Nd-isotope and geochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite suite of rocks in the southern Bastar craton,central India: petrogenesis and tectonic significance

ABSTRACT

Nd-isotope and lithogeochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite (BN) suite of rocks from the southern Bastar craton, central India, are presented to understand their nature, origin, and tectonic setting of emplacement. Various types of evidence, such as field relationships, radiometric metamorphic ages, and the global distribution of BN magmatism, suggest emplacement in an intracratonic rift setting, commonly around 2.4–2.5 Ga. On the basis of geochemistry these high-Si high-Mg rocks are classified as high-Ca boninites, high-Mg norites, and high-Mg diorites. Nd-isotope data indicate that the high-Mg norite and the high-Mg diorite samples are similar, whereas the high-Ca boninites have a different isotopic character. The high-Mg norite and the high-Mg diorite samples have younger T_DM model ages than the high-Ca boninites. Geochemical and Nd-isotopic characteristics of the studied rocks indicate some prospect of crustal contamination; however, the possibility of mantle metasomatism during ancient subduction event cannot be ignored. Trace-element modelling suggests that the high-Ca boninites may have crystallized from a magma generated by a comparatively greater percentage of melting of a lherzolite mantle source than the source for the other two varieties. Furthermore, the high-Ca boninite rocks are most likely derived from an Archaean subduction process (the Whundo-type), whereas the other two types are the products of the interaction of subduction-modified refractory mantle wedge and a plume, around the Neoarchaean–Palaeoproterozoic boundary. The emplacement of the high-Mg norites and the high-Mg diorites may be linked to crustal thickening and associated cratonization at the end of the Archaean.     

Juxtaposition of adakite,boninite, high-TiO2 and low-TiO2 basalts in the Devonian southern Altay,Xinjiang, NW China

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.     

Precambrian mafic magmatism in the Singhbhum craton,eastern India

The Singhbhum craton has a chequred history of mafic magmatism spanning from early Archaean to Proterozoic. However, lack of adequate isotopic age data put constraints on accurately establishing the history of spatial growth of the craton in which mafic magmatism played a very significant role. Mafic magmatism in the craton spreads from ca.3.3 Ga (oldest “enclaves” of orthoamphibolites) to about 0.1 Ga (‘Newer dolerite’ dyke swarms). Nearly contemporaneous amphibolite and intimately associated tonalitic orthogneiss may represent Archaean bimodal magmatism. The metabasic enclaves are appreciably enriched and do not fulfill the geochemical characteristics of worldwide known early Archaean (>3.0 Ga) mafic magmatism. The enclaves reveal compositional spectrum from siliceous high-magnesian basalt (SHMB) to andesite. However, the occurrence of minor depleted boninitic type within the assemblage has so far been overlooked. High magnesian basalt with boninitic character of Mesoarchaean age is also reported in association with supracrustals from southern fringe of the granitoid cratonic nucleus. The subcontinental lithospheric mantle (SCLM) below the craton is conjectured to have initiated during the early Archaean. Significantly, recurrence of depleted magma types in the craton is observed during the whole span of mafic igneous activity which has been vaguely related to “mantle heterogeneity”, although the alternative model of sequential mantle melting is also being explored. The Singhbhum craton includes the Banded Iron Formation (BIF) associated mafic lavas, MORB-like basic and komatiitic ultrabasic bimodal volcanism — documented as Dalma volcanics, Dhanjori lavas, and the Proterozoic Newer dolerite dykes. Three different types of REE fractionation patterns are observed in the BIF-associated mafic lavas. These are the REE unfractionated type is more depleted than N-MORB and some lavas with boninitic type of REE distribution. MORB-like basic and komatiitic ultrabasic (Dalma volcanics) are emplaced within the Proterozoic Singhbhum Basin (PSB). The vista of magmatism in the basin was controlled by a miniature spreading centre represented by the mid-basinal Dalma volcanic ridge. The volcano-sedimentary basinal domain of Dhanjori emerged at the interface of two subprovinces (viz. the mobile volcano-sedimentary belt of PSB and rigid granite platform) under unique stress environment related to extensional tectonic regime. Trace element distribution in Dhanjori lavas is remarkably similar to that in PSB minor intrusions and lavas (except a Ta spike in the latter). The Proterozoic Newer dolerite dykes within Singhbhum nucleus manifest an unusually wide spam of intrusive activity (ca 2100 Ma to 1100 Ma) and unexpectedly uniform mantle melting behaviour.     

Simultaneous boninitic and arc-tholeiitic volcanisms in the Izu forearc region during early arc volcanism, based on ODP Leg 125 Site 786

Early arc volcanism during Eocene to Oligocene in the Izu forearc region was investigated during ODP Legs 125 and 126 in 1989, and effusive and intrusive volcanics were recovered from Leg 125 Site 786. These rocks were all classified into boninites and associated rocks by Leg 125 Shipboard Scientific Party, and they concluded that boninitic volcanism had occurred before 40 Ma, and arc tholeiitic volcanism began after 40 Ma. In this study, lava flows and breccias that classified into boninite series are divided into two groups, tholeiite and boninite, based on petrographical and petrological properties. Both series are also distinguished by bulk rock composition. It is considered that the sources of both rock types have similar depleted compositions because of their similar, very low bulk HFSE concentrations. We suggest that boninitic and tholeiitic volcanism occurred closely in time and space, and reflected different temperature and water condition.     

