陕西凤太矿集区多金属成矿作用的构造控制

陕西凤县-太白(简称凤太)矿集区铅、锌、金、银、铜多金属资源丰富,已发现二十余个大中小型矿床。在大地构造位置上,凤太矿集区位于南秦岭造山带北缘,紧邻商丹缝合带。以往的工作缺乏对矿集区整体的构造研究,本次工作通过比较系统的构造测量和解析,提出在南秦岭晚三叠世碰撞造山过程中,凤太矿集区南北两条边界断裂带的左行走滑运动导致在区内衍生了NNE向主压应力场,从而形成了NWW向复式褶皱、脆韧性剪切带、断裂和节理(纵向破裂)、B型线理,以及NNE向断裂和节理(横向破裂)、劈理、张裂隙等一系列构造组合,所有构造形迹都是在统一构造应力场下随着构造层次不断抬升,脆韧性和脆性递进变形叠加的产物,共同构成了一个大型压扭性走滑双重构造变形系统。在构造几何学上,凤太矿集区整体上表现为一个隔档式复式褶皱,由一组NWW向紧闭复背斜和一组相对宽缓复向斜组成。区内的多金属成矿作用、岩浆活动、动力变质变形作用的同位素年龄数据集中于230~190Ma。综合地质演化和成矿作用的研究成果,提出在南秦岭碰撞造山过程中引发的动力变质变形作用和岩浆活动提供了成矿元素和成矿流体,在温压梯度以及浮力效应的驱动下向上运移至走滑双重构造变形系统中的有利扩容空间中发生充填型和交代型矿化,即凤太矿集区多金属矿床是区域大规模变形变质-岩浆活动-流体作用的产物,是在构造作用这一主导因素控制下形成的一个多金属后生热液成矿系统。     

陕西凤太矿集区柴蚂金矿床脉状闪锌矿Rb-Sr同位素测年及意义

柴蚂金矿床位于陕西省凤太矿集区西北部八卦庙超大型金矿床的西侧约0.5km处,二者在成矿地质背景和控矿条件等方面均相似。该矿床共划分出5个含矿带,其产出位置受地层和构造联合控制。本次工作对柴蚂金矿床中发育的脉状闪锌矿进行了Rb-Sr同位素测年研究,获得了等时线年龄为(210.8±2.4)Ma,即晚三叠世;闪锌矿的~(87)Sr/~(86)Sr_i值为0.710 55±0.000 11,指示铅锌矿化的成矿物质可能主要来源于大陆壳。结合前人的研究成果分析认为,凤太矿集区内的铅锌矿化和金矿化是在秦岭造山带印支期碰撞-后碰撞过程中同一时代同一成矿作用的产物。     

陕西凤太矿集区金、多金属矿产分布特征及成矿作用浅析

凤太矿集区矿产资源丰富。区内NWW向构造与NE向构造汇交成菱形格子状构造格局,奠定了凤太矿集区金、多金属矿产分布具有东西成带、北东成行的特征。铅锌、金都表现出“层控 构造 热流体”的特征。     

陕西省凤太矿集区二里河铅锌矿床的成矿时代: 来自闪锌矿Rb-Sr同位素年龄的证据

八方山-二里河铅锌矿床位于陕西凤县-太白(简称凤太)矿集区西北部,矿体主要产于中泥盆统古道岭组与上泥盆统星红铺组接触带中,受NWW向八方山-二里河背斜控制。本次工作对二里河铅锌矿床主成矿阶段的闪锌矿进行了Rb-Sr同位素测年研究,获得了等时线年龄为220.7±7.3Ma,表明矿床形成于晚三叠世,该年龄对于整个凤太矿集区的铅锌成矿时代具有同样约束意义。闪锌矿的⁸⁷Sr/⁸⁶Sr_i值为0.714145±0.000031,指示成矿物质可能主要来源于大陆壳。结合前人的研究成果分析认为,二里河铅锌矿床是凤太矿集区在印支期区域性强烈的构造-岩浆-成矿作用过程中的产物。     

