Li—F花岗岩液态分离的微量元素地球化学标志

华南和世界其他国家典型Ｌｉ－Ｆ花岗岩１９５个微量元素分析结果的研究表明,随Ｌｉ－Ｆ花岗岩自下而上不同岩相变化：Ｚｒ／Ｈｆ－Ｆ、Ｎｂ／Ｔａ－Ｆ等有负相关变化;同样,随Ｆ增加,Ｔａ（Ｎｂ）、Ｓｎ、Ｗ、Ａｌ升高和Ｎｂ／Ｔａ（Ｚｒ／Ｈｆ）降低;在Ｋ／Ｒｂ－Ｒｂ图中黄英岩成分点位于相关斜线左下方;在Ｋ－Ｌｉ图中有低Ｌｉ、Ｋ的异常变化;在Ｒｂ／Ｓｒ－Ｐ２Ｏ５图中相关的二￣三个数量级异常变化等,均是Ｌｉ－Ｆ花岗     

海南岛中元古代花岗岩地球化学及成因研究

海南岛中元古代花岗岩岩体主要由二长花岗岩、花岗冈长岩等岩石组成，构成一个明显的 自花岗岩向花岗闪长岩和英云闪长岩的岩浆演化系列及钙碱性演化趋势。该岩体为一套板块碰撞 后隆起期原地一半原地过铝质花岗岩。是板块碰撞引起的地壳增厚升温和随之的玄武岩浆底侵加 热联合作用下，主要由抱板群变质沉积岩及斜长角闪片麻岩部分融熔、并在幔源物质的参与下形 成的，所形成的花岗质岩浆在“走滑扩容泵吸”机制驱动下沿戈枕剪切带上升、固结就位，因而具壳 幔二元混合成因特点。化学成分以高 ＳｉＯ２、Ｋ２Ｏ、Ｒｂ、Ｂａ、Ｔａ、Ｃｅ和贫Ｐ、Ｔｉ、Ｚｒ、Ｓｒ、Ｆｅ２Ｏ３＋ＦｅＯ、 ＭｇＯ、ＣａＯ为特征；元素比值Ｚｒ／Ｎｂ、Ｌａ／Ｎｂ、Ｂａ／Ｎｂ、Ｒｂ／Ｎｂ、Ｋ／Ｎｂ、Ｂａ／Ｌａ及Ｃｒ、Ｃｏ、Ｎｉ、Ｖ均接近 大陆中下地壳成分，Ｒｂ、Ｓｒ、Ｂａ、Ｔａ、Ｚｒ及比值Ｋ／Ｓｒ、Ｒｂ／Ｓｒ石ｒ／Ｂａ变化范围小，反映岩浆源区成分 或熔融方式上的一致性；轻重稀土较强分馏，负铕异常明显，稀土配分模式总体相似，呈左高右低 型，和抱板群变质沉积岩稀上元素组成基本一致；εＮｄ（ｔ）值普遍高于抱板群地层，（８７Ｓｒ／８６Ｓｒ）ｉ值变化 大，暗示幔源参与信息。结合抱板群变基性火山岩的     

鄂东北大别杂岩中深熔混合岩存在的地质地球化学证据

基于地质地球化学研究结果提出识别大别杂岩中深熔混合岩的证据：①浅色体粗大可横切面理，伴有复杂褶皱，帮助发育；②浅色体和古成体中斜长石牌号有明显差异；③矿物成分和组合指示曾达到深熔条件；④浅色体中富含Ａｌ２Ｏ３、Ｆｅ２Ｏ３、ＴｉＯ２和不活动、不相容元素，如ＬＲＥＥ、Ｔｈ、Ｈｆ、Ｚｒ。最结合混合岩矿物空间分布和质量平衡研究结果得出结论：大别核心杂岩中混合岩的主导成因机制是深熔。     

