山东省平度市大庄子金矿区黄铁矿、方铅矿与金的共生关系研究

通过对山东省平度市大庄子金矿区黄铁矿、方铅矿三个蚀变阶段特征研究,发现金矿化主要发生在第二阶段,强烈的石英-黄铁矿-碳酸盐化与金矿化的关系最为密切。金多数以包体的形式赋存于黄铁矿等金属硫化物中,并且在黄铁矿、方铅矿、闪锌矿等矿物共同产出时更有利于金的富集。研究认为石英和黄铁矿组合以及黄铁矿、黄铜矿、方铅矿、闪锌矿的组合可作为金的富集指示性矿物组合,伴生矿物之中方铅矿含金性最好。方铅矿、黄铜矿、闪锌矿和磁黄铁矿呈细脉状、网脉状、斑杂状产于含金石英脉和团块状黄铁矿的裂隙中,研究发现细脉状较团块状黄铁矿含金性要好。     

南秦岭黄龙金矿磁黄铁矿标型矿物学特征及含金性研究

南秦岭南部构造带具备较好的金矿成矿条件与成矿背景,是该区域规模较大金矿带.金沟矿段是黄龙金矿床最主要的组成部分,该矿段矿石中磁黄铁矿和黄铁矿发育,其中磁黄铁矿矿石是矿床中含量最高的硫化物矿石.磁黄铁矿存在两种产出状态,分别为早期形成的呈浸染状、团块状分布的磁黄铁矿与晚期形成的脉状磁黄铁矿.成分分析结果表明以单斜磁黄铁矿为主.该矿床属中-低温矿床.微量元素结果显示富Co贫Ni,与金矿化关系密切.在含金性方面,脉状产出的磁黄铁矿优于团块状分布的磁黄铁矿,且脉体越细含金性越好,因此细脉状磁黄铁矿可作为该区重要的找矿标志.     

甘肃阳山金矿区黄铁矿的赋存状态与分布特征

甘肃阳山金矿是迄今为止中国发现的最大金矿。已发现的6个矿段均赋存于泥盆系中,矿石中金属矿物主要为黄铁矿和毒砂。黄铁矿有3种类型:微细粒浸染状、半自形颗粒集合体、自形单晶大颗粒;主要分布在千枚岩、花岗闪长岩、石英脉里,具有多期次多类型的特点。根据黄铁矿的特征,金矿化与石英脉体中细粒浸染状的一期黄铁矿有关。黄铁矿为重要的载金矿物之一,自然金(Au)主要以微细粒的形式赋存于黄铁矿晶体的裂隙内以及晶体与晶体的空隙间。黄铁矿赋存状态和分布特征的研究,对矿区进一步找矿具有指导意义。     

辽宁东平金矿床地质特征及找矿方向

南秦岭南部构造带具备较好的金矿成矿条件与成矿背景，是该区域规模较大金矿带.金沟矿段是黄龙金矿床最主要的组成部分，该矿段矿石中磁黄铁矿和黄铁矿发育，其中磁黄铁矿矿石是矿床中含量最高的硫化物矿石.磁黄铁矿存在两种产出状态，分别为早期形成的呈浸染状、团块状分布的磁黄铁矿与晚期形成的脉状磁黄铁矿.成分分析结果表明以单斜磁黄铁矿为主.该矿床属中-低温矿床.微量元素结果显示富Co贫Ni，与金矿化关系密切.在含金性方面，脉状产出的磁黄铁矿优于团块状分布的磁黄铁矿，且脉体越细含金性越好，因此细脉状磁黄铁矿可作为该区重要的找矿标志.     

