Chromian spinels in lherzolite inclusions from Itinome-gata,Japan

Spinel, which constitutes from 0.7% to 3% of lherzolite inclusions, occurs as primary anhedral grains (chrome-rich variety) and as a secondary phase as breakdown products of garnet (alumina-rich variety). Although individual primary spinel grains are chemically homogeneous, spinels are characterized by a wide range of Cr/Al ratios and a relatively narrow range of Mg/Fe″ ratios, even in a single lherzolite sample. The chemical variations of spinels are considered to have the following origin: When garnet lherzolite enters the stability field of the spinel peridotite facies as a consequence of slow upward transport, both orthopyroxenes and clinopyroxenes are recrystallized with loss of jadeite and some Tschermak's component to reach equilibrium. A part of the Tschermak's component reacts with olivine to form pyroxene and spinel. This secondary spinel component is alloted to the primary chromian spinel. However, these reactions did not always reach equilibrium with the major constituent minerals in the lherzolites.     

Thermal and petrological structure of the lithosphere beneath Hannuoba, Sino-Korean Craton, China: evidence from xenoliths

Deep-seated xenoliths entrained in the Hannuoba basalts of the northern Sino-Korean Craton include mafic and felsic granulites, mantle wall-rock from spinel– and garnet–spinel peridotite facies, and basaltic crystallisation products from the spinel-pyroxenite and garnet-pyroxenite stability fields. The mineral compositions of the xenoliths have been used to estimate temperatures and, where possible, pressures of equilibration, and to construct a geothermal framework to interpret the upper mantle and lower crustal rock-type sequences for the region. The xenolith-derived paleogeotherm is constrained in the depth interval of 45–65 km and like others from areas of young basalt magmatism, is elevated and strongly convex toward the temperature axis. Two-pyroxene granulites give the lowest temperatures and garnet pyroxenites the highest, while the spinel lherzolites fall between these two groups. The present-day Moho beneath the Hannuoba area is defined at 42 km by seismic data, and coincides with the deepest occurrence of granulite. Above this boundary, there is a lower crust–upper mantle transition zone about 10-km thick, in which spinel lherzolites and mafic granulites (with variable plagioclase contents) are intermixed. It is inferred that this underplating has resulted in a lowering of the original pre-Cenozoic Moho (then coinciding with the crust–mantle boundary, CMB) from about 30 km to its present-day position and was due to intrusions of basaltic magmas that displaced peridotite mantle wall-rock and equilibrated to mafic granulites. Trace element patterns of the diopsides (analysed by laser ablation-ICPMS) from the Cr-diopside series spinel lherzolites and associated layered xenoliths (spinel lherzolites and pyroxenites) indicate a fertile uppermost mantle with moderate depletion by low degrees of partial melting and little evidence of metasomatic activity. The similarity in major and trace element compositions of the minerals in both rock types suggests that the layered ultramafic xenoliths formed by mantle deformation processes (metamorphic segregation), rather than by melt veining or metasomatism.     

Indicator minerals of diamond in the lamproitic diatreme, Kostomuksha region, Karelia

The mineralogy of a new lamproitic diatreme 200–250 m in diameter and 3 ga in area is studied in detail. The chemical and 3-D mineralogical analysis identify the diatreme rocks as strongly altered olivine lamproites with a large volume (50–60%) of xenoliths of strongly altered spinel (garnet) lherzolites and harzburgites-dunites. Numerous grains-xenocrysts of indicator minerals of diamond have been extracted from the heavy concentrates (the weight of the initial product is 742 g and the size is 100–500 μm) as a result of hydroseparation: (1) subcalcium (CaO_av. 2.6 wt %) high-Cr (Cr₂O_{3 av.} 5.3 wt %) pyrope (50 grains); (2) chrome diopside (7 and 8 mol % of kosmochlor and jadeite components, respectively, >40 grains); (3) high-Cr chromite (Cr₂O₃ > 62 wt %); and (4) picroilmenite (MgO 12–13.8 wt %) and Cr-rutile (Cr₂O₃ 1.1 wt %). Xenocrysts prove the mantle endogene (the level of garnet lherzolites) source of the magmatic center of lamproites and forecast the diamond potential of the new diatreme in the Kostomuksha ore district.     

