多硅白云母b0值对澜沧群中压和高压变质的反映

多硅白云母b₀值作为相对地质压力计的理论和方法,已受到各国地质学家的普遍重视。本文以澜沧群多硅白云母作为研究对象,提出运用多硅白云母b₀值区分不同压力变质的方法。研究结果表明澜沧群经历了中压和高压变质作用,两期变质的多硅白云母b₀值分别为9.027Å和9.047Å。     

东帕米尔北缘韧性剪切带中的多硅白云母及其地质意义

本文系统地研究了东帕米尔北缘韧性推覆剪切带内糜棱岩中的多硅白云母，电子探针分析和Ｘ射线衍射测试：从剪切带边缘→中心，多硅白云母硅平均含量为３．２０３４→３．３６０９；晶胞参数ｂ０值为９．０２４→９．０２７→９．０４１→９．０４５，其物相均为２Ｍ１型。发现糜棱岩中局部夹有硅线石，糜棱岩组合之上还发育数层红帘石石英岩。多硅白云母Ｋ－Ａｒ年龄平均值为３６．９５±１．２Ｍａ。故此确定该剪切带糜棱岩形成于低温（局部可达高温）、中至高压环境，形成时代为始新世末（３７Ｍａ）。     

多硅白云母地质压力计的研究进展

白云母是变质岩中分布最广泛的矿物之一,在大多数矿物组合中白云母的Si含量随着变质作用压力的增加而增加,可作为地质压力计。对KMASH体系3个有限组合中多硅白云母的Si含量与温压条件关系的实验研究结果表明,多硅白云母Si含量地质压力计明显与矿物组合有关。因此,不能把这些实验结果简单地外延到矿物组合不同的天然岩石中。在KMASH体系的温压视剖面图上模拟白云母的Si含量等值线与质量较好的实验结果非常接近,由此可以把这种方法推广到KFMASH或更复杂的体系中。在利用多硅白云母Si的含量确定天然矿物组合的变质作用压力时,最好利用视剖面图的方法。     

多硅白云母压力计在退变质作用中的稳定性探讨

探讨多硅白云母地质压力计在低温退变质过程中的稳定性，在对大别山东缘和苏鲁造山带西缘郯庐左旋走滑韧性剪切带糜棱岩中的多硅白云母残斑由中心向两侧边缘进行电子探针分析后发现：由中心向两侧边缘Si减少,Al增加,Fe，Mg略有降低，部分样品中K，Na有不同程度的增加．而Ti则显示不活动富集。这是由于退变质过程中流体的活动常会改变残斑白云母的成分．并且在流体活动过程相对短暂的情况下，使残斑白云母的成分不能发生充分变化．最终会导致白云母不同部位具有不同的成分。因而,经历了富流体活动的退变质作用后,岩石中的多硅白云母残斑已不能完全保存其形成时的压力信息。     

宿松杂岩中白云母的矿物学特征及地质意义

大别山为印支期扬子陆块和华北陆块之间的碰撞造山带。太湖—宿松地区位于大别山东段部位,主要由扬子陆块北缘不同变质程度的变质基底和少量浅变质盖层组成。本文选择了宿松杂岩中的白云母进行探针分析以及X射线粉末衍射分析,研究结果表明宿松杂岩中的白云母都是2M₁型且均为多硅白云母。其中,多硅白云母的晶胞参数b₀平均值为9.039,显示宿松杂岩的变质压力为中压—高压。根据宿松杂岩中白云母的显微变形特征可以知道白云母至少存在着两期变形,一期是导致石榴子石压力影形成和白云母右旋的构造作用,应该对应着燕山期大别造山带中-下地壳物质发生平行造山带向东流动的地质事件。另一期是导致白云母形成涡流构造形成的构造作用,这一期构造应该对应扬子板块和华北板块碰撞事件。根据白云母中的Ti温度计和多硅白云母压力计可以得出宿松杂岩的变质条件为T=480 ℃～579 ℃,P=0.7～1.2 GPa,属于绿片岩相到角闪岩相。     

滇西澜沧变质带中白云母b_0值特征及其多期变质作用意义

滇西澜沧变质带中199件白云母b_0值分析结果表明,b_0值均在0.9020nm以上。与澜沧变质带遭受蓝片岩相高压变质作用的事实相吻合。此外,白云母b_0值的统计规律显示,澜沧变质带经历了多期变质作用,一期为高压变质作用,另一期为中压变质作用,这也与已知的地质现象相符。由此可见,白云母b_0值可以很好地反映多期变质作用。     