金银矿床中黄铁矿的标型特征

黄铁矿是一种遍在矿物,从岩浆矿床→热液矿床→沉积矿床→变质矿床中,几乎都有产出. 在热液矿床中黄铁矿与金的关系尤为密切,绝大多数原生金一银矿床中都有大量黄铁矿产出.例如:金-黄铁矿-石英脉;金     

小秦岭大湖矿区钼、金矿体地质、地球化学特征与差异性分析

本文针对小秦岭金矿田大湖钼金矿矿床地质、地球化学特征进行了系统的分析。矿区浅部为石英脉型金矿体,向深部延伸出现石英脉型钼矿体,F5断层是大湖矿区内金、钼矿主要的含矿构造,钼矿体与金矿体共生或独立存在。钼矿体顶板围岩主要发育钾长石化,而金矿体顶底板围岩则发育硅化、绢云母化、黄铁矿化,其中绢云母化和中细粒黄铁矿化与金矿体关系最为密切。含金石英脉流体包裹体气相组分以CO2、H2O为主,含有少量CH4、C2H2等还原性气体,液相组分主要为Na+、Ca2+、Cl-、F-等离子。钼矿体与金矿体的H、O同位素数据显示钼矿脉与金矿脉的成矿流体主要都是来自岩浆水,但是两种矿体的H、O同位素组成又表现出一定的差异。辉钼矿化石英脉与金矿体中钾长石化和黄铁矿化石英脉中的稀土组成具有明显的不同,辉钼矿化石英脉具有较高的的∑REE和轻重稀土分馏,指示金矿体与钼矿体成矿流体来源不同,金、钼可能形成于不同的成矿期。     

祁连山西段党河南山北坡3个不同特征的金矿床研究

黑刺沟金矿床以富As和Sb的微细浸染蚀变岩型金矿化和部分石英脉型锑－金矿化为特征,典型矿物组合为黄铁矿-毒砂(辉锑矿)-石英;贾公台金矿床以少硫化物石英脉型金矿化和蚀变岩型金矿化为特征,As和Sb的质量分数不高,典型矿物组合为黄铁矿-自然金(方铅矿)-石英-钾长石;鸡叫沟金矿床以蚀变岩型金矿化为主,次之为石英脉型金矿化,典型矿物组合为黄铁矿-黄铜矿-石英.3个金矿床的成因均与岩浆岩有密切联系,但各矿区的岩浆岩在岩石学、岩石化学、微量元素及稀土元素特征具有差异,表明其成因不尽相同.这可能是造成3个金矿床地质特征差异的主要原因.     

小秦岭大湖矿床石英脉组构和黄铁矿微量元素地球化学对金钼独立成矿作用及其成脉构造环境的制约

本研究以大湖矿床金、钼矿化石英脉体形态、空间关系、矿物共生组合序列等地质特征研究为基础,采用显微镜和LA-ICP-MS分析技术重点对金、钼热液脉体组构以及黄铁矿微量元素地球化学特征进行系统对比研究,以揭示小秦岭地区金、钼成矿作用关系及成脉构造环境。研究结果表明,钼矿化石英脉具晶洞状构造和自形-半自形晶结构,黄铁矿贫As、Au、Te、Bi、Cu、Pb元素,和发育自然金、黄铜矿、铜铅铋硫盐矿物浑圆粒状显微包裹体等特点,反映钼矿化石英脉形成于张性构造空间,经历了相对缓慢冷却结晶作用过程。结合钼矿化石英脉厚度大,且变化明显,以及空间延伸稳定性差等特点,认为钼矿化石英脉可能形成于相对较低的区域性差异应力场环境,受控于水力断裂作用形成的张性断裂控矿体系,为与印支期板块碰撞造山过程相关的独立成矿事件。大湖矿床的金矿化以条带状黄铁矿石英脉型矿化占主导,其矿物共生组合序列、蚀变类型以及黄铁矿贫As、富Au-Bi-Te元素组合等特征,与小秦岭地区其他脉型金矿床特征一致,表明它们统属小秦岭大规模金成矿作用的产物。结合包括大湖矿床在内的小秦岭地区含金石英脉相对较小的厚度,且变化性小、矿床和区域尺度延伸相对稳定,以及含金石英脉近东西向优势排列趋势等特征,认为小秦岭地区大规模含金石英脉形成于相对较高的区域差异应力场环境,受控于同成矿的南北向伸展构造应力场、近东西向张扭性断裂体系。含金石英脉的形成与小秦岭变质核杂岩隆升剥露过程相耦合,大湖矿床含金石英脉的塑性变形和脆性碎裂结构可能是赋矿变质核杂岩隆升冷却过程的重要记录。     

