大兴安岭北部主要金属矿床成矿系列和区域矿床成矿谱系

文章以大兴安岭北部内生金属矿床、海相火山岩型硫铁矿矿床和砂金矿床为研究对象,按照矿床成矿系列的学术思想将其划分为7个矿床成矿系列,即:多宝山地区与加里东期中酸性火山_侵入活动有关的铜、钼矿床成矿系列,呼玛地区与华力西期辉长岩和花岗岩有关的铁、钛、金矿床成矿系列,伊尔施_黑河地区与华力西期花岗岩和海相火山岩有关的铁、铜、锌、硫铁矿矿床成矿系列,牙克石地区与华力西期海相中基性火山岩有关的铁、锌、硫铁矿矿床成矿系列,得尔布干地区与印支期_燕山期中酸性火山_侵入活动有关的铅、锌、银、铜、钼、金矿床成矿系列,伊尔施_呼玛地区与燕山期中酸性火山_侵入活动有关的金、铁、锌、铜、钼、钨矿床成矿系列和黑龙江流域与第四纪冲积沉积作用有关的砂金矿床成矿系列。大兴安岭北部区域矿床成矿谱系表明,从奥陶纪到新生代该区不同构造单元经历了7个主要的构造演化及成矿时期,依次出现奥陶纪岛弧环境的斑岩型矿床、泥盆纪陆块边缘拉张环境的岩浆型和热液脉型矿床、泥盆纪—石炭纪俯冲_碰撞环境的海相火山岩型和矽卡岩型矿床、石炭纪弧后盆地环境的海相火山岩型矿床、晚三叠世—早白垩世俯冲_碰撞_后碰撞环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床、早侏罗世—早白垩世俯冲环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床和新生代地壳差异运动带砂金矿床。大兴安岭北部优势矿种为铜、钼、金、银、铅、锌,主攻矿床类型为斑岩型、热液脉型、低硫化浅成低温热液型、冲积型和海相火山岩型。     

青海省枪口南银多金属矿床地质特征、控矿因素及矿床成因

枪口南银多金属矿床地处东昆仑多金属成矿带东段,枪口—哈龙休玛海西-燕山期铁、银、铅、锌、铜、金、钼成矿亚带部分,成矿地质条件优越。枪口南银多金属矿区目前已圈定9条矿化带,21个矿体,主要矿种有金、银、铜、铅、锌、钼等,矿石类型主要为构造热液(脉)型铜铅锌银矿石、构造蚀变岩型金矿石。枪口南矿区构造-岩浆活动强烈,印支期—燕山期构造岩浆活动为矿区成矿提供了热源、成矿物质,区内NE向断裂控制区内金、铜、铅锌等矿体的产出,NW向断裂组控制着区内金、银矿(化)体。NW向断裂组,是区内重要控矿构造;区内中部发现的Ⅳ号含矿斑岩体,具有斑岩型矿床蚀变特征,显示其具有斑岩成矿条件。枪口南银多金属矿床成因有构造热液(脉)型、构造蚀变岩型和斑岩型。     

U–Pb and Re–Os Geochronology of the Tongcun Molybdenum Deposit and Zhilingtou Gold‐Silver Deposit in Zhejiang Province,Southeast China,and Its Geological Implications

Mesozoic ore deposits in Zhejiang Province, Southeast China, are divided into the northwestern and southeastern Zhejiang metallogenic belts along the Jiangshan–Shaoxing Fault. The metal ore deposits found in these belts are epithermal Au–Ag deposits, hydrothermal‐vein Ag–Pb–Zn deposits, porphyry–skarn Mo (Fe) deposits, and vein‐type Mo deposits. There is a close spatial–temporal relationship between the Mesozoic ore deposits and Mesozoic volcanic–intrusive complexes. Zircon U–Pb dating of the ore‐related intrusive rocks and molybdenite Re–Os dating from two typical deposits (Tongcun Mo deposit and Zhilingtou Au–Ag deposit) in the two metallogenic belts show the early and late Yanshanian ages for mineralization. SIMS U–Pb data of zircons from the Tongcun Mo deposit and Zhilingtou Au–Ag deposit indicate that the host granitoids crystallized at 169.7 ± 9.7 Ma (2σ) and 113.6 ± 1 Ma (2σ), respectively. Re–Os analysis of six molybdenite samples from the Tongcun Mo deposit yields an isochron age of 163.9 ± 1.9 Ma (2σ). Re–Os analyses of five molybdenite samples from the porphyry Mo orebodies of the Zhilingtou Au‐Ag deposit yield an isochron age of 110.1 ± 1.8 Ma (2σ). Our results suggest that the metal mineralization in the Zhejiang Province, southeast China formed during at least two stages, i.e., Middle Jurassic and Early Cretaceous, coeval with the granitic magmatism.     

