新疆磁海铁矿床产出特征及成矿构造演化

磁海铁矿床产于早二叠世东天山南缘裂陷槽大地构造环境中,为次火山-矿浆侵入-热液充填交代矿床。通过对该隐伏矿床的露天挖掘开采,发现铁矿床在成矿后,早期有多期次辉绿岩墙以不同方向穿插于向北陡倾之铁矿体中,从而使铁矿体的完整性受到破坏,肢解成众多向南倾小矿体。经矿区调研填图,圈定出主矿体是由两条呈倾向340°、倾角70°～80°的巨型扁豆状矿囊组成。被成矿后期脉岩穿插肢解呈"向南倾斜的小矿体",构成了矿体的假产状。笔者重新建立了磁海铁矿床的矿体模型和成矿演化构造模式。     

新疆磁海铁矿区镁铁质岩及正长岩锆石U-Pb年代学、岩石地球化学特征:对成岩、成矿作用的制约

对新疆磁海铁矿区镁铁-超镁铁质岩与铁成矿关系、正长岩与镁铁质岩关系的解剖,是认识磁海矿区成岩、成矿过程及构造背景的关键。本文利用SIMS锆石U-Pb测年法,获得磁海辉绿岩、辉长辉绿岩、磁南辉长岩、磁海北角闪石英正长岩的206Pb/238U-207Pb/235U谐和年龄分别为275.1±2.2Ma、281.9±3.2Ma、273.0±1.9Ma和273.0±1.8Ma,这与北山乃至北疆地区主要含铜镍-钒钛磁铁矿的镁铁-超镁铁质岩年龄一致。岩石地球化学特征研究显示,从辉石岩到辉长岩,再到辉绿岩,经历了Ti逐渐富集、Mg#和m/f值先增加后降低的过程,角闪石英正长岩具有A型花岗岩特征,与辉长岩、辉绿岩在成因上存在互补关系。综合年代学和地球化学特征,磁南辉石岩、辉长岩、磁海辉绿岩、辉长辉绿岩以及磁海北边的角闪石英正长岩为同源岩浆演化的产物,岩浆演化过程中受地壳混染作用微弱,在岩浆演化的早期,磁铁矿的结晶分离主导着岩浆成分的改变,当岩浆演化到辉长岩阶段,岩浆开始以结晶分异作用为主;磁铁矿的分离结晶时间早于钛铁矿,岩浆型的金属硫化物为磁铁矿和钛铁矿结晶过渡阶段的产物。磁海镁铁-超镁铁质岩石在成岩及成矿作用上可能与在时间和空间上相邻近的塔里木早二叠世大火成岩省有密切关系。     

广东大宝山多金属矿床花岗岩锆石LA-ICP-MSU-Pb定年及其地质意义

广东大宝山矿床位于南岭花岗岩带中带。它是我国著名的大型多金属矿床,开采历史久远。近年来的研究表明大宝山矿床与成矿作用有关的斑岩体为燕山早期岩浆活动的产物,因而人们较多地关注中生代的岩浆活动,而忽视了对其他时代岩浆活动的研究。本文在前人研究的基础上,利用锆石LA-ICP-MS U-Pb定年方法系统地测试了大宝山多金属矿床多个花岗质岩体和辉绿岩脉的形成时代,研究表明徐屋片理化流纹斑岩年龄为426.9±2.2Ma、九曲岭黑云母花岗闪长斑岩、船肚花岗闪长岩和大宝山花岗闪长斑岩形成时代分别为162.2±0.7Ma、160.2±0.9Ma和161.0±0.9Ma。矿区内两条辉绿岩脉的年龄分别为210.4±1.4Ma和163.9±1.8Ma。这些结果证实大宝山矿区内存在加里东期、印支期和燕山期等多个旋回的岩浆活动,中晚侏罗世铁镁质的岩浆活动可能存在对成矿的贡献。     

新疆磁海铁矿区镁铁-超镁铁岩地球化学特征及其地质意义

磁海铁矿床地处塔里木盆地北缘北山成矿带内, 为一与镁铁-超镁铁岩有关的岩浆分异-矿浆贯入-热液交代型复成因铁矿床。对磁海矿区镁铁-超镁铁岩的岩石学特征和岩石地球化学特征等进行了较为系统的研究, 认为这套镁铁-超镁铁岩石属于铁质钙碱性玄武岩系列。稀土及微量元素特征与原始地幔成分接近,表明岩浆上升侵位过程中局部遭受陆壳混染。结合前人的研究成果, 认为该矿床形成于后碰撞拉张构造环境。原始岩浆的结晶分异和后期热液蚀变对磁海铁矿形成和富集起重要作用。     

东天山镁铁-超镁铁岩含矿性评价以及Cu-Ni(PGE)成矿规律与隐伏矿定位预测

新疆镁铁-超镁铁质岩分布广泛,是我国铜镍矿床的主要产地之一,占全国探明镍储量的13. 8%,占新增镍储量的90%以上.东天山成矿带是中亚造山带的重要组成部分,也是世界上典型的增生型造山带,早二叠世后碰撞驰张构造阶段,大量镁铁-超镁铁岩沿深大断裂带上侵,形成了一系列岩浆铜镍硫化物矿床.     

