阿尔泰造山带晚古生代高温变质作用与塔里木地幔柱活动的成因联系:来自泥质和镁铁质麻粒岩的证据

阿尔泰造山带是中亚造山带(CAOB)的重要组成部分,在其南缘出露有高温泥质和镁铁质麻粒岩,确定其P-T轨迹对于理解阿尔泰造山带南缘在晚古生代的构造演化历史具有重要意义。通过对该区乌恰沟泥质和镁铁质麻粒岩样品精细的岩相学观察,显示其变质矿物组合分别为石榴石+堇青石+黑云母+斜长石+石英+磁铁矿+钛铁矿±斜方辉石±尖晶石±钾长石,斜方辉石+单斜辉石+角闪石+黑云母+斜长石+钾长石+石英+钛铁矿+磁铁矿。使用传统温压计和平均温压计算方法对其变质峰期及峰期后的P-T条件进行了计算,并利用Thermocalc软件对其中两个泥质麻粒岩进行了P-T视剖面图模拟,确定了其峰期变质条件为770~865℃和3.0~5.1kbar,并得到了两条峰期后近等压冷却(IBC)的P-T演化轨迹。这样近等压冷却的P-T轨迹表明高温变质作用可能发生于一个总体伸展的大地构造背景之下。已有年代学数据支持该区高温变质事件发生于二叠纪(270~280Ma),与塔里木地幔柱活动的时间(~275Ma)高度一致。这说明阿尔泰二叠纪高温变质事件可能与塔里木地幔柱有着密切的成因联系。因此,我们认为二叠纪地幔柱活动引起的幔源岩浆底侵和加热可能提供了阿尔泰南缘高温-超高温变质作用所需的热源。     

冀西北怀安地区中性辉石麻粒岩的锆石U-Pb、Lu-Hf及微量元素组成对区域退变质时代的制约

冀西北怀安地区位于华北克拉通北缘中段。其区域麻粒岩相变质峰期时间及所代表的碰撞造山时限一直存在不同认识。本文对出露于区内的中性辉石麻粒岩体(变石英闪长岩)进行锆石U-Pb、Lu-Hf及微量元素组成的分析研究,探讨其锆石同位素年龄的地质意义。该类岩石的矿物组合表明它们在中压麻粒岩峰期变质之后经历了角闪岩相退变质作用。锆石阴极发光显示,辉石麻粒岩中存在两种类型锆石:1)具双层结构锆石:核部锆石晶形保存相对完好并具生长环带,幔部为无内部结构的变质增生边;2)内部结构均一,无生长环带,为变质增生的新生锆石。其中具生长环带的核部锆石²⁰⁷Pb/²⁰⁶Pb年龄分布在2542~1902Ma(1σ),并与之相应的Th/U比值(0.10~1.92)、ΣHREE(59.1×10^-6~452×10^-6)和ε_Hf(t)值呈正相关关系,表明核部锆石曾发生过不同程度的变质重结晶作用。其中谐和度高且年龄大于2400Ma的锆石(Th/U=0.42~1.92)获得了2471±18Ma(2σ, MSWD=6.7)加权平均年龄,该年龄可近似代表原岩的形成时代;相应的单阶段Hf模式年龄(t_DM=2550~2621Ma,峰值2586Ma)和两阶段模式年龄(t_DM^C=2596~2716Ma,峰值2665Ma)以及与较高的ε_Hf(t)值(4.1~6.7),反映其原岩的源区具新生下地壳特征,暗示本区新太古代末发生过地壳增生事件。变质增生锆石具更低的Th/U(<0.10)和¹⁷⁶Lu/¹⁷⁷Hf比值(<0.0001)以及明显偏低的重稀土含量。结合岩相学分析表明,这些变质锆石应是麻粒岩相向角闪岩相退变质过程中的产物,非峰期麻粒岩相产物。锆石Ti温度计算结果(683~714 ℃)也进一步支持这种解释。它们获得的1831±7Ma(2σ, MSWD=2.5)加权平均年龄应代表中压麻粒岩相变质晚期至角闪岩相退变质时代。为此,我们认为本区麻粒岩广泛记录的1850~1800Ma的变质年龄应代表古元古代末地壳抬升退变质事件。     

