西昆仑塔什库尔干地块马尔洋一带中寒武世 花岗岩的发现及地质意义

西昆仑塔什库尔干地块马尔洋一带发育一期中寒武世花岗质岩浆活动,岩石类型为片麻状花岗闪长岩和二长花岗岩,LA-ICP-MS锆石U-Pb测年表明,其侵入时代分别为（506.0±6.8）Ma和（514.0±9.3）Ma。岩石SiO₂含量为67.83%~75.76%,具中高钾、准铝质-弱过铝质等特征;岩石稀土总量与平均陆壳相当（∑REE=90.85×10-6~186.10×10-6）,轻、重稀土分馏程度较强（（La/Yb）_N=5.38~22.43）,负Eu异常明显（δEu=0.42~0.71）;微量元素以富集Rb、K、Ba、Th、U等大离子亲石元素和亏损Nb、Ta、P、Ti等高场强元素为特征。地质学及岩石地球化学特征指示该期花岗岩属准铝质到弱过铝质高分异Ⅰ型花岗岩,锆石饱和温度指示其为高温岩浆岩,总体具有壳幔混源的特征,富云包体指示壳源成分占有较大的比例。该期花岗岩与邻区中-晚寒武世中酸性侵入岩指示塔什库尔干-甜水海地块南缘很可能存在一条中寒武世以来的岩浆弧带,其可能为在原特提斯（有限）洋盆于中寒武世向北俯冲、消减背景下幔源物质上涌底侵加热古老陆壳进而发生部分熔融的产物。这也预示着塔什库尔干地区在经过震旦纪-早寒武世伸展裂解阶段之后,于中-晚寒武世其大地构造环境及地球动力学背景发生了重大转折。      

内蒙古维拉斯托矿区花岗岩类地球化学特征及其构造意义

维拉斯托铜多金属矿床是近年来在大兴安岭发现的大型银铜多金属矿床,为了深入讨论维拉斯托矿区花岗岩类的大地构造环境及其形成的动力学背景,通过系统观察和分析,讨论了维拉斯托矿区钻孔内出露的黑云母花岗岩、黑云母二长花岗岩以及石英闪长岩的岩石学及地球化学特征。黑云母花岗岩及黑云母二长花岗岩具高硅特征,A/NCK平均值为1.07,里特曼指数小于3.3,属于钙碱性系列;稀土总量较高,轻重稀土元素分馏强烈,中等Eu负异常;(⁸⁷Sr/⁸⁶Sr)t值为0.705 93~0.710 75,ε_Nd(t)值为-4.45~-0.63,具有高分异I型花岗岩特征。石英闪长岩的SiO2含量中等,准铝质,高镁(3.12%~7.58%),高Cr、Ni;稀土总量较低,轻重稀土元素分馏不明显,弱Eu负异常;(⁸⁷Sr/⁸⁶Sr)t值0.705 05~0.707 68,ε_Nd(t)值在-0.88 ~1.04,具有赞岐岩的元素组成特点。黑云母花岗岩及黑云母二长花岗岩主要来源于年轻陆壳的部分熔融,上侵过程经历较强烈的分异作用;石英闪长岩来源于俯冲流体/熔体或残余洋壳部分熔融对岩石圈地幔改造后的产物,岩浆演化后期并未经历强烈的地壳混染及分异作用。综合研究认为：维拉斯托矿区花岗岩类侵位于晚石炭世,形成于后碰撞环境。兴蒙造山带内大量出露晚石炭世-早二叠世的钙碱性高分异I型花岗岩及A型花岗岩,同时大量沉积学及地层古生物的证据均显示兴蒙造山带该时期已经进入陆内演化阶段。     

