川东鄂西上二叠统生物礁白云石化岩石学和地球化学

川东鄂西上二叠统生物礁常有白云岩发育。白云石化的晶间孔和溶孔是礁型气田的主要储集空间。岩石学和地球化学资料表明,礁白云石化为埋藏成因。交代的流体是盐度比海水要高的地层水。在埋藏成岩作用过程中,礁白云岩是多次交代形成的。     

川西北晚三叠世海綿点礁组合的岩石学特征

作者自1975年以来对川西北晚三叠世海绵点礁的分布作了详细的普查,并进行了野外及室内岩石学、古生态及沉积相的初步研究。本文只涉及对点礁组合的岩石学方面的初步认识。一、点礁组合的地质简况这一海绵点礁组合分布于四川盆地西北部绵竹县及安县一带(图1),其层位属于上三叠统卡尼阶汉旺组,造礁生物主要是海绵,粘结生物是蓝—绿藻。礁的高度一般     

东川落雪式铜矿的含铜“礁一硅岩组合”与海底喷流热液成矿

从区域地质背景、岩石学、岩石化学、微量元素、氧同位素及稀土元素组成等方面论证东川铜矿含铜“礁—硅岩组合”中的含铜硅质条带—硅质白云岩为海底喷流热水沉积成因；提出了该类层状铜矿的深源含铜富硅混合热液海底喷流—生物富集的沉积成岩成矿模式。并提出东川落雪式层状“马尾丝”铜矿含矿岩系为“含铜礁—硅岩组合”的新观点。     

东川落雪式铜矿的含铜“礁—硅岩组合与海底喷流热液成矿

从区域地质背景，岩石学，岩石化学，微量元素，氧同位素及稀土元素组成等方面论证东川铅矿含铜“礁－硅岩组合”中的含铜硅质条带－硅质白云岩为海底喷流热水沉积成因；提出了该类层状铜矿的深源含铜富硅混合热液海底喷流－生物富集的沉积成岩成矿模式，并提出了东川落雪层状“马尾丝”铜矿合矿岩系为“含铜礁－硅岩组合”的新观点。     

湘中禾青铅锌矿床中上泥盆统沉积相及其与成矿关系之研究

岩石学基本特征和地球化学资料说明,湘中禾青中上泥盆统碳酸盐岩属于台地相区,并可细分为潮坪(包括浑水潮坪与清水潮坪)、粒屑滩、生物礁、局限海湾和潮下风暴岩五个微相。剖面对比说明区内以大乘山为界发生沉积分异,其北边为局限台地,南边为开阔台地。区内的局限台地相带为成矿提供了大量而足够的矿质,禾青生物礁相在物质与环境上为成矿提供了必要条件而成为聚矿微相,生物礁相的高孔隙率加上其下的浑水潮坪页岩为成矿提供了充分必要条件。     

广西隆林下二叠统生物礁的综合研究

本文首先讨论了该礁的生物组成。在此基础上,对礁体进行群落古生态学研究,从而划分出五种群团和十种群落,并对群落的演替及生活环境进行了探讨。通过对礁体的沉积岩石学研究,提出了礁组合岩石结构类型的概念,共划分出六大类十二种岩石结构类型,并讨论了它们的形成环境。最后,讨论了礁发育的特点及海绵礁的形成环境。     

生物岩石学的定义

生物岩石学是研究生物岩（即生物成因岩石）的特征、形成机制、形成环境及其与矿产资源关系的一门新兴交叉学科,其研究内容至少包括生物矿化、现代生物礁、古代生物礁、现代微生物岩石和古代微生物岩石5个方面。生物矿化作用和现代生物岩研究为古代生物岩研究提供了认识基础。由于现代生物圈和环境不同于古代,现代生物矿化作用和生物岩的研究成果并不能全部直接应用于古代生物岩研究。古代生物岩和生物矿化作用的类型比现代丰富得多,不可能全部从现代生物岩和生物矿化作用中找到参照,但可以为现代生物矿化实验研究提供设计思路。生物岩石学的相关学科包括生物学、微生物学、古生物学、古微生物学、沉积学、沉积岩石学、矿物学、地球化学、地质微生物学等。生物岩石学研究需要应用这些学科的知识,也会反哺这些学科。     

中国二叠纪生物礁的研究现状及新进展

对我国二叠纪生物礁的类型、演化规律及研究方法进行了系统的总结。按造礁生物种类的不同可将二叠纪生物礁分为珊瑚礁和海绵礁;按古地理位置的不同可分为岸礁、台地边缘礁及点礁。生物礁研究的方法包括传统方法、结合成岩作用的方法、定量地层学方法、地球化学方法及地球物理方法等。最后对东昆仑地区最新发现的生物礁作了简单的介绍。     