陕西商洛杨斜金矿床地质特征与控矿因素探讨

陕西杨斜金矿床为东秦岭杨斜-丰北河金钨成矿带东段的一中型金矿床。金矿体主要为热液石英脉型,赋存于商丹断裂带内北东—北北东与北西—北北西向次级断裂中,赋矿围岩为新元古代杨斜片麻岩套。矿石金属矿物为黄铁矿-自然金-黄铜矿-黝铜矿-闪锌矿-方铅矿等中低温组合;热液成矿过程可划分钾长石-石英、石英-粗粒黄铁矿-自然金、石英-细粒黄铁矿-自然金-多金属硫化物和碳酸盐4个阶段;近矿围岩蚀变以钾化、硅化及黄铁矿化为特征,远矿蚀变主要为绿泥石化和碳酸盐化。金矿床主要受断裂、围岩及岩体(脉)控制,成矿时代不早于晚三叠世。     

关于金矿床成因的新资料

从矿物学角度看,法国的舍金滑石菱镁片岩(listvenite)与某些金矿脉是个分类似的。这种相似性表明超基性岩是这些脉中大部分金属(Fe,Mg,Ni,Co,Au)的主要来源。金首先赋存于早期形成的磁黄铁矿中(在Hermites脉中可达30ppm),并在这些磁黄铁矿分解转变为黄铁矿-白铁矿组合时从中分离出来。金从而也获得了其确定的矿物学形式:或呈自然金出现,这时磁黄铁矿的分解是发生在矿化晚期(如在开放型大脉中),或者“隐藏”在含铁硫化物如毒砂(可含1.6%金,在chatelet脉中)、黄铁矿和辉铁锑矿(可含300ppm金,在Marmeissat脉中)中,这时磁黄铁矿的分解是发生在矿化早期(如在无明显张裂的“剪切带”式矿床中)。在后一种情况下,我们应该考虑到在含铁硫化物中存在Fe、Au置换的可能性。     

招远两涧地区金矿特征及成矿规律探讨

招远两涧地区位于玲珑金矿田的东北部边界,多数矿脉延至本区尖灭,本区金矿的特征为:矿脉众多,矿体规模为中小型,矿石类型以含金黄铁绢英岩化碎裂岩、含金黄铁石英脉为主,矿石品位较高。成矿规律为:矿体均受断裂构造控制;矿区南部矿体赋存在地表至-200 m标高之间共计600 m的范围内;36号脉、510号脉、209号脉为本区较大规模的矿脉,所含矿体在规模、数量、赋存位置等方面具有各自的规律。     

金英金矿成矿阶段化分初探

简单地介绍了金英金矿围岩、含矿岩层和矿区构造特征,矿石结构构造、矿物共生组合、矿物生成顺序、矿脉间的穿切包容关系,将矿床形成划分为4个矿化阶段,即早期硅化石英-金-烟灰色黄铁矿阶段;微细粒硅化石英-金-星散浸染状黄铁矿阶段;重晶石、玉髓-金-赤铁矿阶段和微含金细粒黄铁矿—白铁矿迭加矿化阶段。详细地论述了个成矿阶段每一成矿阶段具体特征。     