Eclogites in the Makuti gneisses of Zimbabwe: implications for the tectonic evolution of the Zambezi Belt in southern Africa

The gneisses of the Makuti Group in north-west Zimbabwe are characterized by complex geometries that resulted from intense non-coaxial deformation in a crustal scale high-strain zone that accommodated extensional deformation along the axis of the Zambezi Belt at c. 800 Ma. Within low-strain domains in the Makuti gneisses, undeformed metagabbroic lenses preserve eclogite and granulite facies assemblages, which record a part of the metamorphic history that predates Pan-African events. Eclogitic rocks can be subdivided into: (1) corona-textured metagabbros that preserve igneous textures, and (2) garnet–omphacite rocks in which primary textures are destroyed. The lenses of eclogitic rocks are enveloped in a mantle of garnet–clinopyroxene–hornblende gneiss, which is a common rock type in the Makuti gneisses. The eclogites preserve multi-staged, domainal, symplectic reaction textures that developed progressively as the rocks experienced loading followed by decompression–heating. In the metagabbros, the original clinopyroxene, plagioclase and olivine domains acted separately during the peak of metamorphism, with plagioclase being replaced by garnet and kyanite, and olivine being replaced by orthopyroxene and possibly omphacite. The peak assemblage was overprinted by: (1) the multi-mineralic corona assemblage pargasite–orthopyroxene–spinel–plagioclase replacing garnet–kyanite–clinopyroxene (possibly at c. 19 kbar, 760±25 °C); (2) orthopyroxene–pargasite–plagioclase–scapolite coronas replacing orthopyroxene (15±1.5 kbar, 750±50 °C); and (3) moats of orthopyroxene–plagioclase replacing garnet (10±1 kbar, 760±50 °C). The garnet–omphacite rocks record similar peak conditions (15±1.1 kbar, 760±60 °C). Garnet–clinopyroxene–hornblende–plagioclase gneisses envelop the eclogites and record matrix conditions of 11±1.5 kbar at 730±50 °C using assemblages that are oriented in the regional fabric. These rocks are characterized by decompression-heating textures, reflecting temperature increases during exhumation of the Makuti gneisses. The eclogite facies rocks formed during a collisional event prior to 850 Ma. Their formation could be related to a suture zone that developed along the axis of the Zambezi Belt during the formation of Rodinia (between 1400 and 850 Ma). The main deformation-metamorphism in the Makuti gneisses occurred around 800 Ma and involved extension and exhumation of the high-P rocks (break-up of Rodinia), which experienced a high-T metamorphic overprint. Around 550–500 Ma, a collisional event associated with the formation of Gondwana resulted in renewed burial and metamorphic recrystallization of the Makuti gneisses.     

Temperature-dependent distribution of Cr between olivine and pyroxenes in lherzolite xenoliths

The temperature effect on the exchange reaction Cr₂O₃(ol)=Cr₂O₃(px) was studied for coexisting olivine and both clino and ortho pyroxenes. The distribution of Cr between olivine and clinopyroxene in 31 coarse garnet lherzolites and 10 porphyroclastic garnet lherzolites from kinberlites, and in 17 coarse spinel lherzolites from basalts, obeys a van't Hoff relation (c.f. Stosch 1981) with the Wells two-pyroxene temperature: T(Kelvin)=8,787 (In D _Cr+ 2.87) where D _Cr(opx/ol)=wt.% Cr(clinopyroxene)/Cr(olivine). An analogous exchange for olivine and orthopyroxene with 0.7–1.6 wt.% Al₂O₃ in 41 garnet lherzolites from kimberlites shows considerable scatter about the following relation: T(Kelvin)=5,540/(ln D _cr+1.86) where D _cr(opx/ol)= wt.% Cr(orthopyroxene)/Cr(olivine). Spinel lherzolites and a garnet lherzolite from the Malaita alnöite do not obey the second relation. For orthopyroxene with 2.5–5.1 wt.% Al₂O₃, D _cr(opx/ol) is 1.7 to 3 times higher, and for 0.1 wt.% Al₂O₃ is 2 times lower than for the garnet lherzolites. Experimental calibration is needed, especially to check the possible effect of Al on D _cr(opx/ol).     

