喂子坪秦岭杂岩麻粒岩相变沉积岩的变质作用p-T演化及其构造意义

秦岭杂岩位于秦岭造山带北秦岭构造带,是研究秦岭造山带早古生代构造演化的重要岩石构造单元。喂子坪地区发育有典型的秦岭杂岩,其中的混合岩是由变沉积岩经历了强烈的深熔作用形成的。本研究对其进行了岩相学、变质相平衡模拟和LA-ICP-MS锆石U-Pb年代学研究,以深入揭示它们的变质温压演化特征,进而阐明它们指示的构造意义。混合岩的中色体由含石榴子石角闪黑云斜长片麻岩和含石榴子石黑云角闪斜长片麻岩组成。含石榴子石角闪黑云斜长片麻岩只记录了峰期变质矿物组合,为镁铁闪石+石榴子石+斜长石+石英+黑云母+钛铁矿+熔体,而含石榴子石黑云角闪斜长片麻岩记录了3个变质演化阶段,分别是早期进变质阶段（M1）：黑云母+斜长石+石英; 峰期变质阶段（M2）：镁铁闪石+石榴子石+斜长石+石英+黑云母+钛铁矿+熔体; 退变质阶段（M3）：普通角闪石+斜长石+黑云母+石英+熔体。全岩成分视剖面图模拟计算显示含石榴子石角闪黑云斜长片麻岩和含石榴子石黑云角闪斜长片麻岩压力峰期的变质温压条件分别为790~810℃/990~1 040 MPa和840~862℃/1 000~1 190 MPa。含石榴子石黑云角闪斜长片麻岩3组局部矿物组合域成分视剖面图模拟计算得到压力峰期后变质阶段的温压条件为735~814℃/400~810 MPa、721~794℃/430~700 MPa、740~810℃/470~780 MPa。因此,本研究揭示了喂子坪地区秦岭杂岩片麻岩记录了近等温降压的p-T轨迹。LA-ICP-MS锆石U-Pb定年得到含石榴子石角闪黑云斜长片麻岩和2个浅色体样品中的变质锆石²⁰⁶Pb/²³⁸U加权平均年龄分别为383.2±7.0 Ma、400±3.6 Ma和406.7±7.8 Ma。结合已发表的数据,喂子坪地区变沉积岩麻粒岩相峰期变质作用和强烈的混合岩化作用的时代约为410~390 Ma,而约380 Ma的年龄可能代表退变质冷却到固相线的时代。片麻岩近等温降压的变质演化轨迹指示喂子坪地区秦岭杂岩的变沉积岩在下地壳经历了麻粒岩相变质作用和随后的快速抬升,与碰撞造山引起的地壳增厚和随后的地壳伸展有关。     

东喜马拉雅地区高压麻粒岩岩石学研究及构造意义

 将该区内的高喜马拉雅结晶岩划分为南部的角闪岩相岩石和北部的中低压麻粒岩相岩石,后者沿那木拉逆冲断层向南推覆于前者之上。高压麻粒岩相岩石仅以残余产出于后者,主要包括石榴石蓝晶石片麻岩和石榴石透辉石岩。前者的峰期矿物组合为石榴石+蓝晶石+三元长石+石英+金红石;后者的峰期组合为石榴石(铁铝榴石10_±钙铝榴石_>80)+透辉石+石英+方柱石+榍石(Al₂O₃为4%-4.5%).变质温压估计结果表明高压麻粒岩相岩石形成于大约1.7-1.8GPa,890℃,然后经历了近等温降压变质作用至0.5±0.1GPa,850±50℃。它们的原岩可能是大理岩及泥质岩。这表明在区内曾存在一高压麻粒岩带,那木拉冲断层可能是高喜马拉雅结晶岩内的一条重要的构造界线。     

东南极茹尔群岛超高温麻粒岩的研究进展

茹尔群岛(又称赖于尔群岛)位于东南极普里兹构造带的东部边缘,是一个由太古宙和中元古代岩石组成的复合高级变质地体。中元古代岩石是含有富Fe-Al的含石榴子石-矽线石的费拉副片麻岩组合,经历了格林维尔和泛非两期变质作用。太古宙正片麻岩是含有富Mg-Al的含假蓝宝石的超高温泥质麻粒岩组合(梅瑟副片麻岩组合),主要由经历超高温变质作用的含假蓝宝石的泥质麻粒岩、富Mg的石榴子石-矽线石泥质片麻岩、斜方辉石-矽线石石英岩、含石榴子石镁铁质麻粒岩和钙硅酸盐麻粒岩等组成。其中,含假蓝宝石泥质麻粒岩中石榴子石变斑晶和矽线石集合体(蓝晶石假象)周围分别发育峰期后由假蓝宝石+斜方辉石和假蓝宝石+堇青石后成合晶组成的典型减压结构。含石榴子石镁铁质麻粒岩中石榴子石变斑晶周围则发育峰期后由斜方辉石+斜长石后成合晶组成的典型白眼圈减压结构。不同研究者得出了具有不同超高温峰期条件、峰期前及峰期后演化历史、不同形式的顺时针变质P-T轨迹。对超高温变质事件发生的时间和构造背景的认识也存在较大分歧,有认为超高温变质事件发生于格林维尔期(~1000 Ma)并与碰撞造山和弧岩浆作用有关,也有研究认为发生于泛非期(~590 Ma或~530 Ma)并与普里兹造山及冈瓦纳大陆聚合有关。因此,为理清该区超高温麻粒岩的变质演化历史和构造背景,需要对其进一步进行详细深入的矿物组合-变质结构分析、P-T轨迹重建及高精度的锆石-独居石U-Pb年代学研究,并进行区域上对比。      

