贵州紫云上石炭统叶状藻礁灰岩胶结物特征

贵州紫云县猴场镇扁平村的上石炭统叶状藻礁及其周边灰岩中广泛发育大量的各类胶结物。通过对胶结物的形态、结构和阴极发光特征以及胶结物间的接触关系的研究,可以确定成岩作用的先后并识别成岩环境。浅海海底同生成岩阶段大的孔隙中形成等厚环边针状胶结物、葡萄状胶结物,小的孔隙里形成微晶胶结物。早成岩阶段形成微亮晶和斑块状亮晶方解石胶结物和放射纤维扇状胶结物,表生成岩阶段的溶蚀作用和胶结作用强烈,胶结物类型有斑块状或等粒的方解石胶结物和等厚环壁柱状胶结物,等厚环壁柱状胶结物在所有胶结物中体积是较大的。早期胶结作用使叶状藻礁灰岩孔隙度大为降低。中、晚成岩阶段,孔隙被等厚环壁刃状胶结物和晶簇或斑块状亮晶方解石所充填,有些先成的胶结物被热液改造。后生作用阶段发生的主要是构造破裂作用,其中少数裂隙被红褐色含Fe2O3微晶层和晶体粉砂及渗流豆粒充填。叶状藻礁灰岩的孔隙在晚成岩阶段前或中被胶结而之后没有创造出大且连通的孔隙,是它没能成为油气储集层的原因之一。     

贵州紫云上石炭统叶状藻礁灰岩的成岩作用

贵州紫云县猴场镇扁平村的上石炭统中的叶状藻礁及其周边灰岩中发育强烈的成岩作用和胶结物,这些胶结物在猴场研究区内是显著的和有代表性的。通过观察、分析野外露头、光片、薄片、薄片的阴极发光和染色,来研究礁体岩石的成岩作用,确定了成岩作用序列、成岩环境、成岩阶段。成岩作用类型主要有泥晶化、溶蚀、胶结、新生变形、机械压实、剪切或...     

海南岛全新世海滩岩的胶结作用与成岩环境的关系

我国海南岛及南海诸岛沿岸,广泛发育海滩岩。1980年我队赴海南岛考察现代沉积时,对海滩岩的分布、岩性特征及其与周围环境的关系进行了观察和采样。样品采自崖县鹿回头三亚湾水尾岭海蚀崖、西洲岛、小东海、东瑁岛、西瑁岛、天涯海角,乐东县莺歌海,文昌县渔业等地(图1)。有关的地质、地貌及岩性特征等,已有许多描述,对海滩岩的岩石学及成岩作用也有许多研究。本文侧重探讨海滩岩的胶结作用及与成岩环境的关系。     

Fabrics and sequences of submarine carbonate cements in Holocene Bermuda cup reefs

A variety of precipitative synsedimentary CaCO₃ cements lines or fills cavities and surrounds sediment particles within Recent algal cup reefs which dot the rim of the Bermuda platform. These include aragonite needle, spherulitic, and lath cements as well as calcite micrite, palisade, scale, and blocky cements, listed according to respective relative abundances. No distribution pattern of cements is apparent; various combinations of three or four cements are found in almost every sample or thin section. From the occurrence of various cements, factors determining composition and fabric are deduced:

1. Morphology, composition, and coating of the substrate.
2. Direct or indirect influence of organisms such as algae, pelecypods, or crustaceans.
3. Micro-environment, specifically size and permeability, rate of sea-water circulation through the micro-environment, substrates and organisms within the microenvironment.

Various sequences of two or three precipitative cements result from changes in microenvironment; the only cause of such change recognized is the entrance of endolithic algae into partly cemented cavities. This study provides some insight into the origin of submarine cements and a basis for comparative interpretation of cements in fossil marine environments, especially fossil reefs.     

巴布亚新几内亚合恩半岛晚第四纪上升珊瑚礁造礁珊瑚的成岩历史

更新世以来,剧烈的构造运动已将巴布亚新几内亚合恩半岛东北海岸的晚第四纪珊瑚礁阶地抬升上千米.阶地中造礁珊瑚的成岩变化和成岩产物的组构特征反映了该礁的成岩历史,充分体现该区快速构造上升的影响.海水潜流带和淡水渗流带为上升礁的主要成岩环境.生物钻孔、生物碎屑填隙、珊瑚文石针粗化、珊瑚骨骼的溶解和新生变形转化,以及其不同矿物成分和组构的种种胶结物的胶结作用是造礁珊瑚经历的主要成岩作用.地球化学资料表明其成岩变化发生于开放的化学体系之中.     