秦岭成矿带成矿特征和找矿方向

秦岭成矿带是我国有色、贵金属工业的重要矿产资源基地,也是最具成矿潜力和找矿远景的地区之一。近年的综合研究工作表明,秦岭造山带是一个多旋回复合大陆碰撞造山带,自太古代以来经历了多种构造体制的转化和多期构造热事件发生,伴随有多个构造成矿旋回,所形成的含矿建造、成矿作用及矿床组合具有多样性。根据成矿时代、构造、建造、成矿作用及矿床组合特征分析,认为秦岭造山带铜、钼、铅、锌、银、金、汞、锑等内生金属矿床主要受7个主要的成矿系统控制,形成了18个主要成矿系列,并对各成矿系列及其典型矿床的地质特征和近几年找矿新发现进行了系统的论述,建立了铜、金、铅、锌、银等矿床系列的区域成矿模式。对区域优势矿种的成矿谱系研究表明,本区成矿在时间演化上表现出明显多旋回性、继承性、新生性和叠加性特征,华力西期与印支末-燕山期是成矿大爆发期,最有利于大型超大矿床形成;在空间分布上,具有明显的侧向和垂向分带性。在此基础上,对秦岭成矿带的成矿潜力及成矿远景区进行了评价和划分,指出秦岭地区热水喷流沉积型与密西西比型铅锌银矿床、微细浸染型与石英脉构造蚀变岩型金矿床、斑岩型钼钨铜矿床及低温热液型汞锑矿床等具有很大的找矿前景。并划分出5个区域成矿远景带和17个重要成矿预测区。     

东昆仑祁漫塔格成矿带矿床类型、时空分布及多金属成矿作用

基于笔者近几年对东昆仑祁漫塔格地区的野外调查和室内岩矿测试分析研究,综合论述了祁漫塔格成矿带的成矿地质背景、多金属矿床的主要类型、基本特征、时空分布和成矿作用特点。该区金属成矿元素组合复杂,矿床类型多样,矿种以F e、Cu、Pb、Zn、M o、W、Sn、A u为主,矿床类型主要有矽卡岩型、斑岩型、沉积-改造型和高温热液型等。探讨了祁漫塔格地区多金属矿床的成岩成矿时代、成矿物质和成矿流体来源,以及成矿地球动力学背景。提出中—晚三叠世和早古生代晚期是本区重要的成矿时期;形成于中—晚三叠世的斑岩型和矽卡岩型矿床金属成矿物质主要来源于岩浆和含碳酸盐岩地层,成矿流体主要来源于岩浆水,两者系同一构造岩浆活动在不同阶段、不同深度和不同部位发生成矿作用的产物。     

Metal deposits in the Da Hinggan Mountains,NE China: styles,characteristics, and exploration potential