东昆仑造山带三叠纪岩浆混合成因花岗岩的岩浆底侵作用机制

东昆仑造山带广泛出露三叠纪岩浆混合成因花岗岩，它们具有共同的特征：岩体成分变化大；花岗岩类岩石中富含镁铁质微粒包体（mafic microgranular enclave--MME）；不同岩性之间常常呈渐变过渡关系。同时，这些岩体无一例外都和代表下地壳的深变质岩共生，暗示岩浆就位于地壳深部。此外，东昆仑地区广泛发育基性侵入体，它们产在深变质岩中，或者与岩浆混合成因花岗岩类共生，暗示下地壳物质的部分熔融和岩浆混合成因花岗岩的形成有可能与基性岩浆底侵作用有关。笔者选择东昆仑加鲁河这一典型的岩浆混合成因花岗岩体为例，对其岩石学、地球化学、同位素地球化学等特征进行了详细研究，认为幔源岩浆底侵作用是这类岩体形成的直接原因，并对幔源岩浆底侵作用和岩浆混合成因花岗岩之间的成因联系以及幔源岩浆底侵作用在东昆仑造山带三叠纪地壳生长和构造演化中所起的重要作用进行了讨论，构建了加厚陆壳背景下的断离-底侵-混合-拆沉作用模型。     

滇东南个旧白云山碱性岩年代学和地球化学及成因意义滇东南个旧白云山碱性岩年代学和地球化学及成因意义

报道了滇东南个旧超大型锡多金属矿区西区北部白云山碱性岩新的锆石U-Pb年龄、全岩地球化学和Sr-Nd同位素数据。LA-ICP-MS锆石U-Pb定年结果表明,白云山碱性正长岩形成于晚白垩世（80.0±0.6 Ma）,与个旧地区的中基性岩及花岗岩均为同一次构造岩浆事件的产物;碱性正长岩与霞石正长岩具有相似的主微量元素地球化学特征及Sr-Nd同位素组成,暗示二者很可能是源于同一富集地幔源区并经历了不同程度演化的产物。结合已有的元素和同位素组成结果,认为碱性岩、中基性岩和成矿花岗岩很可能分别源自富集的岩石圈地幔、正常的岩石圈地幔和地壳源区。在晚白垩世伸展构造背景控制下,源于不均一岩石圈地幔的碱性和中基性的岩浆底侵,促使中下地壳岩石部分熔融形成花岗质熔体,在上升至近地表过程中引起构造活动带成矿物质的富集,从而形成个旧超大型锡多金属矿床的矿化格局。可以说,源于富集地幔的碱性岩浆在含矿花岗质岩浆的成岩成矿过程中,应不只是提供热量的贡献。     

黔西北铅锌矿床REE特征及其意义

据各类样品的REE组成，研究了三个矿床矿石，恂变围岩及其原岩REE地球化学特征，计算出近似的成矿流体REE成分，讨论了REED 成矿（蚀变）过程中的地球化学行为，结合其他地质地球化学特征认为成矿物质主体是来源于下部的富金属流体，蚀变围岩的REE模式可作为寻找盲矿标志。     

西藏中部塔吉冈矿区早白垩世花岗岩成因及地质意义

塔吉冈铜多金属矿位于南羌塘地块的南缘,是认识班公湖-怒江成矿带构造-岩浆-成矿作用的理想窗口.以塔吉冈铜多金属矿区内出露的花岗岩为研究对象,对其进行了系统的锆石U-Pb定年、全岩地球化学和锆石原位Hf同位素研究.结果显示塔吉冈花岗岩形成于早白垩世晚期(120～118 Ma),岩石地球化学具有高SiO2、高碱(Na2O+...     

北淮阳地区与斑岩型钼矿床相关岩浆岩的地质地球化学特征及成因

位于秦岭-大别造山带东段的北淮阳地区分布有众多的斑岩型钼矿床,其成矿与岩浆作用紧密相关。对该区与斑岩型钼矿床密切相关的岩浆岩进行了系统的岩石化学、微量元素和同位素地球化学研究,深入探讨了其成因。研究认为,成矿岩体规模较小,岩性为花岗(斑)岩类,受北东向与北西向区域性断裂的次级构造控制。岩石化学成分以高硅、高钾、富碱为特征,为高钾钙碱性钾玄岩系列、准铝过铝质岩石。岩石微量、稀土元素特征相似并显示壳源特征。岩石Sr Nd Pb Hf同位素地球化学特征显示这些花岗质岩浆与整个大别地区白垩纪花岗岩的成岩物质来源一致,源于新元古界北大别片麻岩和扬子克拉通北缘TTG型岩浆,并混入一些古元古代扬子克拉通古老地壳物质(如崆岭杂岩)。在白垩纪发生的下地壳拆沉、软流圈上涌及大规模地壳伸展等机制下,扬子克拉通北缘的地壳熔融并提供了主要的成岩物质,幔源岩浆的上涌可能提供了热源,其物质的加入是次要的。该区与斑岩型钼矿床相关岩浆岩与东秦岭地区类似,属深源浅成型花岗岩类。     