新疆磁海超大型铁矿区基性岩及其成矿背景指示

新疆磁海超大型铁矿区基性岩与铁成矿关系密切,是认识大规模铁成矿及其背景的关键.磁海铁矿区基性岩以辉绿岩为主,辉绿岩中断裂-裂隙控制板状铁矿脉群,单颗粒锆石U-Pb法测得206Pb/238U平均年龄为263.8±3.6 Ma(n＝11,MSWD=1.3),与二叠纪塔里木、东天山造山带、北山构造-成矿带等区域基性岩同时代.磁海铁矿区基性岩球粒陨石标准化微量元素蛛网图较平坦,Sr、Ba显示弱富集,Nb略亏损,球粒陨石标准化的REE配分曲线平坦,岩浆起源于亏损软流圈地幔,与其所在区域的北山构造-成矿带、东天山造山带、塔里木等地的基性岩均属碱性-钙碱性系列,它们的微量元素组成相近,岩浆性质相似,成生关系密切.磁海铁矿区基性岩可能是二叠纪地幔柱成因塔里木大火成岩省的组成部分,大规模铁成矿于地幔柱背景,北山构造-成矿带可能是塔里木地幔柱的一枝.      

东天山黄山岩体的侵位时代及其地质意义

东天山黄山—镜儿泉地区分布有众多镁铁质—超镁铁质岩体,岩体成群成带分布,受区域性韧性剪切带和断裂构造控制.为进一步确定黄山—镜儿泉基性—超基性岩带的侵位时代、成因和大地构造背景,对选自黄山岩体辉长岩相中单颗粒锆石进行了LA-ICP-MS U-Pb定年研究,将其结果[(284.5±2.5)Ma]与黄山岩体和黄山—镜儿泉一带其他基性—超基性岩中已有的定年成果进行了对比,并结合近年来该区研究成果,分析得到黄山辉长岩侵位于晚石炭世—早二叠世,此时正值东天山后碰撞大规模岩浆侵位和成矿时期.黄山镁铁质—超镁铁质岩带形成于后碰撞的伸展构造环境.     

西准噶尔夏尔莆岩体岩浆混合的锆石U-Pb年代学证据

尽管岩相学标志是识别岩浆混合的最直接、最重要的证据,但其寄主岩石、幔源包体及基性岩墙群的精确同位素定年则是对岩浆混合证据的重要补充。夏尔莆岩体由寄主岩石、微细粒镁铁质包体和中基性岩墙群组成,高精度LA-ICP-MS锆石U-Pb测年表明三者的年龄分别为297.6±2.5Ma、298.2±8.0Ma、298.9±5.0Ma,在误差范围内一致,说明三者是同一岩浆事件的产物,为夏尔莆岩体岩浆混合成因提供了年代学证据。夏尔莆岩体的岩浆混合成因的确立证实了早二叠世西准噶尔地壳深部发生过强烈的壳幔岩浆混合作用,并导致了该地区一次重要的地壳垂向生长事件,而岩体中大量的微细粒镁铁质包体和中基性墙群正是这次生长事件的物质记录者。     

甘肃金川铜镍(铂)硫化物矿床中高镁辉绿岩脉的发现及其意义

位于华北板块西缘赋存于超镁铁质岩中的金川矿床,是目前世界第三大镍硫化物矿床.金川铜镍硫化物矿床的原生岩浆问题一直存在着较大的争议,前人通过研究金川铜镍硫化物矿体中的堆晶橄榄岩中橄榄石的成分,从而推导原生岩浆的成分.而作者通过对金川铜镍硫化物矿体内部的基性岩脉深入研究,从另一个角度探究金川铜镍硫化物矿床的原生岩浆成分.通过对岩脉岩相学、主量元素的研究表明金川铜镍硫化物矿体中的岩脉主要是辉绿岩,因其MgO的含量的不同可以划分为高镁辉绿岩和低镁辉绿岩.辉绿岩脉的主量元素和微量元素显示这两类岩脉发生过分离结晶作用.PGE元素特征显示辉绿岩脉和金川矿床是同一期次产物,Pmelts的模拟演化得出本文中辉绿岩脉的液相线矿物橄榄石的牌号为Fo86,与金川矿床发现最高牌号Fo86一致.同时Ol-CATS-Q相图表明JC100925-5样品形成的源区在3GPa以上.多种因素显示这种高镁的岩浆是金川矿区的原生岩浆.     