Microbially induced cementation of carbonate sands: are micritic meniscus cements good indicators of vadose diagenesis?

Characteristic fabrics such as micrite envelopes, calcified filaments and micritic grain-to-grain bridges are observed in a modern subtidal firmground (Wood Cay, Bahamas) and in a variety of firm- and hardgrounds of Lower Cretaceous and Upper Jurassic platform carbonates (Swiss and French Jura Mountains). Their similarity to microbial fabrics described in grapestones and in intertidal to continental vadose environments suggests that microbial activity played an important role in the initial stabilization and cementation of carbonate sands. 'Meniscus-type cements' (to distinguish them from vadose meniscus cements), which clearly formed in subtidal environments, are related to filament calcification, trapping of percolating micrite and microbially induced carbonate formation. Such meniscus-type cements are commonly micritic, but meniscus-shaped precipitation of fibrous aragonite or sparitic calcite around organic filaments is also observed. Therefore, an interpretation of vadose early diagenesis should not be based on meniscus cements alone. Similarly, subtidally formed filamentous structures can strongly resemble alveolar septal structures and be interpreted incorrectly as related to subaerial exposure.     

Controls of facies and sediment composition on the diagenetic pathway of shallow-water Heterozoan carbonates: the Oligocene of the Maltese Islands

Relatively few studies have so far addressed diagenetic processes in Heterozoan carbonates and the role that sediment composition and depositional facies exert over diagenetic pathways. This paper presents a study of Oligocene shallow-water, Heterozoan carbonates from the Maltese Islands. We investigate stratigraphic distribution, abundance and timing of diagenetic features and their relationship to sediment composition and depositional facies. The studied carbonate rocks comprise rud- to packstones of the Heterozoan association predominantly containing coralline red algae, bryozoans, echinoids and benthic foraminifers. XRD analyses show that all high-Mg calcite has been transformed to low-Mg calcite and that no aragonite is preserved. Diagenetic processes include dissolution of aragonitic biota, neomorphism of high-Mg calcitic biota to low-Mg calcite and cementation by fibrous, bladed, epitaxial and blocky cements. Stable isotopes on bulk rock integrated with petrographic data suggest that the study interval was not exposed to significant meteoric diagenesis. We interpret early cementation to have taken place in the marine and marine burial environment. The distribution and abundance of early diagenetic features, determining the diagenetic pathway, can be related to the primary sediment composition and depositional texture. Sorting and micrite content are important controls over the abundance of diagenetic features.     

Growth and submarine fossilization of algal cup reefs,Bermuda*

Small charges of explosives were used to section cup-shaped reefs that occur on the margins of the Bermuda Platform. Study of these artificial outcrops, up to 10 m high, and the samples collected from them show how the reef-building community is rapidly converted to well-lithified reef rock in the marine development. The reefs, known locally as boilers and breakers, occur along the wave-swept south shore of the Bermuda Islands and around the northeast and northwest margins of the Platform. They are cup-shaped, up to 30 m in long dimensions, and rise up to the sea surface as much as 12 m above the surrounding sea floor. The reefs are built by an intergrowth of encrusting organisms, principally crustose coralline algae, an encrusting hydrozoan, Millepora sp., and an attached gastropod, Dendropoma irregulare. The growth framework of these algal cup reefs has extensive voids: large and intermediate-sized growth framework and shelter pores; borings of bivalves and sponges; and both intra- and inter-particle pores. A variety of vagile and sessile organisms (coelobites) inhabit these pores: an encrusting Foraminifera, Homotrema rubrum, is the most abundant attached coelobite; the tests of a variety of benthic Foraminifera and ostracods are common: branched coralline algae, barnacles, bivalves, ahermatypic corals, bryozoans, and burrowing crustaceans occur in varying abundance. Beginning millimetres below the living surface, internal sediments accumulate in the extensive voids. Coarse-grained skeletal sand derived from the surface of the reefs is characteristic of the larger voids; lime mud with the tests of planktonic Foraminifera and planktonic algae occurs generally in the smaller voids. Most specimens from the interior of the reefs show multiple generations of internal sediment that vary in grain size, composition, and colour. The sand-sized sediments are pumped into the voids by the frequent and intense wave action; the lime mud settles out in the smaller, less agitated pores. Cementation of internal sediments and surrounding growth frame begins centimetres below the living surface; it is so pervasive that marble-hard reef rock is developed within 1/2 m or less. The cement is principally high-magnesium calcite of micrite size, and subordinately acicular aragonite, but there are locally wide variations in crystal size and morphology. The occurrence of the cement within the reefs well below sea level, the isotope ratios of the cement crystals, the mineralogy, and the age inferred from radiocarbon age determinations of the growth frame all indicate that the cement is submarine and deposited from water of oceanic composition. The algal cup reefs of Bermuda demonstrate the reef-building ability of a community of encrusting organisms that form only crusts in the intertidal zone of the Mediterranean and Northern Brazil. The cup reefs of the northern margins of the Bermuda Platform are true reefs, not merely veneers covering eroded blocks of Pleistocene limestone. In their composition, location, and early diagenesis, the cup reefs closely resemble the algal or lithothamnion ridge of Pacific atolls. Synsedimentary cementation of internal sediments and growth frame makes a major contribution to the rigidity of these ocean-facing reefs and atoll rims. The assemblage of features that characterize the submarine fossilization of the cup reefs is widespread elsewhere in the modern seas: the floors of the Persian Gulf and parts of the Mediterranean; the margins of Pacific atolls; and the reefs off the north coast of Jamaica. This fossilization is characterized by reiterated generations of coelobites, internal sediments, and synsedimentary cements that can in time replace a major part of the original growth framework. Major variations in the sequence of these generations from pore to pore is the signature of this kind of fossilization. The same features of fossilization are described from reefs in the Devonian, Permian, and Triassic.     

