北欧海深层水的研究进展简

As a connection region between North Atlantic and Arctic Oceans, the Nordic Sea plays a critical role in global climate system. In the Nordic Seas, surface water converts into intermediate water and deep water after cooling and other effects. These waters transport southward, and enter into North Atlantic as a form of overflow, therefore, they are the main source of the North Atlantic Deep Water(NADW), which play a key role in global ocean conveyor. The causes and processes of the deep water formation in the Nordic Seas are still uncertain. Based on a review of current and historical research results of the deep water in the Nordic Seas, the most important process for deep water formation convection is addressed. Factors and physical processes that may have impact on deep water formation are summarized. The transport of deep water in the Nordic Seas is summed up. Multi year variation of the deep water is described with the aim of giving some instructions and research directions to the readers.     

Seasonally ice free glacial nordic seas without deep water ventilation

At present the Nordic Seas are a key region of North Atlantic Deep Water (NADW) formation. Two alternative scenarios have been suggested by some authors for the Last Glacial Maximum: (i) the Nordic Seas were permanently covered by sea ice, preventing the formation of NADW, or (ii) that they were seasonally free of ice and that deep water formation did occur. A modified scenario is presented here based on parallel ocean circulation modelling results from the GFDL primitive equation model and a planetary geostrophic model. It is suggested that the glacial Nordic Seas were at least seasonally ice free, but it is observed that there was never deep water formation from the surface; rather it occurred only in the North Atlantic south of 40°–50°N. North of 40°N, the weaker LGM northward flowing thermohaline conveyor is subducted below a reverse conveyor which occurred to a depth of over 1000 m. Various modelling experiments presented here indicate that the reversed conveyor was primarily caused by the colder conditions of the glacial North Atlantic that led to far stronger zonality of glacial analogue of the North Atlantic Current.     

Variability of the Denmark Strait Overflow during the Last Glacial Maximum

The Denmark Strait Overflow (DSO) today compensates for the northward flowing Norwegian and Irminger branches of the North Atlantic Current that drive the Nordic heat pump. During the Last Glacial Maximum (LGM), ice sheets constricted the Denmark Strait aperture in addition to ice eustatic/isostatic effects which reduced its depth (today ∼630 m) by ∼130 m. These factors, combined with a reduced north-south density gradient of the water-masses, are expected to have restricted or even reversed the LGM DSO intensity. To better constrain these boundary conditions, we present a first reconstruction of the glacial DSO, using four new and four published epibenthic and planktic stable-isotope records from sites to the north and south of the Denmark Strait. The spatial and temporal distribution of epibenthic δ¹⁸O and δ¹³C maxima reveals a north-south density gradient at intermediate water depths from σ₀ ∼28.7 to 28.4/28.1 and suggests that dense and highly ventilated water was convected in the Nordic Seas during the LGM. However, extremely high epibenthic δ¹³C values on top of the Mid-Atlantic Ridge document a further convection cell of Glacial North Atlantic Intermediate Water to the south of Iceland, which, however, was marked by much lower density (σ₀ ∼28.1). The north-south gradient of water density possibly implied that the glacial DSO was directed to the south like today and fed Glacial North Atlantic Deep Water that has underthrusted the Glacial North Atlantic Intermediate Water in the Irminger Basin.     

Late Quaternary changes in surface water and deep water masses of the Nordic Seas and north-eastern North Atlantic: a review