五台山腹地早前寒武纪变质岩中白云母的初步研究

五台山早前寒武纪变质岩中的白云母属二八面体的2M型多型变体,其中五台群中的白云母为富含绿鳞石分子的普通白云母,滹沱群为多硅白云母。通过对这些白云母化学成分和b_0值测定,确定五台群变质条件属中低压相系,滹沱群属中高压相系。五台群绿片岩相的变质压力为0.3—0.5 GPa,滹沱群为0.5—0.6 GPa。基于白云母成分和b_0值的研究,对划分变质级别、变质类型;确定变质作用期次;进行地层对比和构造分析等方面是可行的。     

滇西澜沧变质带变质作用和变形作用的关系

滇西澜沧变质带经历了两期变质变形事件，其时代分别为５１９Ｍａ和２８０～１９０Ｍａ。早期变质变形事件（Ｍ１Ｄ１）可由销长石和石榴石变斑晶的包裹体痕迹确定，形成近Ｅ－Ｗ向的变形构造格局。晚期变质变形作用（Ｍ２Ｄ２）以形成蓝片岩相矿物组合，如以蓝门石（青铝门石）＋多硅白云母＋绿泥石＋石英等为特征，并形成近Ｎ－Ｓ向的变形构造格局．钠质问石以青铝闪石和蓝闪石为主，白云母多为３Ｔ＋２Ｍ；型多硅白云母，其ｂｏ均值在９．０４０Ａ以上；蓝片岩相变质作用的Ｐ、Ｔ条件估计分别为０．６～０．７ＧＰａ和３００℃。晚期变质变形事件经历了二个主要阶段（Ｍ２ａＤ２ａ和Ｍ２ｂＤ２ｂ），分别伴随透入性面理（Ｓ２）和褶劈理（Ｓ３）的形成，蓝门石的４０Ａｒ－３９Ａｒ定年分别为２７９Ｍａ和２１４Ｍａ；Ｍ２ｃＤ２ｃ期局部受到热的扰动，以及出现大量的膝折带或宽缓褶皱。上述变质变形演化历史代表了澜沧变质带的隆升及剥蚀过程。     

大别山变质带的多硅白云母

白云母是变质岩中广泛分布的一种变质矿物,其特征与变质作用的密切关系已引起人们的极大重视。尤其是2M型和3T型多硅白云母,是高压低温变质带的特征矿物之一,有着重要的地质意义。1976年,河南信阳一带首次发现了我国2M型和3T型多硅白云母。1978年,我们对大别山进行地质调查时发现2M型和3T型多硅白云母广泛出现于该区的各变质带内,并对它们进行了矿物学研究,现将结果报导如下。     

西藏东部嘉玉桥变质杂岩内中侏罗世高压剪切作用:来自多硅白云母的证据

藏东嘉玉桥变质杂岩分布于班公错-怒江缝合带南西,出露宽度约15～20km,延伸长度约120km。藏东嘉玉桥变质杂岩与上覆中侏罗统呈滑脱断层接触,滑脱带内发育各种韧性剪切组构。滑脱带内钠长石英构造片岩中石英呈矩形条带,多硅白云母与石英矩形条带构成S-C组构,石英颗粒应变测量表明Flinn图解K=∞,代表近水平伸展滑脱。获得多硅白云母变质条件相当于蓝片岩相,压力属于高压变质相,多硅白云母测年结果为167.27±0.99 Ma,为中侏罗世高压剪切作用,暗示班公-怒江缝合带中侏罗世伸展与高压剪切作用密切相关。     

Zoning and recrystallization of phengitic micas: implications for metamorphic equilibration

White micas (phengites) in the metasediments of the Scottish Dalradian display a large range of compositions within single samples. The variations in the composition of these phengites are strongly controlled by their structural age, with early fabrics containing a paragonite-poor, celadonite-rich phengite whereas in later fabrics the micas are generally paragonite-rich and celadonite-poor. Retrograde phengite growth, identified using back scattered electron imaging, occurs as celadonite-rich rims on micas within all existing fabrics and appears to be preferentially developed along existing white mica-plagioclase grain boundaries. The presence of these chemically distinct phengite populations within single samples implies that chemical exchange between the individual micas was inefficient. It is proposed that diffusion-controlled exchange reactions in phengites have relatively high closure temperatures below which major element exchange is effectively impossible. This closed system behaviour of micas questions the ease with which phengites may equilibrate with other phases during prograde greenschist and lower amphibolite facies metamorphism. Many of the chemical variations preserved in phengites from such metamorphic rocks may reflect deformation/recrystallization controlled equilibria.     