麻粒岩相变质作用与花岗岩成因-I:变质泥质岩/杂砂岩高温-超高温变质相平衡

麻粒岩相岩石作为洞察下地壳的窗口一直备受重视。二十世纪九十年代以来麻粒岩研究的一个重要进展是利用变质相平衡的定量研究方法模拟岩石中所发生的深熔变质反应、熔体成分变化、及熔体丢失对变质矿物组合的影响等。本文利用KASH、NKASH和KFMASH等简单体系的相平衡关系,做出P-T投影图、组分共生图解和基于固定全岩成分的P-T视剖面图解,并结合有关实验岩石学结果,讨论了高温和超高温条件下变质泥质岩和杂砂岩中的变质熔融反应、矿物组合、全岩成分与P-T条件之间的相互关系。多数变质泥质岩和杂砂岩中饱和流体固相线熔融反应可利用NKASH体系中有水流体参与的熔融反应模拟,在没有外来流体注入时,这些反应可形成<3mol%熔体。在不同体系中白云母脱水熔融反应型式及其P-T条件不同,如在NKASH和KFMASH体系中模拟计算的白云母脱水熔融反应与相应的实验结果相似,分别控制了白云母分解熔融的温度下限和上限;白云母的分解温度会随着其中Fe、Mg和Ti含量的增加而升高,也随着共生斜长石中钙长石组分增加而升高,泥质岩中白云母脱水熔融可以形成~10mol%熔体。在KFMASH体系中黑云母脱水熔融反应表现为4条单变反应,其理论计算的温度比实验模拟的结果低一些。在NCKFMASH体系或实际岩石中黑云母脱水熔融反应为滑动反应,如NCKFMASH体系中黑云母从其开始熔融到最后消失在泥质岩中可跨越~100℃,在杂砂岩中可跨越30~50℃。黑云母的稳定温度随着镁值升高而升高,其稳定上限受钛影响更大,黑云母脱水熔融可以形成超过30mol%~40mol%熔体。KFMASH体系中的相平衡模拟表明以出现斜方辉石+夕线石和假蓝宝石为特征的超高温组合易于出现于富镁泥质岩中,而对正常成分泥质岩在达到1000℃的超高温条件下,主要出现石榴石+夕线石(即夕线榴),该组合在更高温度反应形成假蓝宝石+尖晶石。利用饱和水固相线反应和白云母与黑云母分解反应可以更好地限定不同的变质相。如中压和低压条件下低角闪岩相和高角闪岩相的界限可利用NKASH体系中有水流体和白云母参与的熔融反应和亚固相线条件下的白云母分解反应限定;实验确定的泥质岩中黑云母开始熔融与消失的反应可分别用于限定高角闪岩相与(正常)麻粒岩相的界限,以及(正常)麻粒岩相和超高温麻粒岩相的界限。因此,从矿物组合角度,正常麻粒岩相可限定在黑云母开始熔融到完全消失的温度范围,超高温麻粒岩相可限定在黑云母消失(有石英存在)之后的温度范围。     

阿尔泰晚古生代超高温麻粒岩流体特征及其意义

北疆阿尔泰造山带南缘晚古生代超高温麻粒岩存在高铝斜方辉石+夕线石+石英和尖晶石+石英等超高温特征矿物组合,其退变质作用主要以典型的降压反应矿物堇青石的形成为标志。对其中新发现的石榴子石及石英流体包裹体开展显微测温和激光拉曼探针分析,结果表明:基质中的石英以及被石榴子石包裹的石英中孤立分布的原生流体包裹体成分为近纯CO₂(部分含少量的N₂),均一温度在10.1~29℃之间,其对应的密度在0.631~0.861g/cm³。石榴子石中的原生和假次生CO₂包裹体费米峰差在104.1cm^-1左右,低于石英中CO₂包裹体的费米峰差(~104.7cm^-1),暗示其密度低于石英中的CO₂包裹体。由CO₂流体包裹体密度所得到的等容线从P-T轨迹退变质阶段的下方穿过结合区域地质背景,我们初步认为阿尔泰超高温麻粒岩的形成与幔源岩浆底侵有关。基性岩浆的底侵不但提供了异常高的地温梯度,同时其所释放的大量CO₂降低了水活度,使得变质作用峰期的特征矿物得以保存。低密度的CO₂流体指示了阿尔泰超高温麻粒岩沿顺时针P-T轨迹紧随超高温峰期变质之后快速抬升降压,捕获的同变质流体包裹体因腔体体积增大而密度降低的一种退变质过程。     