东秦岭两类花岗岩与两个金矿系列

本文根据东秦岭地区花岗岩金矿的特征，全面地探讨了花岗岩与金矿化的关系，将东秦岭地区与花岩有关的金矿床分为深源浅成型花岗岩金矿系列和浅源深成型花岗岩金矿系列。不同成因系列的花岗岩与金矿的关系完全不同。文中还简要地阐述了与两个系列金矿有关的花岗岩的地花岗岩的地质地球化学特征和秦岭造山带的构造演化。     

The Genetic Types of Some Granite Intrusions Associated with Tin Polymetallic Deposits in the Nanling Region

Tin polymetallic deposits are the most important type of tin deposit in the Nanling region. Manyresearchers both at home and abroad consider this type of tin deposit to be the product of differentiation andevolution of granite magmas resulting from anatexis of continental crust and to be genetically related to thetransformation-type (S-type) granitoids. In this paper, on the basis of the geological settings, petrology, REEgeochemistry and strontium and oxygen isotopic compositions of 6 granite intrusions associaied with tinpolymetallic deposits in the Nanling region, the authors suggest that the ore-bearing granites of this type areprobably the products of differentiation and evolution of acid magmas resulting from 40-50‰ fractionalcrystallization of magmas formed by partial melting of the pre-existing intermediate-basic volcanic rocks ofmantle origin in the lower crust and a small amount of sialic material and belong to crust-mantle-derivedgranitoids (approaching I-type of B. W. Chappell and A.J.R. White, but being evidently different from theS-type granitoid related to W, Sn, Nb, Ta and REE deposits).     

Are South China granites special in forming ion-adsorption REE deposits?

Ion-adsorption REE deposits associated with clay minerals are the main global HREE producer. The majority of these deposits are formed by the weathering of granites in South China, but whether there is any fundamental difference between the granites in and outside South China is still unclear. Besides, an effective evaluation system of granite mineralization potential is urgently needed for HREE exploration.To answer this question, we compiled a global granite geochemical dataset from within (n = 1932) and outside (n = 6109) South China, together with a dataset of representative REE deposits in South China (n = 128). The geochemical comparation shows that the South China granites share similar REE contents with those of many granites from places outside South China. Such similarity has also been found between REE ore-related and ore-barren granites in South China. This shows that granites from outside South China could also have ore-forming potential. Warm humid climate and quasi-equalized crustal state promote chemical weathering to continuously leach REEs and store them in the weathering crust. The enrichment ratio (Rx) can be used to quantify the climatic effect between orebodies and parent rocks. The calculated average Enrichment Ratios (Rx) of LREE- and HREE-rich deposits are 2.41 and 2.68, respectively. Sufficient REE content in granite is the prerequisite for mineralization, and we propose that the combination of the minimum REE + Y (172 and 108 ppm in LREE- and HREE-rich parent rocks, respectively) and REE oxide ratio (1.32) can reveal the granite metallogenic potential. Together with the suitable tropical and temperate climate area with ion-adsorption REE deposits, we further identified certain regions with high REE mineralization potential outside South China to assist future exploration.     

黑龙江省张广才岭南部早侏罗世花岗岩暗色微粒包体成因研究

黑龙江省张广才岭南部早侏罗世花岗岩具有明显的岩浆混合特征。岩体中暗色微粒包体发育,主要为细粒闪长质岩浆包体,包体形态多样,与寄主岩呈截然、过渡关系。包体的矿物组合明显不平衡,如矿物具有定向排列的特点,斜长石发育自形环带并存在新、老两个世代,发育针状磷灰石。由电子探针对斜长石、角闪石和黑云母等矿物分析结果可知,寄主花岗岩和包体中各主要矿物含量基本一致。岩石地球化学特征研究显示,包体与寄主花岗岩关系密切,两者在稀土元素和微量元素方面也表现为明显的地球化学亲缘关系。这表明张广才岭南部早侏罗世花岗质岩石具有壳幔混合成因特征,暗色微粒包体是由较基性的地幔岩浆进入寄主岩浆中淬火结晶而成,花岗质岩浆的源区主要为新生的地壳物质。     