东天山-北山镁铁-超镁铁质岩特征、成矿意义及构造背景

东天山-北山地区镁铁-超镁铁质岩体成群成带分布,明显受区域内主干断裂控制,主要分布于东天山、中天山地块和北山裂谷。镁铁-超镁铁质岩体与Cu-Ni矿化密切相关,小岩体成大矿为普遍现象。含矿岩相多集中在橄榄辉长岩、角闪橄榄岩、辉橄岩和各岩相接触带上。岩体低Ti高Mg,高m/s和m/f是评价其含矿性的良好指标。SrNd同位素显示镁铁-超镁铁质岩体整体上源于亏损地幔,在演化过程中经历了同化混染作用,中天山和北山地区较东天山地区混染程度较小。成岩成矿集中在早二叠世约280 Ma,指示其可能是统一地球热力学的产物。镁铁-超镁铁质岩体的构造背景复杂,争议较多,单一的构造背景不能解释所有问题,后碰撞伸展和地幔柱的共同作用可能诱发大规模成岩成矿事件。     

The post-collisional Cihai iron skarn deposit,eastern Tianshan,Xinjiang, China

The Cihai iron skarn deposit is located in the southern part of the eastern Tianshan, Xinjiang, northwestern China. The major iron orebodies are banded and nearly parallel to each other. The iron ores are hosted in an early diabase dike and in skarn. Post-ore diabase dikes cut the iron ores and their hosting diabase. Hydrothermal activity can be divided into four stages based on geological and petrographic observations: initial K–Na alteration (stage I), skarn-minor magnetite event (II), retrograde skarn-magnetite main ore event (III), and quartz–calcite–sulfide veining (IV). Zircon U–Pb dating yields ages of 286.5 ± 1.8 Ma for early diabase and 275.8 ± 2.2 Ma for post-ore diabase dikes. Amphibole separated from massive magnetite ore gives a ⁴⁰Ar–³⁹Ar plateau age of 281.9 ± 2.2 Ma and is the time of ore formation. Formation of the Cihai iron deposit is closely related to post-collisional magmatism and associated Cu–Ni–Au polymetallic mineralization in the eastern Tianshan.     

新疆磁海铁（钴）矿床次火山热液成矿学

磁海铁（钴）矿床颇具特色,以“石榴石－透辉石－磁铁矿”为基本矿石建造;成矿作用发生在早二叠世北山裂陷作用和火成活动晚期,以基性次火山岩浆期后富铁流体的（交代）充填为成矿方式,矿体产于辉绿岩体原生裂隙系统;成矿流体的化学演化具有典型（火山）岩浆期后热深演化特点,形成了一系列热液蚀变其中石榴石透辉石岩有别于传统理解的“夕卡岩”;成矿物质源于碱性玄武岩浆,基性次火山岩浆多次脉动式入侵是矿床形成的必要条件     

Newly Discovered Native Gold and Bismuth in the Cihai Iron-Cobalt Deposit, Eastern Tianshan, Northwest China

The Cihai iron-cobalt deposit is located in the southern part of the eastern Tianshan ironpolymetallic metallogenic belt. Anomalous native gold and bismuth have been newly identified in Cinan mining section of the Cihai deposit. Ore formation in the deposit can be divided into three stages based on geological and petrographical observations:(I) skarn, with the main mineral assemblage being garnet-pyroxene-magnetite;(II) retrograde alteration, forming the main iron ores and including massive magnetite, native gold, native bismuth, and cobalt-bearing minerals, with the main mineral assemblage being ilvaite-magnetite-native gold-native bismuth; and(III) quartz-calcitesulfide assemblage that contains quartz, calcite, pyrrhotite, cobaltite, and safflorite. Native gold mainly coexists with native bismuth, and they are paragenetically related. The temperature of initial skarn formation was higher than 340℃, and then subsequently decreased to ~312℃ and ~266℃. The temperature of the hydrothermal fluid during the iron ore depositional event was higher than the melting point of native bismuth(271℃), and native bismuth melt scavenged gold in the hydrothermal fluid, forming a Bi-Au melt. As the temperature decreased, the Bi-Au melt was decomposed into native gold and native bismuth. The native gold and native bismuth identified during this study can provide a scientific basis for prospecting and exploration for both gold- and bismuth-bearing deposits in the Cihai mining area. The gold mineralization in Cihai is a part of the Early Permian Cu-Ni-Au-Fe polymetallic ore-forming event, and its discovery has implications for the resource potential of other iron skarn deposits in the eastern Tianshan.     