The Da Hinggan Mountains mineral province (DHMP), northeastern China, is divided into three tectonic units and corresponding metallogenic belts. The tectonic units of the Da Hinggan Mountains are the Erguna fold zone on the northwest, the Hercynian fold zone on the north, and the Hercynian fold zone on the south. The corresponding metallogenic belts are the Erguna Cu-Pb-Zn-Ag-Mo-Au belt of the NW DHMP, the Cu-Pb-Zn-Mo-Fe-Au belt of the northern DHMP, and the Pb-Zn-Ag-Cu-Sn-Fe-Mo belt of the southern DHMP. Distinct ore bodies, mostly associated with Mesozoic granites and volcanics, comprise (1) hydrothermal vein deposits including Pb-Zn-Ag-(Cu) and W‐Sn-Cu, (2) exhalative (Pb-Zn-Ag, Cu) deposits, (3) porphyry (Cu, Au, Mo), (4) skarn (Fe, Zn, Cu), and (5) epithermal Au-Ag deposits. The hydrothermal veins are hosted by a range of different rock types, whereas the exhalative ores are confined to Permian strata. The porphyry deposits occur within granite porphyries. The epithermal deposits are related to Mesozoic volcanic-subvolcanic rocks and occur within superjacent igneous structures. The first type, represented by the Bairendaba deposit, shows many characteristics of hydrothermal deposits. The second type occurs in a Permian clastic-chemical sedimentary sequence. Most Fe-Zn-Cu deposits related to granites and granodiorites are skarns. Granodiorite and granite-related deposits are typical porphyry ores, formed during Hercynian and Mesozoic time. Promising metallogenic conditions and the recent discovery of many large metal deposits indicate that this mineral province has a great exploration potential.     

西藏冈底斯东段构造演化及铜金多金属成矿潜力分析

地质、物探、化探、遥感的综合研究表明，西藏冈底斯东段蕴含着巨大的找矿潜力，矿化类型齐全，以斑岩型及喷流型为主。与构造演化相关形成四大成矿系列：与新特提斯洋壳俯冲作用（125－96Ma）有关的岩浆型（Cr，Pt，Cu，Ni）矿床系列及喷流型（Cu，Pb，Zn，Ag）矿床系列；与弧－陆碰撞造山作用（85－50Ma）有关的浅成低温热液型（Au，Ag，Pb，Zn，Sb）、构造蚀变岩型（Au）及矽卡岩型（Cu）矿床系列；与造山期后伸展走滑作用（22－12Ma）有关的斑岩型（Cu，Mo）、隐爆角砾岩型（Cu，Au，Pb，Zn）、剪切带型（Au，Ag，Sb）及矽卡岩型（Cu，Fe）矿床系列。由俯冲杂岩带向北，具有由结晶分异型（熔离型）－剪切带型（蚀变岩型）－矽卡岩型、浅成低温热液型－斑岩型－斑岩型十喷流型－喷流型－热液充填交代型的分带趋势，成矿总体显示出同源多位、同位多期、深源浅成、多因复成的特点。     

http://www.sciencedirect.com/science/article/pii/S1674987114000711

The West Junggar region,located in the loci of the Central Asian Orogenic Belt,is a highly endowed metallogenic province with >100 tonnes Au,>0.7 Mt Cu,>0.3 Mt Mo,and >2.3 Mt chromite as well as significant amounts of Be and U.The West Junggar region has three metallogenic belts distributed systematically from north to south:(1) late Paleozoic Saur Au-Cu belt;(2) early Paleozoic XiemisitaiSharburt Be-U-Cu-Zn belt;(3) late Paleozoic Barluk-Kelamay Au-Cu-Mo-Cr belt.These belts host a number of deposits belonging to at least eight economically important styles,including epithermal Au,granite-related Be-U,volcanogenic massive sulfide(VMS) Cu-Zn,podiform chromite,porphyry Cu,hydrothermal quartz vein Au,porphyry-greisen Mo(-W),and orogenic Au.These deposit styles are associated with the tectonics prevalent during their formation.Five tectonic-mineralized epochs can be recognized:(1) Ordovician subduction-related VMS Cu-Zn deposit;(2) Devonian ophiolite-related podiform chromite deposit;(3) early Carboniferous subduction-related epithermal Au and porphyry Cu deposits;(4) late Carboniferous subduction-related granite-related Be-U,porphyry Cu,and hydrothermal quartz vein Au deposits;and(5) late Carboniferous to early Permian subduction-related porphyry-greisen Mo(-W) and orogenic Au deposits.     