阿尔泰晚古生代超高温麻粒岩流体特征及其意义

北疆阿尔泰造山带南缘晚古生代超高温麻粒岩存在高铝斜方辉石+夕线石+石英和尖晶石+石英等超高温特征矿物组合,其退变质作用主要以典型的降压反应矿物堇青石的形成为标志。对其中新发现的石榴子石及石英流体包裹体开展显微测温和激光拉曼探针分析,结果表明:基质中的石英以及被石榴子石包裹的石英中孤立分布的原生流体包裹体成分为近纯CO₂(部分含少量的N₂),均一温度在10.1~29℃之间,其对应的密度在0.631~0.861g/cm³。石榴子石中的原生和假次生CO₂包裹体费米峰差在104.1cm^-1左右,低于石英中CO₂包裹体的费米峰差(~104.7cm^-1),暗示其密度低于石英中的CO₂包裹体。由CO₂流体包裹体密度所得到的等容线从P-T轨迹退变质阶段的下方穿过结合区域地质背景,我们初步认为阿尔泰超高温麻粒岩的形成与幔源岩浆底侵有关。基性岩浆的底侵不但提供了异常高的地温梯度,同时其所释放的大量CO₂降低了水活度,使得变质作用峰期的特征矿物得以保存。低密度的CO₂流体指示了阿尔泰超高温麻粒岩沿顺时针P-T轨迹紧随超高温峰期变质之后快速抬升降压,捕获的同变质流体包裹体因腔体体积增大而密度降低的一种退变质过程。     

山东半岛早前寒武纪高级变质基底中超镁铁质岩的成因

山东半岛早前寒武纪高级变质基底广泛出露超镁铁质岩,它们呈大小不等的透镜体产于TTG片麻岩中,且与基性高压麻粒岩密切"伴生"。岩相学和矿物相转变分析、温压条件估算以及锆石原位U-Pb定年结果表明,山东半岛超镁铁质岩记录了十分复杂的演化历史,其中早期残留的原岩标志性的矿物组合 (M₁) 以尖晶石 (富Mg)+橄榄石 (富Mg)+斜方辉石 (富Mg) 为特征,相应的岩浆结晶温压条件T=980~1050℃、P=1.55~1.65GPa;峰期高压麻粒岩相变质阶段 (M₂) 的典型的矿物组合以尖晶石 (富Fe)+橄榄石 (富Fe)+斜方辉石 (富Fe) 为特征,相应的温压条件T=840~880℃、P=1.40~1.55GPa,此阶段形成的变质锆石记录的高压麻粒岩相变质时代为1858~1877Ma;峰后中低压角闪-麻粒岩岩相退变质阶段 (M₃) 的矿物组合以斜方辉石+单斜辉石+橄榄石+角闪石 (富 (Na+K))+尖晶石+磁铁矿(富Cr) 为特征,相应的温压条件T=760~820℃、P=0.55~0.65GPa,此阶段形成的变质锆石记录的退变质时代为1820~1840Ma;晚期低角闪岩相-绿片岩相变质阶段 (M₄),以形成角闪石 (贫 (Na+K))+磁铁矿 (贫Cr)+蛇纹石±绿泥石±金云母的矿物组合为特征,相应的温压条件T=500~600℃、P=0.32~0.40GPa。超镁铁质岩的变质演化具有典型碰撞造山带顺时针P-T-t轨迹,指示山东半岛超镁铁岩是古老陆块之间碰撞造山的产物。该项成果对于进一步深入探讨华北克拉通东南缘早前寒武纪古老陆块的碰撞-拼贴及其演化的动力学过程具有重要科学意义。     

祁连地块北缘前寒武基底早古生代再活化:变基性岩相平衡模拟和锆石年代学证据

北祁连造山带是典型的早古生代增生型造山带，具有典型增生型造山带的"沟-弧-盆"体系。祁连地块位于北祁连造山带南部，由深变质的前寒武纪基底和新元古代到中生代的沉积盖层组成。在连祁地块北缘门源宝库河附近延伸数千米的变基性岩（主体为斜长角闪岩和角闪岩）中识别出了基性麻粒岩，峰期矿物组合为石榴子石+斜长石+钾长石+普通辉石+角闪石+钛铁矿+石英，相平衡模拟计算结果显示峰期温压条件为P=10.6kbar、T=800℃，峰期之后经历了近等温降压的P-T轨迹。锆石LA-ICP-MS U-Pb年代学结果显示变基性岩的原岩结晶年龄分别为1110±18Ma和1140±30Ma，变质年龄分别为478.2±3.9Ma和469±4.6Ma，结合近等温降压的P-T轨迹，469~478Ma的变质年龄应近似代表了麻粒岩相变质作用时代。结合区域资料，我们认为早古生代北祁连洋存在南北双向俯冲极性，祁连洋南向俯冲使得祁连地块前寒武纪基底在早古生代再活化。变基性岩的原岩年龄与祁连地块南部欧龙布鲁克地块（全吉地块）中发现的变基性岩和花岗质片麻岩原岩年龄及副片麻岩的变质年龄一致，均为~1100Ma，表明祁连地块与欧龙布鲁克地块一起卷入了格林威尔造山事件。     