甘孜-理塘结合带中段蛇绿岩的地质特征

甘孜—理塘结合带中的蛇绿岩，从时间、空间分布及其岩石学、岩石化学、地球化学特征来看，可分为两部分。早期卡尔蛇绿岩组为大陆裂谷型蛇绿岩；晚期瓦能蛇绿岩组合为洋岛—洋中脊过渡型蛇绿岩。     

北京延庆大海坨岩体的“超单元组合—超单元—单元”划分及成因探讨

本文在 1 / 5万区调工作的基础上 ,通过对大海坨岩体的主要地质特征、岩石学特征、岩石化学特征、地球化学特征以及同位素年龄等方面的综合分析研究 ,对该岩体进行了“超单元组合—超单元—单元”划分 ,并对该岩体的成因进行了初步探讨     

湖南晚二叠世生物礁成岩作用的碳,氧同位素研究

本文通过对湖南晚二叠世生物礁中的有关胶结物及岩石的碳、氧稳定同位素研究,并结合薄片观察、探针成分分析、包裹体测温等,探讨了该地区生物礁成岩作用中的有关成岩特征。研究认为：①湖南晚二叠世生物礁中胶结物从早期到晚期δ＾１３Ｃ和δ＾１８Ｏ值总体上均有变轻的趋势,反映了礁体为一连续埋藏的成岩过程;②生物礁中所见白云石化现象主要属埋藏压实成因,礁休基本未受早期淡水或混合水影响;③礁中粗晶方解石胶结物形成于深     

Coral-stromatolite reef framework, Upper Miocene, Almería, Spain

Stromatolitic crusts on stick-like and platy Porites corals forming Messinian reefs in Almería played an important role in supporting and binding the brittle corals. The crusts were previously regarded as probable marine cements. However, their clotted, peloidal, and micritic fabrics are directly comparable with those of stromatolites. They accreted allochthonous grains even on vertical faces, and include bushy fabrics closely comparable with those produced by cyanobacterial calcification. They contain numerous fenestrae, exhibit rapid fabric variation, and locally form micro-columns and laminated domes. Their similarities to peloid micrite crusts in Recent reefs suggest that at least some of these Recent crusts are microbial in origin, even though they have widely been interpreted as marine cements. The sedimentary effects of crust development substantially affected both the morphology and relief of the reefs and the generation of reefal clasts. Binding of the reef-frame in the Pinnacle and Thicket zones in the lower and middle parts of the reef created a rigid margin which shed large (commonly up to 5 m) cuboidal blocks of coral-stromatolite frame. The blocks broke along planes of weakness provided by the vertical Porites sticks and were deposited on the Fore-Reef Slope. In the uppermost parts of the reefs crusts dominate the structure, constituting 80% or more of the rock. Veneers up to 15 cm thick encrust thin irregular Porites plates to create a solid Reef Crest Zone which has not been recognized before. The coral-stromatolite framework is associated with echinoids, crustose corallines and halimedacean algae which, together with the scleractinians, indicate normal marine salinity throughout reef growth.     

Late Miocene Halimeda alga-microbial segment reefs in the marginal Mediterranean Sorbas Basin, Spain

A ～6 Ma Messinian (late Miocene) Bioherm Unit on the southern slope of the Sorbas Basin, SE Spain, contains numerous biotically diverse lensoid patch reefs that formed on a shelf to basin slope during a cycle of relative sea-level change. Halimeda reefs are the largest and most complex of the patch reefs and are divisible into core, cap, and flank facies. On the upper and midslope they are up to 40 m thick and 400 m long. They become smaller downslope. The core consists of jumbled Halimeda segments, released by spontaneous disaggregation of the alga. The segments were stabilized close to their sites of growth and rapidly lithified by micritic and peloidal microbial crusts. Residual cavities were further veneered by isopachous marine cements. Flank facies, consisting of bedded packstones to rudstones, form wedge-shaped units lateral to the mounds. Cap facies consist of bioclastic calcarenites/calcirudites and microbial carbonates. Synsedimentary lithification assisted rapid accretion and inhibited off-mound export of sediment. Allochthonous reef-derived blocks on the mid-slope reflect penecontemporaneous rigidity of the Halimeda bioherms. Proximal Porites coral frame patch reefs associated with calcarenites were located near the shelf margin during the initial lowstand stage. Halimeda segment reefs associated with calcarenites and silty marls developed on the midslope and bivalve-bryozoan-serpulid reefs formed on the lower slope in silty marls with occasional turbidites. During the transgressive stage, coral patch reefs near the shelfbreak were overgrown by Halimeda. During highstand progradation, cap facies spread basinward as a sheet connecting many of the midslope patch reefs. These ancient analogues differ from most modern Halimeda reefs in being discrete laterally restricted patch reefs, surrounded by marly sediment, and located on a slope. They are, however, broadly comparable in biota, thickness, and depositional depth. Intense early lithification by microbial crusts and marine cements is an important feature of these Messinian segment reefs. It has not been reported from modern examples.     