Geochemistry and zircon geochronology of the Archean granite suites of the Rio Maria granite-greenstone terrane,Carajás Province,Brazil

The Archean granites exposed in the Mesorchean Rio Maria granite-greenstone terrane (RMGGT), southeastern Amazonian craton can be divided into three groups on the basis of petrographic and geochemical data. (1) Potassic leucogranites (Xinguara and Mata Surrão granites), composed dominantly of biotite monzogranites that have high SiO₂, K₂O, and Rb contents and show fractionated REE patterns with moderate to pronounced negative Eu anomalies. These granites share many features with the low-Ca granite group of the Yilgarn craton and CA2-type of Archean calc-alkaline granites. These granites result from the partial melting of rocks similar to the older TTG of the RMGGT. (2) Leucogranodiorite-granite group (Guarantã suite, Grotão granodiorite, and similar rocks), which is composed of Ba- and Sr-rich rocks which display fractionated REE patterns without significant Eu anomalies and show geochemical affinity with the high-Ca granite group or Transitional TTG of the Yilgarn craton and the CA1-type of Archean calc-alkaline granites. These rocks appear to have been originated from mixing between a Ba- and Sr-enriched granite magma and trondhjemitic liquids or alternatively product of interaction between fluids enriched in K, Sr, and Ba, derived from a metasomatized mantle with older TTG rocks. (3) Amphibole-biotite monzogranites (Rancho de Deus granite) associated with sanukitoid suites. These granites were probably generated by fractional crystallization and differentiation of sanukitoid magmas enriched in Ba and Sr.The emplacement of the granites of the RMGGT occurred during the Mesoarchean (2.87–2.86 Ga). They are approximately coeval with the sanukitoid suites (∼2.87 Ga) and post-dated the main timing of TTG suites formation (2.98–2.92 Ga). The crust of Rio Maria was probably still quite warm at the time when the granite magmas were produced. In these conditions, the underplating in the lower crust of large volumes of sanukitoid magmas may have also contributed with heat inducing the partial melting of crustal protoliths and opening the possibility of complex interactions between different kinds of magmas.     

Late Neoproterozoic A-type granites in the northernmost Arabian-Nubian Shield formed by fractionation of basaltic melts

Geochemical, isotopic and age constraints support a comagmatic origin for Ghuweir Mafics and the Feinan A-type granites. The two rocks types, named collectively in this paper as the Feinan Ghuweir Magmatic Suite (FGMS), formed between 556 and 572 Ma ago according to Rb-Sr whole-rock dating. FGMS has low Sr initial ratios, which preclude a significant contribution of much older crust in the magma genesis.The FGMS has a wide range of silica contents, with a gap at 55-65 wt% SiO₂. It has a transalkaline to alkaline character; belongs to the medium to high K calc-alkaline series; it ranges from metaluminous to mildly peraluminous character and belongs to the alkali and alkali-calcic series. The Feinan granites and the Ghuweir rhyolites and rhyodacites are classified as A-type granites and belong to group A2 of Eby [Eby, N.G., 1992. Chemical subdivision of the A-type granitoids: petrogenetic and tectonic iplications. Geology 20, 641-644].According to geochemical modeling the Ghuweir Mafics were derived from a subduction modified lithospheric mantle by 10% batch modal partial melting of a phlogopite-bearing spinel lherzolite. The intra-suite geochemical variations can be ascribed to fractional crystallization of olivine, pyroxene, and plagioclase. The accumulation of apatite in the most evolved samples is responsible for the high concentrations of REE.The Feinan granites and the Ghuweir rhyolites and rhyodacites were derived from the mafic magma by the fractional crystallization of ≈78% of the original magma to the mineral assemblage olivine+pyroxene+plagioclase+magnetite. The intra-suite geochemical variations in the Feinan A-type granites are due to the fractional crystallization of the mineral phases: amphibole +Na and K-feldspar+apatite +magnetite+zircon+allanite.The FGMS correlates with time-equivalent rocks in many parts of the Arabian-Nubian Shield and the surrounding areas.     