Separate or shared metamorphic histories of eclogites and surrounding rocks? An example from the Bohemian Massif

Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H₂O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H₂O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km^?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.     

Petrography and mineral chemistry of Ca-rich inclusions in the Allende meteorite

There are two types of white, coarse-grained, Ca-Al-rich inclusions in Allende. Type A inclusions contain 80–85 per cent melilite, 15–20 per cent spinel, 1–2 per cent perovskite and rare plagioclase, hibonite, wollastonite and grossularite. Clinopyroxene, if present, is restricted to thin rims around inclusions or cavities in their interiors. Type B inclusions contain 35–60 per cent pyroxene, 15–30 per cent spinel, 5–25 per cent plagioclase and 5–20 per cent melilite. The coarse pyroxene crystals in Type B's contain >15 per cent Al₂O₃ and >1.8 per cent Ti, some of which is trivalent. Type A pyroxenes contain <9 per cent Al₂O₃ and <0.7 per cent Ti.Electron microprobe analyses of 600 melilite, 39 pyroxene, 35 plagioelase, 33 spinel and 20 perovskite grains were performed in 16 Type A, 1 intermediate and 9 Type B inclusions in Allende and 1 Type A in Grosnaja. Melilite composition histograms from individual Type A inclusions are usually peaked between Ak10 and Ak30 and are 15–20 mole % wide while those from Type B inclusions are broader, unpeaked and displaced to higher åkermanite contents. Most pyroxenes contain < 1 per cent FeO. All plagioclase is An 98 to An 100. Spinel is almost pure MgAl₂O₄. Perovskite contains small (< 1 per cent) but significant amounts of Mg, Al, Fe, Y, Zr and Nb.Inferred bulk chemical compositions of Type A inclusions are rather close to those expected for high-temperature condensates. Those of Type B inclusions suggest slightly lower temperatures but their Ca/Al ratio seems less than the Type A's, indicating that the Type B's may not be their direct descendants. Some textural features suggest that the inclusions are primordial solid condensetes while others indicate that they may have been melted after condensation. Fragmentation and metamorphism may have also occurred after condensation.     

Coronitic textures in the ferrogabbroids of the Elet’ozero intrusive complex (northern Karelia,Russia) as evidence for the existence of Fe-rich melt. 1. Types of coronas

Fe–Ti oxides (magnetite, Ti-magnetite, ilmenite, and associated high-Al spinel) in the ferrogabbroids of the Middle Paleoproterozoic Elet’ozero syenite–gabbro intrusion are intercumulus minerals usually surrounded by coronitic rims of two types. The first type usually represents multilayer amphibole–biotite ± olivine coronas along contacts of Fe–Ti oxides with cumulus moderate-Ca plagioclase and more rarely, clinopyroxene. Two-layer rim is developed in contact with high-Ca plagioclase; the inner rim consists of pargasite and spinel, while the outer rim is made up of sadanagaite and spinel. The second type is represented by two-stage coronitic textures developed along boundaries of olivine and Fe–Ti oxide clusters with plagioclase. Initially, the olivine was surrounded by orthopyroxene rim, while Fe–Ti oxides were rimmed by pargasite with thin ingrowths of high-Al spinel (hercynite). At the next stage, the entire cluster was fringed by a common symplectite reaction rim, the composition of which also depended on the composition of plagioclase matrix: the spinel–sadanagaite rim was formed in contact with high-Ca plagioclase, while pargasite–muscovite–scapolite rim was formed in contact with moderate-Ca plagioclase. The formation of the outer rims occurred after hydration of the inner parts of coronas around olivine and oxides within the clusters. It is suggested that the Fe–Ti oxides and surrounding coronitic rims were microsystems formed by crystallization of drops of residual hydrous Fe-rich liquid.     