大兴安岭北部伊列克得组玄武岩的地球化学特征

大兴安岭北部伊列克得组玄岩类具有富碱（Ｋ２Ｏ＋Ｎａ２Ｏ〉６．３７％）、高Ｋ２Ｏ（２．６２％～３．１１％）,高Ｋ２Ｏ／Ｎａ２Ｏ比值（０．７～０．８）和Ｔｈ／Ｔａ、Ｃｅ／Ｎｂ、Ｔａ／Ｎｂ比值,以及强烈富集大离子亲石元素（ＬＩＬＥ）和轻稀土元素（ＬＲＥＥ）的特征,属于钾玄质系列,低Ｓｒ／Ｎｄ比值（１３～１７．５）的特征类似于洋岛玄武岩,但其Ｔａ／Ｈｆ,Ｔｈ／Ｔａ比值特征及与Ａ型花岗岩共生等特征表明,钾玄     

等离子体质谱法测定岩石中的铌,钽,锆,铪,钍,铀

应用ＩＣＰ－ＭＳ法测定了岩石中的痕量Ｎｂ、Ｔａ、Ｚｒ、Ｈｆ、Ｔｈ、Ｕ，给出了检出限，并对酸溶和碱熔两种制样方法进行了对比实验。     

华南扬子与华夏陆块古-中元古代基底地壳微量元素地球化学示踪探讨

从早期宙以垂向分异增长为主的思路出发,将华南扬子陆块和华夏陆块变质基底中相似岩类（陆源碎屑岩、变基性火山岩夹层和晋宁期花岗岩类）作为研究对象,选择了相容性接近的７对元素（Ｒｂ／Ｃｓ、Ｓｒ／Ｂａ、Ｔｈ／Ｕ、Ｎｂ／Ｔａ、Ｚｒ／Ｈｆ、Ｐｄ／Ｐｔ和Ｃｒ／Ｎｉ）作为示踪手段,对华南大陆古－中元古代基底的物源特征和后期演化进行了探讨,得出了几点初步认识：（１）扬子、华夏两陆块前元古宙“原始”地壳具有相近的物质     

滇东早寒武世梅树村期浅色粘土岩层的地球化学特征和地质意义

滇东早寒武世梅树村期含磷岩系中出现的十多层浅色粘土岩层为酸性火山灰蚀变而成的变斑脱岩，它们是火山喷发事件和事件地层对比的标志。这些浅色粘土岩层中稳定微量元素Ｈｆ、Ｎｂ、Ｙ、Ｔｈ、Ｚｒ含量高于非火山成因的粘土，而Ｆｅ、Ｎｉ、Ｃｏ、Ｃｒ含量低于筇竹寺组泥岩。ＴｉＯ２／Ａｌ２Ｏ３、Ｚｒ／Ｈｆ、Ｔｉ／Ｔｈ比值属于酸性岩浆范围，球粒标准化稀土元素配分模式和具中至大的Ｅｕ负异常类似于花岗岩稀土配分模式。岩浆判别图指示了梅树村期变斑脱岩具板内花岗岩位置的亚碱性流纹岩和粗面岩岩浆亲缘性。变斑脱岩在地层序列上和区域上分布表明扬子地台西缘早寒武世初期火山活动频繁，火山喷发事件与古大陆解体和板内拉张构造运动有关     

滇东早寒武世梅树村期浅色粘土岩层的地球化学特征和地质意义

滇东早寒武世梅树村期含磷岩系中出现的十多层浅色粘土岩层为酸性火山灰蚀变而成的变斑脱岩，它们是火山喷发事件和事件地层对比的标志。这些浅色粘土岩层中稳定微量元素Ｈｆ、Ｎｂ、Ｙ、Ｔｈ、Ｚｒ含量高于非火山成因的粘土，而Ｆｅ、Ｎｉ、Ｃｏ、Ｃｒ含量低于筇竹寺组泥岩。ＴｉＯ２／Ａｌ２Ｏ３、Ｚｒ／Ｈｆ、Ｔｉ／Ｔｈ比值属于酸性岩浆范围，球粒标准化稀土元素配分模式和具中至大的Ｅｕ负异常类似于花岗岩稀土配分模式。岩浆判别图指示了梅树村期变斑脱岩具板内花岗岩位置的亚碱性流纹岩和粗面岩岩浆亲缘性。变斑脱岩在地层序列上和区域上分布表明扬子地台西缘早寒武世初期火山活动频繁，火山喷发事件与古大陆解体和板内拉张构造运动有关。     

