藏东南迦巴瓦地区雅鲁藏布江蛇绿混杂岩中玻安岩的地球化学特征和地质意义

对南迦巴瓦地区雅鲁藏布江蛇绿混杂岩带内旁辛蛇绿岩中变基性岩的地球化学特征进行研究后,发现该基性岩为玻安岩,具有SiD2＞53%,镁指数(Mg#)＞0.6,难熔元素(Cr、Co和Ni)明显富集,而高场强元素(Nb、Zr、Ti和Y)亏损等玻安岩所具有的典型地球化学特征.旁辛蛇绿岩中玻安岩的主要地球化学特征不仅能与世界著名的玻安岩进行对比,而且也能与雅鲁藏布江蛇绿岩带的日喀则和得几蛇绿岩中的玻安岩进行对比.因此,可以认为南迦巴瓦地区雅鲁藏布江蛇绿混杂岩形成于岛弧环境.     

藏东南迦巴瓦地区雅鲁藏布江蛇绿混杂岩中玻安岩的地球化学特征和地质意义

对南迦巴瓦地区雅鲁藏布江蛇绿混杂岩带内旁辛蛇绿岩中变基性岩的地球化学特征进行研究后,发现该基性岩为玻安岩,具有SiO2>53%,镁指数(Mg#)>0.6,难熔元素(Cr、Co和Ni)明显富集,而高场强元素(Nb、Zr、Ti和Y)亏损等玻安岩所具有的典型地球化学特征。旁辛蛇绿岩中玻安岩的主要地球化学特征不仅能与世界著名的玻安岩进行对比,而且也能与雅鲁藏布江蛇绿岩带的日喀则和得几蛇绿岩中的玻安岩进行对比。因此,可以认为南迦巴瓦地区雅鲁藏布江蛇绿混杂岩形成于岛弧环境。     

藏东南迦巴瓦地区雅鲁藏布江蛇绿混杂岩中玻安岩的地球化学特征和地质意义

对南迦巴瓦地区雅鲁藏布江蛇绿混杂岩带内旁辛蛇绿岩中变基性岩的地球化学特征进行研究后,发现该基性岩为玻安岩,具有SiD2＞53%,镁指数(Mg#)＞0.6,难熔元素(Cr、Co和Ni)明显富集,而高场强元素(Nb、Zr、Ti和Y)亏损等玻安岩所具有的典型地球化学特征.旁辛蛇绿岩中玻安岩的主要地球化学特征不仅能与世界著名的玻安岩进行对比,而且也能与雅鲁藏布江蛇绿岩带的日喀则和得几蛇绿岩中的玻安岩进行对比.因此,可以认为南迦巴瓦地区雅鲁藏布江蛇绿混杂岩形成于岛弧环境.     

西藏丁青弧前蛇绿岩的地球化学特征

丁青蛇绿岩位于班化湖－丁青－怒江蛇绿岩带的东段，其地幔岩出露规模是该带中最大的。本文报道的丁青蛇绿岩主要由地幔橄榄岩、堆晶岩、辉长岩和斜长花岗岩组成。蛇绿岩剖面上覆硅岩中的放射虫化石是早株罗世和晚三叠世诺利克期的，中侏罗统砂岩和砾岩不整合覆盖在蛇绿岩之上，由此确定丁青蛇绿岩是晚三叠－早侏罗世的，在中株罗世之前侵位，丁青蛇绿岩属于玻安岩系，玻安岩的特点是富Si、Mg和大离子亲石元素（LILE），贫高场强元素（Ti、P、Zr、Y、Yb和Nb）。丁青蛇绿岩的堆晶岩、辉长岩和辉绿岩均具“U”型REE分布，暗示丁青玻安岩是由于亏损的地幔源岩和来自消减带的水和流体两组分的混合形成的。丁青玻安岩的地球化学特征类似西太平洋第三纪玻安岩，而明显不同于MORB的地球化学性质， 表明丁青玻安岩应当形成于洋内岛弧的弧前环境，属于弧前蛇绿岩。     

青藏高原西部蛇绿岩中玻安岩(boninite)及其地质意义

简要报道了在青藏高原西部班公湖蛇绿岩带和狮泉河蛇绿岩带之间的火山岩中识别出的玻安岩。玻安岩是俯冲岩浆作用的产物,在青藏高原东部及周边地区已有玻安岩或玻安岩系岩石存在的报道。结合西部出现的玻安岩说明青藏高原地区俯冲作用普遍存在。玻安岩的形成时代为J₂-K₁,埃达克岩的形成时代为K₁,由J₂-K₁,的玻安岩至K₁的埃达克岩反映冈底斯北部岛弧带由不成熟的洋内弧向成熟岛弧转变的过程,它们是中生代冈底斯北部大陆水平生长(侧向增生)的记录。     