Quantitative and semiquantitative proxy data based on more than 200 core-top samples and 100 deep-sea cores lead to important new insights about late Quaternary changes in paleo-oceanography, climate and microfaunal habitats in the north-eastern North Atlantic and Nordic Seas, insights resulting from a detailed investigation by the Kiel research project SFB 313/132 summarized in this paper. Planktonic foraminifera species provide reliable tracers of past sea surface temperatures and currents. The genus Beella in particular was found to trace subtropical water masses up to the far north. Benthic foraminifera species served as sensors of bottom currents and local flux rates of organic matter. New orders of time resolution are reached via stable isotope stratigraphy and accelerator mass spectrometry carbon-14 dating, allowing the identification of meltwater events lasting a few hundred years and shorter, a time range where, however, the yet unquantified role of bioturbation presents a growing problem. Based on this high-resolution stratigraphy a number of time slices (synoptic time intervals) are defined to reconstruct the incursion of Atlantic water masses, to map paleocurrent patterns within the Nordic Seas and the north-eastern North Atlantic and to test alternative circulation models — for example, for the last glacial maximum (LGM) and various meltwater episodes. These are clearly coeval with Dansgaard-Oeschger events found in Greenland ice cores, with the actual cause of the flickering climate as yet unknown. Likewise, there is ongoing controversy about the extent of past sea-ice cover and about possible changes from the present anti-estuarine to estuarine mode of deep water exchange between the North Atlantic and the Nordic Seas during the LGM. South of Iceland, however, the history of deep water renewal over the last glacial cycle covering the last 30000 years was largely deciphered.     

An Overview of Hydrological Characteristics and Changing Mechanism of Modern Nordic Seas Overflows

As a connection region between Arctic and North Atlantic oceans, the Nordic seas play a critical role in global climate system. The density waters overflow through Greenland-Scotland Ridge from the Nordic seas, as the main source of the North Atlantic Deep Water (NADW), which plays a key role in global ocean conveyor. The causes and processes, which give some instruction of the overflow variation are still uncertain. Based on a review of current and historical research results of modern Nordic seas overflows, hydrological and flux characteristics and variation features of overflows through three channels, which are Faroe-Shetland Channel, Iceland-Faroe Ridge and Denmark Strait, from Nordic sea were addressed separately. The origins of overflows water and factors and physical processes that may have impact on the three overflows were also analyzed separately. Intense mixing in overflow through Faroe-Shetland Channel was discussed. At last, the changing mechanism of the whole overflow from Nordic seas and relationships among overflows through different channels were summed up. The aim of this paper is to give some instructions and research directions to the internal readers.     

A new concept for the paleoceanographic evolution of Heinrich event 1 in the North Atlantic

New records of planktonic foraminiferal δ¹⁸O and lithic and foraminiferal counts from Eirik Drift are combined with published data from the Nordic Seas and the “Ice Rafted Debris (IRD) belt”, to portray a sequence of events through Heinrich event 1 (H1). These events progressed from an onset of meltwater release at ～19 ka BP, through the ‘conventional’ H1 IRD deposition phase in the IRD belt starting from ～17.5 ka BP, to a final phase between 16.5 and ～15 ka BP that was characterised by a pooling of freshwater in the Nordic Seas, which we suggest was hyperpycnally injected into that basin. After ～15 ka BP, this freshwater was purged from the Nordic Seas into the North Atlantic, which preconditioned the Nordic Seas for convective deep-water formation. This allowed an abrupt re-start of North Atlantic Deep Water (NADW) formation in the Nordic Seas at the Bølling warming (14.6 ka BP). In contrast to previous estimates for the duration of H1 (i.e., 1000 years to only a century or two), the total, combined composite H1 signal presented here had a duration of over 4000 yrs (～19–14.6 ka BP), which spanned the entire period of NADW collapse. It appears that deep-water formation and climate are not simply controlled by the magnitude or rate of meltwater addition. Instead the location of meltwater injections may be more important, with NADW formation being particularly sensitive to surface freshening in the Arctic/Nordic Seas.     

Palaeoceanographic changes in the North Atlantic during the Mid‐Pleistocene Transition (MIS 31–19) as inferred from planktonic foraminiferal and calcium carbonate records

