浙西开化桐村斑岩型Mo(Cu)矿床含矿斑岩岩石化学、SHRIMP锆石U-Pb年代学及Sr-Nd同位素研究

浙西开化桐村矿床是近年来新发现的一个中型斑岩钼铜矿床。基于翔实的野外调查,文中研究了桐村矿区岩浆岩的岩相学、岩石化学、年代学以及Sr Nd同位素特征,指出：(1)该矿区内花岗斑岩、花岗闪长斑岩属于高钾钙碱性系列,具有高SiO2、富K2O和低Na2O的特点,富集轻稀土元素,轻重稀土分馏较强,铕负异常不明显;富集Rb、Th、K、U、La、Ce、Pb,亏损Ti、P、Nb、Ta、Zr、Hf等元素;(2)桐村矿区岩体SHRIMP锆石U Pb谐和年龄为(162±3) Ma,MSWD=2.7,加权平均年龄为(162.1±3.4) Ma,MSWD=2.7,说明黄柏坑岩体的侵入事件发生在中-晚侏罗世;(3)含矿斑岩具较高的Sr初始值(0.712 21),εNd(t)值为-6.7～-2.0,其模式年龄为1 628～2 029 Ma,表明花岗岩源岩可能为古元古代的老基底,暗示斑岩源区为壳幔混合型。研究区内花岗斑岩和花岗闪长斑岩为同源岩浆在不同阶段演化的产物。高氧化态、强演化程度和较多的地壳混染可能是桐村矿床成Mo且规模有限的重要原因。     

湘南郴桂地区酸性斑岩的时代划分及成矿专属性

郴柱地区酸性斑岩概括为花岗闪长斑岩、花岗斑岩、石英斑岩三类，划分为T3，J1，J2，J3，K1和K2等6个时代形成，包括壳源物质熔融和壳幔源物质同熔两种成因类型。J1未形成的壳幔源物质同熔型花岗闪长斑岩与铜、钼、铅、锌、金等成矿作用有关，J1末至J2及K2的壳源物质熔 融型花岗斑岩、石英斑岩与锡、铅、锌、铜等矿化关系密切；和成矿有关的酸性斑岩体规模较大，其为深部或附近较大规模岩浆岩体的分异物或浅成相物。     

云南九顶山正长斑岩年代学、岩石地球化学及Sr-Nd-Hf同位素特征

九顶山复式岩体沿北西向金沙江–红河断裂与南北向程海断裂交汇处发育,处于南北地洼区与滇西地洼区接触带,是滇西地洼期斑岩成矿带中段的代表性富碱斑岩体之一。该岩体由呈岩株、岩脉、岩墙或岩床等产出的斑状花岗岩、正长斑岩、(二长)花岗斑岩、碱长花岗斑岩和煌斑岩等组成。本文着重对正长斑岩的形成年代、岩石地球化学和成因特征开展研究,结果表明:正长斑岩的LA-ICP-MS锆石U-Pb年龄为34.6±0.7 Ma,即岩浆侵位于始新世(E2),属滇西地洼激烈期及新生代富碱岩浆活动高峰期(45~30 Ma)的产物;岩石具高硅(Si O256%)、高钾(K2O=3.38%~8.92%,K2O/Na2O1)、富碱(ALK=8.15%~11.15%)和低Mg O(3%)的特征,属钾玄岩系列–高钾钙碱性系列过铝质(A/CNK=0.71~1.22)花岗岩;在微量元素组成上,岩石高Sr(400×10-6)、低Y(18×10-6)和Yb(1.9×10-6),与陆内造山环境形成的"C型"钾质埃达克岩地球化学特征类似;全岩的Sr-Nd-Hf同位素组成特征显示岩浆源区是壳幔物质混合的"EMII型"富集地幔源。正长斑岩的形成应与印度–欧亚板块碰撞俯冲背景下,金沙江–红河断裂大规模左行走滑引起的热扰动和局部引张作用有关,在这种区域热–动力学条件下,地幔部分熔融与地壳物质发生混合作用,形成活化型壳幔混合源高钾富碱岩浆。     