A clinoenstatite-bearing cumulate Olivine Pyroxenite from Howqua,Victoria

The Howqua Olivine Pyroxenite of eastern Victoria, Australia, intrudes a metamorphosed sequence of Cambrian high-Mg lavas. It crystallized an unusual mineral assemblage: Cr-rich magnesiochromite, olivine (Fo₉₄), and protoenstatite (now inverted to polysynthetically-twinned clinoenstatite). Residual liquid crystallized strongly-zoned interstitial pyroxenes followed by pargasite. Pargasite, often showing quench habit, crystallized in interstitial glass which is now altered to serpentine.The extremely refractory nature of the cumulus phases indicates a very high temperature of crystallization for liquidus olivine and chromite from a high-MgO, low-Al₂O₃ parent liquid similar in some respects to Archaean peridotitic komatiites. The suggested origin by hydrous melting of depleted mantle peridotite, plus other compositional and mineralogical similarities (especially the olivine-liquid reaction producing protoenstatite) indicate that the parent magma of the Howqua Olivine Pyroxenite had many features in common with the high-SiO₂, high-MgO clinoenstatite-bearing boninitic lavas of the Western Pacific. It is interpreted as a more extreme melt with affinities to boninite and it demonstrates that ultramafic magmas existed in the Cambrian.     

Juxtaposition of adakite, boninite, high-TiO2 and low-TiO2 basalts in the Devonian southern Altay, Xinjiang, NW China

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.     

Petrology and geochemistry of boninite series volcanic rocks from the Mariana trench

Boninite series volcanic rocks have been recovered from three dredge hauls on the inner slope of the Mariana Trench. These hauls included olivine boninites, boninites, boninitic andesites and boninitic dacites, as well as island arc tholeiitic basalts and andesites. The boninite series volcanics range from 52 to 68% SiO₂, and are characterized by very low abundances of high-field-strength cations and heavy-rare-earth elements. Boninites and olivine boninites have phenocrysts of olivine and orthopyroxene, the andesites phenocrysts of orthopyroxene and clinopyroxene, and the dacites orthopyroxene, clinopyroxene, and plagioclase. Most of the major and trace element variation in the series from boninite to boninitic dacite can be modelled by fractionation of olivine, orthopyroxene, clinopyroxene, and plagioclase in the proportions 2.5412, leaving 47% residual liquid. The fractionation must be in part open-system: reverse zoned phenocrysts, resorbed olivine and plagioclase xenocrysts, and bulk rock compositions which cannot be fit by simple closed system crystallization indicate some magma mixing and phenocryst accumulation. Two boninitic magma stems can be identified, with similar high-field-strength element abundances, but different amounts of Ca, Na, Al and light-rare-earth elements. There is also evidence for a magma stem transitional in chemistry from the boninites to arc tholeiites. The compositions of these boninites are consistent with hypotheses for boninite formation by partial melting of a depleted mantle mixed with an incompatible element enriched fluid. The Mariana forearc boninite series lacks a strong iron enrichment, but produces andesites with lower Ti, Al and Y/Zr, and higher Mg, Ni and Cr than typical calcalkaline arc andesites and dacites. Boninites in the Mariana system were erupted only in the earliest phases of subduction zone activity.     

Mineralogy, Chemistry, and Genesis of the Boninite Series Volcanics, Chichijima, Bonin Islands, Japan

The Bonin archipelago represents an uplifted fore-arc terrainwhich exposes the products of Eocene supra-subduction zone magmatism.Chichijima, at the centre of the chain, represents the typelocality for the high-Mg andesitic lava termed boninite. Therange of extrusives which constitute the boninite series volcanicsare present on Chichijima, and are disposed in the sequenceboninite-andesite-dacite with increasing height in the volcano-stratigraphy.Progression to evolved compositions within the Chichijima boniniteseries is controlled by crystal fractionation from a boniniteparental magma containing 15% MgO. Olivine and clinoenstatiteare the initial liquidus phases, but extraction of enstatiticorthopyroxene, followed by clinopyroxene and plagioclase, isresponsible for the general evolution from boninite, throughandesite, to dacite. Some andesites within the overlying MikazukiyamaFormation are petrographically distinct from the main boniniteseries in containing magnetite phenocrysts and a high proportionof plagioclase. As such, these andesites have affinities withthe calc-alkaline series. Major and trace element data for 74 boninitic series rocks fromChichijima are presented. Although major element variation isdominantly controlled by high-level crystal fractionation, thelarge variations in incompatiable trace element concentrationsat high MgO compositions cannot be explained by this mechanism.Nd, Pb, and Sr isotopic data indicate the following: (1) a strongoverprint on ⁸⁷Sr/⁸⁶Sr by seawater alteration; (2) Pb isotopeslie above the northern hemisphere reference line (NHRL) andare thus similar to the <30-Ma are and basin lavas of theIzu—Bonin system, and (3) _Nd(40 Ma) ranges between 2.8and 6.8 within the boninite series volcanics. Differences inrare-earth elements (REE), Zr, Ti, and ¹⁴³Nd/¹⁴⁴Nd at similardegrees of fractionation can be explained by the addition ofa component of fixed composition from the down-going oceaniccrustal slab to a variably depleted source region within theoverlying wedge. Data presented for Sm/Zr and Ti/Zr indicatethat boninite series volcanics are characterized by low valuesfor both of these ratios. In particular, boninites appear tohave uniquely low Sm/Zr ratios. These characteristics may bethe result of slab melting in the presence of residual amphibole;the resultant melt could combine with typical slab dehydrationfluids and infiltrate the overlying mantle wedge. Such a fluid—meltcomponent could mix either with shallow mantle or directly withprimitive melts from depleted mantle. Trace elements, REE, andisotope data thus point to a model for boninite genesis whichrequires tightly constrained pressure—temperature conditionsin the slab combined with melting of a variably depleted sourcein the overlying wedge. Such constraints are rarely met exceptduring the subduction of juvenile oceanic crust beneath a young,hot overriding plate.     