Marine sediments from the Integrated Ocean Drilling Project (IODP) Site U1314 (56.36°N, 27.88°W), in the subpolar North Atlantic, were studied for their planktonic foraminifera, calcium carbonate content, and Neogloboqudrina pachyderma sinistral (sin.) δ¹³C records in order to reconstruct surface and intermediate conditions in this region during the Mid‐Pleistocene Transition (MPT). Variations in the palaeoceanography and regional dynamics of the Arctic Front were estimated by comparing CaCO₃ content, planktonic foraminiferal species abundances, carbon isotopes and ice‐rafted debris (IRD) data from Site U1314 with published data from other North Atlantic sites. Site U1314 exhibited high abundances of the polar planktonic foraminifera N. pachyderma sin. and low CaCO₃ content until Marine Isotope Stage (MIS) 26, indicating a relatively southeastward position of the Arctic Front (AF) and penetration of colder and low‐salinity surface arctic water‐masses. Changing conditions after MIS 25, with oscillations in the position of the AF, caused an increase in the northward export of the warmer North Atlantic Current (NAC), indicated by greater abundances of non‐polar planktonic foraminifera and higher CaCO₃. The N. pachyderma sin. δ¹³C data indicate good ventilation of the upper part of the intermediate water layer in the eastern North Atlantic during both glacial and interglacial stages, except during Terminations 24/23, 22/21 and 20/1. In addition, for N. pachyderma (sin.) we distinguished two morphotypes: non‐encrusted and heavily encrusted test. Results indicate that increases in the encrusted morphotype and lower planktonic foraminiferal diversity are related to the intensification of glacial conditions (lower sea‐surface temperatures, sea‐ice formation) during MIS 22 and 20.     

Mud volcano gas hydrates in the Gulf of Cadiz

ABSTRACT This paper presents new geochemical data on gas-hydrate-bearing mud volcanoes discovered for the first time in the Gulf of Cadiz during cruises TTR9 and TTR10 of the R/V Professor Logachev in 1999–2000. The estimated gas hydrate content is 3–16% of sediment volume and 5–31% of pore space volume. Estimated values of the water isotopic composition for the Ginsburg mud volcano are very heavy for δ¹⁸O (up to +53‰) and light for δD (up to − 210‰). Gas released from the hydrates contains 81% of C₁ and 19% of C₂₊. The inferred source of the gas in the hydrates is enriched in C₂–C₆ (≤ 5%), indicating that the gas has a thermogenic origin. Gas hydrate of cubic structure II should be formed from a gas of such composition. It is interpreted that the composition of the mud volcano fluid corresponds to deep oil basins below the Gulf of Cadiz.     

Freshwater pulses in the eastern Arctic Ocean during Saalian and Early Weichselian ice-sheet collapse

Improved multiparameter records from the northern Barents Sea margin show two prominent freshwater pulses into the Arctic Ocean during MIS 5 that significantly disturbed the regional oceanic regime and probably affected global climate. Both pulses are associated with major iceberg-rafted debris (IRD) events, revealing intensive iceberg/sea ice melting. The older meltwater pulse occurred near the MIS 5/6 boundary (∼131,000 yr ago); its ∼2000 year duration and high IRD input accompanied by high illite content suggest a collapse of large-scale Saalian Glaciation in the Arctic Ocean. Movement of this meltwater with the Transpolar Drift current into the Fram Strait probably promoted freshening of Nordic Seas surface water, which may have increased sea-ice formation and significantly reduced deep-water formation. A second pulse of freshwater occurred within MIS 5a (∼77,000 yr ago); its high smectite content and relatively short duration is possibly consistent with sudden discharge of Early Weichselian ice-dammed lakes in northern Siberia as suggested by terrestrial glacial geologic data. The influence of this MIS 5a meltwater pulse has been observed at a number of sites along the Transpolar Drift, through Fram Strait, and into the Nordic Seas; it may well have been a trigger for the North Atlantic cooling event C20.     

中国第二次北极科学考察路线上温室气体瓶采样结果分析

用气相色谱和非红外色散分析方法,分析了中国第二次北极科学考察路线上采集到的气体样品中温室气体(CO₂和CH₄)的浓度,对不同纬度带上CO₂和CH₄平均浓度变化特征进行了研究.结果表明:海洋表面不同纬度带上CO₂的浓度呈现出随纬度升高而减小的趋势,这与全球范围内CO₂的年平均浓度的地理分布特征相反,显示了海洋对CO₂气体的吸收作用.45°N以北的海洋表面,CH₄浓度有随纬度升高而增大的趋势,这与全球范围内CH₄的年平均浓度的地理分布特征相同;中纬度近海岸地区温室气体浓度变化无明显规律,可能受到区域或局地气团的影响较大.     