吉乃县塔斯特岩体地质地球化学特征及含矿性评价

塔斯特岩体由石英闪长岩、英云闪长岩、二长花岗岩和钾长花岗岩组成。岩石均具有高Ｎａ低Ｋ,Ｎａ２Ｏ、Ｆｅ２Ｏ３、Ｈｆ、Ｋ／Ｒｂ偏高,Ｋ２Ｏ、ＣａＯ、ＦｅＯ、Ｒｂ、Ｓｒ、Ｎｂ、∑ＲＥＥ、δ＾１８Ｏ、Ｒｂ／Ｓｒ明显偏低的特点。岩石化学和地球化学特征表明该岩体为形成于火山弧环境的“Ｉ”型花岗岩。岩体中Ａｕ、Ａｇ、Ａｓ、Ｂｉ、Ｃｕ等成矿元素明显富集,并与该岩体中金矿床、矿点的元素组合一致,说明该岩体与Ａｕ的成     

陕西商县—丹凤地区丹凤群变质玄武岩的微量元素和同位素地球化学

丹凤祥变质玄武岩可以分为两类：一类是ＬＲＥＥ富集型的钙碱性玄武岩，另一类是ＬＲＥＥ平坦型的拉斑玄武岩。ＬＲＥＥ富集型的变质玄武岩［（Ｃｅ／Ｙｂ）Ｎ为５～２０］贫Ｔｉ、Ｎｂ、Ｔａ，Ｔｈ＞Ｔａ，Ｎｂ／Ｌａ＜０．８，Ｈｆ／Ｔｈ＞８，Ｚｒ／Ｙ＜３，表明其形成于消减带之上的洋内岛弧环境。该玄武岩的εＮｄ（ｔ）＝＋４．９～＋７．３，εＳｒ（ｔ）＝３．０～＋３２，可能是亏损地幔端元（ＤＭＭ）与第二类富集地幔端元（ＥＭⅡ）混合形成的。大多数玄武岩的（２０６Ｐｂ／２０４Ｐｂ）ｉ比值（１６．５～１７．６）较低，（２０８Ｐｂ／２０４Ｐｂ）ｉ和（２０７Ｐｂ／２０４Ｐｂ）ｉ比值（分别为３６．２～３６．９和１５．３～１５．５）较高，ε１８Ｏ变化较大（５．５‰～９．２‰）。因此，根据微量元素和同位素地球化学资料，丹凤群变质玄武岩的源区可能包括下述组分：１）亏损的软流圈地幔（ＤＭ）；２）富集地幔（ＥＭ）；３）洋内岛弧下地壳（镁铁和超镁铁质岩）；４）消减带岩片带入的组分。而ＬＲＥＥ亏损的拉斑玄武岩具ＭＯＲＢ的特征，Ｔｈ／Ｔａ和Ｌａ／Ｔａ比值近似等于１，ＴｉＯ２＝１．６５％，Ｔｉ／Ｖ＝２２，指示来自亏损的软流圈地幔，形成在与消减作用无关的拉张     

小兴安岭二龙山林场堆晶辉长岩地球化学特征及构造环境

小兴安岭北部二龙山林场辉长岩的主量、微量和稀土元素的测试分析结果显示: 二龙山辉长岩为钙碱性系列、偏铝质岩石; δEu 正异常,Sr 元素含量富集明显,具有堆晶辉长岩特征; Rb /Sr、Nb / Ta、LILE/HFSE、Th /Ta、Nb /U 和Nb /La 比值特征均显示,辉长岩岩浆来自受到俯冲流体交代的地幔源区。Nb /Zr、Th /Nb、Th /Ta 和Ta /Hf 比值特征及对Th /Hf --Ta /Hf 构造环境判别图解投点表明,二龙山辉长岩形成于陆内拉张环境。     