藏南定结地区早中新世淡色花岗岩的形成机制及其构造动力学意义

定结日玛那穹窿位于高喜马拉雅带中段,由花岗片麻岩、变泥质岩、变基性岩及大量淡色花岗岩等组成,经历了角闪岩-麻粒岩相变质作用。为厘定淡色花岗岩的形成机制以及与高级变质岩的关系,我们对淡色花岗岩和高级变质岩进行了全岩元素和Sr和Nd同位素组成和SHRIMP锆石U-Pb地质年代学测试。全岩元素和Sr-Nd同位素测试结果揭示淡色花岗岩具有以下特征:(1)高SiO₂ (>72%),高Al₂O₃ (>12%)和高A/CNK比值 (>1.0);(2)高Rb,低Sr,高Rb/Sr比值(>1.0);(3)高∑REE和明显的负Eu异常;(4)高Sr同位素初始比值(0.7621~0.8846)和低ε_Nd(t)值(-13.0~-20.2)。淡色花岗岩的高Rb/Sr比值和Sr-Nd同位素系统特征表明其形成机制为主要为白云母脱水部分熔融作用,源区为由花岗片麻岩和变泥质岩组成的混合源区。SHRIMP锆石U-Pb年代学研究揭示出定结地区淡色花岗岩具有21.0±0.7Ma和15.8±0.1Ma 2期年龄,花岗片麻岩的锆石变质增生边年龄为22.2±1.4Ma,与该区的榴辉岩退变质年龄一致。这些数据共同表明,花岗片麻岩和 变泥质岩在22~21Ma发生高级变质和深熔作用,形成早期淡色花岗岩岩浆,在~16Ma进一步深熔,形成晚期淡色花岗岩岩浆。     

阿尔泰超高温变泥质麻粒岩的锆石U-Pb年龄及其地质意义

最近我们通过岩相学观察和矿物温压计算,首次确定了在阿勒泰喀拉苏附近存在超高温变泥质麻粒岩,其矿物组合为石榴石+斜方辉石+夕线石+堇青石+尖晶石+黑云母+斜长石+石英等。斜方辉石成分具有高铝特点,其Al₂O₃含量高于8.0%,指示了其峰期变质作用达到了超高温(>900℃)的条件。P-T计算结果显示其峰期变质条件为:P=~8.0kb, T=~960℃。初步P-T估算结果表明了一个峰期后近等压冷却的逆时针P-T轨迹。我们对其中锆石进行了LA-ICP-MS U-Pb年龄测定,年龄结果主要分布于260~280Ma之间,具有峰值年龄271±5Ma,个别年龄为380~390Ma,继承锆石主要分布于450~500Ma之间。该年龄结果表明阿尔泰超高温变质事件发生于二叠纪,在时间上与二叠纪塔里木地幔柱活动的时间(~275Ma)高度一致,且也和该区广泛的二叠纪(260~280Ma) 后造山或非造山的基性岩和花岗岩侵入是同时的。因此,阿尔泰二叠纪超高温变泥质麻粒岩的形成,可能与由二叠纪塔里木地幔柱活动引起的岩浆底侵和下地壳伸展加热密切相关,这也与该超高温变泥质麻粒岩的逆时针P-T轨迹所反映的构造背景一致。     

藏南错那洞穹隆高分异淡色花岗岩的矿物学特征

藏南特提斯喜马拉雅东部的错那洞淡色花岗岩产出有白云母、石榴子石、电气石等特征性矿物,显示具有高度分异岩浆岩的特征。从二云母花岗岩到电气石花岗岩到石榴子石花岗岩,碱性长石均为正长石,斜长石从更长石演变为钠长石,白云母Al₂O₃、Na₂O含量逐渐升高,反映花岗岩逐渐向富Al富Na演化的趋势。二云母花岗岩中黑云母X_Fe值、Al^Ⅵ逐渐升高,表明二云母花岗岩之间存在结晶分异演化。电气石X_vac值、Al、Mg和Fe含量之间的变化,反映电气石花岗岩到花岗伟晶岩岩浆结晶环境中Na含量的增加,表明花岗伟晶岩结晶分异演化程度高于电气石花岗岩。石榴子石高X_Fe、X_Mn值的特征,也是高分异花岗岩的标志。上述矿物学研究结果表明,错那洞二云母花岗岩是由岩浆早期结晶矿物与残余的母岩浆组成的糊状物经过长期结晶形成的,而电气石花岗岩和石榴子石花岗岩由从晶粥体中分离出来的衍生熔体形成。     