A synthesis of iron deposits in the eastern Tianshan,NW China

The northern Xinjiang region is one of the most significant iron metallogenic provinces in China.Iron deposits are found mainly within three regions:the Altay,western Tianshan,and eastern Tianshan orogenic belts.Previous studies have elaborated on the genesis of Fe deposits in the Altay orogenic belt and western Tianshan.However,the geological characteristics and mineralization history of iron deposits in the eastern Tianshan are still poorly understood.In this paper I describe the geological characteristics of iron deposits in the eastern Tianshan,and discuss their genetic types as well as metallogenic-tectonic settings,Iron deposits are preferentially distributed in central and southern parts of the eastern Tianshan.The known iron deposits in the eastern Tianshan show characteristics of magmatic Fe-Ti-V(e.g.,Weiya and Niumaoquan),sedimentary-metamorphic type(e.g.,Tianhu),and iron skarn(e.g.,Hongyuntan).In addition to the abovementioned iron deposits,many iron deposits in the eastern Tianshan are hosted in submarine volcanic rocks with well-developed skarn mineral assemblages.Their geological characteristics and magnetite compositions suggest that they may belong to distal skarns.SIMS zircon U-Pb analyses suggest that the Fe-Ti oxide ores from Niumaoquan and Weiya deposits were formed at 307.7±1.3 Ma and 242.7±1.9 Ma,respectively.Combined with available isotopic age data,the timing of Fe mineralization in the eastern Tianshan can be divided into four broad intervals:Early Ordovician-Early Silurian(476-438 Ma),Carboniferous(335-303 Ma),Early Permian(295-282 Ma),and Triassic(ca.243 Ma).Each of these episodes corresponds to a period of subduction,post-collision,and intraplate tectonics during the Paleozoic and Mesozoic time.     

新疆东天山小白石头钨(钼)矿辉钼矿Re-Os同位素年龄及成矿时代

小白石头钨(钼)矿床位于新疆东天山造山带中的中天山地块南缘,该矿床是一个由黑云母花岗岩和花岗闪长岩侵入中元古界卡瓦布拉格群形成的矽卡岩型钨(钼)矿床。辉钼矿作为其主要的矿石矿物之一,呈不同产出状态分布于花岗闪长岩、黑云母花岗岩、矽卡岩和石英脉中。目前,对于小白石头钨(钼)矿成矿时代尚有争议,特别是与花岗闪长岩有关的辉钼矿化形成时代缺乏精确的限定。本文选取与花岗闪长岩有关的不同产状辉钼矿进行Re-Os同位素定年,获得Re-Os加权平均模式年龄为245. 0±1. 7Ma,Re-Os等时线年龄为245. 5±4. 3Ma。准确的Re-Os同位素定年限定小白石头钨(钼)矿床的成矿年龄和花岗闪长岩的侵位年龄为245Ma左右,为矿床模型建立和找矿方向确定提供了关键依据,同时也为东天山区域成矿规律总结提供了重要的年代学证据,并指出新疆东天山—甘肃北山地区存在一条找矿潜力巨大的三叠纪钨钼成矿带。     

西藏措勤隆格尔铁矿岩体成岩时代及其地质意义

西藏措勤县的隆格尔铁矿位于拉萨地块隆格尔-工布江达弧背断隆带的西段,是冈底斯西段中生代矽卡岩型铁矿中重要的矿床之一。野外和室内工作表明,隆格尔铁矿床属矽卡岩型铁矿,与成矿有关的岩体为粗粒二长花岗岩。因此,本文通过对隆格尔铁矿成矿岩体的LA_ICP_MS和SHRIMP锆石U_Pb定年来探讨其成矿时代。分析结果表明:隆格尔粗粒二长花岗岩年龄为115.5±2.1 Ma,可近似代表铁成矿年龄。隆格尔铁矿与其东侧同处于同一构造单元内的尼雄铁矿床成岩成矿年龄为110~116 Ma,两者间的洛布勒铁矿床的成岩成矿年龄为111.3±1.6 Ma。这些铁矿床处于相同的构造单元,具相似的成矿特征和相近的成岩成矿年龄,构成一条东西向展布的早白垩世矽卡岩型铁矿成矿带,并可能向西延伸包括帮部勒、龙认拉、查加寺等矽卡岩型铁矿床。该带上还发育有晚白垩世的矽卡岩型铜金矿床,如日阿铜金矿床,成矿年龄均为87 Ma。因此,这一成矿带应当具有相同或相似的地质背景和构造-岩浆演化过程。隆格尔铁矿床乃至整个成矿带成铁的岩浆活动可能与洋壳断离前的板片回卷过程相关,成铜金的岩浆活动可能与洋壳断离过程相关,而矿区内石英闪长岩的侵入处于两者之间。     