Copper-Polymetal Metallogenic Series and Prospecting Perspective of Eastern Section of Gangdise

Geological, geophysical, geochemical and remote sensing comprehensive studies show that big ore-prospecting potentiality is contained in the eastern section of the Gangdise Mountains, Tibet.There are various mineralization types with dominant types of porphyry and exhalation. According to their relations with tectonic evolution, they are divided into four kinds of metallogenic series as follows:magnmtic type (Cr, Pt, Cu, Ni) and exhalation type (Cu, Pb, Zn, Ag) ore deposit series related to Neo-Tethys oceanic crust subduction action (125-96 Ma); epithermai type (Au, Ag, Pb, Zn, Sb), altered fractured rock type (Cu, Mo) and skarn rock type (Cu) ore deposit series related to arc-continental collision; porphyry type (Cu, Mo), cryptoexplosion breccia type (Cu, Au, Pb, Zn), shear zone type (Au, Ag, Sb) and skarn rock type (Cu, Fe) ore deposit series with relation to post-orogenic extensional strike-slip. From subductive complex to the north, zoning appears to be crystallization differentiation type (segregation type)-shear zone type (altered rock type)-skarn rock type, epithermai type-porphyry type-porphyry type and exhalation type-exhalation type-hydrothermai filling-replacement type.The ore deposit is characterized by multi-places from the same source, parity and multi-stage, hypabyssal rock from the deep source and poly genetic compound as a whole.     

西南三江锌铅银铜锑金成矿带成矿特征及资源潜力

西南三江成矿带是我国重要有色金属和贵金属多金属成矿带之一,锌铅银铜锑金等多金属矿产资源十分丰富。本文从西南三江成矿带范围、成矿地质条件、主攻矿种、矿床类型和矿产资源潜力等方面概述了西南三江成矿带的成矿特征及资源潜力。西南三江成矿带地处特提斯—喜马拉雅构造域的东部,是欧亚板块与印度板块碰撞结合带,大地构造复杂,地层发育齐全,岩浆活动频繁,成矿地质条件优越。西南三江成矿带划分了与富碱性斑岩有关的金铜钼铅锌矿床成矿系列、与碳酸盐岩—碎屑岩系有关铅锌矿床成矿系列和与碰撞造山韧性剪切带有关的金镍铬矿床成矿系列等二十个矿床成矿系列,主攻矿种为锌、铅、铜、银、金和锑,发育有斑岩型、沉积-改造型和MVT型等多种矿床类型。兰坪金顶超大型铅锌矿床和鹤庆北衙超大型金矿床是西南三江成矿带多期多类型叠加成矿的典型矿床,本文简要介绍了其矿床地质特征。根据全国矿产资源潜力评价项目最新成果,本文按预测深度汇总了西南三江成矿带锌、铅和铜等20种矿产的预测资源量,划分了青海多彩地区铜多金属、西藏夏日多—多霞松多铜钼、云南兰坪—云龙铅锌铜和云南鹤庆—祥云金多金属等24个成矿远景区,初步总结了其中13个重点远景区的主攻矿种、主攻矿床类型和资源潜力。     

武夷山Cu- Pb- Zn多金属成矿带主要成矿地质特征及潜力分析

武夷山Cu-Pb-Zn多金属成矿带是华夏地块内的重要成矿区域,长期处于全球超大陆聚散与南北大陆离散拼合的交接转换地带,拥有复杂多样的成矿环境和有利的成矿条件,需要重点部署找矿勘查工作。文章从研究区构造演化历史出发,分析了该成矿带区域成矿地质背景,并在此基础上建立了成矿谱系。作者根据全国矿产资源潜力评价成果,经汇总和综合分析,同时结合新的找矿理论和找矿进展,对本成矿带下一步矿产勘查工作提出了部署建议,建议主攻矿种为:稀土、萤石、铜、钼、铅、锌、锡、金、银等,主攻类型为:风化淋积型稀土矿、斑岩型铜钼金矿、沉积改造型铅锌银多金属矿、岩浆热液型萤石矿以及与酸性岩浆有关的热液型钨锡铋钼铌钽矿等,并在成矿带内圈定了19个找矿远景区,其中8个为重点远景区,11个为一般远景区。     