东南极茹尔群岛超高温麻粒岩的研究进展

茹尔群岛(又称赖于尔群岛)位于东南极普里兹构造带的东部边缘,是一个由太古宙和中元古代岩石组成的复合高级变质地体。中元古代岩石是含有富Fe-Al的含石榴子石-矽线石的费拉副片麻岩组合,经历了格林维尔和泛非两期变质作用。太古宙正片麻岩是含有富Mg-Al的含假蓝宝石的超高温泥质麻粒岩组合(梅瑟副片麻岩组合),主要由经历超高温变质作用的含假蓝宝石的泥质麻粒岩、富Mg的石榴子石-矽线石泥质片麻岩、斜方辉石-矽线石石英岩、含石榴子石镁铁质麻粒岩和钙硅酸盐麻粒岩等组成。其中,含假蓝宝石泥质麻粒岩中石榴子石变斑晶和矽线石集合体(蓝晶石假象)周围分别发育峰期后由假蓝宝石+斜方辉石和假蓝宝石+堇青石后成合晶组成的典型减压结构。含石榴子石镁铁质麻粒岩中石榴子石变斑晶周围则发育峰期后由斜方辉石+斜长石后成合晶组成的典型白眼圈减压结构。不同研究者得出了具有不同超高温峰期条件、峰期前及峰期后演化历史、不同形式的顺时针变质P-T轨迹。对超高温变质事件发生的时间和构造背景的认识也存在较大分歧,有认为超高温变质事件发生于格林维尔期(~1000 Ma)并与碰撞造山和弧岩浆作用有关,也有研究认为发生于泛非期(~590 Ma或~530 Ma)并与普里兹造山及冈瓦纳大陆聚合有关。因此,为理清该区超高温麻粒岩的变质演化历史和构造背景,需要对其进一步进行详细深入的矿物组合-变质结构分析、P-T轨迹重建及高精度的锆石-独居石U-Pb年代学研究,并进行区域上对比。      

藏南定结地区早中新世淡色花岗岩的形成机制及其构造动力学意义

定结日玛那穹窿位于高喜马拉雅带中段,由花岗片麻岩、变泥质岩、变基性岩及大量淡色花岗岩等组成,经历了角闪岩-麻粒岩相变质作用。为厘定淡色花岗岩的形成机制以及与高级变质岩的关系,我们对淡色花岗岩和高级变质岩进行了全岩元素和Sr和Nd同位素组成和SHRIMP锆石U-Pb地质年代学测试。全岩元素和Sr-Nd同位素测试结果揭示淡色花岗岩具有以下特征:(1)高SiO₂ (>72%),高Al₂O₃ (>12%)和高A/CNK比值 (>1.0);(2)高Rb,低Sr,高Rb/Sr比值(>1.0);(3)高∑REE和明显的负Eu异常;(4)高Sr同位素初始比值(0.7621~0.8846)和低ε_Nd(t)值(-13.0~-20.2)。淡色花岗岩的高Rb/Sr比值和Sr-Nd同位素系统特征表明其形成机制为主要为白云母脱水部分熔融作用,源区为由花岗片麻岩和变泥质岩组成的混合源区。SHRIMP锆石U-Pb年代学研究揭示出定结地区淡色花岗岩具有21.0±0.7Ma和15.8±0.1Ma 2期年龄,花岗片麻岩的锆石变质增生边年龄为22.2±1.4Ma,与该区的榴辉岩退变质年龄一致。这些数据共同表明,花岗片麻岩和 变泥质岩在22~21Ma发生高级变质和深熔作用,形成早期淡色花岗岩岩浆,在~16Ma进一步深熔,形成晚期淡色花岗岩岩浆。     

东昆仑西段夏日哈木-苏海图早古生代榴辉岩的发现及意义

1:25万区域地质调查在东昆仑西段昆中断裂以北的北昆仑变质基底中发现了呈构造透镜分布的榴辉岩及其退变质的榴闪岩,沿小灶火-苏海图-夏日哈木-拉宁灶火断续延伸长达20km.榴辉岩经历了强烈的退变质作用,大部分已退变为榴闪岩,由峰期变质矿物组合石榴石+绿辉石+金红石+钛铁矿和后期退变矿物组合普通角闪石(绿色)+斜长石组成,石榴石边缘发育似针状普通角闪石及微粒状斜长石组成的后合成晶结构,形成宽0.15~1cm的"白眼圈"结构.石榴石成分为Alm_52-53And_4.2Spess_0.7-1.2Gros_21.7-22Pyrope_19-20,绿辉石中硬玉分子量30.14mol%~37.7mol%.估算榴辉岩相变质温压条件P≈20kbar、T≈660~700℃,榴闪岩相退变温压条件P≈7kbar、T≈550℃,岩石经历了明显的降温降压过程.榴辉岩中锆石阴极发光图像显示大部分具有扇形分带或"杉树叶"结构,17颗锆石Th/U极低,在0.007~0.09之间,其(LA-ICP-MS)U-Pb年龄411.1±1.9Ma代表了榴辉岩相峰期变质年龄,结合区域构造岩浆事件,确定本次高压变质的峰期时代为晚志留-早泥盆世,其形成可能与大规模的陆-陆碰撞事件有关,这一发现为研究东昆仑造山带的构造演化具有重要意义.     