超高压榴辉岩金红石中高场强元素变化的控制因素及其地球动力学意义

利用LA-ICP-MS对CCSD-MH超高压榴辉岩中金红石进行了详细的原位微区微量元素组成分析.金红石中高场强元素Nb和Ta含量主要受全岩Nb、Ta和TiO₂含量控制, Zr、Hf含量比较稳定基本不受全岩含量影响.粒间金红石中, 同一颗粒金红石核部Zr含量系统高于边部, 而边部则出现了明显的Pb和Sr富集特征.CCSD-MH榴辉岩中金红石与全岩的Nb/Ta比值呈现明显的不一致性.全岩Nb/Ta比值明显低于金红石且与全岩TiO₂含量负相关, 而金红石的Nb/Ta比值与全岩Nb、Ta含量和Nb/Ta比值没有明显的相关关系.金红石和全岩之间非完全耦合的Nb/Ta组成表明, 金红石并非形成于原岩的结晶过程中而是在超高压变质作用过程中形成, 尽管金红石是榴辉岩中Nb、Ta含量的主要载体矿物, 但金红石的Nb/Ta比值并不一定能完全代表全岩的特征, 而与全岩Nb、Ta和TiO₂的含量有关.粒间金红石核部Zr含量所记录的温度与粒径之间具有明显的正相关性, 反映金红石中的Zr在其形成后没有封闭.粒间金红石所表现出的明显的边部富集Pb和Sr的特征, 反映了后期流体活动对金红石组成的影响.这些研究结果为金红石中Zr在高温下的扩散作用和后期流体活动的影响提供了重要证据, 这可能是利用金红石Zr含量地质温度计计算的苏鲁-大别榴辉岩变质温度(598~827℃) 偏低的主要原因.      

Zr/Hf ratio as an indicator of fractionation of rare-metal granites by the example of the Kukulbei complex,eastern Transbaikalia

The concept of granitic melt fractionation as the main process in the concentration of rare elements in granites calls for the development of a reliable method to determine the evolutionary sequences of granite series. We propose to use for this purpose a zirconium-hafnium indicator, the Zr/Hf weight ratio in granitic rocks (Zaraisky et al., 1999, 2000). By the example of three classic regions of rare-metal deposits, eastern Transbaikalia, central Kazakhstan, and Erzgebirge (Czech Republic and Germany), it was empirically shown that the Zr/Hf ratio of granites decreases during the fractional crystallization of granite magmas in the sequence granodiorite → biotite granite → leucogranite → lithium-fluorine granite. The reason is the higher affinity of Hf compared with Zr to a granite melt. This implies that the crystallization and settling of accessory zircon will cause the progressive enrichment of Hf relative to Zr in the residual melt. As a result, the Zr/Hf ratio decreases regularly in the series of sequential phases of granite intrusion related to a single magma chamber from granodiorite to biotite granite, leucogranite, and Li-F granite (from 45-30 to 10-2). Our experimental investigations supported the preferential enrichment of haplogranite melt in Hf and zircon crystals in equilibrium with melt in Zr (T= 800°C and P = 1 kbar). The Zr/Hf indicator was tested by the example of the wellknown Kukulbei rare-metal granite complex of eastern Transbaikalia (J3), which is unique in the degree of fractionation of initial granite melt with the formation of three phases of granite emplacement and vein derivatives. An important feature of the complex is its “short” differentiation trend. It was supposed that the granite magma of the first phase is parental, and the later phases forming small intrusive bodies in large massifs of biotite granites of the first phase are sequential products of its crystallization differentiation in a magma chamber. The biotite granites of the first phase are barren. The leucocratic granites of the second phase are accompanied by tin-tungsten greisen deposits (e.g., Spokoininskoe), and the upper part of cupola-like stocks of Li-F amazonite granites of the third phase host apogranite-type tantalum deposits (Orlovka, Etyka, and Achikan). In addition to three granite phases, the Kukulbei complex includes dikes of ongonites, elvans, amazonite granites, and chamber miarolitic pegmatites. All of the granitic rocks of the complex have similar isotopic ages of 142± 0.6 Ma. The Zr/Hf ratio decreases systematically from phase 1 (40–25), to phase 2 (20–10), and phase 3 (10–2). The ongonites, elvans, and pegmatites have similar Zr/Hf ratios (15-5), falling between the ranges of leucocratic muscovite granites and Li-F granites. Compared with other granite series, the granitic rocks of the Kukulbei complex show specific petrographic and geochemical features: they are strongly enriched in Rb, Li, Cs, Be, Sn, W, Mo, Ta, Nb, Bi, and F but depleted in Mg, Ca, Fe, Ti, P, Sr, Ba, V, Co, Ni, Cr, Zr, REE, and Y. From the early to late intrusion phases, the degree of enrichment and depletion in these element groups increases regularly. This is accompanied by a significant decrease (from 40 to 2) in Zr/Hf, which can be used as a reliable indicator of genetic relations, degree of fractionation, and rare-metal potential of granites. Granites with Zr/Hf values lower than 25 are promising for prospecting for Sn, W, Mo, and Be greisen deposits, whereas the formation of Ta deposits requires Zr/Hf values lower than 10.     