安徽沿江地区岩浆成矿带

安徽沿江地区可分为三个岩浆成矿带：内带（主带） 、北（ 外） 带和南（ 外） 带。内带沿长江断裂带分布，与地幔隆起带一致，幔源高钾碱性玄武岩浆通过不同程度的ＡＦＣ混合机制和结晶分异机制，形成了不同的岩石组合和矿床，基性岩到酸性岩均有分布，其共同点是高钾富碱，侵入岩以高钾钙碱性岩系为主，火山岩以橄榄安粗岩系为主，广义矽卡岩型Ｃｕ、Ｆｅ、Ｓ、Ａｕ 及火山岩型Ｆｅ、Ｓ矿床是主要的矿床类型；南（外） 带以花岗闪长斑岩为主，高硅低碱，属钙碱性岩系，是上地壳下部易熔组分重熔的产物，成矿元素也由主带的Ｃｕ、Ｆｅ、Ｓ、Ａｕ 转向Ｐｂ、Ｚｎ（Ａｇ） 、Ｃｕ、Ｍｏ、Ｗ 等，是斑岩型Ｍｏ、Ｃｕ 矿床的远景带；北（外） 带比较复杂，主体部分属钙碱性岩系，花岗岩与花岗闪长岩侵入体是下地壳重熔的产物，部分花岗闪长斑岩形成广义矽卡岩型Ｃｕ、Ａｕ 矿床，另一部分以幔源物质为主的闪长玢岩，形成斑岩型Ｃｕ 矿。不同的岩浆成矿带受不同的基底控制。Ｎｄ 、Ｓｒ、Ｐｂ 同位素研究表明，主带和北带存在太古宙麻粒岩相变质基底，南带岩浆岩则源于元古宙角闪岩相到绿片岩相变质基底。地幔隆起与幔源物质参与成矿作用，以及由地幔隆起带来的高热流是成矿的最有利条件。建议深入研究幔脊     

滇西北香格里拉东炉房铜钼矿床斑岩-热液成矿特征及找矿预测

东炉房铜钼矿床位于扬子西缘坳陷带,是滇西北香格里拉地区近年新勘查评价的中型矿床,该矿床具大型规模远景。本次通过地质详查及综合研究工作,基本查明了矿床特征,理清了成矿规律,提出了深部及外围找矿预测区。研究认为:铜钼铅锌金多金属矿化与石英闪长玢岩-石英二长斑岩复式侵入岩紧密相关,矿化蚀变具有斑岩型-矽卡岩型-中低温热液脉型成矿系统特征;矿区共圈定24条矿体,其中斑岩型钼(铜)矿体3条,矽卡岩型铜(钼)矿体14条,中低温热液脉型铅锌(金)矿体7条,具有由内到外,由高温至中低温为Mo(Cu)→Cu(Mo)、Fe→Pb、Zn、Au的斑岩成矿系统元素分带特征;结合矿区矿床地质、地球物理、土壤地球化学特征,矿区外围及深部圈定3处寻找斑岩型-矽卡岩型铜钼多金属矿找矿靶区。该矿床的评价对区内寻找同类型矿床具有重要指示意义。     

吉林延边地区中生代火山岩金铜成矿系列及区域成矿模式

延边地区为我国东部滨太平洋的一个重要金、铜 - (多金属 )矿化集中区。成矿带在时、空和物质组成上主要受控于中生代火山 -岩浆侵入作用 ,形成多种金、铜矿床类型组合的成矿带。在分析成矿带内不同矿床成因类型的基础上 ,建立了该成矿带的成矿系列 ,即斑岩铜钼、火山热液金银、次火山热液金银铅锌成矿系列。将成矿系列控矿条件和火山 -岩浆侵入作用相结合 ,探讨成矿系列的构造环境和成矿模式     