Geochemical features of rare-metal granites of the Zashikhinsky Massif,East Sayan

The paper presents detailed geochemical data on the rocks of the Zashikhinsky Massif and mineralogical–geochemical characteristics of the ores of the eponymous deposit. The rare-metal granites are divided into three facies varieties on the basis of the degree of differentiation and ore potential: early facies represented by microcline–albite granites with arfvedsonite, middle facies represented by leucocratic albite–microcline granites, and late (most ore-bearing) facies represented by quartz–albite granites grading into albitites. Microprobe data were obtained on major minerals accumulating trace elements in the rocks and ores. All facies of the rare-metal granites, including the rocks of the fluorite–rare-metal vein, define single compositional trends in the plots of paired correlations of rock-forming and trace elements. In addition, they also show similar REE patterns and spidergrams. The latter, however, differ in the depth of anomalies of some elements. Obtained geological, petrographic, and geochemical data suggest a magmatic genesis of the rocks of different composition and their derivation from a single magma during its differentiation. On the basis of all characteristics, the Zashikhinskoe deposit is estimated as one of the largest tantalum rare-metal deposits of alkaline-granite type in Russia.     

老挝班康姆铜金矿床火山-侵入杂岩地球化学特征及地质意义

班康姆铜金矿床是近年来新发现的大型铜金矿床。前人研究初步表明研究区成矿作用与古特提斯洋壳俯冲消减所产生的岩浆作用密切有关,但是缺乏岩石地球化学证据。笔者于研究区地表、钻孔采集了13件火山岩-侵入岩新鲜岩石,开展了主量元素、微量元素、稀土元素分析测试。研究表明该区安山质-侵入杂岩具有岛弧钙碱性火山岩的地球化学特征,构造环境判别图显示该套岩石属于大洋弧环境,形成于大洋消减带,与洋壳板片俯冲有关。安山质-侵入杂岩来源于地幔楔,并经历了结晶分异作用,而煌斑岩形成于板片消减而富集的地幔部分熔融。通过与黎府构造带矿床稀土、微量元素特征对比,证实班康姆矿区与Chatree矿区火山岩及金矿床形成于同一期构造岩浆成矿作用,进一步表明了黎府构造岩浆带在晚二叠世—早三叠世发生了一次重要的区域成矿作用。     

华南产铀花岗岩的一种成因模式—递进部分熔融

本文建立了产铀岩体的递进部分熔融成因模式,研究了部分熔融过程中铀的地球化学性状和富集机理,阐述了递进部分熔融机制的找矿意义。该模式较好地解释了华南产铀花岗岩类所具有的一些地质地球化学特征,并认为有关岩浆型产铀花岗岩类系周围出露的富铀地层重熔而成的传统观念尚有值得推敲之处,指出富铀地层作为围岩与岩浆型产铀岩体的联系主要取决于花岗质熔体上侵和结晶演化过程中熔体中水的溶解度变化以及熔体对围岩的同化作用。     

REE Abundance and REE Minerals in Granitic Rocks in the Nanling Range,Jiangxi Province,Southern China,and Generation of the REE‐rich Weathered Crust Deposits

Studies of Mesozoic granites associated with rare earth element (REE)‐rich weathered crust deposits in southernmost Jiangxi Province indicate that they have high‐K to shoshonite compositions and belong to ilmenite‐series I‐type granites. Of the studied rocks at 59–292 ppm of bulk REE content, the highest are seen in the biotite granites of Dingnan (358, 429 ppm) and mafic biotite granite of the Wuliting Granite (344 ppm) near the Dajishan tungsten mine, both areas where weathered‐crust REE deposits occur. REE‐bearing accessory minerals in these granites are mainly zircon, apatite and allanite, and REE‐fluorocarbonates are common. REE enrichment occurs in the rims of apatite crystals, and in fluorocarbonates that occur along grain boundaries of and cracks in major silicate minerals, and in fluorocarbonates that replaced altered biotite. It is therefore thought that a major part of the REE content of these granites was concentrated during deuteric activity, rather than during magmatic crystallization. The crack‐filling REE‐fluorocarbonates could subsequently have been easily leached out and deposited in weathered crust developed during a long period of exposure.     