陕西凤太矿集区铅锌矿床的成矿模型及其找矿意义

陕西凤太(凤县-太白)矿集区是南秦岭铅锌金多金属成矿带的重要组成部分,区内发育7个大中型铅锌矿床以及许多小型矿床(点)。关于铅锌矿床成因前人提出了多种观点,这些成因认识的根本分歧在于是同生成矿还是后生成矿,是一期成矿还是两期成矿。多年来笔者在凤太矿集区开展了比较全面的研究工作,文章综合这些研究成果,并结合近十年来有关的区域地质、矿产研究和找矿勘查工作等方面的新进展,系统论述了铅锌成矿地质特征、控矿因素、成矿流体和成矿元素来源,厘定成岩成矿时代和成矿动力学背景,建立成矿模型,并提出新的找矿方向。笔者认为凤太矿集区铅锌矿床形成于晚三叠世秦岭造山运动的后碰撞阶段,是区域大规模构造变形变质-岩浆作用-流体活动的产物,是同一期成矿事件中后生成矿流体在不同构造扩容空间充填交代形成不同矿化类型铅锌矿体,共同组成了一个多源流体成矿系统。根据成矿模型,提出了中泥盆世古道岭组灰岩的内部及灰岩与中酸性岩体接触带附近是今后深部找矿勘查的新目标。     

秦岭凤太矿集区铅锌金矿区域成矿规律研究

陕西秦岭凤太矿集区位于商丹缝合带和勉略缝合带之间,是著名的铅锌金多金属矿集区,区内发育海相沉积改造型铅锌矿和构造蚀变岩型金矿,成矿类型多样。在矿床地质特征、成矿地质条件、铅锌金矿时空分布规律、成矿流体来源研究分析的基础上,对凤太矿集区铅锌金矿成矿规律进行了剖析。认为凤太矿集区铅锌金矿床是多种成矿作用叠加改造形成的,早期泥盆纪热水沉积预富集形成矿胚,晚期印支—燕山期脆韧性变形-岩浆热液作用富集形成工业矿床。     

湘西北五伦铅锌矿床闪锌矿Rb-Sr定年及其地质意义

五伦铅锌矿床位于扬子陆块东南缘之江南（雪峰）造山带北西侧,是湘西北铅锌矿带内新近发现的热液脉型矿床.铅锌矿床产于万民岗背斜轴部,矿体沿NE向比铁溪-陈家河断裂旁侧派生的NW向断裂呈陡倾脉状产出,直接容矿围岩为奥陶系下统桐梓组和红花园组.对该矿床主成矿期的闪锌矿进行Rb-Sr等时线法定年,获得成矿年龄为238.9±4.5 Ma（MSWD=1.8）,（87Sr/86Sr）_i值为0.710 86±0.000 16,指示其主成矿期为中三叠世晚期.结合已有的成矿年代学资料,通过地球动力学背景探讨,结果表明湘西北地区至少存在两期铅锌成矿作用,分别对应于加里东期构造运动后伸展作用和印支早期华南陆块汇聚碰撞形成的局部伸展作用.五伦铅锌矿床的成矿物质应主要来源于含矿层之下成矿元素高含量的南华纪-寒武纪早期地层中的碎屑岩系,其较高的（87Sr/86Sr）_i值指示成矿过程中陆壳影响较为明显.      

佳木斯地块中部岩浆岩锆石U-Pb年代学、地球化学及其大地构造意义

佳木斯地块中部桦南隆起区广泛发育古生代-中生代岩浆岩,这些岩石的成因对深入探讨中亚造山带的形成演化具有重要的指示意义。LA-ICP-MS U-Pb定年和地球化学测试分析结果表明,研究区广泛分布的片麻状花岗闪长岩形成于中二叠世(267±2Ma),具有I型花岗岩的地球化学特征,表明其岩浆起源可能和俯冲板片产生的熔体有关,形成于岛弧构造环境。而正长花岗岩形成于中三叠世(244±2Ma),地球化学揭示其岩浆起源于下部陆壳物质的部分熔融,具有同碰撞花岗岩的地球化学特点。上述特征表明,研究区在中二叠世处于大陆边缘的构造背景,与古亚洲洋板块俯冲于佳木斯板块之下的构造作用相关,而中三叠世处于同碰撞的构造环境,俯冲此时已经消失,古亚洲洋已经最终闭合,因此三叠纪应该为中亚造山带重要的地质转折期。     