大兴安岭北段岔路口斑岩Mo-热液脉状Zn-Pb成矿系统硫化物微量元素的分布、起源及其勘探指示

岔路口斑岩Mo-Zn-Pb矿床位于大兴安岭北段,是近年来新发现的超大型斑岩-热液脉状Mo-Zn-Pb成矿系统,脉状Zn-Pb矿化直接叠置在斑岩Mo矿化顶部。本文挑选岔路口斑岩型矿化及热液脉型矿化的黄铁矿、闪锌矿、方铅矿,通过EMPA、ICP-MS等多种方法分析硫化物的主微量元素组成,发现岔路口各阶段硫化物均富集Mo元素,相比于斑岩型矿化各阶段中的黄铁矿,Zn、Pb、Mn、Cd、Ga、Ag、Bi等元素在铅锌矿阶段内相对富集;相比于过渡阶段,铅锌阶段闪锌矿中Mo、Co元素及方铅矿中的Bi、Cd和Ag元素含量下降。微量元素在不同阶段内的变化可能是流体降温和天水混合的结果。黄铁矿的稀土总量与成矿岩体最接近,且与成矿岩体和围岩有相似的稀土配分模式,并有较明显的Eu负异常;黄铁矿宽广的Y/Ho比值(25.0~39.0)与成矿岩体的Y/Ho比值范围(27.4~38.7)最接近,同时包括了围岩相对较窄的Y/Ho比值(25.7~31.3),这表明成矿物质主要与成矿岩体同源,可能加入了一定量的围岩物质,岔路口硫化物富Mo的特征受控于深部斑岩Mo矿化岩浆-热液系统。对比东秦岭-大别W-Mo-Pb-Zn矿集区的远源热液脉状Pb-Zn矿床,岔路口浅部近源脉状矿化中的黄铁矿具有更高含量Mo/Ag-Bi/Sb比值和Mo/Pb-Sn/Sb比值,因此浅部硫化物的高Mo含量以及黄铁矿中相关元素比值的高值,可为脉状Zn-Pb矿化附近隐伏斑岩钼矿化的勘探提供新线索。此外,与其他热液脉状和斑岩型矿床相比,岔路口矿床硫化物更富集中高温元素;且综合分析多类矿床的硫化物的微量元素后,本文还初步查明不同矿床类型硫化物富集的微量元素,这一尝试可为矿床成因的判断提供新的思路。     

斑岩铜矿-浅成低温热液银铅锌一远接触带热液金矿矿床模型：一个新的矿床模型——以德兴地区为例

在前人研究的基础上,通过系统的野外考察,论证了位于赣东北德兴地区德乐中生代火山盆地中的德兴铜矿、银山银铜铅锌矿和金山金矿及蛤蟆石金矿属于同一成矿系统。德兴铜矿是典型的斑岩铜矿,成矿流体和金属元素主要来自岩浆;银山银铜铅锌矿是一个下部为斑岩铜矿、上部为浅成低温热液型银铅锌矿,成矿流体早期以岩浆为主,晚期有较多的大气降水参与,成矿物质主要来自岩浆;金山和蛤蟆石金矿是远接触带热液矿床,成矿流体为岩浆热液与大气降水的混合产物,金主要来自围岩——双桥山群浅变质岩。这3套矿床以中酸性花岗斑岩或石英斑岩（高钾钙碱质花岗岩）为核心具有明显的分带性,自中心向外或深部向浅部为：斑岩铜金钼矿、浅成低温热液型银铅锌矿和远接触带热液型金矿。这种矿床组合关系不同于已知的经典斑岩铜矿模型和斑岩铜矿一浅成低温热液金银矿床模型,因而,有必要提出一个新的模型：斑岩铜矿一浅成低温热液银铅锌矿一远接触带热液金矿模型。这套矿『末形成于中侏罗世,抑或是古太平洋俯冲板片局部重熔或撕裂重熔的产物,抑或是在活动大陆边缘岩浆弧后伸展带由地幔底侵的结果。     

Porphyry Cu–Au–Mo–epithermal Ag–Pb–Zn–distal hydrothermal Au deposits in the Dexing area, Jiangxi province, East China—A linked ore system