Ordovician low- to intermediate-Mg calcite marine cements from Sweden: marine alteration and implications for oxygen isotopes in Ordovician seawater

Petrography demonstrates the presence of three types of fibrous calcite cement in buildup deposits of the Kullsberg Limestone (middle Caradoc), central Sweden. Translucent fibrous calcite has intrinsic blue luminescence (CL) indicative of pure calcite. This cement has 2–5 mol% MgCO₃, low Mn and Fe (≤ 100 p.p.m.), and is considered to be slightly altered to unaltered, primary low- to intermediate-Mg calcite. Grey turbid fibrous calcite has variable but generally low MgCO₃ content (most analyses <2 mol%) and variable CL response, with Mn and Fe concentrations up to 1200 and 500 p.p.m., respectively. The heterogeneous characteristics of this variety of fibrous calcite are caused by diagenetic alteration of a translucent fibrous calcite precursor. Light-brown turbid fibrous calcite has low MgCO₃ (near 1 mol%) and variable Mn (up to 800 p.p.m.) and Fe (up to 500 p.p.m.) concentrations, with an abundance of bright luminescent patches, which formed during alteration caused by reducing diagenetic fluids. The δ¹³C and δ¹⁸O values of all fibrous calcite form a tight field (δ¹³C=1·7 to 3·1‰ PDB, δ¹⁸O= ? 2·6 to ? 4·1‰ PDB) compared with fibrous calcite isotope values from other units. Fibrous calcite δ¹⁸O values are larger than adjacent meteoric or burial cements, which have δ¹⁸O δ ? 8‰ PDB. Consequently, most diagenetic alteration of Kullsberg fibrous calcite is interpreted to have occurred in the marine diagenetic realm. First-generation equant and bladed calcite cements, which pre-date fibrous calcite, are interpreted as unaltered, low-Mg calcite marine cements based on δ¹³C and δ¹⁸O data (δ¹³C = 2·3 to 2·7‰ PDB, δ¹⁸O= ? 2·8 to ? 3·5‰ PDB). Unlike fibrous cement, which reflects global sea water chemistry, first-generation equant and bladed calcite are indicators of localized modification of seawater chemistry in restricted settings. Kullsberg abiotic marine cements have larger δ¹⁸O values than most Caradoc marine precipitates from equatorial Laurentia. Positive Kullsberg δ¹⁸O values are attributed to lower seawater temperatures and/or slightly elevated salinity on the Baltic platform relative to seawater from which other marine precipitates formed.     

鄂尔多斯盆地南部奥陶系碳酸盐储层的胶结作用

鄂尔多斯盆地南部奥陶系马家沟组主要由原始沉积的碳酸盐岩和岩溶角砾岩组成。储集空间以次生孔隙为主。中奥陶世沉积作用之后不久,即发生了溶解作用、白云石沉淀、干化脱水作用、机械压实作用、岩溶作用和胶结作用。胶结作用很普遍,主要发生在中石炭世之后的埋藏条件下,是对储层重要的破坏作用。充填于硬石膏结核溶模孔和非组构选择性溶蚀孔、洞、缝的方解石和白云石是最常见的胶结物。这些方解石和白云石胶结物具泥晶、嵌晶状或粒状晶粒结构。泥晶白云石基质的δ18O值-10.98‰~-0.8‰,平均-5.54‰;δ13C值-4.76‰~5.77‰,平均1.51‰。充填于溶蚀孔、缝中的白云石的δ18O值-12.54‰~-2.67‰,平均-7.34‰;δ13C值-5.56
‰~3.48‰,平均0.28‰。充填于溶蚀孔、缝方解石的δ18O值-15.42‰~-6.02‰,平均-9.51‰;δ13C值-12.44‰~1.33‰,平均-3.20‰。总的来说,白云石和方解石胶结物的δ18O和δ13C值低于泥晶白云石基质的,原因是形成晚,受淡水淋滤、埋藏作用和有机质影响较大。泥晶白云石基质的Na含量0~350 μg/g,平均59 μg/g; Sr含量0~380 μg/g,平均10 μg/g;Fe含量0~14 570 μg/g,平均1 040 μg/g;Mn含量0~4 670 μg/g,平均183 μg/g。充填于次生孔隙中的胶结物的Na、Sr、Mn含量与泥晶白云石基质的差别不大,因这些元素含量均低。充填于次生孔隙的碳酸盐胶结物较泥晶白云石基质有明显高的Fe含量。胶结物包裹体的均一温度在90℃~140℃范围内。胶结物沉淀于埋藏较深,温度较高的还原条件下。流体包裹体的气相成分以CH4最为普遍,液相成分以H2O占绝大多数。早期胶结物形成于天然气形成前,晚期胶结物形成于天然气形成之后。岩溶洼地是胶结作用最发育的地带。     