豆荚状铬铁矿床的研究现状及进展

豆荚状铬铁矿床是工业上冶金级铬铁矿石的最主要来源,对于其成因研究依然是各国地质学家最为关注的热点之一。文章着重概述了近年来国内外地质学者对豆荚状铬铁矿床成因研究的现状和最新进展。最新研究表明,显生宙以来的豆荚状铬铁矿床具有一定的成矿专属性,主要赋存于蛇绿岩套底部(壳-幔边界,即岩石莫霍面)地幔橄榄岩中的一定层位中。世界上含矿的地幔橄榄岩普遍具有垂直熔融分带特征,即上部偏基性,下部偏酸性。豆荚状铬铁矿床与纯橄岩-方辉橄榄岩相密接相关,却很少见有豆荚状铬铁矿床产于二辉橄榄岩中。豆荚状铬铁矿的成矿作用经历了由洋中脊(MOR)扩张环境向岛弧体系俯冲环境的转变过程,而岛弧环境(岛弧、弧后盆地、弧前盆地等)是形成冶金级豆荚状铬铁矿的最为有利的构造环境。富铬铬铁矿与纯橄岩、玻安岩(Boninite)均为亏损地幔橄榄岩再次高度熔融的最终产物,而玻安岩普遍产于岛弧环境。虽然玻安岩不是铬的有效载体,但玻安岩的熔离促使铬铁矿达到进一步的富集。铬铁矿中的铬来自原始地幔,主要来自于地幔橄榄岩中两种辉石的不一致熔融及其对副矿物铬尖晶石的改造。随着部分熔融程度的增高,地幔橄榄岩逐渐向富镁方向演变,而对应的造矿铬尖晶石也逐渐向富镁、富铬方向演变。     

西秦岭商丹缝合带寒武纪斜长花岗岩的成因机制——对原特提斯洋俯冲起始的启示

大洋斜长花岗岩是指分布在蛇绿岩或现今洋壳中的少量长英质侵入体,可形成在洋中脊及俯冲带等多种构造环境,虽然其在洋壳和蛇绿岩中所在体积很小,但对探究大洋岩石圈演化、俯冲起始及洋-陆转化机制具有重要意义。本文对北秦岭造山带西段商丹缝合带内新识别出的斜长花岗岩开展了岩石学、地球化学和锆石U-Pb年代学的综合研究。全岩地球化学结果指示花岗闪长岩具有高的SiO₂、Al₂O₃含量以及较低的K₂O、TiO₂含量,属于低钾亚碱性、准铝质到弱过铝质的岩石。微量元素相对富Sr、贫Nb、Ta和Ti,具有平坦的稀土元素配分模式,是弧前环境中由俯冲板片在浅部层次部分熔融成因的大洋斜长花岗岩。3个斜长花岗岩样品分别记录了526±4 Ma、515±4 Ma和517±6 Ma的锆石U-Pb年龄,结合前人同时代的玻安岩、高镁安山岩的报道,西秦岭商丹缝合带保留有与伊豆-小笠原-马里亚纳(IBM)俯冲带相似的弧前岩石组合,这些弧前的玻安岩、高镁安山岩和斜长花岗岩表明商丹洋在早寒武世发生了洋壳的初始俯冲。结合区域地质资...     

中国蛇绿岩的分布、时代及其形成环境

中国蛇绿岩分布很广，主要在中国的西部，西南部和北部，中部和南部较少，蛇绿岩形成的时代可分为元古宙，早古生代、晚古生代和中－新生代四个时期，中国元古宙蛇绿岩分布零星。星生宙蛇绿岩主要分布在古亚洲洋，秦祁昆洋，古特提斯洋，新特提斯洋和和环太平洋等5个区域，古亚洲洋蛇绿岩位于塔里木和华北地块之北的中国北方，秦祁昆洋位于塔里木、华北和扬子地块之间，古特提斯洋和新特提斯洋位于中国的西南地区，环太平洋带有东北和台湾的蛇绿岩，中国蛇绿岩的地和玻安岩产出，指示产于消减带之上的构造环境，在这些蛇绿岩中也有MORB产出，可能是弧后盆地环境的，也可能有正常大洋岩石圈碎片的残留。古特提斯蛇绿岩MORB发育，而减少与消减作用有关的岩石组（IAT和玻安岩），推测形成在陆间洋盆环境。     