西秦岭夏河—合作地区与还原性侵入岩有关的金成矿系统及其动力学背景和勘查意义

西秦岭造山带是我国最重要的金成矿带之一。以往研究大多认为造山型金矿床和(类)卡林型金矿床是西秦岭主要的金矿床类型,并且两类金矿床的金成矿作用主要与造山过程中的区域变质作用有关,而与岩浆活动不存在直接的成因联系。位于西秦岭造山带西段的夏河—合作地区大面积出露花岗岩类侵入体,其周缘发育有富金的夕卡岩型铜(钨)矿床。近年来该地区新发现的多个大型—超大型石英脉型金矿床和微细粒浸染型金矿床都与中酸性侵入岩的空间关系紧密,暗示这些金矿床可能和岩浆活动有成因联系。论文在作者研究结果以及总结前人成果基础上,综述了夏河—合作地区典型金(铜)矿床的地质矿化特征、地球化学特征、时空分布特征,以及中酸性侵入岩的岩性特征、形成时代和演化过程。年代学研究结果显示,夏河—合作地区的早子沟微细粒浸染型金矿床、德乌鲁夕卡岩型金(铜)矿床和老豆石英脉型金矿床均形成于250~240 Ma,与邻近的早中三叠世花岗闪长质石英闪长质侵入岩近于同时形成。拉布在卡等石英脉型金矿床略晚于区内中三叠世末期侵位的闪长玢岩脉(约230~225 Ma)形成。H、O、S、C、B、Pb等多种同位素地球化学特征指示该地区早中三叠世金矿床的成矿热液均为岩浆来源,并且显示低氧逸度的特征。早中三叠世中酸性侵入岩的还原性钛铁矿系列花岗岩类特征,以及同时代的多种金矿化类型和成矿分带性,表明夏河—合作地区在早中三叠世(约250~230 Ma)多期次侵位的钛铁矿系列I型中酸性岩浆是金成矿作用的成矿流体和成矿物质的主要来源,其中与250~240 Ma多期金成矿事件有关的准铝质弱过铝质、高钾钙碱性系列花岗岩类侵入岩均经历了幔源基性熔体和壳源酸性熔体的岩浆混合作用,而与约230 Ma的金成矿作用有关的闪长质岩浆岩则可能指示了更多幔源基性熔体的加入。与金(铜)成矿有关的早中三叠世还原性中酸性岩是在古特提斯洋俯冲过程中局部弧后伸展条件下交代富集地幔楔部分熔融形成的基性岩浆与壳源酸性岩浆混合作用的产物。夏河—合作地区形成于早中三叠世的夕卡岩型、电气石石英脉型、石英方解石脉型和微细粒浸染型金矿床共同构成了一个与还原性侵入岩有关的金成矿系统。夏河—合作地区与还原性侵入岩有关的金成矿系统的发现,丰富了西秦岭造山带区域成矿作用的类型,并为西秦岭西段其他早中三叠世岩浆岩分布区(如青海同仁地区)的金矿勘查工作提供了新的思想和方向。     