完达山地块跃进山矽卡岩型铜金矿区酸性侵入岩锆石U-Pb年龄、地球化学特征及成因

跃进山小型矽卡岩型铜金矿床位于完达山地体西南部,矿体主要赋存于矽卡岩、花岗斑岩及其构造裂隙中,呈扁豆状或脉状。本文对矿区花岗闪长岩和花岗斑岩进行锆石U-Pb年代学和岩石地球化学研究,以了解矿床形成时代、成岩（矿）构造背景及矿床成因。测年结果表明,花岗斑岩和花岗闪长岩成岩年龄分别为（115.8±1.0）Ma和（126.9±1.7）Ma,铜金矿化时代与花岗斑岩成岩时代基本一致,为早白垩世晚期。岩石地球化学研究表明,花岗闪长岩属过铝质钙碱性系列岩石,稀土配分模式图为轻稀土富集,重稀土亏损,具较强的铕负异常,无铈异常,岩浆主要来源于壳源物质;花岗斑岩属过铝质钙碱性系列岩石,轻稀土富集,重稀土亏损,具弱铕负异常,无铈异常,相对富集大离子亲石元素（Rb、Ba、K、Sr）和不相容元素（U、Th）,亏损高场强元素（Ta、Nb、P、Ti）和HREE,岩浆来源于壳幔物质混合源区,形成于碰撞后构造环境,成岩成矿作用与太平洋板块强烈俯冲作用后的伸展体制密切相关。     

贵州从江地区花岗质斑岩的地球化学特征

从江地区花岗质斑岩分布于摩花岗岩体的周级,主要有二长花岗斑岩、普通花斑岩、碱长花岗斑岩、混合花岗斑岩４种类型。就岩石化学特征而言,二长花岗斑岩以壳源为主, 幔源成分的壳幔混源成因;普通花岗斑岩属壳源交代成因;而混合花岗斑岩与区内负变质岩的岩石化学成分相似。     

江西省村前铜多金属矿床斜长花岗斑岩LA-ICP-MS锆石U-Pb年龄及地质意义

村前铜多金属矿床是产于钦杭成矿带东段的重要的斑岩-矽卡岩矿床,含矿岩体为黑云母斜长花岗斑岩和斜长花岗斑岩,具有多次侵入特点及钙碱性岩石的地球化学特征.本研究采用了LA-ICP-MS技术,首次对含矿的斜长花岗斑岩岩体中的锆石进行了U-Th-Pb同位素分析,获得其成岩年龄为(169.3±1.1 )Ma.这一年龄与钦杭成矿带中德兴花岗闪长斑岩、银山石英斑岩、冷水坑花岗斑岩、桐村花岗斑岩等岩体的年龄十分接近,揭示在钦杭成矿带175～156Ma经历了一次大规模的岩浆侵位与成矿事件,形成了众多与埃达克质或钙碱质花岗岩有关的斑岩-矽卡岩型铜多金属矿床,进一步说明钦杭成矿带在此时期在同一岩浆-动力背景下形成了斑岩-矽卡岩型铜多金属矿成矿系列.     

内蒙古新巴尔虎右旗特格乌拉地区花岗斑岩年代学及地球化学特征

对大兴安岭特格乌拉地区花岗斑岩进行岩石学、地球化学、成因及构造环境研究结果显示，花岗斑岩年龄为145.9±1.2 Ma，形成时代为早白垩世晚期.岩石具有富硅、富碱和富铝质的特点，属于准铝质-铝质高钾钙碱性系列.矿物组合及地球化学特征显示特格乌拉地区花岗斑岩为高分异I型花岗岩，富集大离子亲石元素（Rb、Th、U）和轻稀土元素（La、Ce、Pr），负Eu异常明显，显示壳源岩浆或岩浆被地壳物质混染的地球化学特点.特格乌拉地区花岗斑岩形成于造山后伸展环境，这种构造背景可能与蒙古-鄂霍次克缝合带闭合后加厚陆壳的拆沉作用有关.     