内蒙古达茂旗哈尔陶勒盖地区蛇绿岩形成环境探讨

内蒙古达茂旗哈尔陶勒盖地区蛇绿岩的堆晶岩为橄榄岩 辉石岩 辉长岩组合,即为PPG型;通过岩石化学、地球化学研究,首次从辉长岩中识别出有玻安岩存在,为本区蛇绿岩的形成环境从岩类学方面提供依据;玄武岩具洋脊玄武岩特征,但俯冲带组分(Th等)富集;在混杂带内分布有泥盆纪岛弧型中-中酸性火山岩,整合于硅泥质岩之上。基于上述几个方面的分析,提出本区蛇绿岩的形成环境应为SSZ型,既形成于初始俯冲,在俯冲带之上(弧前)形成新的洋壳,并逐渐向岛弧演化。     

西藏雅鲁藏布江缝合带西段达巴蛇绿岩年代学、地球化学特征及其构造意义

达巴蛇绿岩位于雅鲁藏布江蛇绿岩带西段南亚带,主要由地幔橄榄岩、基性岩脉和硅质岩组成,其形成时代和构造背景尚不清楚.首次报道了达巴蛇绿岩中基性岩脉的岩石学、锆石U-Pb年代学、全岩地球化学数据.达巴辉长岩和辉绿岩具有高的Al和Mg、低Ti、K和P,为低钾钙碱性玄武质岩石.岩石具有与N-MORB一致的稀土配分模式,但是N-MORB标准化蛛网图中显示Nb负异常,显示了受到俯冲板片流体的影响.辉绿岩的锆石U-Pb年龄为120.0±1.7 Ma,为早白垩世晚期,地球化学特征显示源自于低程度的尖晶石相地幔源区的部分熔融.结合前人研究成果,认为达巴蛇绿岩形成于与初始俯冲有关的弧前扩张中心,是受到俯冲板片流体交代的上覆地幔楔部分熔融的产物.      

Neoproterozoic zirconium-depleted boninite and tholeiitic series rocks from Adola, southern Ethiopia

In Adola, southern Ethiopia, mafic and ultramafic igneous rocks occur in narrow, 4–10 km wide, north-south-trending belts bounded by high-grade gneisses and migmatites. The mafic/ultramafic rocks are complexly deformed and metamorphosed in greenschist to lower amphibolite facies and are thought to be tectonically dismembered parts of an ophiolite complex. Preliminary geochemical and geochronological data highlight that the high-grade rocks in southern Ethiopia and northern Kenya include a significant portion of juvenile rocks that were accreted at the same time as ophiolitic rocks at 885-765 Ma. This is also the time of widespread oceanic magmatism and closure in the Arabian-Nubian Shield to the north.The Adola mafic rocks were previously described as island arc tholeiites and mid-ocean ridge basalts (MORB). New chemical analyses on the Megado belt rocks reveal the presence of boninites and related dacites interspersed with tholeiitic rocks. The Adola boninites are similar to the Cambrian boninites in western Tasmania in having relatively low Zr/Sm (≤32). Boninites with similarly low ratios have not been reported from elsewhere.The Adola tholeiites have high Ti/Zr (150–300). Mixing between tholeiite and boninite magmas may have resulted in elevated Ti/Zr (80–126) in some Adola boninites. Otherwise, Ti/Zr in the latter is low (20–40). Low Ti/Zr is characteristic of Tertiary boninites in the west Pacific. The fact that both Ti/Eu and Zr/Sm increase from the Adola and Tasmania type to the Tertiary boninites at constant Ti/Zr suggests that Ti might be an element that is also metasomatically added to the source of boninites and raises doubts about the role of amphibole in boninite petrogenesis.     

Petrology and geochemistry of boninite series volcanic rocks from the Mariana trench