2012年夏季挪威海和格陵兰海水文特征分析

利用2012年夏季在北欧海(挪威海和格陵兰海)的水文考察数据,对调查区域内海洋水团性质和分布进行了分析,并对北欧海冷却对流的发展加深过程进行了研究。在上层,从东侧暖而咸的大西洋水跨越锋区至西侧低温低盐的格陵兰海盆上层水体,温度和盐度的变化分别可以达到8℃和0.4 psu。中层与深层水体的性质则相对均匀和稳定,3个海盆内从浅至深依次分布着北极中层水、海盆深层水、北极深层水以及海盆底层水。格陵兰海盆中深层水体在3 500 m深度上位温约为-0.97℃,相比较1970s观测到的-1.30℃,升温幅度超过了0.3℃,表明海盆深层存储的热量显著增加。在只考虑局地表面冷却的简化条件下,当前格陵兰海内部通过冷却对流混合至季节性跃层下界需要向大气释放0.9×109~1.2×109J的热量,这一过程至少需要2个月的时间而不利于对流向深层的发展。大量的热量被存储于北欧海深海盆中使得北欧海已经成为北半球高纬海域的热量存储器,对当前北极气候变化的影响有待深入研究。     

Neodymium isotopes in seawater from the Barents Sea and Fram Strait Arctic-Atlantic gateways

The neodymium concentration, C_Nd, and isotopic composition, ε_Nd, in seawater have been determined in the water column at five sites in the Barents Sea-Fram Strait area where most of the water exchange between the Arctic Ocean and the North Atlantic takes place. In the main Arctic Ocean inflow branch across the Barents Sea the concentration and isotopic composition (C_Nd = 15.5 pmol/kg and ε_Nd = −10.8) are similar to those reported for the northeastern Nordic Seas, which is consistent with this region being a source area for the Arctic inflow. Due to the addition of Nd from Svalbard shelf sediments, the C_Nd in the surface waters above 150 m, in the Fram Strait inflow branch is higher by a factor of 2 and the ε_Nd is shifted to lower values (−11.8).In the stratified Nansen Basin, where cold low salinity water overlies warmer Atlantic water the C_Nd and ε_Nd do not vary with the vertical temperature-salinity structure but are essentially constant and similar to those of the Atlantic inflow throughout the entire water column, down to 3700 m depth, which indicates that the Nd is to a large extent of Atlantic origin.Compared to the Atlantic inflow water, the Nd in the major Arctic Ocean outflow, the Fram Strait, show higher C_Nd in the surface waters above 150 m, and a higher ε_Nd (−9.8) throughout the entire water column down to 1300 m depth. Sources for the more radiogenic Nd isotopic composition in deep water of the Fram Strait outflow most likely involve boundary exchange with sediments on the shelf and slope as the water passes along the Canadian archipelago. River water is a possible source in the surface water but it also seems likely that Pacific water Nd, modified by interactions on the shelf, is an important component in the Fram Strait surface outflow. Changes in the relative proportions of inflow of river water and flow of Pacific water through the Arctic Ocean could thus influence the isotopic composition of Nd in the North Atlantic.     

Paleogeography and paleobathymetry of the Mesozoic and Cenozoic North Atlantic Ocean

The history of the North Atlantic Ocean has been traced quantitatively back in time using age and subsidence of the oceanic crust in an attempt to reconstruct the vertical and horizontal elements of its physiographic evolution. Special emphasis has been paid to the history of the Iceland-Faeroe Ridge and of the epicontinental seas around this young basin. The implications of this evolution for changes in the hydrographic regime and for temporal as well as spatial contraints of the surface and bottom water circulation of the North Atlantic are enormous. During its early history this part of the world ocean was connected to the circum-equatorial Tethys Ocean (Late Jurassic to mid-Cretaceous). However, the formation of a deep water pathway to the South Atlantic towards the end of the Mesozoic and the opening of the Norwegian-Greenland Seas during the Early Cenozoic caused the North Atlantic to become part a longitudinal basin allowing an exchange between the Artic and Antarctic polar water masses.Dedicated to Professor Dr. E. Seibold, President of the German Research Society, on the occasion of his 60th birthday.     