西准噶尔南部庙尔沟岩体晚石炭世花岗闪长斑岩岩石成因及其动力学背景

位于西准噶尔南部的庙尔沟岩体主体由碱长花岗岩和少量紫苏花岗岩组成。本文在前人工作基础上,以岩体东南边缘新发现的花岗闪长斑岩为研究对象,开展岩石学、年代学和Hf同位素以及全岩地球化学研究,确定花岗闪长斑岩形成时代、揭示岩石成因类型及源区属性、探讨其与碱长花岗岩和紫苏花岗岩岩浆演化成因联系及其形成的深部动力学过程。锆石U-Pb定年结果显示,花岗闪长斑岩形成于317.4±1.9Ma,为晚石炭世早期岩浆活动的产物,明显早于紫苏花岗岩(～307Ma)和碱长花岗岩(～303Ma)。岩石地球化学数据表明,花岗闪长斑岩具有较高硅、中等铝,贫钙、铁、镁,富集Rb、K、Th、U,强烈亏损Nb、Ta、Ti的特征,为钙碱性弱过铝质I型花岗岩;紫苏花岗岩更多的表现出钙碱性-高钾钙碱性镁质I型紫苏花岗岩特征;碱长花岗岩为碱性准铝质-弱过铝质A型花岗岩。锆石Hf同位素分析结果表明,花岗闪长斑岩、紫苏花岗岩和碱长花岗岩均具有高正的ε_(Hf)(t)值(+11.6～+15.8)和年轻的二阶段模式年龄(325～600Ma),表明其原始岩浆主要起源于亏损地幔新衍生的年轻地壳物质。综合分析认为,庙尔沟岩体花岗闪长斑岩形成于晚石炭世早期洋壳俯冲背景,由底侵的、受流体交代的幔源基性岩浆与其诱发的年轻下地壳酸性岩浆在深部混合而成。紫苏花岗岩和碱长花岗岩形成于弧后伸展背景,前者是伸展初期继续底侵于下地壳的幔源玄武质岩浆降温释放大量的水和热诱使早期侵位于下地壳的镁铁质岩石再次发生部分熔融的产物,后者是伸展后期大规模软流圈地幔上涌底垫加热年轻中下地壳使其部分熔融而成。     

秦祁昆结合部瓦勒根金矿床含矿斑岩体岩石学和LA-ICP-MS锆石U-Pb年龄

秦祁昆结合部广泛发育中三叠世岛弧钙碱性岩浆作用,已发现大量与其相关的斑岩型—夕卡岩型铜金、铜钼和银铅锌多金属矿床。瓦勒根金矿床是近年来在该区新发现的一个斑岩型金矿床,矿区内出露有众多的石英斑岩和花岗斑岩,且均发育有金矿化,其中石英斑岩与金矿化关系更为密切。LA-ICP-MS锆石U-Pb年龄表明,花岗斑岩形成于中三叠世(237Ma),其中包含有丰富的晚古生代及元古宙继承性锆石。这一特征与区域上的斑岩型铜金矿床含矿岩体具有相似性。进一步说明,古特提斯洋在秦祁昆结合部发生向北消减所形成的岩浆捕获了早于三叠纪的壳源和幔源物质,从而形成了岛弧钙碱性岩浆及相关的斑岩型—夕卡岩型矿床组合。     