有效全岩成分的计算方法及其在变质相平衡模拟中的应用

变质相平衡模拟是变质岩领域近几十年最重要的进展之一，它已经成为确定变质作用P-T-t轨迹和探索变质演化过程的有力工具。变质岩的矿物组合不但与其形成的温度（T）和压力（P）条件有关，而且受控于岩石的全岩成分（X）。但是变质岩通常是不均匀的并且往往保留两期以上的矿物组合，因此计算不同成分域或不同变质演化期次的有效全岩成分是模拟P-T视剖面图的核心问题之一。在中-低温变质岩中，石榴石变斑晶的生长会不断地将其核部成分"冻结"而不参与后续变质反应，这导致根据实测全岩成分计算的P-T视剖面图无法有效地模拟石榴石幔部或边部生长阶段的变质演化过程。"瑞利分馏法"和"球体积法"利用电子探针实测的石榴石成分环带可以模拟计算石榴石各个生长阶段所对应的有效全岩成分，本文推荐使用这两个方法来处理石榴石变斑晶的分馏效应问题。相比较而言，石榴石在高温变质岩中通常无法保留生长阶段的成分环带特征，这是因为石榴石成分在高温条件下会发生扩散再平衡，并同时与多数基质矿物达到热力学平衡，这时一般不需要考虑石榴石的分馏效应。但是高温变质岩通常会发生部分熔融并伴随熔体的迁移，进而改变岩石的有效全岩成分。因此，通过P-T视剖面图模拟熔体迁移前后的变质演化过程需要使用"相平衡法"计算迁移的熔体成分以及熔体迁移前后岩石的有效全岩成分。此外，后成合晶与反应边是变质岩中最常见的退变质反应结构，但是后成合晶或反应边中的矿物之间并未达到热力学平衡。这种情况需要结合岩相学观察和矿物成分，利用最小二乘法确定后成合晶或反应边中发生的平衡反应方程式，进而获取变质反应发生时的有效全岩成分并通过计算P-T视剖面图来估算退变质的温压条件。除此之外，岩石体系中三价铁（Fe₂O₃）和H₂O含量的估算一直以来都是相平衡模拟研究中的难点，本文推荐使用P/T-X（Fe³⁺/Fe^tot，MH₂O）视剖面图来确定这两个组分的含量，这是因为P/T-X图可以估算各个变质演化阶段或特定矿物组合的Fe₂O₃或H₂O含量。     

赞皇前寒武纪变质杂岩区变质反应结构与变质作用P-T-t轨迹

赞皇变质杂岩位于华北克拉通中部造山带中南段、太行山东麓低山区。出露于该变质杂岩区中南部的含石榴石的斜长角闪片麻岩、泥质片麻岩,均保存了三期矿物组合:进变质、峰期变质和退变质矿物组合。这两大类变质岩石中,进变质阶段矿物组合(M₁)以石榴石变斑晶核部的包裹体矿物组合为代表,变质高峰期矿物组合(M₂)由石榴石变斑晶"边部"和基质矿物组成,退变质阶段矿物组合(M₃)主要是环绕石榴石边部发育的"白眼圈"状后成合晶矿物组合。泥质片麻岩中的石榴石变斑晶均保存了明显的成分环带,且在边部很窄的范围内X_Mn有所增加、Mg/(Mg+Fe)有所降低,指示存在变质高峰期后的退变质过程。温度与压力计算结果表明,赞皇斜长角闪片麻岩所经历的进变质阶段(M₁)温度约为640~710℃、 压力约为8.2~8.6kbar;高峰期(M₂)变质温度超过810℃,压力大于12.1kbar;退变质阶段(M₃)的温压范围为590~670℃和3.2~5.6kbar。此前的研究已说明泥质片麻岩的进变质阶段(M₁)变质温度为660~690℃,压力为9.0~9.2kbar;高峰期(M₂)变质温度超过780℃,压力大于12.5kbar。变质高峰属于中压相系的顶部至高压相系的底部。斜长角闪片麻岩、泥质片麻岩均记录了典型的顺时针P-T轨迹,并显示近等温减压(ITD)的退变质片段。对泥质片麻岩中多颗锆石的变质增生边的SHRIMP U-Pb定年表明,变质高峰期时代为1821±17Ma。变质作用历史说明赞皇变质岩区卷入了华北克拉通东部陆块和西部陆块之间的俯冲-碰撞、随后的快速隆升过程,为华北克拉通中部造山带早元古代末期(~1850Ma)存在的造山事件提供了新的证据 。     

Ultra high temperature metamorphism of mafic granulites from South Altyn Orogen,West China: A result from the rapid exhumation of deeply subducted continental crust

The South Altyn orogen in West China contains ultra high pressure (UHP) terranes formed by ultra‐deep (>150–300 km) subduction of continental crust. Mafic granulites which together with ultramafic interlayers occur as blocks in massive felsic granulites in the Bashiwake UHP terrane, are mainly composed of garnet, clinopyroxene, plagioclase, amphibole, rutile/ilmenite, and quartz with or without kyanite and sapphirine. The kyanite/sapphirine‐bearing granulites are interpreted to have experienced decompression‐dominated evolution from eclogite facies conditions with peak pressures of 4–7 GPa to high pressure (HP)–ultra high temperature (UHT) granulite facies conditions and further to low pressure (LP)–UHT facies conditions based on petrographic observations, phase equilibria modelling, and thermobarometry. The HP–UHT granulite facies conditions are constrained to be 2.3–1.6 GPa/1,000–1,070°C based on the observed mineral assemblages of garnet+clinopyroxene+rutile+plagioclase+amphibole±quartz and measured mineral compositions including the core–rim increasing anorthite in plagioclase (X_An = 0.52–0.58), core–rim decreasing jadeite in clinopyroxene (X_Jd = 0.20–0.15), and TiO₂ in amphibole (Ti^M2/2 = 0.14–0.18). The LP–UHT granulite facies conditions are identified from the symplectites of sapphirine+plagioclase+spinel, formed by the metastable reaction between garnet and kyanite at <0.6–0.7 GPa/940–1,030°C based on the calculated stability of the symplectite assemblages and sapphirine–spinel thermometer results. The common granulites without kyanite/sapphirine are identified to record a similar decompression evolution, including eclogite, HP–UHT granulite, and LP–UHT granulite facies conditions, and a subsequent isobaric cooling stage. The decompression under HP–UHT granulite facies is estimated to be from 2.3 to 1.3 GPa at ~1,040°C on the basis of textural records, anorthite content in plagioclase (X_An = 0.25–0.32), and grossular content in garnet (X_Grs = 0.22–0.19). The further decompression to LP–UHT facies is defined to be >0.2–0.3 GPa based on the calculated stability for hematite‐bearing ilmenite. The isobaric cooling evolution is inferred mainly from the amphibole (Ti^M2/2 = 0.14–0.08) growth due to the crystallization of residual melts, consistent with a temperature decrease from >1,000°C to ~800°C at ~0.4 GPa. Zircon U–Pb dating for the two types of mafic granulite yields similar protolith and metamorphic ages of c. 900 Ma and c. 500 Ma respectively. However, the metamorphic age is interpreted to represent the HP–UHT granulite stage for the kyanite/sapphirine‐bearing granulites, but the isobaric cooling stage for the common granulites on the basis of phase equilibria modelling results. The two types of mafic granulite should share the same metamorphic evolution, but show contrasting features in petrography, details of metamorphic reactions in each stage, thermobarometric results, and also the meaning of zircon ages as a result of their different bulk‐rock compositions. Moreover, the UHT metamorphism in UHP terranes is revealed to represent the lower pressure overprinting over early UHP assemblages during the rapid exhumation of ultra‐deep subducted continental slabs, in contrast to the cause of traditional UHT metamorphism by voluminous heat addition from the mantle.     