Evidence for delayed poleward expansion of North Atlantic surface waters during the last interglacial (MIS 5e)

The Last Interglacial (Marine Isotopic Stage or MIS 5e) surface ocean heat flux from the Rockall Basin (NE Atlantic) towards the Arctic Ocean was reconstructed by analysing dinoflagellate cyst (dinocyst) assemblages in four sediment cores. Together with records of stable isotopes and ice-rafted detritus, the assemblage data reflect the northward retreat of ice(berg)-laden waters and the gradual development towards interglacial conditions at the transition from the Saalian deglaciation (Termination II) into MIS 5e. At the Rockall Basin, this onset of the Last Interglacial is soon followed by the appearance of the thermophilic dinocyst species Spiniferites mirabilis, with relative abundances higher than those observed at present in the area. North of the Iceland-Scotland Ridge, however, S. mirabilis only appears in significant numbers during late MIS 5e, between ～118 and 116.5 ka. Hence, fully marine Last Interglacial conditions with most intense Atlantic surface water influence occurred during late MIS 5e in the Nordic seas, and consequently also farther north in the Arctic Ocean, and at times when northern hemisphere summer insolation was already significantly decreased. The stratigraphic position of this Late Interglacial optimum is supported by planktic foraminifers and contrasts with the timing of the early Holocene climatic optimum in this area. We interpret the delayed northward expansion of Atlantic waters towards the polar latitudes as a result of the Saalian ice sheet deglaciation and its specific impact on the subsequent water mass evolution in this region.     

Thermosteresis and Transportation of Atlantic Water Along Eurasian Basin of the Arctic Ocean

It is summarized based on previous studies that warm and salty Atlantic Water (AW) brings huge amount of heat into Arctic Ocean and influences oceanic heat distribution and climate. Both heat transportation and heat release of AW are key factors affecting the thermal process in Eurasian Basin. The Arctic circumpolar boundary current is the carrier of AW, whose flow velocity varies to influence the efficiency of the warm advection. Because the depth of AW in Eurasian Basin is much shallower than that in Canadian Basin, the upward heat release of AW is an important heat source to supply sea ice melting. Turbulent mixing, winter convention and double-diffusion convention constitute the main physical mechanism for AW upward heat release, which results in the decrease of the Atlantic water core temperature during its spreading along the boundary current. St. Anna Trough, a relatively narrow and long trough in northern continental shelf of Kara Sea, plays a key role in remodeling temperature and salinity characteristics of AW, in which the AW from Fram Strait enters the trough and mixes with the AW from Barents Sea. Since the 21^st Century, AW in the Arctic Ocean has experienced obvious warming and had the influence on the physical processes in downstream Canada Basin, which is attributed to the anomalous warming events of AW inflowing from the Fram Strait. It is inferred that the warming AW is dominated by a long-term warming trend superimposed on low frequency oscillation occurring in the Nordic Seas and North Atlantic Ocean. As the Arctic Ocean is experiencing sea ice decline and Arctic amplification, the role of AW heat release in response to the rapid change needs further investigation.     

Anthropogenic CO2 in Southern Ocean surface waters: evidence from stable organic carbon isotopes

We present an approach for tracing the fate of anthropogenic CO₂, compiling a large data set of stable organic carbon isotope ratios from surface sediments, plankton, and sinking matter in the Atlantic Ocean. The δ¹³C values of sinking matter are generally lower by 0.5–4.6‰ compared to the surface sediments. This difference increases with increasing latitude, which is explained by a stronger modern increase in surface water [CO₂ (aq)] in the Southern Ocean relative to the Tropical/Subtropical Ocean. Preindustrial dissolved CO₂ concentrations in Atlantic surface waters, estimated from the δ¹³C_org of surface sediments, are compared to recently measured surface water [CO₂ (aq)] values taken from literature. We obtain only a slight increase in [CO₂ (aq)] at lower latitudes but a significant change of about 7 ± 2 μ m in high latitudinal surface waters which we attribute to anthropogenic perturbation. Our results suggest that CO₂ released by human activities has been stored in Southern Ocean surface waters.     