陕西略阳张家山金矿成矿作用及Au-Se矿物形成物理化学条件研究

陕西略阳煎茶岭金矿矿集区中的张家山金矿主要由破碎蚀变岩型、角砾岩型和含金石英黄铁矿脉型矿石组成。含金石英-黄铁矿脉型矿石产于断层下盘的石英菱镁岩中。黄铁矿发育富As黄铁矿边,环边受As含量的变化呈现一定的韵律变化,自然金赋存在富As黄铁矿中。在断裂发育形成断层角砾岩的过程中,流体充填破碎石英菱镁岩的裂隙中形成热液矿物,包括硫化物、硒化物以及自然金。石英菱镁岩发生破碎形成的网状裂隙被含金石英-方解石-黄铁矿脉充填。破碎蚀变岩型矿石中,自然金主要分布在含金石英-黄铁矿脉的石英之中或靠近热液脉的菱镁矿或石英间隙。随着大量方解石脉沿裂隙贯入,进一步促进石英菱镁岩的破碎及岩石角砾的分离,形成由石英菱镁岩碎屑、石英和褐铁矿组成的复成分角砾岩,自然金和硒化物呈浸染状分布在角砾岩中。笔者在角砾岩型矿石中发现了灰硒汞矿、直硒镍矿、硒铅矿等硒化物,这些硒化物往往与自然金密切共生。结合矿物组合以及相关化学反应关系,通过热力学计算,构建了该矿床在不同温度条件下的热力学相平衡关系图,限定了硒化物与其他相关矿物稳定存在的物理化学条件。硒化物一般与自然金和石英共生,高的f(Se2)值和f(Se2)/f(S2)比值是控制硒化物形成的关键因素。     

The Bepkong gold deposit,Northwestern Ghana

The Bepkong gold deposit is located in the Wa–Lawra belt of the Paleoproterozoic Baoulé-Mossi domain of the West African Craton, in NW Ghana. It occurs in pelitic and volcano-sedimentary rocks, metamorphosed to greenschist facies, in genetic association with zones of shear interpreted to form during the regional D₃ deformational event, denominated D_B1 at the deposit scale. The ore zone forms a corridor-like body composed of multiple quartz ± carbonate veins surrounded by an alteration envelope, characterized by the presence of chlorite, calcite, sericite, quartz and disseminated pyrite, arsenopyrite plus subordinate pyrrhotite and chalcopyrite. The veins contain only small proportions of pyrite, whereas most of the sulphides, particularly arsenopyrite, occur in the altered host rock, next to the veins. Pyrite is also common outside of the ore zone. Gold is found in arsenopyrite, where it occurs as invisible gold and as visible – albeit micron-size – grains in its rims, and as free gold within fractures cross-cutting this sulphide. More rarely, free gold also occurs in the veins, in fractured quartz. In the ore zone, pyrite forms euhedral crystals surrounding arsenopyrite, but does not contain gold, suggesting that it formed at a late stage, from a gold-free hydrothermal fluid.     

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.     

福建太阳山破碎带蚀变岩型金矿形成的矿相学证据

系统的矿相学研究表明,太阳山金矿矿石矿物主要为黄铁矿、磁黄铁矿、含银自然金、闪锌矿、黄铜矿;矿床围岩蚀变种类较多,主要有硅化、绢云母化、钾长石化、石墨化。矿石结构包括自形—半自形粒状结构、假象结构、压碎结构、包含结构、错断结构等,矿石构造包括浸染状、微脉浸染状、脉状、网脉状构造。金主要以包裹金、粒间金、裂隙金、赋存于石英、黄铁矿、磁黄铁矿中。矿区内常见的是碎裂岩和糜棱岩化岩石,很少见到糜棱岩,不存在超糜棱岩、构不成糜棱岩系列。本矿床地质特征与典型的破碎带蚀变岩型金矿山东焦家金矿极为相似。因此,太阳山金矿属于典型的破碎带蚀变岩型金矿。     