福建明溪上地幔热结构及流变学特征

通过对采自福建明溪的幔源包体样品的详细研究,建立了该区上地幔的地温线,探讨其流变学特征。所获地温线高于大洋地温线,但稍低于中国东部和澳大利亚东南部地温线。由该地温线推导的壳幔边界为３８ｋｍ左右,但尖晶石二辉橄榄岩在３２ｋｍ左右即已开始出现,表明存在上地幔物质的底侵作用。同样,尖晶石二辉橄榄岩和石榴子石二辉橄榄岩包体平衡温度有所重叠,表明两者不是截然分开,其间存在有５￣１０ｋｍ的过渡带。包体的变形特     

Petrological constraints on the cooling history of high-temperature garnet peridotite massifs in lower Austria

High-temperature peridotite massifs occur as lensoid bodies with high-pressure granulites in the southern Bohemian massif. In lower Austria the peridotites comprise garnet lherzolites lacking primary spinel, rare garnet and garnet-spinel harzburgites, and harzburgites containing Cr-rich primary spinel instead of garnet. These phase assemblages suggest initial high-pressure equilibration and are consistent with results from garnet-orthopyroxene geobarometry indicating equilibration at around 3–3.5 GPa. Maximum temperature estimates obtained on core compositions of coexisting minerals from the peridotites are not higher than ca. 1100 °C. In contrast, pyroxene megacryst compositions, garnet exsolution textures in the garnet pyroxenites, and results from geothermometry indicate much higher original equilibration temperatures in most of the pyroxenites (up to 1400 °C). High temperatures, modal zoning, the occasional presence of Mg-rich garnetites and chemical evidence suggest that the pyroxenites are cumulates which crystallized from low-degree melts derived from the sub-lithospheric mantle. Isothermal interpolation of the high temperatures to an upper mantle adiabat suggests that the melts were derived from a minimum depth of 180–200 km. The formation of small garnet II grains and garnet exsolution lamellae in the pyroxenites and pyroxene megacrysts may reflect isobaric cooling of the cumulates from temperatures above 1400 °C to ca. 1100–1200 °C (at 3–3.5 GPa) to approach the ambient lithospheric isotherm. This model differs from other models in which the formation of garnet II was explained by an increase in pressure during cooling in a subduction zone. Isobaric cooling was followed by near-isothermal decompression from 3–3.5 GPa to 1.5–2 GPa at 1000–1200 °C, as indicated by the increase of Al in pyroxenes near garnet. Further cooling in the spinel lherzolite stability field is indicated by spinel exsolution lamellae in pyroxenes from lherzolites. The formation of symplectites and kelyphites indicate sub-millimetre scale re-equilibration during exhumation in the course of the Carboniferous collision in the Bohemian massif. The peridotite massifs represent fragments of normal (non-cratonic) lithospheric mantle from a Paleozoic convergent plate margin. Received: 22 July 1996 / Accepted 28 February 1997     

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.     

Application of K-feldspar–jadeite–quartz barometry to eclogite facies metagranites and metapelites in the Sesia Lanzo Zone (Western Alps, Italy)*

The eclogite facies assemblage K-feldspar–jadeite–quartz in metagranites and metapelites from the Sesia-Lanzo Zone (Western Alps, Italy) records the equilibration pressure by dilution of the reaction jadeite+quartz=albite. The metapelites show partial transformation from a pre-Alpine assemblage of garnet (Alm₆₃Prp₂₆Grs₁₀)–K-feldspar–plagioclase–biotite±sillimanite to the Eo-Alpine high-pressure assemblage garnet (Alm₅₀Prp₁₄Grs₃₅)–jadeite (Jd_80–97Di_0–4Hd_0–8Acm_0–7)–zoisite–phengite. Plagioclase is replaced by jadeite–zoisite–kyanite–K-feldspar–quartz, and biotite is replaced by garnet–phengite or omphacite–kyanite–phengite. Equilibrium was attained only in local domains in the metapelites and therefore the K-feldspar–jadeite–quartz (KJQ) barometer was applied only to the plagioclase pseudomorphs and K-feldspar domains. The albite content of K-feldspar ranges from 4 to 11 mol% in less equilibrated assemblages from Val Savenca and from 4 to 7 mol% in the partially equilibrated samples from Monte Mucrone and the equilibrated samples from Montestrutto and Tavagnasco. Thermodynamic calculations on the stability of the assemblage K-feldspar–jadeite–quartz using available mixing data for K-feldspar and pyroxene indicate pressures of 15–21 kbar (±1.6–1.9 kbar) at 550±50 °C. This barometer yields direct pressure estimates in high-pressure rocks where pressures are seldom otherwise fixed, although it is sensitive to analytical precision and the choice of thermodynamic mixing model for K-feldspar. Moreover, the KJQ barometer is independent of the ratio PH2O/P_T. The inferred limiting a(H₂O) for the assemblage jadeite–kyanite in the metapelites from Val Savenca is low and varies from 0.2 to 0.6.     

