;其Mg#值为32.4～32.8,Ni、Cr含量低于20μg/g,反映玄武岩浆形成后经历过橄榄石和单斜辉石分离结晶等后期演化作用;其Nb、Ta相对于La亏损,初始87Sr/86Sr为0.7062,εNd(t)为-12.25,反映岩浆源区主要为富集EMI型地幔。和林格尔晚中新世玄武岩为橄榄拉斑玄武岩,其组合指数σ为2.1～2.8,Mg#值变化于46.7～52.4,Ni含量变化于111.1～125.8μg/g,Cr为123～178μg/g,Mg#值和Ni、Cr含量的变化反映岩浆原生程度随时间变新有所增大;其Nb、Ta相对富集,具有相似于OIB的微量元素特征,但仍表现相对富集的Sr-Nd同位素性质,初始87Sr/86Sr比值变化于0.7051～0.7053,εNd(t)为-1.91～-0.74,推测为软流圈与EMI型岩石圈地幔相互作用的产物。杭锦旗与和林格尔玄武岩的207Pb/204Pb比值都较低,△207/204为3.6～6.5,△208/20460,均具EMI型Dupal异常。玄武岩地球化学特征进一步表明,华北克拉通西部的鄂尔多斯地块所处的岩石圈自早白垩世以来发生过较小规模的伸展减薄作用,但其伸展减薄和被改造的程度远弱于华北东部。     

Petrogenesis of Cenozoic Basaltic Rocks from Jiangsu Province,China:Evidence from Geochemical Constraints

Cenozoic（Miocene to Pleistocene） basaltic rocks in Jiangsu province of eastern China include olivine tholeiite and alkali basalt.We present major,trace element and Sr-Nd isotopic data as well as Ar-Ar dating of these basalts to discuss the petrogenesis of the basalts and identify the geological processes beneath the study area.On the basis of chemical compisitions and Ar-Ar dating of Cenonoic basaltic rocks from Jiangsu province,we suggest that these basalts may belong to the same magmatic system.The alkali basalts found in Jiangsu province have higherΣFeO,MgO,CaO,Na₂O, TiO₂ and P₂O₅ and incompatible elements,but lower Al₂O₃ and compatible elements contents than olivine tholeiite which may be caused by fractional crystallization of olivine,pyroxene and minor plagioclase.In Jiangsu basaltic rocks the incompatible elements increase with decreasing MgO/ΣFeO ratios.The primitive mantle-normalized incompatible elements and chondrite-normalized REE patterns of basaltic rocks found in Jiangsu province are similar to those of OIB.Partial loss of the mantle lithosphere accompanied by rising of asthenospheric mantle may accelerate the generation of the basaltic magma.The ¹⁴³Nd/¹⁴⁴Nd vs.⁸⁷Sr/⁸⁶Sr plot indicates a mixing of a depleted asthenospheric mantle source and an EMI component in the study area.According to Shaw’s equation,the basalts from Jiangsu province may be formed by l%-5%partial melting of a depleted asthenospheric mantle source.On the basis of Ar-Ar ages of this study and the fractional crystallization model proposed by Brooks and Nielsen（1982）,we suggest that basalts from Jiangsu province may belong to a magmatic system with JF-2 as the primitive magma which has undergone fractional crystallization and evolved progressively to produce other types of basalts.     

昌宁—孟连缝合带乌木龙—铜厂街洋岛型火山岩地球化学特征及其大地构造意义

详细的地球化学解析表明,乌木龙—铜厂街地区出露的蛇绿混杂岩主要包括方辉橄榄岩、纯橄榄岩和碱性玄武岩。其中,方辉橄榄岩和纯橄榄岩具有极低的CaO含量(<0.1%)、稀土总量(<5×10-6)和(La/Yb)N(0.96～1.14)值,(Ce/Yb)N为1.04～1.37,为轻稀土弱亏损型。本区碱性玄武岩具有高TiO2(2.57%～3.33%)、高K2O(2.29%～5.52%)的显著特征,(La/Yb)N为15.42～19.81,(Ce/Yb)N为12.48～14.76,为轻稀土强烈富集型;岩石Ti/V、Th/Ta、Th/Yb、Ti/Yb、Ta/Yb与来自亏损地幔的MORB以及与俯冲有关的岛弧火山岩明显不同,而主要显示为OIB型火山岩的微量元素地球化学特征,乃是典型的大洋板块内部岩浆作用的产物。该区洋岛型火山岩的厘定,表明昌宁—孟连古洋盆在石炭—二叠纪期间曾经历过一个由初始洋盆到成熟洋盆的完整发育演化过程。