Early Permian A‐type Granites in the Zhangdaqi Area,Inner Mongolia,China and Their Tectonic Implications

There is a controversy regarding the amalgamation of Xing'an and Songnen Blocks along the Hegenshan-Heihe Suture(HHS) in the eastern Central Asian Orogenic Belt(CAOB). To solve this problem, we performed detailed study on the granites from the Zhangdaqi area, adjacent to the north of the HHS in the northern part of the Great Xing'an Range, NE China. Geochemically, the granites in the study area are metaluminous-weak peraluminous and high-K calc-alkaline series. Trace elements of the granites show that LREEs are relatively enriched, while HREEs are relatively deficient and obvious REE fractionation. The granites are characterized by obvious negative Eu anomalies, meanwhile, they are relatively enriched in Rb, K, Th and depleted in Ba, Nb, Sr, P, Ti. All the geochemical features suggest that the granites in the Zhangdaqi area are aluminum A-type granites. The zircon LA-ICP-MS U-Pb ages of these granites are 294–298 Ma, indicating that they formed in the Early Permian. These granites also have positive ε_(Hf)(t) values(8.4–14.2) and a relatively young two-stage model age between 449 Ma and 977 Ma, implying that the magma was derived from the re-melting of the Early Paleozoic-Neoproterozoic juvenile crust. Combined with geochemical characteristics(Nb/Ta ratios of 9.0–22.2, and Zr/Hf ratios of 52.3–152.0), we believe that the magmatic source area is a mixture of partial melting of the lower crust and depleted mantle. A-type granites and bimodal volcanic rocks along the Hegenshan-Heihe Suture formed during the Late Carboniferous-Early Permian, indicating that the HHS between Xing'an and Songnen Blocks closed in the late EarlyCarboniferous. Subsequently, the Zhangdaqi area was in a post-orogenic extensional environment from Late Carboniferous to Early Permian and resulted in the formation of the A-type granites.     

浙东地区晚中生代火山岩地球化学特征、岩石成因及构造环境

中国东部中生代发生的大规模岩浆活动是地学界长期以来关注的课题之一。本文通过对浙东地区晚中生代火山岩锆石U-Pb年代学、主量、稀土及微量元素地球化学的研究,讨论其岩石成因及形成的构造环境。研究表明,大爽组底部火山岩年龄为155.2±1.4 Ma(MSWD=0.83),显示浙东地区晚中生代火山岩的形成时代并不限于白垩纪,火山喷发至少于晚侏罗世就已经开始;岩石总体属高钾钙碱性系列,少量属钾玄岩系列;基性岩石、中性岩石与中酸性(酸性)岩之间不具有同源演化关系,基性岩石来源于富集地幔,并受到了不同程度的地壳混染,中性岩石可能来源于先存于下地壳深部的新元古代岛弧岩石,中酸性(酸性)岩石来源于地壳,中酸性岩浆与酸性岩浆之间存在演化关系;岩石总体形成于地壳幕式减薄环境,而其弧岩浆岩特征主要反映源岩属性。     

浙东白垩纪北漳和梁弄花岗岩体及其暗色岩石包体研究

浙东地区晚中生代花岗岩类在岩性上分为三类：花岗岩-二长花岗岩、钾长花岗岩和A型花岗岩。对后两类花岗岩已有较多研究,但对前一类,尤其是二长花岗岩的研究还较薄弱。选择浙东具代表性的北漳和梁弄二长花岗岩体及其所含暗色岩石包体,以及共生的石英闪长岩类,通过系统的岩石学与地球化学对比研究,提出浙东二长花岗岩属准铝质、高钾钙碱性Ⅰ型花岗岩类演化系列,暗色岩石包体是由花岗质岩浆在深部析离出的镁铁质微粒包体(MME),成分特征类似于石英闪长岩,说明三者具内在成因联系,均与俯冲作用关系密切。