北淮阳地区与斑岩型钼矿床相关岩浆岩的地质地球化学特征及成因

位于秦岭-大别造山带东段的北淮阳地区分布有众多的斑岩型钼矿床,其成矿与岩浆作用紧密相关。对该区与斑岩型钼矿床密切相关的岩浆岩进行了系统的岩石化学、微量元素和同位素地球化学研究,深入探讨了其成因。研究认为,成矿岩体规模较小,岩性为花岗(斑)岩类,受北东向与北西向区域性断裂的次级构造控制。岩石化学成分以高硅、高钾、富碱为特征,为高钾钙碱性钾玄岩系列、准铝过铝质岩石。岩石微量、稀土元素特征相似并显示壳源特征。岩石Sr Nd Pb Hf同位素地球化学特征显示这些花岗质岩浆与整个大别地区白垩纪花岗岩的成岩物质来源一致,源于新元古界北大别片麻岩和扬子克拉通北缘TTG型岩浆,并混入一些古元古代扬子克拉通古老地壳物质(如崆岭杂岩)。在白垩纪发生的下地壳拆沉、软流圈上涌及大规模地壳伸展等机制下,扬子克拉通北缘的地壳熔融并提供了主要的成岩物质,幔源岩浆的上涌可能提供了热源,其物质的加入是次要的。该区与斑岩型钼矿床相关岩浆岩与东秦岭地区类似,属深源浅成型花岗岩类。     

德兴铜矿、银山铜铅锌矿床的岩浆岩岩石化学特征及其成岩成矿机理探讨

德兴斑岩铜矿和银山铜铅锌矿床位于江南古陆与钱塘坳陷之过渡带,赣东北深大断裂的北西盘。德兴斑岩铜矿与燕山期(169Ma)浅成花岗闪长斑岩侵入体具有成因联系,侵入体属低硅钠质组合,铝质参数A[A=Al-(K+Na+2Ca)]值变化于-13—93,表现为铝次饱和到不饱和特征,镁铁质参数B(B=Fe+Mg+Ti)值变化于100—265,二者构成负斜率岩浆演变趋势线,表明岩浆起源于上地幔或下地壳。银山矿床的形成与燕山期(145—142Ma)陆相火山一次火山岩系有关,其属高硅钾质火山岩组合,铝质参数A值变化于7—17     

钦-杭成矿带东段村前含矿斑岩地球化学特征及其构造环境与成矿意义

村前铜多金属矿床位于钦杭成矿带东段,为一具有矽卡岩型矿化和斑岩型矿化的铜多金属矿床,含矿岩体为燕山早期花岗闪长斑岩,岩石具有富硅、富铝、富碱的特点,属于偏铝-过铝质钙碱性花岗岩类。岩体具有从深部向浅部蚀变增强,大部分组分活动性不明显,而成矿元素Cu-Mo-Fe-Pb-Zn-Au-Ag含量明显增加,Na2O、Sr含量降低,REE元素除Eu少量丢失外,其余均呈一致的迁入特征。岩体属Ⅰ型花岗质岩石,由具角闪石+石榴子石残留相的火成岩部分熔融形成的熔浆,混合或混染了地壳重熔型岩浆上侵就位而成。钦杭结合带东段,燕山期中酸性岩浆活动具有从176~150Ma的埃达克岩或具岛弧花岗岩特征的Ⅰ型花岗岩,至150~140Ma的S型花岗岩,向140~110Ma的A型花岗岩演化趋势,显示了地壳由厚减薄的过程,暗示其大地构造背景为岩石圈的伸展减薄环境,而形成于169.3±1.1Ma的村前斑岩体正处于伸展阶段早期。综合岩体成矿特征表明,钦杭成矿带东段及邻近地区,176~160Ma主要形成与Ⅰ型花岗质岩石有关的以Cu为主的多金属矿床;160~150Ma主要形成与Ⅰ型花岗质岩石有关的Cu-Mo矿床与W-Sn矿床;150~140Ma主要形成与S型花岗质岩石有关的以W-Sn-Mo为主的多金属矿床,以及以Ag-Pb-Zn为主的多金属矿床;140~110Ma主要形成与A型花岗质岩石有关的以W-Sn-Mo为主的多金属矿床,少量与Ⅰ型花岗质岩石有关的Pb-Zn矿床。     

德兴铜矿花岗闪长斑岩物质来源的微量元素研究

对德兴铜矿铜厂和富家坞花岗闪长斑岩样品的微量元素和稀土元素分配特征分析研究表明,铜厂和富家坞两个矿区的花岗闪长斑岩具有一致的来源,两个斑岩体均由混有少量地壳物质的地幔岩浆演化而来.结晶分异作用可能是岩浆演化的主要原因.     