西秦岭西成矿集区厂坝岩体的钼矿化特征及其Re-Os年龄

甘肃西成矿集区是西秦岭最重要的多金属成矿区之一,以铅锌矿床为主,其次发育有金、铜、钼等矿床(点)。厂坝黑云母二长花岗岩体位于西成矿集区中东部,岩体南缘接触带部位发育石英脉型钼矿,辉钼矿呈中粗粒半自形团块状产于粗粒石英脉内。Re-Os同位素年代学研究表明,其模式年龄范围为207.7±3.0~209.8±2.8Ma,加权平均年龄为208.9±1.1 Ma,等时线年龄为209±15 Ma,指示钼矿化发生于晚三叠世。辉钼矿的铼含量介于18.82×10~(-6)~21.97×10~(-6)之间,平均19.65×10~(-6),表明成矿物质主要为壳幔混合来源,可能以壳源为主。钼矿化与区域岩浆活动以及金、铅锌成矿作用时代相近,是印支期区域构造-岩浆-流体活动的产物。钼矿化年龄的厘定为区内找矿提供了新的思路。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Total mercury and monomethylmercury in water, sediments, and hydrophytes from the rivers, estuary, and bay along the Bohai Sea coast, northeastern China

Mercury contamination in aquatic environments is of worldwide concern because of its high biomagnification factor in food chains and long-range transport. The rivers, estuary and the bay along the northwestern Bohai Sea coast, northeastern China have been heavily contaminated by Hg due to long-term Zn smelting and chlor-alkali production. This work investigated the distributions of total Hg (THg) and monomethylmercury (MMHg) in the water, sediment and hydrophytes from this area. Concentrations of THg in sediment (0.5–64 mg kg⁻¹) and water (39–2700 ng L⁻¹) were elevated by 1–3 orders of magnitude compared to background concentrations, which induced high concentrations of MMHg in these media. The highest concentration of MMHg in sediment reached 35 μg kg⁻¹, which was comparable to that in the Hg mining area, Wanshan, China, and the highest MMHg concentration of 3.0 ng L⁻¹ in the water sample exceeded the MMHg Chinese drinking water guideline of 1.0 ng L⁻¹. Concentrations of THg in a sediment profile from Jinzhou Bay were found to be consistent with annual Hg emission flux from a local Zn smelter (r = 0.74, p < 0.01), indicating that Hg contamination was mainly caused by Zn smelting locally. For some freshwater hydrophytes, concentrations of THg and MMHg ranged from 5.2 to 100 μg kg⁻¹ and 0.15 to 12 μg kg⁻¹, respectively. Compared to sediment, concentrations of THg in hydrophytes were 2–3 orders of magnitude lower but MMHg was comparable or higher, indicating that the bioaccumulation in plants was distinct for the two Hg species studied. The data suggest that a significant load of Hg has been released into the northwestern coastal region of the Bohai Sea.     

Metals,arsenic, and sulfur in the Aue and Eibenstock granites,Erzgebirge

Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO _Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO _Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.     

Text, talk, things, and the subpolitics of performing place

This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.     

Distribution of REE,LILE, and HFSE between biotite,feldspar, and the melt in the granulite facies migmatite,nimnyr block,Aldan shield

The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt D_i^min/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE D_i are a little below 1, while those of LREE, especially D_i for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the D_i of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.     

Dielectric constants of apatite,epidote, vesuvianite,and zoisite,and the oxide additivity rule

The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ _a=9.93 tan δ=0.006 κ′ _c=9.79 tan δ=0.005 vesuvianitel κ′ _a=10.02 tan δ=0.002 κ′ _c=9.85 tan δ=0.003 zoisite1 κ′ _a =10.49 tan δ=0.0006 κ′ _b =15.31 tan δ=0.0008 κ′ _c=9.51 tan δ=0.0008 zoisite2 κ′ _a =10.55 tan δ=0.0011 κ′ _b =15.45 tan δ=0.0013 κ′ _c=9.39 tan δ=0.0008 epidote κ′ ₁₁= 9.52 tan δ=0.0008 κ′ ₂₂=17.1 tan δ=0.0009 κ′ ₃₃= 9.37 tan δ=0.0006 fluorapatite1 κ′ _a =10.48 tan δ=0.0008 κ′ _c = 8.72 tan δ=0.0114 fluorapatite2 κ′ _a =10.40 tan δ=0.0010 κ′ _c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α _D (mineral)=∑ α _D (oxides) for vesuvianite is ～ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (V_o) is believed to affect the total polarizabilities, the variation of V_o in these Ca minerals is too small to observe the effect.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.