滇西澜沧变质带中白云母的研究及其地质意义

本文以滇西澜沧变质带中最为广泛分布的造岩矿物—白云母为对象，详细研究和 分析了其成分、多型类型及ba值等，探讨了白云母的发育规律。研究结果表明，本带中绝大多数白云母为多硅白云母，且为3T+2M,型，与蓝闪石共生的则以3T多硅白云母为主。此外，斓沧变质 带经历了蓝闪石片岩亚相的高压变质作用，与古特提斯构造演化密切相突，并可与世界著名的高 压带对比。     

40Ar/39Ar dating of white micas from an Alpine high-pressure metamorphic belt on Naxos (Greece): the resetting of the argon isotopic system

Overprinting of white micas from high pressure, low to medium temperature (M ₁) metamorphic assemblages in pelitic schists on Naxos during subsequent thermal dome (M ₂) metamorphism ranges from minor in the southeast of the island to complete recrystallization in the amphibolite facies rocks near the migmatites in the centre of the dome. The original (M ₁) minerals are phengites (Si⁴⁺=6.7–7.0) and the overprinting minerals are muscovites (Si⁴⁺=6.0–6.45). ⁴⁰Ar/³⁹Ar step heating analyses of white mica separates from rocks in the area where phengite and muscovite occur together yield complex age spectra, characterized by low apparent ages in the first and the last stages of gas release and high apparent ages in between. These upward-convex age spectra are shown to be caused by mixing of two generations of micas, each of which has a different age spectrum and argon release pattern. Seemingly good plateaus in some age spectra from white micas of the area must be interpreted as providing meaningless intermediate ages. Further, the upward-convex age spectra have been used to trace the isotopic signature of phengites toward increasing M ₂ metamorphic grade, and suggest that as long as phengites can be observed in the rocks upward-convex age spectra occur. On Naxos, crystallization of muscovite at the expense of phengite appears to be the main mechanism of resetting argon isotopic ages in white micas. However, there is also good evidence for argon loss by volume diffusion from phengites. Simple diffusion calculations suggest that the M ₂ metamorphism was caused by a shortlived heat source.Now at Department of Geology, University of Alberta, Edmonton T6G 2E3, Canada     

Polymetamorphic evolution of pelitic schists and evidence for Permian low-pressure metamorphism in the Vepor Unit, West Carpathians

Phase equilibrium modelling and monazite microprobe dating were used to characterize the polymetamorphic evolution of metapelites from the northern part of the Vepor Unit, West Carpathians. Three generations of garnet and associated metamorphic assemblages found in these rocks correspond to three distinct metamorphic events related to the Variscan orogeny, a Permian phase of crustal extension and the Alpine orogeny. Variscan staurolite‐bearing and Alpine chloritoid‐bearing assemblages record medium‐temperature and medium‐pressure regional metamorphisms reaching 540–570 °C/5–7.5 kbar and 530–550 °C/5–6.5 kbar respectively. The Permian metamorphic assemblage involves garnet, andalusite, sillimanite, biotite, muscovite, plagioclase and corundum and locally forms silica‐undersaturated andalusite‐biotite‐spinel coronas around older staurolite. The transition from andalusite to sillimanite indicates a prograde low‐pressure and medium‐temperature metamorphism characterized by temperature increase from 500 to 650 °C at ～3 kbar. As accessory monazite is abundant in the rocks, an attempt was made to derive its age of formation by means of electron microprobe‐based Th‐U‐Pb chemical dating. Despite the polymetamorphic nature of the metapelites, the monazite yielded uniform Permian ages. Microstructures confirm that monazite was formed in relation to the low‐pressure and medium‐temperature paragenesis, and the weighted average ages obtained for two different samples are 278 ± 5 and 275 ± 12 Ma respectively. The virtual lack of Variscan and Alpine monazite populations points to interesting aspects concerning the growth systematics of monazite in metamorphic rocks.     

胶东元古宙变质硅质岩的地球化学及其成因

胶东元古宙变质硅质岩为蛇绿岩端员组分一，其SiO2含量大于高于90％，具轻稀土富集型的稀土配分模式，铕，铈异常具有明显的相关性，岩石中多硅白云母的存在显示其曾经受了中－高压的变质作用，变质硅质岩 地球化学特征表明其原岩形成于早元古宙的大洋中脊环境，沉积成 岩时的氧化还原条件是变化的，产同蛇绿岩其他端员组分一起发生过深腐冲作用。     

K — Ar age determinations on phengites from the internal part of the Sesia Zone,Western Alps,Italy