Petrogenesis of Ore‐Related Granodiorite Porphyry in the Jiande Copper Deposit,SE China: Implications for the Tectonic Setting and Mineralization

Adakitic rocks and related Cu–Au mineralization are widespread along eastern Jiangnan Orogen in South China. Previous studies have mainly concentrated on those in the Dexing area in northeastern Jiangxi Province, but information is lacking on the genesis and setting of those in northwestern Zhejiang Province. The Jiande copper deposit is located in the suture zone between the Yangtze and Cathaysia blocks of South China. This paper presents systematic LA–ICP–MS zircon U–Pb dating and element and Sr–Nd–Hf isotopic data of the Jiande granodiorite porphyry. Zircon dating showed that the Jiande granodiorite porphyry was produced during the Middle Jurassic (ca. 161 Ma). The Jiande granodiorite porphyry is characterized by adakitic geochemical affinities with high Sr/Y and La_N/Yb_N ratios but low Y and Yb contents. The absence of a negative Eu anomaly, extreme depletion in Y and Yb, relatively low MgO contents, and relatively high ²⁰⁷Pb/²⁰⁴Pb ratios, indicated that the Jiande granodiorite porphyry was likely derived from partial melting of the thickened lower continental crust. In addition, the Jiande granodiorite porphyry shows arc magma geochemical features (e.g., Nb, Ta and Ti depletion), with bulk Earth‐like ε_Nd (t) values (?2.89 to ?1.92), ε_Hf (t) values (?0.6 to +2.8), and initial ⁸⁷Sr/⁸⁶Sr (0.7078 to 0.7105). However, a non‐arc setting in the Middle Jurassic is indicated by the absence of arc rocks and the presence of rifting‐related igneous rock associations in the interior of South China. Combined with the regional Neoproterozoic Jiangnan Orogeny, it indicates that these arc magma geochemical features are possibly inherited from the Neoproterozoic juvenile continental crust formed by the ancient oceanic crust subduction along the Jiangnan Orogen. The geodynamic environment that is responsible for the development of the Middle Jurassic Jiande granodiorite porphyry is likely a localized intra‐continental extensional environment along the NE‐trending Jiangshan‐Shaoxing Deep Fault as a tectonic response to far‐field stress at the margins of the rigid South China Plate during the early stage of the paleo‐Pacific plate subduction. In terms of Cu mineralization, we suggest that the metal Cu was released from the subducted oceanic slab and reserved in the juvenile crust during Neoproterozoic subduction along the eastern Jiangnan Orogen region. Partial melting of the Cu rich Neoproterozoic juvenile crust during the Middle Jurassic time in the Jiande area caused the formation of adakitic rocks and the Cu deposit.     

LA-ICP-MS/FT方法在矿床保存研究中的应用——以赣东北德兴铜矿和银山铅锌矿床为例

矿床保存是成矿系统研究的重要组成部分,其中裂变径迹研究是揭示矿床保存条件和程度的有效手段之一。本文建立了LA-ICP-MS/FT方法,该方法获得磷灰石裂变径迹年龄值与已有外探测器法分析结果对比表明这一方法是可行的。基于此方法,对赣东北德兴铜矿与银山铅锌矿进行了磷灰石裂变径迹分析,得到了德兴成矿岩体的磷灰石裂变径迹年龄71.4±8.6 Ma,银山地区英安斑岩的磷灰石裂变径迹年龄为77.1±8.3 Ma。这一结果表明,在区域整体抬升背景下,两个矿区均以较低的剥蚀抬升速率抬升至地表。两个矿区样品磷灰石平均裂变径迹围限长度分别为12.32±1.77μm和12.56±1.91μm,对应Dpar值为2.45±0.19μm和1.84±0.17μm,径迹长度频度分布属于单峰型,证实两个矿区为单向冷却过程且没有遭受后期明显的热扰动。进一步温度‒时间热模拟路径显示,德兴和银山在70 Ma前经历了快速隆升过程,然后开始缓慢抬升,到约20 Ma开始再次快速隆升。结合前人报道的U-Th/He定年结果,100 Ma以来,德兴可能比银山具有相对更高的隆升量(~1 km)。     