长江中下游地区燕山晚期基性岩浆活动的记录

江苏省宁镇地区位于长江中下游沿江成矿带的最东端,是长江中下游成矿带的重要组成部分,蒋庙岩体是宁镇地区唯一的基性岩体.对此岩体进行了锆石U-Pb年代学、矿物化学、岩石地球化学和Sr-Nd-Hf同位素研究,讨论了其成因及地幔源区性质.岩体主要由橄榄辉长岩、角闪辉长岩和辉石闪长岩组成,其中辉石闪长岩的锆石LA-ICP-MS(laser ablation inductively coupled plasma mass spectrometry) U-Pb年龄为121±1 Ma.锆石ε_Hf(t)值介于-2.9~-6.4.全岩地球化学研究显示岩石样品富钠低钾,富集轻稀土元素,重稀土元素亏损不明显,富集大离子亲石元素(如K、Ba、Sr等),亏损高场强元素(如Nb、Ta、Ti、Zr、Hf等).蒋庙基性侵入岩在长江中下游地区中生代岩浆岩中具有最高的ε_Nd(t)值以及最低的(87Sr/86Sr)_i值,其Sr-Nd同位素组成介于软流圈地幔(depleted MORB mantle,DMM)-富集岩石圈地幔(enriched mantle Ⅱ,EMⅡ)之间.研究认为,蒋庙岩体应来源于软流圈地幔和富集岩石圈地幔的混合组分,可能有少量的俯冲板片物质加入源区,并在成岩过程中经历了一定程度的结晶分异.结合区域地质、年代学、矿物学和地球化学资料,表明蒋庙岩体的形成可能与古太平洋板块俯冲事件密切相关.      

Constraints from eclogite and MARID xenoliths on origins of mantle Zr/Hf–Nb/Ta variability