Ultra-high temperature overprinting of high pressure pelitic granulites in the Huai'an complex,North China Craton: Evidence from thermodynamic modeling and isotope geochronology

Paleoproterozoic granulite facies rocks are widely distributed in the North China Craton (NCC). The Huai'an terrane, located within the northern segment of the Trans-North China Orogen (TNCO), a major Paleoproterozoic collisional belt in the central NCC expose mafic and pelitic granulites as well as TTG (tonalite-trondhjemite-granodiorite) gneisses. Here we investigate the pelitic granulites from this complex and identify four distinct mineral assemblages corresponding to different metamorphic stages. The prograde metamorphism (M1) is recorded by relict biotite and the compositional profile of X_ca (grt) isopleths. The P_max (M2) is distinguished by the X_ca (grt) isopleths, which corresponds to the kyanite stable area with an inclusion mineral assemblage of Grt-c–(Ky)-Qz-Rt-Kfs-liq suggesting that the pressures were higher than 12 kbar with a temperature below 900 °C. However, kyanite is absent in thin sections suggesting its consumption during later stages. The T_max metamorphism (M3) is characterized by the assemblage: Grt-m-Qz-Pl-Rt-Kfs-Sil-liq in the garnet mantle and also reflected in the compositional profile. Two-feldspar geothermometry yields a P-T range of 940 °C–950 °C and 9.5–10.5 kbar, indicating ultra-high temperature (UHT) metamorphic overprinting. The subsequent retrograde metamorphic stage (M4) is characterized by Grt-r-Bt-Sil-Kfs-Pl-Qz ± Rt ± Ilm with symplectites of Bt-Sil-Qz in the garnet rim suggesting garnet breakdown with P-T conditions estimated as 770 °C–840 °C and 6.5–8 kbar. The pelitic granulites show a clockwise path, with P-T estimates higher than those in estimated in previous studies using conventional techniques.LA-ICP-MS U–Pb analysis of metamorphic zircon grains yield two groups of ages at 1972.9 ± 8.1 Ma and 1873.3 ± 9.9 Ma. We suggest that the protoliths of the Manjinggou HP-UHT granulites were deep subducted where they experienced HP metamorphism associated with the collision of the Ordos and Yinshan blocks at ca. 1.97 Ga. Subsequently, the UHT metamorphic overprint occurred during the assembly of the unified Western and Eastern Blocks of the NCC along the TNCO at ca. 1.87 Ga.     

Paleoproterozoic emplacement and Cambrian ultrahigh-temperature metamorphism of a layered magmatic intrusion from the Central Madurai Block,southern India: From Columbia to Gondwana