河南省罗山县金城金矿黄铁矿标型特征及其意义

通过对河南罗山县金城金矿Ⅱ号矿体黄铁矿产出特征、金在黄铁矿中的赋存状态、化学成分、热电性等一系列标型特征的研究,认为本区含金黄铁矿主要为热液成因。黄铁矿中硫同位素具有变化范围窄(2.75‰~5.5‰)、极差值小(2.75‰)、平均值为4.195‰的特点,表明硫主要来源于深源岩浆。热电性测试显示,黄铁矿的热电系数(α)变化范围较大(-281.0~466.0μV/℃),平均为-148.9~268.2μV/℃,热电场导电类型N型、P-N型、N-P型及P型均有,总体上具有N-P混合型特征,同一世代黄铁矿热电性在空间上具有正向垂直分带的规律,表明本矿区的黄铁矿成分复杂,具有受多期次热液叠加的特征。黄铁矿热电性数据统计直方图明显出现两个峰值,表明本矿床至少具有两次金成矿作用阶段。通过经验公式计算预测该矿体的剥蚀深度为矿体中部位置,深部尚有较大的找矿潜力。这一研究反映了黄铁矿的标型特征对进一步扩大矿床规模和找矿具有重要的指示意义。     

Mossman orogenic gold province in north Queensland,Australia: regional metallogenic controls and undiscovered gold endowment

The Hodgkinson and Broken River provinces of the Mossman Orogen in north Queensland host numerous orogenic gold deposits and still remain under-explored. This paper discusses regional metallogenic controls and results of a probabilistic quantitative assessment of undiscovered gold potential in the region. Significant orogenic gold deposits in the region occur only within relatively small well-endowed metallogenic zones, likely to be controlled by the eastern margin of the Paleoproterozoic continental crust underlying the western Mossman Orogen. Three distinct styles of primary orogenic gold deposits are present in the area: gold–quartz veins, refractory gold associated with quartz–pyrite–arsenopyrite veins and stockworks and stibnite–quartz±gold veins. Refractory gold deposits are estimated to have the highest potential for significant undiscovered resources in the region. The Hodgkinson Province is estimated to host between one and ten significant undiscovered refractory gold ore fields, with a 50 % probability of at least 20 t of total contained gold and a 90 % probability of at least 1 t. The Broken River Province is estimated to host up to five significant undiscovered refractory gold ore fields, with a 50 % probability of at least 12 t of contained gold.     

黔东南坑头金矿床热液蚀变特征及成矿过程研究

黔东南金成矿区位于江南造山带金成矿省的西南端,成矿条件优越。坑头金矿床是黔东南金成矿区的一个中型矿床,在其深部找矿中,发现除石英脉型矿体外,还存在蚀变岩型矿体。然而,这种蚀变岩型矿体的构造形态、蚀变类型、与石英脉型矿体之间关系和金的赋存状态尚不清楚。本研究与当前的勘查工作紧密结合,围绕石英脉型矿体和新发现的蚀变岩型矿体为研究切入点,借助微区分析技术(扫描电镜和电子探针)进行系统的“流体- 蚀变- 成矿”研究。蚀变矿物金红石矿物化学显示为热液成因,具有典型造山型金矿床的金红石标型特征。围岩的沉积- 成岩过程(包括低级变质作用过程),主要形成了草莓状黄铁矿和含铁碳酸盐岩,为后期含金硫化物(黄铁矿和毒砂)的形成提供物质基础(如Fe)。金的成矿富集过程主要经历了绢云母+毒砂+黄铁矿+石英(Ser+Apy+Py+Qtz)阶段、黄铁矿+毒砂+石英(Py+Apy+Qtz)阶段和自然金+石英(Au0+Qtz)阶段。在Ser+Apy+Py+Qtz阶段,主要表现为含矿流体与围岩的初级交代,形成大量浸染状黄铁矿+毒砂的硫化带;Py+Apy+Qtz阶段主要为流体沿着剪切带再交代,形成蚀变岩型矿体;Au0+Qtz阶段主要表现为含金石英大脉的形成。金的赋存状态研究显示,蚀变岩矿体中Au以他形显微- 次显微自然金赋存在蚀变岩硫化物裂隙中,或以化学结合态方式赋存在黄铁矿和毒砂中(后者占主导)。在晚期Au0+Qtz阶段,自然金呈自形、粗粒(~0. 5 mm)赋存在石英脉中。综合研究认为,多期构造(流体)交代导致的溶解- 再沉淀可能是坑头金富集成矿主要原因之一。