Boninite series volcanic rocks have been recovered from three dredge hauls on the inner slope of the Mariana Trench. These hauls included olivine boninites, boninites, boninitic andesites and boninitic dacites, as well as island arc tholeiitic basalts and andesites. The boninite series volcanics range from 52 to 68% SiO₂, and are characterized by very low abundances of high-field-strength cations and heavy-rare-earth elements. Boninites and olivine boninites have phenocrysts of olivine and orthopyroxene, the andesites phenocrysts of orthopyroxene and clinopyroxene, and the dacites orthopyroxene, clinopyroxene, and plagioclase. Most of the major and trace element variation in the series from boninite to boninitic dacite can be modelled by fractionation of olivine, orthopyroxene, clinopyroxene, and plagioclase in the proportions 2.5412, leaving 47% residual liquid. The fractionation must be in part open-system: reverse zoned phenocrysts, resorbed olivine and plagioclase xenocrysts, and bulk rock compositions which cannot be fit by simple closed system crystallization indicate some magma mixing and phenocryst accumulation. Two boninitic magma stems can be identified, with similar high-field-strength element abundances, but different amounts of Ca, Na, Al and light-rare-earth elements. There is also evidence for a magma stem transitional in chemistry from the boninites to arc tholeiites. The compositions of these boninites are consistent with hypotheses for boninite formation by partial melting of a depleted mantle mixed with an incompatible element enriched fluid. The Mariana forearc boninite series lacks a strong iron enrichment, but produces andesites with lower Ti, Al and Y/Zr, and higher Mg, Ni and Cr than typical calcalkaline arc andesites and dacites. Boninites in the Mariana system were erupted only in the earliest phases of subduction zone activity.     

Liquid Immiscibility of Boninite in Xiangcheng, Southwestern China, and Its implication to Genetic Relationship between Boninite and Komatiitic Basalt

Boninitic rocks and associated high-magnesian basalt and high-iron tholeiite in the Xiangcheng area constitute the basal horizon of the arc volcanic sequence in the Triassic Yidun Island-Arc, southwestern China. The boninite occurs as pillow, massive and ocellar lavas; the last one possesses well-developed globular structure and alternates with the former two. The boninite is characterized by the absence of phenocrysts of olivine and low-Ca pyroxenes and by low CaO/Al2O3 ratios (<0.67) and high Cr (>1000 ppm) and Ni (>250 ppm). The normalized abundance patterns (NAP) of trace elements to primitive mantle are similar to the NAP of low-Ca modern boninites and SHMB in the Archaean and Proterozoic.As a mechanism of ocellar texture, liquid immiscibility in boninite is supported by the following lines of evidence: (a) sharp contact between ocelli and matrix, (b) constant volumetric ratios of ocelli/matrix and common coalescence of ocelli in ocellar rocks, (c) identical micro-spinifex textures and mineral asse     

内蒙西乌旗白音布拉格蛇绿岩地球化学特征

内蒙古西乌旗白音布拉格蛇绿岩带是新发现的内蒙古西乌旗迪彦庙蛇绿岩带的北带,主要由蛇纹石化方辉橄榄岩、层状-块状辉长岩、斜长岩、枕状玄武岩、角斑岩-石英角斑岩及硅质岩等构造单元组成.白音布拉格蛇绿岩中的熔岩按照地球化学特征可以分为三组:第1组属于玻安岩系,以富Si(SiO2=52.71％、61.22％)、Mg(MgO=6.81％和10.88％)和贫Ti(TiO2 =0.49％、0.51％)、HREE及HFSE为特征;第2组具有低Ti(TiO2 =0.62％～0.78％)、高Mg(MgO =5.20％ ～11.30％)的特征,LREE弱亏损、类似N-MORB的稀土配分模式,但相对N-MORB,又具有富集LILE,亏损Nb、Ta等高场强元素的特征,类似岛弧拉斑玄武岩(IAT);第3组表现为:岩石具有高Ti(TiO2=1.86％、1.91％)、高Mg(MgO=5.25％和5.46％)及高P(P2O5=0.23％、0.27％),LREE和HREE分异较为明显((La/Yb)N=2.32、2.53)等特征,类似OIB.根据玻安岩与IAT的存在,推测白音布拉格蛇绿岩产于岛弧和弧前环境.     

Nd-isotope and geochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite suite of rocks in the southern Bastar craton,central India: petrogenesis and tectonic significance

ABSTRACT

Nd-isotope and lithogeochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite (BN) suite of rocks from the southern Bastar craton, central India, are presented to understand their nature, origin, and tectonic setting of emplacement. Various types of evidence, such as field relationships, radiometric metamorphic ages, and the global distribution of BN magmatism, suggest emplacement in an intracratonic rift setting, commonly around 2.4–2.5 Ga. On the basis of geochemistry these high-Si high-Mg rocks are classified as high-Ca boninites, high-Mg norites, and high-Mg diorites. Nd-isotope data indicate that the high-Mg norite and the high-Mg diorite samples are similar, whereas the high-Ca boninites have a different isotopic character. The high-Mg norite and the high-Mg diorite samples have younger T_DM model ages than the high-Ca boninites. Geochemical and Nd-isotopic characteristics of the studied rocks indicate some prospect of crustal contamination; however, the possibility of mantle metasomatism during ancient subduction event cannot be ignored. Trace-element modelling suggests that the high-Ca boninites may have crystallized from a magma generated by a comparatively greater percentage of melting of a lherzolite mantle source than the source for the other two varieties. Furthermore, the high-Ca boninite rocks are most likely derived from an Archaean subduction process (the Whundo-type), whereas the other two types are the products of the interaction of subduction-modified refractory mantle wedge and a plume, around the Neoarchaean–Palaeoproterozoic boundary. The emplacement of the high-Mg norites and the high-Mg diorites may be linked to crustal thickening and associated cratonization at the end of the Archaean.     