Geochronology and Geochemistry of the Tinggong Porphyry Copper Ore Deposit,Tibet

We have determined the ages of the ore-bearing Tinggong porphyries and the Eocene granites using the LA-ICPMS zircon U-Pb method. Zircons from one adamellite porphyry and two diorite porphyries yield ages of 15.54±0.28 Ma, 15.02±0.25 Ma and 14.74±0.22 Ma, respectively. The ages of two granites are 50.48±0.71 Ma and 50.16±0.48 Ma. Light Rare Earth Elements(LREE) are enriched in the ore-bearing adamellite porphyries, which are high-K calc-alkaline and metaluminous, while Heavy Rare Earth Elements(HREE) and Y are strongly depleted, indicating an adakitic affinity. The Large Ion Lithophile Elements(LILE) of the adamellite porphyries are highly enriched, whereas some High Field Strength Elements(HFSE) are depleted. The diorite porphyry in this study is chemically similar to the adamellite porphyries, except that the Mg# of the diorite porphyry is a little higher, demonstrating more mantle contamination. Four samples from different rocks are selected for in situ zircon Hf isotopic analyses. The samples show positive εHf(t) values and young Hf model ages, indicating their derivation from juvenile crust. However, the adamellite porphyry and diorite porphyry formed in the Miocene exhibit more heterogeneous Hf isotopic ratios, with lower εHf(t) values than the granites formed in the Eocene, suggesting the involvement of old Indian continent crust in their petrogenesis. The geochronology and geochemistry of the adamellite porphyries and the diorite porphyries indicate that they formed from the same source region in a post-collisional environment, but contaminated by crust and mantle materials in different ratios. The metallic minerals formed mainly during the older adamellite porphyry stage, but they were recycled and reactivated by the diorite porphyry intrusion.     

西藏青草山斑岩铜金矿床含矿斑岩锆石U-Pb年代学及岩石成因

西藏青草山Cu-Au矿床是班公湖-怒江缝合带北侧新发现的具有大型远景的斑岩型矿床,但该矿床含矿斑岩的年龄、成因及源区一直未得到有效的约束.对青草山花岗闪长岩以及含矿花岗岩闪长斑岩进行了锆石年代学、Hf同位素以及岩石地球化学研究.结果显示,花岗闪长岩与含矿花岗闪长斑岩的侵入时代分别为131.2±0.3 Ma与117.9±0.8 Ma,代表了班公湖-怒江缝合带早期的成岩作用以及斑岩Cu-Au成矿作用.二者具有相似的地球化学特征,表明二者可能具有相同的岩浆源区,是不同时期同源岩浆活动的产物.结合含矿花岗闪长斑岩锆石Hf同位素组成,认为青草山含矿斑岩形成于班公湖-怒江洋壳向北俯冲过程中,是下地壳部分熔融的产物,受到了少量地幔物质的混合.      

Hydrothermal Alteration and Mineralization of Middle Jurassic Dexing Porphyry Cu-Mo Deposit, Southeast China