Ultra-high-pressure metamorphism of carbonate rocks in the Dabie Mountains, central China

Abstract Widespread ultra-high-P assemblages including coesite, quartz pseudomorphs after coesite, aragonite, and calcite pseudomorphs after aragonite in marble, gneiss and phengite schist are present in the Dabie Mountains eclogite terrane. These assemblages indicate that the ultra-high-P metamorphic event occurred on a regional scale during Triassic collision between the Sino-Korean and Yangtze cratons. Marble in the Dabie Mountains is interlayered with coesite-bearing eclogite and gneiss and as blocks of various size within gneiss. Discontinuous boudins of eclogite occur within marble layers. Marble contains an ultra-high-P assemblage of calcite/aragonite, dolomite, clinopyroxene, garnet, phengite, epidote, rutile and quartz/coesite. Coesite, quartz pseudomorphs after coesite, aragonite and calcite pseudomorphs after aragonite occur as fine-grained inclusions in garnet and omphacite. Phengites contain about 3.6 Si atoms per formula unit (based on 11 oxygens). Similar to the coesite-bearing eclogite, marble exhibits retrograde recrystallization under amphibolite–greenschist facies conditions generated during uplift of the ultra-high-P metamorphic terrane. Retrograde minerals are fine grained and replace coarse-grained peak metamorphic phases. The most typical replacements are: symplectic pargasitic hornblende + epidote after garnet, diopside + plagioclase (An₁₈) after omphacite, and fibrous phlogopite after phengite. Ferroan pargasite + plagioclase, and actinolite formed along grain boundaries between garnet and calcite, and calcite and quartz, respectively. The estimated peak P–T conditions for marble are comparable to those for eclogite: garnet–clinopyroxene geothermometry yields temperatures of 630–760°C; the garnet–phengite thermometer gives somewhat lower temperatures. The minimum pressure of peak metamorphism is 27 kbar based on the occurrence of coesite. Such estimates of ultra-high-P conditions are consistent with the coexistence of grossular-rich garnet + rutile, and the high jadeite content of omphacite in marble. The fluid for the peak metamorphism was calculated to have a very low X_CO2 (<0.03). The P–T conditions for retrograde metamorphism were estimated to be 475–550°C at <7 kbar.     

Geothermometry of spinel lherzolites

Three methods of geothermometry, currently used for spinel lherzolites, are refined based on new experiments on subsolidus phase equilibria of olivine, pyroxenes and spinel in CaO-MgO-Al₂O₃-SiO₂ and natural rock systems at 16 kb and 1200 °C. Although quasi-thermodynamic modelling is employed, the methods are essentially based on the pyroxene solvus, alumina contents in clinopyroxene and orthopyroxene. Increasing alumina contents in pyroxenes reduce enstatite and diopside components in clinopyroxene and orthopyroxene, respectively. Thus, neglect of alumina in pyroxenes causes underestimates of temperatures by the solvus method.The three geothermometers were tested by applying them to homogeneous spinel lherzolites which were especially selected for this purpose. Coincidence of the three temperatures thus estimated gives confidence in the effectiveness of the geothermometers.They were also applied to spinel lherzolite nodules in basalts and intrusive lherzolites described in the literature. It was found that equilibration temperature of the nodules varies from 1000 °C to 1300 °C, i.e., temperatures somewhat higher than have been generally thought. In contrast to the nodules, the intrusive spinel lherzolites show extensive disequilibrium, which is probably due to retrogressive metamorphism suffered by the intrusives.     