贵州紫云二叠纪生物礁的胶结作用

应用岩石学和地球化学方法研究了中国西南地区发育最好的紫云二叠纪生物礁组合的胶结作用,识别出七种胶结物类型,详细描述了它们的岩石学及地球化学特征,探讨了礁组合的胶结作用史。     

Evinosponges in the Triassic Esino Limestone (Southern Alps): documentation of early lithification and late diagenetic overprint

A carbonate buildup of Middle Triassic age, the Esino Limestone, outcrops in the Southern Calcareous Alps of Lombardy (N Italy). Along its margin and within the open subtidal facies, the Esino Limestone contains calcite cement-filled cavities of cm to m size. These features, known as evinosponges, may form pervasive networks within the host rock. The filling consists of concentric, isopachous layers of fibrous low-Mg calcite crystals characterized by strong undulose extinction and bent cleavages. The cement crusts are non-luminescent under cathodoluminescence, but both cements and host rock are cross-cut by micro-fractures filled with bright-luminescent calcite, related to late void-filling sparite. Mixing of different carbonates is reflected in stable isotope data. On the hand specimen scale, the oxygen and carbon isotope compositions of cements and host rock show little variation. When compared on a regional scale, the values cover a broad range from δ¹⁸O(PDB)=?5‰ to ?12‰ and from δ¹³O =0‰ to +3‰. The linear covariant trends defined by the oxygen and carbon isotope data for different sampling regions reflect the admixture of late, isotopically depleted calcite with an isotopically enriched non-luminescent calcite of early diagenetic origin. The Esino Limestone fibrous cements, which were probably precipitated in the marine or marine-meteoric phreatic environment, were affected by late diagenetic processes that caused mineral deformation and isotopic depletion through recrystallization and the admixture of a later calcite. These later calcites precipitated from penetrative fluids possibly related to Late Triassic volcanic activity and/or to the Late Cretaceous/Early Palaeogene alpine orogeny.     

Origin of subaerial Holocene calcareous crusts: role of algae, fungi and sparmicritisation