Based on previous studies and detailed field investigations of the Dexing porphyry copper deposit, the Yinshan Ag-Pb-Zn deposit and the Jinshan shear zone – hosted gold deposit in the Dele Jurassic volcanic basin, in the northeastern Jiangxi province, East China, we propose that the three deposits share spatial, temporal and genetic relationships and belong to the same metallogenic system. Dexing is a typical porphyry Cu–Au–Mo deposit in which both ore-forming fluid and metals are derived from the granite porphyry. The Yinshan deposit consists of a porphyry copper ore located in the cupola of a quartz porphyry stock, in the lower part, and Ag–Pb–Zn ore veins in the upper part. The hydrothermal fluids were mainly derived from the magma in the early stages of the mineralizing event and became mixed with meteoric waters in the late stages. Its ore metals are magma-derived. Both the Jinshan base metal veins and the Hamashi, Dongjie and Naikeng quartz vein-type gold deposit are hosted by brittle–ductile structures, which are distal in relation to the porphyry intrusions and were formed by mixed magmatic fluids and meteoric water, whereas the gold was mainly leached from the country rocks (Mesoproterozoic Shuangqiaoshan Group phyllite and schist). The deposits show a distinct spatial arrangement from porphyry Cu, to epithermal Ag–Pb–Zn and distal Au. We suggest a porphyry–epithermal–distal vein ore system model for this group of genetically related mineral deposits. They were formed in a back-arc setting in a Middle Jurassic active continental margin, with magmas derived from the subducted slab.     

Genesis of the Bianjiadayuan Pb-Zn polymetallic deposit,Inner Mongolia,China:Constraints from in-situ sulfur isotope and trace element geochemistry of pyrite

The Southern Great Xing'an Range(S(GXR)which forms part of the eastern segment of the Central Asian Orogenic Belt(CAOB)is known as one of the most important Cu-Mo-Pb-Zn-Ag-Au metallogenic belts in China,hosting a number of porphyry Mo(Cu),skarn Fe(Sn),epithermal Au-Ag,and hydrothermal veintype Ag-Pb-Zn ore deposits.Here we investigate the Bianjiadayuan hydrothermal vein-type Ag-Pb-Zn ore deposit in the southern part of the SGXR.Porphyry Sn± Cu± Mo mineralization is also developed to the west of the Ag-Pb-Zn veins in the ore field.We identify a five-stage mineralization process based on field and petrologic studies including(i)the early porphyry mineralization stage,(ii)main porphyry mineralization stage,(iii)transition mineralization stage,(iv)vein-type mineralization stage and(v)late mineralization stage.Pyrite is the predominant sulfide mineral in all stages except in the late mineralization stage,and we identify corresponding four types of pyrites:Pyl is medium-grained subhedral to euhedral occurring in the early barren quartz vein;Py2 is medium-to fine-grained euhedral pyrite mainly coexisting with molybdenite,chalcopyrite,minor sphalerite and galena;Py3 is fine-grained,subhedral to irregular pyrite and displays cataclastic textures with micro-fractures;Py4 occurs as euhedral microcrystals and forms irregularly shaped aggregate with sphalerite and galena.LA-ICP-MS trace element analyses of pyrite show that Cu,Pb,Zn,Ag,Sn,Cd and Sb are partitioned into pyrite as structurally bound metals or mineral micro/nano-inclusions,whereas Co,Ni,As and Se enter the lattice via isomorphism in all types of pyrite.The Cu,Zn,Ag,Cd concentrations gradually increase from Pyl to Py4,which we correlate with cooling and mixing of ore-forming fluid with meteoric water.Py2 contains the highest contents of Co,Ni,Se,Te and Bi,suggesting high temperature conditions for the porphyry mineralization stage.Ratios of Co/Ni(0.03-10.79,average 2.13)and sulphur isotope composition of sulfide indicate typical hydrothermal origin for pyrites.The δ~(34)S_(cDT) values of Pyl(0.42‰-1.61‰,average1.16‰),Py2(-1.23‰to 0.82‰,average 0.35‰),Py3(—0.36‰to 2.47‰average 0.97‰).Py4(2.51‰--3.72‰,average 3.06‰),and other sulfides are consistent with those of typical porphyry deposit(-5‰to 5‰),indicating that the Pb-Zn polymetallic mineralization in the Bianjiadayuan deposit is genetically linked to the Yanshanian(Jurassic-Cretaceous)magmatic-hydrothermal events.Variations of δ~(34) S values are ascribed to the changes in physical and chemical conditions during the evolution and migration of the ore-forming fluid.We propose that the high Sn content of pyrite in the Bianjiadayuan hydrothermal vein-type Pb-Zn polymetallic deposit can be used as a possible pathfinder to prospect for Sn mineralization in the surrounding area or deeper level of the ore field in this region.     