藏东南雅鲁藏布蛇绿混杂岩带的物质组成及形成环境

雅鲁藏布蛇绿混杂岩带位于藏东南南迦巴瓦峰地区(喜马拉雅东构造结),呈弧形大致沿雅鲁藏布江分布,出露宽度2～10km。带内岩石变质、变形强烈,按产状可分为两大类:基质和岩块(片)。岩块(片)包括蛇绿岩套中的超镁铁岩、辉绿岩墙和辉长岩,石英(片)岩,大理岩和两侧老基底片麻岩等。岩块(片)大小不一,大的延伸可>50km,小的仅约0.5m;基质是塑性变形十分强烈的绢云母石英片岩、二云母石英片岩、绿片岩等岩石组合。变质玄武岩岩石地球化学特征表明,该蛇绿混杂岩带可能由形成环境不同的“碎片”组成,包括弧前扩张带、岛弧、弧后盆地及洋岛等环境,是典型的消减带环境的蛇绿岩(SSZ)。初步的同位素年代学测试结果,说明蛇绿岩可能在200Ma前形成,比原认为距今110～120Ma要早得多,这一结果与该带其它地段的研究成果相似。     

再论蛇绿岩中豆荚状铬铁矿的成因——质疑岩石/熔体反应成矿说

着重论述了蛇绿岩地幔橄榄岩中豆荚状铬铁矿的成因,并对现今盛行的岩石/熔体反应成矿说提出了质疑。世界含铬铁矿的地幔橄榄岩均显示上部偏基性、下部偏酸性的垂直熔融分带,与蛇绿岩堆晶岩中上部偏酸性、下部偏基性的岩浆分异垂直层序恰恰相反。豆荚状铬铁矿与熔融剖面上部的纯橄岩或纯橄岩-方辉辉橄岩杂岩带紧密伴生。豆荚状铬铁矿是原始地幔岩高度熔融再造的产物,高铬型铬铁矿与PPG型蛇绿岩伴生,形成于岛弧或弧前盆地环境;高铝型铬铁矿与PTG型蛇绿岩伴生,形成于扩张脊（MOR）或弧后盆地环境。玻安岩（boninite）与高铬型豆荚状铬铁矿无成因关系,铬铁矿（或富铬矿浆）的形成反而为boninite提供了其形成所需的残余地幔;高铝型铬铁矿不是地幔橄榄岩/拉斑玄武质熔体反应形成的,而是富铬矿浆与基性熔体发生再平衡的产物。豆荚状铬铁矿中超高压矿物包体的出现为其地幔深部成因提供了佐证,而boninite形成于浅部较低压的条件;豆荚状铬铁矿中富集强相容元素IPGE（Os、Ir、Ru）合金,boninite富集不相容元素PPGE (Pt、Pd)硫（砷）化物, 而亏损IPGE,显示其形成较晚。因此,boninite与铬铁矿无生因关系,两者均受岛弧（或弧前盆地）环境的制约而在空间上相伴产出。     

Simultaneous boninitic and arc-tholeiitic volcanisms in the Izu forearc region during early arc volcanism, based on ODP Leg 125 Site 786

Early arc volcanism during Eocene to Oligocene in the Izu forearc region was investigated during ODP Legs 125 and 126 in 1989, and effusive and intrusive volcanics were recovered from Leg 125 Site 786. These rocks were all classified into boninites and associated rocks by Leg 125 Shipboard Scientific Party, and they concluded that boninitic volcanism had occurred before 40 Ma, and arc tholeiitic volcanism began after 40 Ma. In this study, lava flows and breccias that classified into boninite series are divided into two groups, tholeiite and boninite, based on petrographical and petrological properties. Both series are also distinguished by bulk rock composition. It is considered that the sources of both rock types have similar depleted compositions because of their similar, very low bulk HFSE concentrations. We suggest that boninitic and tholeiitic volcanism occurred closely in time and space, and reflected different temperature and water condition.