The Pleistocene Miami Limestone that crops out on the lower Florida Keys is overlain by thin (16 cm or less), discontinuous, Holocene calcareous crusts (caliche) that are usually laminated, composed dominantly of calcite micrite and may or may not incorporate part of the underlying limestone. Both allochems and sparry calcite cement in the former unit contain endolithic algae and fungi, borings and unicellular algae. Biogenic structures identical to those in the Miami Limestone also occur in the calcareous crusts but are somewhat less abundant in the latter unit versus the former unit. The calcareous crusts were formed in the vadose diagenetic environment. Some of the CaCO₃ necessary for the micrite that comprises the bulk of the crusts was probably derived from solution of carbonate from a soil cover and some from wind blown salt spray. Most of the micrite, however, was formed by replacement of the uppermost portions of the Miami Limestone. Replacement involved micritisation of allochems and a previously unreported process, sparmicritisation, the degrading recrystallization of sparry calcite to micrite. Minor sparmicritisation was caused by micrite calcification of endolithic fungi or algae within sparry calcite cement or by micrite precipitation in empty borings within such cement. Most sparmicritisation took place by dissolution of sparry calcite and concomitant precipitation of micrite in the space occupied previously by the dissolved spar. Such sparmicritisation is interpreted to be caused by chemical reactions involving the crystals, pore water which is moving slowly but steadily and organic compounds released during bacterial decomposition of fungi, algae or both. It is recognized that sparmicritisation occurs in the marine diagenetic environment and is not, therefore, necessarily indicative of vadose diagenesis. Incomplete sparmicritisation is responsible for some of the clotted textures typically found within calcareous crusts and may explain such textures in many other carbonate rock types. A combination of sparmicritisation and micritisation has probably greatly influenced the porosity of many reefs and, in some cases, led to the formation of ‘micritic reefs’.     

Siliciclastic grain breakage and displacement due to carbonate crystal growth: an example from the Lueders Formation (Permian) of north-central Texas, U.S.A.

The Lueders Formation (mid-Permian) in Baylor County, Texas, is an intercalated suite of fluvial siliciclastic, shallow marine siliciclastic, and shallow marine carbonate strata. There are at least two generations of carbonate cements (probably originally composed of calcite) in the fluvial sandstones where fractured grains are observed. These cements represent the initial stages of caliche formation. Cementation is envisioned as a two step process. In the first step, calcite cements form from supersaturated fluids in a freshwater, vadose environment as a meniscus cement at grain contacts. Areas of cement formation are restricted to these sites because fluid distribution is restricted to these sites. Stresses generated by the growth of cements at grain contacts are transmitted through and concentrated at quartz/quartz grain point-contacts until the stress is sufficient to fracture quartz grains, even though the ultimate strength of calcite is less than that of quartz, per unit area. This process occurs too rapidly to be accommodated by pressure solution. In the second phase of cementation, cement nucleation is no longer restricted by vadose conditions. In this phase, calcite growth can no longer result in quartz grain breakage; rather, the quartz grains are dispersed in poikilotopic calcite cement.     

The application of cathodoluminescence to interpreting the diagenesis of an ancient calcrete profile

A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone. The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone. Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis. Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence. Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.     

Calcite precipitation and Recrystallization fabrics—their significance in Jurassic Limestones of Europe

Many fabrics in Corallian (Upper Jurassic) carbonates in England, France and Switzerland are bigenetic, forming by solution/precipitation and recrystallization processes. Early precipitated cements are non‐ferroan, whereas those formed later are decidedly ferroan. Mossbauer spectroscopy has shown that the iron in the carbonates is largely divalent, substituting for calcium in the calcite lattice. The cements may be subdivided into those forming in an oxidizing environment, and those forming in a reducing environment. Fabric evidence indicates that a solution period separates the two cement phases. The diagenetic history is linked with the sedimentation pattern. Thus, under progressive build up of sediments into shallow‐water or supratidal conditions, the first‐phase cement probably precipitated from non‐marine, partially oxygenated vadose water. Subsequent subsidence and sedimentation resulted in the depression of partially cemented sediments into zones within the sedimentary pile conducive first to pyrite precipitation, and then to ferroan calcite precipitation. Fabrics can therefore be used to interpret the diagenetic environment of regressive sedimentary associations.     

Early diagenesis in Pleistocene coral reefs, southern Sinai, Egypt: response to tectonics, sea-level and climate