西藏冈底斯岛弧及其铜多金属矿带的基本特征与远景评估

冈底斯岛弧带属冈底斯活动大陆边缘的组成部分。带内早自中侏罗世、晚至第三纪的中酸性火山岩以及与雅鲁藏布江结合带有成因联系的Ⅰ型中酸性岛弧陆缘碱性侵入体（40-100Ma)和陆内汇聚造山引起的S型花岗岩体（15-50Ma)广泛发育。研究证实，冈底斯岛弧带属有色金属、贵金属成矿带。主要矿种的矿床类型有：海底火山热液型或火山喷流沉积型（Cu多金属）、海底热水沉积型（Cu、Pb、Zn等）、斑岩型（Cu、Mo）以及接触交代岩浆期后地下水热液充填的复合型（Cu、Pb、Zn）等。这些多期、多阶段复合叠加成矿作用和多种矿床类型的“同带共存”格局，展示了冈底斯岛弧带的巨大找矿潜力。     

Genesis of the giant Zijinshan epithermal Cu-Au and Luoboling porphyry Cu–Mo deposits in the Zijinshan ore district,Fujian Province,SE China: A multi-isotope and trace element investigation

The Zijinshan ore district occurs as one of the largest porphyry-epithermal Cu–Au–Mo ore systems in South China, including the giant Zijinshan epithermal Cu–Au deposit and the large Luoboling porphyry Cu–Mo deposit. The mineralization is intimately related to Late Mesozoic large-scale tectono-magmatic and hydrothermal events. The Cu–Au–Mo mineralization occurs around intermediate-felsic volcanic rocks and hypabyssal porphyry intrusions. In this study, we summarize previously available Re–Os isotopes, zircon U–Pb age and trace elements, and Sr–Nd–Pb isotope data, and present new Pb–S and Re–Os isotope data and zircon trace elements data for ore-related granitoids from the Zijinshan high-sulfidation epithermal Cu–Au deposit and the Luoboling porphyry Cu–Mo deposit, in an attempt to explore the relationship between the two ore systems for a better understanding of their geneses. The ore-bearing porphyritic dacite from the Zijinshan deposit shows a zircon U-Pb age of 108–106 Ma and has higher zircon Ce⁴⁺/Ce³⁺ ratios (92–1568, average 609) but lower Ti-in-zircon temperatures (588–753 °C, average 666 °C) when compared with the barren intrusions in the Zijinshan ore district. Relative to the Zijinshan porphyritic dacite, the ore-bearing granodiorite porphyry from the Luoboling deposit show a slightly younger zircon U–Pb age of 103 Ma, but has similar or even higher zircon Ce⁴⁺/Ce³⁺ ratios (213–2621, average 786) and similar Ti-in-zircon temperatures (595–752 °C, average 675 °C). These data suggest that the ore-bearing magmatic rocks crystallized from relatively oxidized and hydrous magmas. Combined with the high rhenium contents (78.6–451 ppm) of molybdenites, the Pb and S isotopic compositions of magmatic feldspars and sulfides suggest that the porphyry and ore-forming materials in the Luoboling Cu–Mo deposit mainly originated from an enriched mantle source. In contrast, the ore-bearing porphyritic dacite in the Zijinshan Cu–Au deposit might be derived from crustal materials mixing with the Cathaysia enriched mantle. The fact that the Zijinshan Cu–Au deposit and the Luoboling Cu–Mo deposit show different origin of ore-forming materials and slightly different metallogenic timing indicates that these two deposits may have been formed from two separate magmatic-hydrothermal systems. Crustal materials might provide the dominant Cu and Au in the Zijinshan epithermal deposit. Cu and Au show vertical zoning and different fertility because the gold transports at low oxygen fugacity and precipitates during the decreasing of temperature, pressure and changing of pH conditions. It is suggested that there is a large Cu–Mo potential for the deeper part of the Zijinshan epithermal Cu–Au deposit, where further deep drilling and exploration are encouraged.