New trace-element data of rutile in kimberlite-borne ~1.85 Ga eclogite and pyroxenite xenoliths from the central Slave craton, as well as ~110 Ma MARID xenoliths from the Kaapvaal craton, provide constraints on the origins of lithospheric and sublithospheric mantle variability in high field strength element ratios. Rutiles in eclogites and pyroxenites have Zr/Hf ranging from 20 to 62 and Nb/Ta ranging from 10 to 40. Rutiles in MARID xenoliths have Zr/Hf from 24 to 33 and Nb/Ta from 10 to 41. Calculated whole-rock Zr/Hf is suprachondritic for eclogites with suggested gabbroic protoliths and subchondritic for boninite-like eclogites; the latter is consistent with cpx-controlled depletion in the protolith source. Within each eclogite type, positive correlations of Zr/Hf with La/Lu and negative correlations with Lu/Hf likely reflect fractionation of cpx and/or plagioclase during crystallisation of the protoliths. Zr/Hf–Nb/Ta relationships of some MARID-type rocks, which are products of lithospheric mantle metasomatism, and eclogite xenoliths plot on a silicate differentiation trend, whereas other samples have higher Nb/Ta at a given Zr/Hf. Fractionation of a few percent rutile from an HFSE-rich mafic melt can generate a trend towards strongly increased Nb/Ta at minimally changed Zr/Hf in the residual melt. Superposition of rutile fractionation on the effects of silicate differentiation, which fractionates Zr/Hf more strongly than Nb/Ta, can explain the Zr/Hf–Nb/Ta relationships of most eclogites from the central Slave craton as well as those of MARID rocks, metasomatised peridotites and group II kimberlites. By contrast, Zr/Hf–Nb/Ta relationships suggest that Group I kimberlites are mixtures between depleted peridotite and carbonatite. Thus, high Nb/Ta is a signature of lithospheric processes and may not be important in deeply subducted eclogites that bypass extended residence in the lithosphere. Conversely, considerable primary Zr/Hf variability was inherited by the eclogites, which is indicative of the compositional diversity of ancient subducted oceanic crust, which is expected to have generated substantial heterogeneity in sublithospheric basalt sources.     

Major and trace element variation in ilmenite in the Skaergaard Intrusion: petrologic implications

Ilmenite separates from the floor (LS), roof (UBS), and wall (MBS) sequences of the Skaergaard Intrusion were analyzed for major and trace elements using DCP-AES and ICP-MS techniques. In all three sequences, FeO progressively increases, and MgO and Al₂O₃ progressively decrease with differentiation. Although trace element abundances are, in general, higher in UBS ilmenite than in MBS and LS ilmenite, all three sequences have similar trends for trace element abundance vs. crystallization. Ba, Cs, Rb, Sr, Th, U, Y, and the REEs are excluded elements in ilmenite, and remained at low abundances during differentiation. Cr, Ni, Sc, and V are included elements in ilmenite and other mafic phases, and decreased during differentiation. V contents in ilmenite, however, do not decrease significantly until the upper part of the middle zone, suggesting that magnetite did not begin to affect the magma differentiation trend until much later than when it first appears in the intrusion. Hf, Nb, Ta, and Zr, which are strongly excluded elements in silicates, are included elements in ilmenite. The element ratios Zr/Hf, Y/Ho, Nb/Ta, and U/Th are relatively constant in Skaergaard ilmenite from different parts of the intrusion, suggesting that fluid transport did not significantly effect these elements during differentiation or post-solidification cooling. Calculated partition coefficients for ilmenite in the Skaergaard Intrusion are similar to those reported from previous studies of lunar and terrestrial basalts and kimberlites, and for most elements are significantly lower than those reported for ilmenite in rhyolitic magma. Similar D_i's for Zr, Hf, Nb, and Ta suggest that ilmenite crystallization did not significantly affect Zr/Nb or Hf/Ta in the Skaergaard magma, but the ratios of Zr, Hf, Nb, or Ta to other high field strength elements, such as Th, U, Y, or the REEs, may have been altered by ilmenite fractionation.     

Geochemistry of alkali and nepheline syenites of the Ukrainian Shield: ICP-MS data

We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation.     

甘肃靖远上泥盆统沙流水组沉积地球化学特征及其物源分析

甘肃靖远上泥盆统沙流水组沉积地球化学研究表明:砂岩较泥质岩含有较高的SiO2含量和斜长石,而泥质岩较砂岩含有较高的铁镁质组分和含钾矿物.砂岩和泥质岩样品均亏损Nb、Ta、Sr元素.砂岩中部分样品富集Zr、Hf元素和强烈的Eu的负异常,部分样品显示Zr、Hf亏损和弱的负Eu异常.泥质岩样品均富集Nj、Cr元素,但具有较强...     