Comparative equilibration temperatures and pressures of garnet lherzolites in Norwegian gneisses and in kimberlite

The chemistry of the pyroxenes suggests that the garnet lherzolites enclosed in the Norwegian basal gneisses have equilibrated at depths greater than 70 kilometres along an expected sub-continental geotherm. Such depths are somewhat shallower than the apparent depths of origin of most garnet lherzolite xenoliths in kimberlite pipes. Distribution coefficients for Fe²⁺/Mg²⁺ and Mn²⁺/Mg²⁺ between coexisting clinopyroxenes and garnets support the slightly lower equilibration temperatures deduced for the Norwegian garnet lherzolites compared with the xenolithic garnet lherzolites in kimberlites.The pressure-temperature equilibration conditions deduced for the Norwegian garnet lherzolites (800–1020°C at 22–37 kbs) contrast with previous estimates (625 ± 30° at 14 kbs) for basic eclogite masses in the Norwegian gneisses. This suggests a possible dual paragenesis of the Norwegian eclogites, with the garnet lherzolites being tectonic slices of the sub-continental upper mantle and the basic eclogites deep crustal metamorphic rocks.     

P-T history of a mantle diapir: the Horoman peridotite complex,Hokkaido, northern Japan

The Horoman peridotite complex, Hokkaido, Japan is divided into Lower and Upper zones on the basis of contrasting geological features. The complex recorded a consecutive decompression history in chemical zoning of pyroxenes and plagioclase in plagioclase lherzolite, which is interpreted to have been derived from garnet lherzolite by subsolidus decompression reactions. In the Lower Zone, and earlier decompression history is clearly preserved in large pyroxene porphyroclasts, which show marked M-shaped Al zoning characterized by low Al concentration at the core (Al=0.12/6 oxygens), gradual increase toward the marginal region, and rapid decrease toward the rim. The Ca content in the core is nearly constant (Ca=0.03/6 oxygens) with slight increase toward the margin followed by abrupt decrease toward the rim. The Al and Ca contents in the core of orthopyroxene in plagioclase lherzolite from the Upper Zone (Al=0.22, Ca=0.055/6 oxygens) are much higher than those for the Lower Zone, and the Al content typically decreases monotonously from the core to the rim with several exceptions that show poorly developed M-shaped zoning profiles. The earliest P-T conditions, inferable from the core compositions of pyroxenes are 900–950°C and 20 kbar for the Lower Zone and 1100–1150°C and 20 kbar for the Upper Zone. The increase of Al from the core to the margin is inferred to have resulted from nearly adiabatic decompression from these conditions into spinel peridotite facies. The complex experienced further decompression from the spinel stability field into the plagioclase stability field, which is inferred from plagioclase zoning in fine-grained aggregates composed mostly of plagioclase, chromite spinel, and olivine with minor pyroxenes. The Na-Ca ratio of each plagioclase grain decreases from the core to the rim, suggesting continuous decompression reaction producing olivine and plagioclase from pyroxenes and spinel. The sharp increase in Ca content toward the rim indicates that fairly rapid cooling associated with decompression is necessary to form and preserve the marked zoning. The sharp decrease in Al and Ca contents toward the rim of orthopyroxene was also formed during this final ascent of the complex. The systematic changes of the mineralogic and petrographic features that are gradational between the Lower and Upper zones suggest that the Horoman complex retains a temperature variation from the upper mantle. The Upper Zone is interpreted to have followed a higher temperature decompression path than the Lower Zone and probably represents a relatively hotter portion of a mantle diapir ascending from a depth greater than 60 km in the upper mantle.     