K-Ar age determinations have been carried out on various, well-defined phengite populations from a small area of the internal part of the Sesia Zone, lower Aosta valley. There, the rocks have suffered high-pressure metamorphism, attributed to early Alpine subduction, in the stability field of jadeite + quartz (P15±1 kbar at T=550±50° C). Coarse-grained phengites from well-preserved high-pressure parageneses, and phengites (re)crystallized early during decompression at still elevated temperatures in the stability field of albite, yield identical ages close to 80 Ma. In the most external sample high-pressure phengites yield 72 Ma. The ages around 80 Ma are interpeted as essentially undisturbed cooling ages; they are not notably influenced by paragenesis, chemical composition, polymorphism, grain-size, deformation, and recrystallization at higher temperatures. This part of the Sesia Zone has cooled down about 80 Ma ago to below the blocking temperature for the K-Ar system of white mica. Some of the samples show pronounced retrogression of the high-pressure assemblages, especially formation of albite and fine-grained phengite at the expense of jadeite, and are affected by intense late deformation at temperatures of about 300 to 350° C, estimated from the small grain-size of dynamically recrystallized quartz. The ages obtained from extremely kinked or sheared coarse high-pressure phengites scatter considerably, being partly higher, partly lower than 80 Ma. The fine-grained phengite fractions from these samples yield lowered ages down to 70 Ma. These values are interpreted as mixed ages resulting from variable mixtures of fragmented high-pressure phengites and new phengite replacing jadeite; the K-Ar data suggest that the new phengites have crystallized between 60 and 70 Ma b.p. All phengites formed at low temperatures at the expense of jadeite reveal high Si-contents; these range up to 6.9 for the coarser-grained earlier generations, and up to 6.7 for the very fine-grained last generation. Relatively high pressures are required to stabilize phengites so high in Si. This implies that cooling had not been achieved by uplift and erosion; obviously the thermal structure of the crust was still strongly perturbed by continuing subduction and thrusting during the late Cretaceous.     

北秦岭造山带的早古生代多期变质作用

北秦岭造山带的秦岭岩群以高级变质岩石为特征,主要包括少量榴辉岩、高压麻粒岩和区域上广泛分布的麻粒岩-角闪岩相变质岩石。年代学研究显示秦岭岩群中不同岩石记录了多期变质作用。已有的定年资料给出北秦岭官坡地区的榴辉岩的年龄为500Ma左右,代表榴辉岩相的变质时代。结合岩相学资料,对两个高压麻粒岩样品的SHRIMP和LA-ICPMS U-Pb测定分别获得504±7Ma 和506±3Ma的年龄,应代表高压麻粒岩相变质时代。这表明高压麻粒岩和相邻的榴辉岩有相近的变质时代,但形成在造山带中不同的构热造环境中。西峡地区的角闪二辉麻粒岩的U-Pb定年给出两组早古生代年龄,一组为440±2Ma,可能代表了中低压麻粒岩相的变质时代,另一组为426±1Ma,应代表区域角闪岩相的变质时代。桐柏山北部的石榴二辉麻粒岩的U-Pb定年数据给出436±1Ma的年龄,为中压麻粒岩相的变质时代。这些资料表明北秦岭造山带经历了早奥陶世的俯冲和地壳增厚作用,并在晚志留世遭受了广泛的巴罗式区域变质作用。     

滇西时代不明变质岩系的解体和时代厘定

建立在岩石组合、变质、变形、碎屑组分和同位素年代学基础上的研究成果表明,滇西时代不明变质岩系是两个时代不同的构造岩片,分别相当于中元古界崇山群和二叠系吉东龙组,二者是喜山期构造混杂带的重要组成部分。崇山群在晚元古时期(727～956 Ma)发生区域性的动热变质作用,加里东时期(397 Ma)又叠加了一次变质作用。吉东龙组中有喜山期(32 Ma)变质作用的叠加。     

贵州上二叠统炼焦煤分布成因解析

贵州上二叠统炼焦煤在平面上呈χ型环带状分布特征,通过对该地区深成热变质作用、莫霍面抬高热力异常及岩浆岩分布特征的分析,认为上覆地层及地温梯度影响的深成变质作用是贵州上二叠统炼焦煤呈χ型环带状分布的主控因素,莫霍面抬高形成的地热异常是对这个主控因素的加强,峨眉山玄武岩的楔形分布及研究区大地热流值从西向东的逐渐递减的分布形态是炼焦煤呈χ型环带状分布的不利因素,而燕山期小型侵入体在黔东部的较强活动则刚好是这个不利影响因素的弥补。总之,几种热叠加变质的综合作用,可较好地解释贵州上二叠统炼焦煤呈χ型环带状分布的独特现象。