The Madurai Block in the Southern Granulite Terrane(SGT)of Peninsular India is one of the largest crustal blocks within the Neoproterozoic Gondwana assembly.This block is composed of three sub-blocks:the Neoarchean Northern Madurai block,Paleoproterozoic Central Madurai block and the dominantly Neoproterozoic Southern Madurai Block.The margins of these blocks are well-known for the occurrence of ultrahigh-temperature(UHT)granulite facies rocks mostly represented by Mg-Al metasediments.Here we report a dismembered layered mafic–ultramafic intrusion occurring in association with Mg-Al granulites from the classic locality of Ganguvarpatti in the Central Madurai Block.The major rock types of the layered intrusion include spinel orthopyroxenite,garnet-bearing gabbro,gabbro and gabbroic anorthosite showing rhythmic stratification and cumulate texture.The orthopyroxene-cordierite granulite from the associated Mg-Al layer is composed of spinel,cordierite and orthopyroxene.The pyroxene in both rock units is high-Al orthopyroxene formed under UHT metamorphic conditions.Conventional thermobarometry yields near-peak metamorphic conditions of 9.5–10 kbar pressure and a minimum temperature of 980℃.We computed P–T pseudosections and contoured for the compositional as well as modal isopleths of the major mineral phases,which yield temperature above 1000℃.FMAS petrogenetic grid,Al-in-orthopyroxene isopleth,conventional thermobarometry and calculated pseudosection reveal a clockwise pressure–temperature(P–T)path and near isothermal decompression.The U–Pb data on zircon grains from the layered magmatic suite indicate emplacement of the protolith at ca.2.0 Ga and the metamorphic overgrowths yield weighted ²⁰⁶Pb/²³⁸U mean ages ca.520 Ma.Monazite from the garnet-bearing gabbro and Opx-Crd granulite yielded ²⁰⁶Pb/²³⁸U weighted mean ages of ca.532 Ma and 523 Ma marking the timing of metamorphism.We correlate the layered intrusion to a Paleoproterozoic suprasubduction zone setting,defining the Ganguvarpatti area as part of a collisional suture assembling the Northern and Central Madurai Blocks.The Paleoproterozoic magmatism and late Neoproterozoic-Cambrian UHT metamorphism can be linked to the tectonics of the Columbia and Gondwana supercontinents.     

中国显生宙造山带麻粒岩相高级变质岩石的地质特征、变质时代、P-T轨迹及其形成的大地构造背景

本文重点介绍我国显生宙造山带中麻粒岩的地质特征、岩石类型、P-T轨迹、变质时代及其形成的大地构造背景。我国显生宙造山带主要包括阿尔泰造山带、南天山-西南天山造山带、西昆仑造山带、东昆仑造山带、阿尔金-柴北缘造山带、北秦岭造山带、南秦岭勉略造山带、东秦岭-桐柏-大别造山带、班公湖-怒江造山带和喜马拉雅中东段造山带。这些造山带中麻粒岩的围岩有许多为蛇绿岩套或蛇绿混杂岩带,部分为副片麻岩和花岗质片麻岩,并一起经历了麻粒岩相变质改造,造山带中大多出现一种高压麻粒岩,有的与榴辉岩并存,但少数造山带中(例如阿尔泰造山带)多种压力类型麻粒岩并存,既有低-高压泥质麻粒岩、中低压基性麻粒岩、高压基性和长英质麻粒岩,又有高温-超高温泥质麻粒岩。变质时代除个别为新元古代晚期外,变质时间多为加里东、海西、印支、燕山、喜山期。麻粒岩的P-T轨迹除西天山木札尔特河低压麻粒岩具逆时针轨迹,反映大陆弧构造环境外,其它都是具有等温降压(ITC)特点的顺时针轨迹,形成的大地构造环境大部分为洋陆俯冲碰撞环境,少部分为陆-陆碰撞环境。目前显生宙造山带中麻粒岩的研究大多数尚在起步阶段,少数研究较详细,不少造山带中麻粒岩的类型和变质时代以及形成的构造背景还不清楚,有待深入研究,新的麻粒岩产地有待发现。     

Phase equilibria modelling and zircon age dating of pelitic granulites in Zhaojiayao,from the Jining Group of the Khondalite Belt,North China Craton

The Jining Group occurs as the eastern segment of the Khondalite Belt, North China Craton and is dominated by a series of granulite facies rocks involving ‘normal’ pelitic granulites recording peak temperatures of ~850 °C and ultrahigh‐temperature (UHT) pelitic granulites recording peak temperatures of 950–1100 °C. The P–T paths and ages of these two types of granulites are controversial. Three pelitic granulite samples in the Jining Group comprising two sillimanite–garnet gneiss samples (J1208 and J1210) and one spinel–garnet gneiss sample (J1303) were collected from Zhaojiayao, where ‘normal’ pelitic granulites occur, for determination of their metamorphic evolution and ages. Samples J1208 and J1210 are interpreted to record cooling paths from the T_max stages with P–T conditions respectively of ~870–890 °C/7–8 kbar and >840 °C/>7.5 kbar constrained from the stability fields of the observed mineral assemblages and the isopleths of plagioclase, garnet and biotite compositions in pseudosections. Sample J1303 is interpreted to record pre‐T_max decompression from the kyanite‐stability fields to the T_max stage of 950–1020 °C/8–9 kbar and a post‐T_max cooling path revealed mainly from the stability field of the observed mineral assemblage, the plagioclase zoning and the biotite composition isopleth in pseudosections. The post‐T_max cooling stage can be divided into suprasolidus and subsolidus stages. The suprasolidus cooling may not result in an equilibrium state at the solidus in a rock. Therefore, different minerals may record different P–T conditions along the cooling path; the inferred maximum temperature is commonly higher than the solidus as well as different solidi being recorded for different samples from the same outcrop but experiencing different degrees of melt loss. Plagioclase compositions, especially its zoning in plagioclase‐rich granulites, are predicted to be useful for recording the higher temperature conditions of a granulite's thermal history. The three samples studied seem to record the temperature range covering those of the ‘normal’ and UHT pelitic granulites in the Jining Group, suggesting that UHT conditions may be reached in ‘normal’ granulites without diagnostic UHT indicators. LA‐ICP‐MS zircon U–Pb data provide a continuous trend of concordant ²⁰⁷Pb/²⁰⁶Pb ages from 1.89 to 1.79 Ga for sample J1210, and from 1.94 to 1.80 Ga for sample J1303. These continuous and long age spectrums are interpreted to represent a slow cooling and exhumation process corresponding to the post‐T_max cooling P–T paths recorded by the pelitic granulites, which may have followed the exhumation of deeply buried rocks in a thickened crust region resulted from a collision event at c. 1.95 Ga as suggested by the pre‐T_max decompression P–T path.     