Experimental determination of pargasite stability relations in the presence of orthopyroxene

The stability and partial melting of synthetic pargasite in the presence of enstatitic orthopyroxene (opx), forsterite, diopsidic clinopyroxene (cpx), plagioclase (An₅₀), and water has been studied in the range of 0.4–6.0 kb and 750–1000°C in the system Na₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O with a fixed bulk composition of pargasite+5 opx. The addition of orthopyroxene effectively reduces the stability field of pargasite by approximately 200°C at 1 kb. The invariant point involving pargasite coexisting with water-saturated liquid and anhydrous phase shifts from about 0.85 kb and 1025°C to 2.5±0.5 kb and 925±25°C with the addition of opx. Based on the solidus mineral assemblage and direct chemical analysis of quenched glass, the vapor-saturated liquid has a composition close to that of intermediate plagioclase. A layered silicate, interpreted to be Na-phlogopite, has an upper-thermal stability that nearly equals that of pargasite in the field of partial melting and coexists with liquid, pargasite, cpx, and forsterite at 6 kb, 1000°C. These results support the hypothesis that mantle metasomatism could involve formation of pargasitic amphibole from a silicate melt at depths as shallow as 8–10 km.     

我国金伯利岩中的深源岩石包体

作者研究发现山东胜利1号、辽宁50号、51号及42号岩体中,见有纯橄岩、石榴二辉橄榄岩、尖晶二辉橄榄岩及云母橄榄岩包体;河北涉县及山东红旗2号金伯利岩中见有榴辉岩包体。包体形态为浑圆状、椭圆状,其大小为1-15cm。纯橄岩和石榴二辉橄榄岩比其寄主金伯利岩富含Cr_2O_3、NiO_3、贫CaO、CO_2、K_2O、Na_2O、TiO_2和Al_2O_3,其稀土配分模式为LREE富集型。根据深源岩石包体的温度、压力条件的估算,认为纯橄岩和石榴二辉橄榄岩来自上地幔深处,为上地幔局部熔融的残余物,而河北涉县金伯利岩中榴辉岩包体来自下地壳,云母橄榄岩类为软流圈顶部的地幔交代作用带上的岩石,尖晶二辉橄榄岩是来自上地幔较浅部位,它们为金伯利岩浆的偶然捕虏体。     

Formation of eclogite, and reaction during exhumation to mid-crustal levels, Snowbird tectonic zone, western Canadian Shield

A re‐evaluation of the P–T history of eclogite within the East Athabasca granulite terrane of the Snowbird tectonic zone, northern Saskatchewan, Canada was undertaken. Using calculated pseudosections in combination with new garnet–clinopyroxene and zircon and rutile trace element thermometry, peak metamorphic conditions are constrained to ～16 kbar and 750 °C, followed by near‐isothermal decompression to ～10 kbar. Associated with the eclogite are two types of occurrences of sapphirine‐bearing rocks preserving a rich variety of reaction textures that allow examination of the retrograde history below 10 kbar. The first occurs as a 1–2 m zone adjacent to the eclogite body with a peak assemblage of garnet–kyanite–quartz interpreted to have formed during the eclogite facies metamorphism. Rims of orthopyroxene and plagioclase developed around garnet, and sapphirine–plagioclase and spinel–plagioclase symplectites developed around kyanite. The second variety of sapphirine‐bearing rocks occurs in kyanite veins within the eclogite. The veins involve orthopyroxene, garnet and plagioclase layers spatially organized around a central kyanite layer that are interpreted to have formed following the eclogite facies metamorphism. The layering has itself been modified, with, in particular, kyanite being replaced by sapphirine–plagioclase, spinel–plagioclase and corundum–plagioclase symplectites, as well as the kyanite being replaced by sillimanite. Petrological modelling in the CFMAS system examining chemical potential gradients between kyanite and surrounding quartz indicates that these vein textures probably formed during further essentially isothermal decompression, ultimately reaching ～7 kbar and 750 °C. These results indicate that the final reaction in these rocks occurred at mid‐crustal levels at upper amphibolite facies conditions. Previous geochronological and thermochronological constraints bracket the time interval of decompression to <5–10 Myr, indicating that ～25 km of exhumation took place during this interval. This corresponds to minimum unroofing rates of ～2–5 mm year^?1 following eclogite facies metamorphism, after which the rocks resided at mid‐crustal levels for 80–100 Myr.     

不平衡条件下单斜辉石形成的一些探讨

辉石作为一种主要造岩矿物广泛出现于许多岩类中,在基性火成岩中它更占有重要的地位。平衡条件下辉石的产出条件及其有关的相平衡关系,前人已有大量实验研究。