巴布亚新几内亚合恩半岛晚第四纪上升珊瑚礁造礁珊瑚的成岩历史

更新世以来,剧烈的构造运动已将巴布亚新几内亚合恩半岛东北海岸的晚第四纪珊瑚礁阶地抬升上千米.阶地中造礁珊瑚的成岩变化和成岩产物的组构特征反映了该礁的成岩历史,充分体现该区快速构造上升的影响.海水潜流带和淡水渗流带为上升礁的主要成岩环境.生物钻孔、生物碎屑填隙、珊瑚文石针粗化、珊瑚骨骼的溶解和新生变形转化,以及其不同矿物成分和组构的种种胶结物的胶结作用是造礁珊瑚经历的主要成岩作用.地球化学资料表明其成岩变化发生于开放的化学体系之中.     

The complex diagenetic history of discontinuities in shallow‐marine carbonate rocks: New insights from high‐resolution ion microprobe investigation of δ18O and δ13C of early cements

Sedimentary gaps are a major obstacle in the reconstruction of a carbonate platform's history. In order to improve the understanding of the early diagenesis and the succession of events occurring during the formation of discontinuity surfaces in limestones, secondary ion mass spectrometry was used for the first time to measure the δ ¹⁸O and δ ¹³C signatures of 11 early cement and fabric stages in several discontinuity surfaces from the Jurassic carbonate platform of the Paris Basin, France. Pendant cements show a high variability in δ ¹⁸O, which was impossible to detect by the less precise microdrilling method. The morphology of a given cement can be produced in various environments, and dogtooth cements especially can precipitate in marine phreatic and meteoric phreatic to vadose environments. Marine dogtooth cements and micritic microbially induced fabrics precipitated directly as low‐magnesium calcite in marine waters, as attested to by the preservation of their initial δ ¹⁸O and δ ¹³C signals. Five discontinuity types are recognized based on high‐resolution geochemical analyses, and their palaeoenvironmental history can be reconstructed. Two exposure surfaces with non‐ferroan pendant or meniscus cements formed in the oxidizing vadose zone. A hardground displays marine fibrous cements and non‐ferroan dogtooth cements that formed in a subtidal environment in oxidizing water. Two composite surfaces have undergone both marine and subaerial lithification. Composite surface 1 displays non‐luminescent ferroan dogtooth cements that precipitated in reduced conditions in seawater, followed by brown‐luminescent dogtooth cements characteristic of a meteoric phreatic environment. Composite surface 2 exhibits microbially induced fabrics that formed in marine water with abundant organic matter. The latter discontinuity, initially formed in a subtidal environment, was subsequently exposed to meteoric conditions, as evidenced by ferroan geopetal cements. A high‐resolution ion microprobe study is essential to precisely document the successive diagenetic environments that have affected carbonate rocks and discontinuities with a polygenic and intricate history.     

Stable isotopes of cherts and carbonate cements in the Lake Valley Formation (Mississippian), Sacramento Mts, New Mexico