Experimental Study Assessing the Role of Sedimentary Organic Materials to Control the Redox State of Ground Materials to Control the Redox State of Groundwater: Consumption of Dissolved Oxygen by Humic Acid

Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O₂ concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O₂ concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10^-9 at 25°C, 2.22 × 10^-8 at 45°C, and 1.28 × 10^-7 moles m^-2 s^-1 at 65°C.     

Refinements in BaSO4 to CO2 Preparation and δ18 O Calibration of the Sulfate Reference Materials NBS-127, IAEA SO-5 and IAEA SO-6

Refinements have been made to achieve over 99% yield in the conversion of CO to CO₂ in order to improve the reproducibility and accuracy of δ¹⁸ O measurements in sulfates. BaSO₄ (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO₂; the former gas was simultaneously converted to CO₂ by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ¹⁸ O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO₂ produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO₂ equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from ¹⁸O/¹⁶O of the working calibrator we used CO₂ gas prepared from ocean water sulfate for this purpose. The calibrated δ¹⁸ O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively.     

Chronology and paleoenvironments during the late Weichselian deglaciation of the southwest Iceland shelf

Foraminifera, sedimentology, and tephra geochemistry in core 93030-006 LCF from the southwestern Iceland shelf were used to reconstruct paleoenvironments between 12.7 and 9.4 ¹⁴C ka BP. Seismic-reflection profiles place the core in glacial-marine and marine sediments within one meter of the underlying glacial till. Foraminifers in the earliest glacial-marine sediments provide a record of ice-distal conditions and immigration of slope species onto the shelf in association with warm Atlantic water. Meltwater increased during the Allerød under a weakened Atlantic water influence. Arctic conditions began by 11.14 ₁₄C ka BP with an abrupt increase in meltwater and near exclusion of boreal fauna from the shelf. Meltwater diminished in the early Younger Dryas, coinciding with sea-surface cooling between 11.14 and 10.5 ¹⁴C ka BP. A slight warming recorded in the uppermost glacial-marine sediments was interrupted by an inferred jökulhlaup event emanating from glacier ice on the Western Volcanic Zone. Retreat of the ice margin from the sea sometime between c. 10.3 and 9.94 ¹⁴C ka BP coincided with this event. The onset of postglacial marine sedimentation occurred along with increasing evidence of Atlantic water c. 9.94 ¹⁴C ka BP and was interrupted by a short-lived Pre-boreal cooling of the Irminger Current c. 9.91 ¹⁴C ka BP. Conditions similar to those today were established by 9.7 ¹⁴C ka BP.     

Experimental study of the stability of sudoite and magnesiocarpholite and calculation of a new petrogenetic grid for the system FeO–MgO–Al2O3–SiO2–H2O

The solid-solid reaction magnesiocarpholite = sudoite + quartz has been bracketed between 350 and 500°C, 6.3 and 7.8 kbar. Because it is impossible to synthesize end-member sudoite, all experiments were carried out using natural minerals as starting materials. Although mineral compositions were very close to those of the end-members, the effect of the fluorine content in carpholite was significant. Particularly in those experiments where sudoite grows at the expense of carpholite, electron microprobe analysis of the run products shows that a more stable F-rich carpholite crystallizes too, and consumes the fluorine released in solution by the breakdown of the original carpholite.
Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)_-1 substitutions in phyllosilicates. This allows us to constrain the feasible thermodynamic parameters (H°_f, sud; S ° sud) and (H°_f,car; S °_car) for the Mg end-members. Using the partition coefficients calculated from natural parageneses, we have computed a petrogenetic grid for the system FeO–MgO–Al₂O₃–SiO₂–H₂O. It demonstrates that parageneses involving sudoite and carpholite can be used as indicators of P–T conditions, up to 600° C, 8 kbar for sudoite, and at higher pressure for carpholite.