The uplifted Pleistocene terraces along the coast of southern Sinai exhibit a well developed reef system formed during isotope stage 9, and a younger one formed during isotope stage 5. An intermediate reef corresponding to isotope stage 7 occurs only as an erosional relic in the study area. The sediments comprise reefal framestones, peri-reefal facies, coral rubble, and siliciclastic-dominated beach and aeolian facies. The compositional and textural complexity of the sediments leads to a highly variable spatial distribution of diagenetic features. However, the geometric relationships and elemental analyses allow a reconstruction of the general diagenetic evolution: during the major eustatic sea-level highstand of isotope stage 9, the Older Reef was constructed and cemented with aragonite and high-Mg calcite. Climate was probably semiarid with some rainy periods which permitted the installation of ephemeral freshwater lenses, especially during the minor sea-level lowstand within isotope stage 9. In these lenses, and during the subsequent major sea-level lowstand, some freshwater dissolution occurred. The highstand during isotope stage 7 led to the construction of the Intermediate Reef. In the Older Reef, some high-Mg calcite precipitated at that time. Dolomite cement formed either in marine interstitial waters modified by some freshwater input, or in a hypersaline context. Phreatic-meteoric low-Mg calcite cement covers, and partly replaces, previous marine cements and dolomite, but is still attributed to the major highstand of isotope stage 7 when freshwater lenses could develop during minor sea-level lowstands. The subsequent major sea-level lowstand was dominated by an arid climate, and only a little freshwater corrosion occurred. The Younger Reef formed during the major highstand of isotope stage 5. Aragonite and high-Mg calcite cements, as well as some dolomite, are common within the reef, whereas freshwater cements are limited to beach and aeolian facies. Due to tectonic uplift, only the lower part of the Older Reef was reflooded during isotope stage 5, and only some aragonite crystals precipitated on top of dolomite or low-Mg calcite. The interrelationships between tectonics, sea-level variations of different orders, and climatic changes thus had a profound impact on the diagenetic history of these reef systems.     

Sea level and diagenesis: a case study on Pleistocene beaches,Whalebone Bay,Bermuda

Pleistocene fluctuations of sea level have left marine and aeolian limestones intercalated with glacial red soils on the Bermuda Carbonate Platform (Atlantic, 64°50W, 32°20N). Successive eustatic highstands of similar amplitude drowned the tectonically stable platform and piled up similar sets of sediments. Up to three Pleistocene beaches are stacked in shorelines sections. Post-depositional diagenetic histories of these beaches can be linked to repeated changes in sea level and pore waters.This paper presents field evidence and petrographic results (microscope, X-ray, cathodoluminescence, SEMEDAX) for the diagenetic histories of two superimposed Pleistocene beaches in Whalebone Bay, Bermuda North Shore. The younger beach was deposited during isotopic stage 5e, about 120 ka ago. The age of the older beach may be isotopic stage 9 or older.Diagenesis drastically altered the older beach before the stage 5e transgression. Primary high-Mg calcite (HMC) and aragonite were no longer present. Marine skeletal grains were instead leached or recrystallized to low-Mg calcite (LMC). Primary and secondary pore space were largely reduced by LMC cement. Lines of needle relics reminiscent of marine aragonite cement occur as inclusions within syntaxial rim cements around echinoderm grains, indicating that a marine influence had at least once interrupted this period of freshwater alteration. Finally, before the rocks became buried by the sediments of the younger beach, a crust of marine, bladed HMC cement was precipitated throughout the pore space.The younger beach consists of skeletal grains that are, apart from the effects of non-selective dissolution, essentially unaltered. The sediments are only weakly lithified by cryptocrystalline LMC showing an alveolar texture, tangential fibres and other features characteristic of calichification. A younger post-depositional marine influence is not recorded.These results suggest that, under favourable conditions, diagenetic processes can document sea-level fluctuations. The recorded fluctuations, however, are difficult to assess because even major sea-level highstands may not produce a diagenetic imprint. Correspondence to: R. Vollbrecht     

Magnesian calcite cements and their diagenesis: dissolution and dolomitization, Mururoa Atoll

The most ubiquitous syn-sedimentary cements affecting Mururoa atoll are composed of magnesian calcite. Three main types are distinguished: fibrous, bladed and sparitic on the basis of petrography, morphology and MgCO₃ concentration of the constituting crystals, while peloid infills, a particular form of HMC chemical precipitation, also exist. Petrographic evidence and isotopic signatures are compatible with marine precipitation. Mururoa atoll was exposed several times to meteoric diagenesis resulting in varied diagenetic alterations including selective dissolution and partial dolomitization of Mg-calcite cements. These alterations are responsible for substantial modifications of the initial cement fabrics and may introduce unconformities in the diagenetic chronology. The first stage of the partial dissolution of Mg-calcite induces the development of chalky, white friable zones within the initially crystalline, hard cement layers. At ultrascale, this is due to the creation of micro-voids along the elongate cement fibres. Advanced dissolution includes total disappearance of cement portions as attested to by large voids within the cement crust and/or between superposed cement layers. Mg-calcite dissolution is related to meteoric diagenesis during periods of Quaternary exposure. The creation of voids within Mg-calcite layers is due to the mechanical removal of previously altered calcium carbonate, a process suggesting marine or non-marine water flow, probably in the vadose environment. Selective dolomitization of Mururoa cements involves alternations of calcite and dolomite which form successive cement-like rinds within primary cavities. At Mururoa, these alternations are the result of selective dolomitization of the pre-existing Mg-calcite cements rather than successive precipitation of calcite and dolomite. Selective dolomitization of Mg-calcite cements at Mururoa indicates that a given cement succession is not necessarily a simple chronological sequence. Oxygen isotope values of dolomites are enriched in δ¹⁸6 by about 3‰ PDB within calcite-dolomite pseudo-alternations. The dolomitizing fluid at Mururoa seems similar to present marine water although some mixture with meteoric water is probable to favour dissolution associated with dolomitization.     