The Dexing deposit is located in a NE‐trending magmatic belt along the southeastern margin of the Yangtze Craton. It is the largest porphyry copper deposit in China, consisting of three porphyry copper orebodies of Zhushahong, Tongchang and Fujiawu from northwest to southeast. It contains 1168 Mt of ores with 0.5% Cu and 0.01% Mo. The Dexing deposit is hosted by Middle Jurassic granodiorite porphyries and pelitic schist of Proterozoic age. The Tongchang granodiorite porphyry has a medium K cal‐alkaline series, with medium K₂O content (1.94–2.07 wt%), and low K₂O/(Na₂O + K₂O) (0.33–0.84) ratios. They have high large‐ion lithophile elements, high light rare‐earth elements, and low high‐field‐strength elements. The hydrothermal alteration at Tongchang is divided into four alteration mineral assemblages and related vein systems. They are early K‐feldspar alteration and A vein; transitional (chlorite + illite) alteration and B vein; late phyllic (quartz + muscovite) alteration and D vein; and latest carbonate, sulfate and oxide alteration and hematite veins. Primary fluid inclusions in quartz from phyllic alteration assemblage include liquid‐rich (type 1), vapor‐rich (type 2) and halite‐bearing ones (type 3). These provide trapping pressures of 20–400 ´ 10⁵ Pa of fluids responsible for the formation of D veins. Igneous biotite from least altered granochiorite porphyry and hydrothermal muscovite in mineralized granodiorite porphyry possess δ¹⁸O and δD values of 4.6‰ and ?87‰ for biotite and 7.1–8.9‰, ?71 to ?73‰ for muscovite. Stable isotopic composition of the hydrothermal water suggests a magmatic origin. The carbon and oxygen isotope for hydrothermal calcite are ?4.8 to ?6.2‰ and 6.8–18.8‰, respectively. The δ³⁴S of pyrite in quartz vein ranges from ?0.1 to 3‰, whereas δ³⁴S for chalcopyrite in calcite veins ranges from 4 to 5‰. These are similar to the results of previous studies, and suggest a magmatic origin for sulfur. Results from alteration assemblages and vein system observation, as well as geochemical, fluid inclusion, stable isotope studies indicate that the involvement of hydrothermal fluids exsolved from a crystallizing melt are responsible for the formation of Tongchang porphyry Cu‐Mo orebodies in Dexing porphyry deposit.     

Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China

The Tongcun Mo porphyry deposit in northwest Zhejiang is hosted in three porphyry units: Huangbaikeng, Songjiazhuang, and Tongcun, from southwest to northeast. U–Pb zircon ages of 162?±?3.0 Ma for the Huangbaikeng porphyry, 159.9?±?3.0 Ma for the Songjiazhuang porphyry, and 167.6–155.6 Ma for the Tongcun porphyry indicate that these intrusions formed during the Jurassic and are most likely associated with the northwestward subduction of the Izanagi Plate. Trace element compositions of zircons from the Tongcun deposit constrain the oxygen fugacity (fO₂) of the magma using zircon Ce anomalies and Ti-in-zircon temperatures. The average magmatic fO₂ for the porphyries in the Tongcun deposit is fayalite–magnetite–quartz (FMQ)?+?2.7, which is similar to the Shapinggou (FMQ?+?3.2) and Dabaoshan (FMQ?+?3.5) Mo porphyry deposits, but much higher than that of the reduced Cretaceous ore-barren Shangjieshou porphyry (FMQ-1.1) around 8 km away from the Tongcun deposit. The distinct difference in magmatic oxygen fugacity between the Jurassic and Cretaceous porphyries may help to explain the absence of Mo porphyry mineralization in northwest Zhejiang during the Cretaceous.     

Geological Characteristics and Ore‐forming Time of the Dexing Porphyry Copper Ore Mine in Jiangxi Province

The Dexing porphyry copper ore mine is located in the Qin-Hang metallogenic belt between the Yangtze block and the Cathaysia block. It is a giant porphyry copper mine in China, including 3 ore districts: Tongchang, Fujiawu and Zhushahong. Our analyses of Re in molybdenite indicate that the ore-forming material of the copper ore deposits in Dexing should be mainly mantle-derived. Our study fills in a gap in the study of formation time of the Dexing copper mine, and further proves that the copper ore deposits in the three ore districts should be formed simultaneously, about 170 Ma, belonging to the early Yanshan period, and that the formation time of the copper ore deposits should be consistent with the formation time of granodiorite porphyry in which the copper ore deposits are hosted. Promising areas for seeking porphyry copper ore deposits is predicated to be the west or southwest of Dexing.