塔里木盆地东北缘敦煌群的形成和演化:锆石U-Pb年代学和Lu-Hf同位素证据

采用LA-MC-ICP-MS手段对敦煌地块中敦煌群的白云母石英片岩、石榴斜长角闪岩、石榴黑云斜长片麻岩和长英质伟晶岩脉中的锆石进行了U-Pb 和Lu-Hf同位素分析,获得白云母石英片岩碎屑岩浆锆石的²⁰⁷Pb/²⁰⁶Pb表面年龄为1545~756Ma,主要集中在1200~1000Ma,表明地层的最大沉积时代为756Ma,蚀源区存在中、新元古代的岩浆事件。白云母石英片岩锆石的ε_Hf(t)分为两组,一组为正值,ε_Hf(t)=1.2~10.1,单阶段模式年龄为t_DM=1.09~1.66Ga;一组为负值,ε_Hf(t)=-1~-16,两阶段模式年龄为t_DM2=1.91~2.42Ga。表明蚀源区存在古元古代、中元古代的再造地壳。石榴斜长角闪岩的两粒捕获锆石的年龄为2272Ma 和1208Ma,ε_Hf(t)为-3和14,t_DM2和t_DM为2.82Ga和1.1Ga,暗示捕获区存在太古代再造地壳和中元古代晚期新生地壳。石榴斜长角闪岩碎屑锆石的Th/U比值为0.02~0.42,²⁰⁶Pb/²³⁸U年龄为441±5Ma,代表了岩石遭受变质作用的时代。石榴黑云斜长片麻岩中的碎屑锆石与长英质伟晶岩脉中的继承锆石特征相同,锆石年龄集中在3个峰值区间:2.2~2.1Ga,1.8~1.6Ga,1.2~0.8Ga,相应的的ε_Hf(t)分别为-9~4,-5.4~15,-27~20,相应锆石的模式年龄分别为3.1~2.4Ga,2.6~1.4Ga,3.1~1.7Ga,均大于其形成年龄,表明蚀源区锆石来自于再循环的新太古代、古元古代和中元古代地壳,样品代表的地层的最大沉积时代为新元古代早期。岩石中检测出早古生代的变质锆石, ²⁰⁶Pb/²³⁸U年龄为464~422Ma,可能代表了沉积岩的变质时代。敦煌群锆石U-Pb和Lu-Hf同位素表明蚀源区岩石类型和时代的多样性,也表明部分敦煌群不是前寒武纪的变质基底,而是塔里木盆地变质基底之上新元古代的沉积盖层,后卷入了我国西北部早古生代的造山事件。     

塔里木柯坪地区二叠系沉积岩碎屑锆石U-Pb定年和Hf同位素特征及其对塔里木块体地质演化的限定

塔里木早二叠世大火成岩省是我国继峨眉山大火成岩省得到国际公认后的又一个重要的大火成岩省,对其中广泛出露的多层玄武质熔岩的夹层沉积岩中的锆石年代学和Hf同位素特征研究可以对塔里木早二叠世大火成岩省的岩浆演化以及之前的地质史方面的认识提供重要的信息。本文选取塔里木西北缘柯坪地区印干村大湾沟剖面玄武岩的夹层粉砂岩中3个不同层位的沉积岩样品,对其中碎屑锆石U-Pb年龄和Hf同位素组成进行了较系统的研究。研究表明3个样品碎屑锆石U-Pb年龄中最年轻的一组年龄峰值介于284~291Ma之间,与前人对塔里木早二叠世大火成岩省大规模溢流玄武质岩浆事件相吻合。此外,还存在老于1.7Ga、0.9~1.0Ga和750~850Ma以及410~450Ma的几组年龄,可能分别对应于塔里木哥伦比亚超大陆聚合、罗迪尼亚超大陆的聚合和裂解以及志留系地层的剥蚀沉积等一系列地质事件的发生。对上述3个沉积岩样品中锆石Hf同位素成分分析得出其碎屑锆石源区成分复杂,主要源自塔里木前寒武纪基底、志留系地层和塔里木早二叠世大火成岩省岩浆事件。具有二叠纪年龄的锆石ε_Hf(t)值在-10~4之间,平均值为-4.8,Hf同位素亏损地幔模式年龄t_DM^Hf为 801~1363Ma,表明这些玄武质熔岩中沉积岩夹层的碎屑锆石应该来自古老的富集岩石圈地幔。通过对柯坪地区这些夹层沉积岩的锆石U-Pb年龄和Hf同位素成分研究,有助于对塔里木早二叠世大火成岩省岩浆演化的认识。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...