Metamorphic P‒T paths and Zircon U–Pb ages of Archean ultra-high temperature paragneisses from the Qian’an gneiss dome,East Hebei terrane,North China Craton

The East Hebei terrane of North China Craton is characterized by the dome-and-keel structure, a common feature in most Archean cratons, where supracrustal rocks of granulite facies commonly occur as enclaves or rafts in tonalite–trondhjemite–granodiorite (TTG) gneisses. The metamorphic P–T paths of the granulites are significant for addressing the Archean tectonic regimes. Two types of granulite facies paragneiss with pelitic and greywacke compositions from the western margin of Qian'an gneiss dome are documented for their petrography, mineral chemistry, phase equilibria modelling using thermocalc, and zircon dating. Anticlockwise P–T paths involving the pre-peak pressure increase to the ultra-high temperature peak conditions and post-peak cooling and decompression processes were recognized. The pre-peak pressure increase process was constrained for a pelitic granulite mainly based on the spinel and cordierite inclusions in garnet and rutile corona around ilmenite, where the transition from spinel to garnet is modelled at 6–7 kbar at a fixed T = 1,000°C. For greywacke granulite, the pre-peak pressure increase evolution can be ascertained from the textural relation that orthopyroxene is surrounded by garnet, and the outwards increasing grossular (from 0.03 to 0.05) in the core of the atoll-like garnet (Grt-A), to occur from ~7 kbar at ~1,000°C. The peak P–T conditions for pelitic granulite are roughly limited to 7–11 kbar/890–1,050°C on the basis of the stability of the inferred peak assemblage involving garnet, perthite, sillimanite, rutile/ilmenite, and quartz. The peak P–T condition for greywacke granulite can be well constrained as 9–10 kbar/>1,000°C on the basis of the maximum grossular content (X_Grs = 0.045–0.050) in the core of subhedral garnet (Grt-B) and the mantle of Grt-A together with an average re-integrated anorthite content (X_An = 0.07) in K-feldspar. The peak temperature condition is consistent with the ternary feldspar thermometer results mostly of 950–1,020°C for antiperthite and perthite in greywacke granulite, and in accordance with the development of oriented needle-like exsolution of Ti±Fe oxides in garnet from pelitic granulite. The post-peak cooling and decompression process was consistent with the decreasing X_Grs in the mantle of Grt-A and core of Grt-B in greywacke sample, and the final-stage cooling conditions can be well constrained from the stability of final assemblages marked by the later growth of biotite, as 8–9 kbar/820–880°C for pelitic granulite and 6–9 kbar/840–890°C for greywacke granulite. Zircon dating yields provenance ages from 3.34 to 2.57 Ga and metamorphic ages of c. 2.50 Ga for the two types of granulite. The metamorphic ages overlap the final pulse of the Neoarchean magmatic activity of TTGs that ranges from c. 2.56 to c. 2.48 Ga with a peak at c. 2.52 Ga. Combining the development of dome-and-keel structures, the penecontemporaneity between the metamorphism of supracrustal rocks and TTG magmatic activity, and also the unique anticlockwise P–T paths, we prefer a vertical sagduction regime to interpret the tectonic evolution of the East Hebei terrane, which may be also significant for other Archean cratons.     

华北克拉通孔兹岩带中段大青山-乌拉山变质杂岩立甲子基性麻粒岩年代学及地球化学研究

大青山-乌拉山变质杂岩立甲子基性麻粒岩主要由角闪二辉麻粒岩、含榴角闪二辉麻粒岩和黑云角闪二辉麻粒岩所组成,并以变形岩墙和不规则透镜体形式赋存于富铝片麻岩和花岗质片麻岩之中.立甲子基性麻粒岩中变质锆石含有单斜辉石(Cpx)+角闪石(Amp)+斜长石(Pl)+磷灰石(Ap)的包体矿物,与寄主岩石——基性麻粒岩矿物组合及其化学成分十分一致,相应的207 pb/206 Pb表面年龄变化于1933±39Ma ～ 1834±40Ma,加权平均年龄为1892±7Ma(MSWD =0.50,n=46),应代表立甲子基性麻粒岩原岩经历中低压麻粒岩相的变质时代.在变质过程中,以大离子亲石元素(K、Na、Sr、Rb)为代表的活动元素发生了显著的改变;而高场强元素(Nb、Zr、Ti)和稀土元素基本无变化,保持稳定.立甲子基性麻粒岩原岩属于拉斑玄武质岩石系列,其SiO2集中变化于45.58％ ～51.40％,Mg#值集中介于41 ～54之间;在球粒陨石标准化稀土配分图中,立甲子基性麻粒岩具有平坦型的稀土配分曲线特征((La/Yb)cN=1.30～1.51),Eu异常不明显(Eu/Eu*=0.93～1.04).与显生宙岛孤拉斑玄武岩类似,立甲子基性麻粒岩所有样品皆具有Nb、Zr、Ti负异常特征.综合分析认为,立甲子基性麻粒岩原岩形成于2450～1930Ma,并于～1900Ma经历中低压麻粒岩相变质作用的改造,其主量元素和微量元素组成具有岛弧拉斑玄武质岩石的地球化学特征,其原岩可能是板块汇聚动力学背景下,岛弧构造环境中形成的辉长岩或辉绿岩.     