Diagenetic alteration of early marine cements of Upper Silurian stromatactis

Stromatactis is a spar network whose elements in cross section have flat to undulose lower surfaces and digitate upper surfaces. The network is composed principally of isopachous crusts of centripetal cement and commonly occurs embedded in finely crystalline limestone. It is the cement filling of interconnected cavities. Stromatactis of Upper Silurian red stromatactis limestone from Gaspé Peninsula, Québec Appalachians, exhibits two types of cements: (1) an isopachous cement that lined the walls of the conduits and is interpreted as early marine; and (2) a later blocky cement that occupies the centres of cavities. The first cement is composed exclusively of non-ferroan calcite, whereas the second cement is mixed non-ferroan and ferroan calcite. The early isopachous cement is white on polished slabs and has a turbid aspect under transmitted light. In a few samples, the relative homogeneity of this early cement is broken by the presence of distinctive grey clear calcite. Under cathodoluminscence, the grey clear calcite is non-luminescent and exhibits well defined bladed crystal shapes, whereas the white turbid cement has a dull orange luminescence and indistinct crystal shapes. The relationships between the two cements indicate that the dull luminescent cement is a secondary form of the non-luminescent cement, and it is concluded that the dull cement is the product of alteration of the non-luminescent cement by burial or meteoric fluids. The later blocky cement has the same dull luminescence as the white turbid cement and is thought to have been precipitated from the same fluids as those responsible for the alteration of the early marine cements. Oxygen isotopic values of the dull cement of the early isopachous crusts (mean δ¹⁸O= -6.8%_o are intermediate between those of the non-luminescent early marine cement (mean δ¹⁸O= -5.3%_o) and the dull luminescent blocky cement (mean δ¹⁸O= -11.8%_o), while carbon isotopic values do not differ significantly (δ¹³C=+2.9, +2.4 and +2.6%_o, respectively). The alteration also has affected the distribution of some trace elements, particularly Mg. Both unaltered and altered cements contain less than 1% microdolomite inclusions, but the Mg content of the background calcite of unaltered cement is three times that of altered cement (14171 vs. 5502 ppm). Precursor early marine cement is thought to have been low-Mg calcite. The mean δ¹⁸O value (− 5.3%_o) of unaltered early marine cement is higher than values for the oxygen isotopic signature of Silurian oceans provided by brachiopod shells.     

Rates of vadose diagenesis in quaternary dune and shallow marine calcarenites,Warrnambool, Victoria,Australia

Progressively younger cycles of Quaternary dune limestones and shallow marine calcarenites infill a coastal embayment near Warrnambool in southeastern Australia. The formations have been dated using U/Th and C¹⁴ methods or have had their ages estimated by comparison with adjacent deposits. They provide a well-dated framework for the quantification of diagenetic rates in the fresh-water vadose zone.The sequence as a whole shows progressive increase in diagenetic alteration with age, related to increasing duration of subaerial exposure. Diagenesis includes alteration of high-Mg calcite to low-Mg calcite, dissolution of aragonite and precipitation of increasing amounts of void-filling low-Mg calcite spar. These changes are reflected in the progression of bulk-rock isotope values from the youngest to the oldest strata.The rocks at Warrnambool pass through 3 main stages of diagenetic evolution. The end of stage 1 is marked by the disappearance of high-Mg calcite. This occurs in just less than 90,000 years. The end of stage 2 occurs between 400,000 and 700,000 years and is marked by the disappearance of aragonite. The end of stage 3 and the beginning of stage 4 is marked by the complete infilling of all pore space by low-Mg calcite spar. This is not generally seen in this sequence but is restricted to specific diagenetic sites such as immediately below paleosol horizons.