Oxygen isotopic compositions of chert and calcite cements in the Lake Valley Formation indicate that these diagenetic features cannot be equilibrium co-precipitates in spite of their coexistence in the same interstices. Petrography of megaquartz and non-ferroan calcite cements indicates that both are original precipitates that formed during pre-Pennsylvanian time at shallow burial depths (< 215m) implying precipitation temperatures less than 30°C. Under these constraints the δ¹⁸Os of megaquartz (mean =+27.0^0/00 SMOW; range =+ 24.8 to + 28.9^0/00) and calcite (mean =+ 28.0^0/00 SMOW; range =+ 27.3 to + 28.4^0/00) are best interpreted as unaltered since precipitation; thus, they must reflect the oxygen isotopic composition of pre-Pennsylvanian pore waters. Microquartz and chalcedony are interpreted to have formed from recrystallization of pre-Pennsylvanian opal-CT precursors, and therefore probably re-equilibrated during recrystallization in late or post-Mississippian time. We propose a model integrating the isotopic data with regional petrographic and sedimentological data that explains the greater consistency and generally greater δ¹⁸Os values of the calcites compared to those of the cherts. This model is one of chertification and calcite cementation in a regional meteoric phreatic ground-water system, the seaward terminus of which moved southward during lowering of pre-Pennsylvanian sea level. The calcite cements and some of the opal-CT precursor to microquartz and chalcedony are interpreted to have formed in the more seaward portions of the groundwater system. The megaquartz precipitated in the more inland parts of the phreatic groundwater system where rainfall was isotopically lighter and more variable. As such, the δ¹⁸Os of the megaquartz reflect the isotopic composition of groundwaters in areas undersaturated with respect to calcite.     

Contrasting diagenesis of two Carboniferous Oolites from South Wales: a tale of climatic influence

Two oolites in the Dinantian (Mississippian/Lower Carboniferous) of Glamorgan, SW Britain, were deposited in similar depositional environments but have contrasting diagenetic histories. The Brofiscin and Gully Oolites occur in the upper parts of shallowing-upward sequences, formed through strandplain progradation and sand shoal and barrier growth upon a southward-dipping carbonate ramp. The Brofiscin Oolite is characterized by a first-generation cement of equant calcite spar, preferentially located at grain-contacts and forming non-isopachous fringes around grains, interpreted as meteoric vadose and phreatic in origin. Isopachous fibrous calcite fringes of marine origin are rather rare and occur only at a few horizons. Burial compaction was not important and porosity was occluded by poikilotopic calcite spar. Fitted grain-grain contacts locally occur and could be the result of near-surface vadose dissolution-compaction. Syntaxial overgrowths on echinoderm debris are common. Pre-compaction overgrowths are cloudy (inclusion-rich) and probably of meteoric origin, and post-compaction overgrowths are inclusion-free. By contrast, the Gully Oolite has little first-generation cement. However, marine fibrous calcite is common in oolitic intraclasts, as isopachous fringes of acicular calcite crystals closely associated with peloidal internal sediment; and early equant, drusy calcite spar occurs in the uppermost part of the Gully, beneath a prominent palaeokarst where pedogenic cements also occur. The major feature of Gully diagenesis is burial compaction, resulting in extensive grain-grain dissolution and microstylolitic grain contacts, and post-compaction poikilotopic spar occluded remaining porosity. The Brofiscin Oolite is pervasively dolomitized up-dip but the Gully Oolite for the most part only contains scattered pre-compaction dolomite rhombs and late veins of baroque dolomite, with less pervasive dolomitization. The difference in diagenetic style of the two Dinantian oolites is attributed to prevailing climate. The paucity of early meteoric cements in the Gully is a result of an arid climate, and this is supported by the nature of the capping palaeokarst. The abundant meteoric cements in the Brofiscin reflect a more humid climate, and effective meteoric recharge also resulted in up-dip pervasive mixing-zone dolomitization. The style of early diagenesis in these two oolites exerted a major control on the later burial diagenesis: in the Brofiscin, the early cements inhibited grain-grain dissolution and pressure solution, while these processes operated extensively in the Gully Oolite. Thus, prevailing climate can influence a limestone's diagenetic history from near-surface through into deep burial.     

中韩第五次《东北亚地壳演化》学术研讨会在北京举行

新疆天山东部广泛发育晚石炭世碳酸盐岩隆。这些岩隆主要为生物丘,少数为生物滩及与岩隆有关的生物层,其中生物丘含大量灰泥和内碎屑。基本岩石类型为泥粒状灰岩、粒泥状灰岩、粒泥状－泥粒状灰岩,少量岩石类型包括颗粒岩、骨架岩和障积岩。成岩作用是碳酸盐岩隆发展演化的重要阶段和过程,在生物丘内,已经识别出四种重要的胶结物,即球粒泥晶、纤状方解石、放射轴状方解石和粒状方解石。尽管缺失典型的造礁生物,但通过岩石类型研究和微相分析,认为碳酸盐岩隆的形成主要取决于生物作用及古环境格局。本区碳酸盐岩隆可以同欧洲瓦尔索坦的岩隆对比