大兴安岭南段林西地区中生代酸性岩类岩浆的混染作用

大兴安岭南段林西地区广泛出露以海相玄武安山岩、安山岩为主的晚古生代火山．沉积岩。中生代火山-侵入杂岩也广泛分布其中。花岗岩体的边部普遍二长花岗岩化和花岗闪长岩化(甚至出现闪长岩)，并含有丰富的以玄武质-安山质为主的岩石包体。侵入体-围岩接触带附近为围岩被岩浆侵蚀的港湾状交代反应过渡带。英安岩-粗面英安岩也含有相同的岩石包体，并且与流纹岩密切共生。岩石包体周缘的寄主岩常见淬冷边，聚集针状磷灰石，表明它被捕获时已是冷却的岩石，而非热的玄武岩浆团；它们的Nb／Ta、Zr／Hf比值、弱交代者的化学成分与晚古生代火山-沉积岩一致，Rb-Sr同位素比值散布在晚古生代火山-沉积岩等时线附近，其含量、未交代程度、尖棱状程度、刚性程度在侵入体中从内部到边部增多(强)，且较新鲜者结构构造与围岩相同，表明它们来自晚古生代火山-沉积岩组成的围岩；其含量与岩体边部的位置及二长花岗岩、花岗闪长岩、(粗面)英安岩的成分变化有关，表明包体成分已加入到这些岩石当中。这些岩石的环带状斜长石有两种内核：一种较富钙；另一种较贫钙。两种内核的斜长石外环成分趋同，强交代岩石包体成分和富含岩石包体的酸性岩成分趋同。两者皆记录了两种来源的物质成分同化的过程。同一岩体边部(或火山岩中)酸度较低的岩石化学成分、高场强元素在Harker图解和Nb／Ta(和Zr／Hf)-SiO2及Nb／Ta-Zr／Hf图解中具有中生代花岗或流纹岩浆与晚古生代火山-沉积岩物质混合的特征。这些事实证明林西地区中生代酸性岩浆被较基性的晚古生代火山物质混染，并生成酸度较低的混染岩浆。较基性的火山物质是在低绿片岩相变质的基础上，经钠化交代反应被酸性岩浆同化的。     

滇西腾冲-梁河地块石英闪长岩-二长花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义

高黎贡-腾梁花岗岩带是冈底斯花岗岩带的东延部分。腾梁花岗岩中辉长-闪长质包体、花岗岩、石英闪长岩密切共生。辉长-闪长质包体的结构构造、矿物学特征表明,它们是岩浆快速冷凝结晶的产物。地球化学数据显示,辉长-闪长质包体为钙碱性系列,具有低SiO2、高MgO和Mg#的特征,富集Rb、Sr、Th、Ba和Ce,亏损Nb、Ta、P、Zr、Yb和Y;寄主花岗岩为中钾—高钾钙碱性系列,准铝质到弱过铝质,富集Rb、Th、Zr和Hf,亏损Nb、Ta、Ti、Sr、P和Ba,具有中等程度的负Eu异常;石英闪长岩介于二者之间。锆石U-PbLA-ICP-MS定年显示,石英闪长岩形成年龄为127.10±0.96Ma,花岗岩形成年龄为123.8±2.5Ma。结合辉长-闪长质包体形成年龄为122.6Ma,三者年龄基本一致,从年代学角度为花岗岩、辉长-闪长质包体和石英闪长岩岩浆混合作用成因提供了证据。石英闪长岩锆石εHf(t)值变化于-7.61～-3.80。结合辉长-闪长质包体、花岗岩的εHf(t)值及地球化学特征,认为花岗岩来源于古老地壳的部分熔融,辉长-闪长质包体来源于地幔楔橄榄岩部分熔融,石英闪长岩为幔源岩浆与古老地壳部分熔融的岩浆完全混合的产物。腾梁地块早白垩世侵入岩很可能与班公湖-怒江洋壳岩石圈向南俯冲的动力学背景有关。