Rare-earth element geochemistry of Madras granulites

Archaean granulites from the type charnockite locality of Pallavaram, Madras City, Tamil Nadu, southern India consist of a bimodal suite of basic and silicic orthogneisses, associated with metasedimentary gneisses (khondalites). Charnockite is the dominant rock type. Basic granulites display a tholeiitic trend of strong iron enrichment accompanied by an increase in the concentration of the rare earth elements (REE), and the development of appreciable negative europium anomalies. These trends are considered to reflect low pressure fractional crystallisation of pyroxene-plagioclase assemblages under conditions of lowf _{O 2}. Ultramafic granulites may represent the cumulus material of such a process. The silicic granulites (charnockites) are generally K₂O rich and in marked contrast to the low K₂O (tonalitic) silicic gneisses which dominate most granulite facies terrains. Their REE abundances, however, embrace the complete range of patterns observed in both K-rich and K-poor Archaean gneisses. The presence of a large number of pre-granulite facies potassic pegmatites in the area suggests metasomatism of an originally less potassic suite of rocks. Trace element considerations lead to a model whereby metasomatism and partial fusion of silicic gneisses in the terrain preceded the granulite facies metamorphic event. This sequence of events is best related to fluctuations in the composition of metamorphic fluids in the lower crust.     

Melt loss and the preservation of granulite facies mineral assemblages

The loss of a metamorphic fluid via the partitioning of H₂O into silicate melt at higher metamorphic grade implies that, in the absence of open system behaviour of melt, the amount of H₂O contained within rocks remains constant at temperatures above the solidus. Thus, granulite facies rocks, composed of predominantly anhydrous minerals and a hydrous silicate melt should undergo considerable retrogression to hydrous upper amphibolite facies assemblages on cooling as the melt crystallizes and releases its H₂O. The common occurrence of weakly retrogressed granulite facies assemblages is consistent with substantial melt loss from the majority of granulite facies rocks. Phase diagram modelling of the effects of melt loss in hypothetical aluminous and subaluminous metapelitic compositions shows that the amount of melt that has to be removed from a rock to preserve a granulite facies assemblage varies markedly with rock composition, the number of partial melt loss events and the P–T conditions at which melt loss occurs. In an aluminous metapelite, the removal of nearly all of the melt at temperatures above the breakdown of biotite is required for the preservation of the peak mineral assemblage. In contrast, the proportion of melt loss required to preserve peak assemblages in a subaluminous metapelite is close to half that required for the aluminous metapelite. Thus, if a given proportion of melt is removed from a sequence of metapelitic granulites of varying composition, the degree of preservation of the peak metamorphic assemblage may vary widely.     

Two-stage decompression in garnet-bearing mafic granulites from Sostrene Island, Prydz Bay, East Antarctica

Mafic garnet-bearing granulites from Sostrene Island, 150 km southwest of Davis Station on the coast of Prydz Bay, East Antarctica, exhibit two-stage symplectic coronas on garnet, formed after peak metamorphic conditions (M1). An outer corona of Opx (Mg₆₆) + Pl (An_94–97) + minor Hbl mantles a finer-grained inner corona of Opx (Mg₆₇) + Pl (An_95–96) + Spl (Mg₃₆). Both symplectites contain minor ilmenite–magnetite intergrowths. The finer-grained symplectite also occurs along a fracture cleavage in the garnet. The outer corona originated during a second metamorphic event (M2) via the reaction Grt + Cpx (Hbl) + SiO₂= Opx + Pl (1), whereas the inner corona formed later in response to decompression and minor deformation, resulting in the fracture cleavage in the garnet, according to the reaction Grt = Opx + Pl + Spl (2). The grossular content of the garent (X_Grs= 0.168) is almost exactly that which is required for the stoichiometric breakdown by reaction (2) (calculated X_Grs= 0.167). The mafic rocks are silica undersaturated, and the SiO₂ for reaction (1) was most probably derived externally from the surrounding felsic gneisses. Preferred P–T estimates for M1 based on garnet core (Prp₄₀Alm₄₂Grs₁₇Sps₁)–matrix Opx–Cpx–Hbl pairs are c. 10 kbar at 980°C. The fine-grained symplectite formed post-peak M2 at c. 7 kbar and 850°C. The enclosing felsic gneisses yield pressure estimates of between 5 and 7 kbar, which compare with conditions of c. 6 kbar and 775°C in the nearby Bolingen Islands. These lower P–T estimates are considered to be representative of the widespread 1100-Ma metamorphic event recognized in outcrops along the Prydz Bay coast. The high-P, high-T estimates derived from the garnet relics provide evidence for an earlier, possibly Archaean, high-grade metamorphic event.