Two periods of mineralization in Xiaoxinancha Au–Cu deposit,NE China: evidences from the geology and geochronology

The Xiaoxinancha Au–Cu deposit is located at the eastern segment of the Tianshan–Xingmeng orogenic belt in northeast China. The deposit includes porphyry Au–Cu orebodies, veined Au–Cu orebodies and veined Mo mineralizations. All of them occur within the diorite intrusion. The Late Permian diorite, Late Triassic granodiorite, Early Cretaceous granite and granite porphyry are developed in the ore area. The studies on geological features show that the porphyry Au–Cu mineralization is related to the Late Permian diorite intrusion. New geochronologic data for the Xiaoxinancha porphyry Au–Cu deposit yield Permian crystallization zircon U–Pb age of 257 ± 3 Ma for the diorite that hosts the Au–Cu mineralization. Six molybdenite samples from quartz + molybdenite veins imposed on the porphyry Au–Cu orebodies yield an isochron age of 110.3 ± 1.5 Ma. The ages of the molybdenites coeval to zircon ages of the granite within the errors suggest that the Mo mineralization was genetically related to the Early Cretaceous granite intrusion. The formation of the diorite and the related Au–Cu mineralization were caused by the partial melting of the subduction slab during the Late Palaeozoic palaeo‐Asia Ocean tectonic stage. The Re contents and Re–Os isotopic data indicate that the crustal resource is dominated for the Mo mineralization during the Cretaceous extensional setting caused by the roll‐back of the palaeo‐Pacific plate. Copyright © 2014 John Wiley & Sons, Ltd.     

新疆北山小常山铁矿矿物电子探针分析及矿床成因探讨

小常山铁矿位于新疆北山裂谷带西段,矿体赋存于辉长岩、辉长岩和大理岩接触带中,部分赋存于花岗闪长岩和大理岩接触带。前人研究辉长岩年龄为276±1.2Ma,与坡北铜镍硫化物岩浆矿床形成年龄一致,同属早二叠世。小常山铁矿中可见有明显的岩浆贯入现象。矿体主要呈透镜状、块状、脉状、薄层状。金属矿物主要为磁铁矿,含极少量的褐铁矿和黄铁矿;近矿围岩蚀变较弱,主要有石榴子石化、绿帘石化、大理岩化。电子探针研究表明,磁铁矿FeOT含量范围较大,主要分布在85%范围以上,Al_2O_3含量相对较高,TiO_2-Al_2O_3-(MgO+MnO)图解、TiO_2-Al_2O_3-MgO图解均显示热液接触交代成因特点,表明小常山铁矿的形成和岩浆热液的交代作用有关。石榴子石属于钙铝榴石-钙铁榴石系列,与典型矽卡岩矿床的石榴子石端员组分组成有一定差别。结合小常山铁矿体地质特征以及电子探针分析测试等研究,认为小常山铁矿是多成因的复合型矿床,具有岩浆成因和热液成因特征,但后者是主要成因。     

西天山望峰金矿床绢云母40Ar/39Ar年龄及矿床成因研究

望峰金矿床位于中天山北缘冰达坂韧性剪切带内,成矿单元划分属于博罗科努多金属成矿带内天格尔-可可乃克次级成矿带,矿体主要赋存于糜棱岩化花岗岩中,主要矿石类型为石英脉型和蚀变糜棱岩型矿石。对两种类型矿石中的绢云母进行~(40)Ar/~(39)Ar测年,获得坪年龄分别为(250.9±3.0)Ma、(255.8±3.0)Ma,两个样品正反等时线年龄与坪年龄在误差范围内一致,表明坪年龄结果可信,可以代表成矿年龄,说明望峰金矿床的主成矿期时代为晚二叠世末期,且蚀变糜棱岩型矿石的形成时代比石英脉型矿石略早。结合矿区地质情况及前人的研究结果,认为望峰金矿床是剪切带型金矿床,冰达坂韧性剪切带控制了望峰金矿的成矿过程。