青海省刚察地区高镁安山岩锆石U-Pb LA-ICP-MS年代学及构造意义

基于青海省刚察地区1：5万电泵站等4幅区调项目,在拉脊山蛇绿构造混杂岩带药水泉组中识别一套玄武岩、玄武安山岩、安山岩类岩石组合,其岩相学、岩石地球化学特征与高镁安山岩相类似.岩石斑晶以斜长石和辉石为主,不含橄榄石,基质也含有大量的斜长石.岩石地球化学特征表现为K₂O+Na₂O含量2.55%~5.15%,Na₂O > K₂O,K₂O含量0.22%~0.82%,为低钾;CaO含量5.31%~11.41%,TiO₂含量0.27%~0.55%,变化范围较小;MgO含量为5.78%~11.06%,变化范围不大.总体具有低硅、钛、钾,高钙、镁,富钠之特征.稀土配分曲线为右倾斜状,多呈铕正异常,为轻稀土富集型.微量元素Rb、Ba、Th、Cr、Ni等变化幅度大,反映岩浆生成和演化过程复杂,但演变仍以部分熔融为主.选取玄武岩样品,通过LA-ICP-MS U-Pb锆石微区定年,获得了451.7±1.8 Ma年龄值,其时代为晚奥陶世.总体特征表明,刚察地区火山岩为埃达克型高镁安山岩,其构造环境为活动大陆边缘的岛弧.     

Crystallization Orders and Phase Chemistry of Glassy Lavas from the Pillow Sequences, Troodos Ophiolite, Cyprus

Three genetically unrelated magma suites are found in the extrusivesequences of the Troodos ophiolite, Cyprus. A stratigraphicallylower pillow lava suite contains andesite and dacite glassesand shows the crystallization order plagioclase; augite, orthopyroxene;titanomagnetite (with the pyroxenes appearing almost simultaneously).These lavas can in part be correlated chemically and mineralogicallywith the sheeted dikes and the upper part of the gabbro complexof the ophiolite. The second magma suite is represented in astratigraphically upper extrusive suite and contains basalticandesite and andesite glasses with the crystallizaton orderchromite; olivine; Ca-rich pyroxene; plagioclase. This magmasuite can be correlated chemically and mineralogically withparts of the ophiolitic ultramafic and mafic cumulate sequence,which has the crystallization order olivine; Ca-rich pyroxene;orthopyroxene; plagioclase. The third magma suite is representedby basaltic andesite lavas along the Arakapas fault zone andshows a boninitic crystallization order olivine; orthopyroxene;Ca-rich pyroxene; plagioclase. One-atmosphere, anhydrous phaseequilibria experiments on a lava from the second suite indicateplagioclase crystallization from 1225?C, pigeonite from 1200?C,and augite from 1165?C. These experimental data contrast withthe crystallization order suggested by the lavas and the associatedcumulates. The observed crystallization orders and the presenceof magmatic water in the fresh glasses of all suites are consistentwith evolution under relatively high partial water pressures.In particular, high P_H2O (1–3 kb) can explain the lateappearances of plagioclase and Ca-poor pyroxene in the majorityof the basaltic andesite lavas as the effects of suppressedcrystallization temperatures and shifting of cotectic relations.The detailed crystallization orders are probably controlledby relatively minor differences in the normative compositionsof the parental magmas. The basaltic andesite lavas are likelyto reach augite saturation before Ca-poor pyroxene saturation,whereas the Arakapas fault zone lavas, which have relativelyless normative diopside and more quartz, reached the Ca-poorpyroxene-olivine reaction surface and crystallized Ca-poor pyroxeneafter olivine.     

西藏丁青地区与玻镁安山岩类有关的蛇绿岩的矿物学特征

西藏丁青蛇绿岩的东杂岩体是一种与玻镁安山岩(Boninite)有关的特殊的蛇绿岩类型。其 堆晶斜方辉石岩、辉长岩和辉绿岩的岩石化学、微量元素以及稀土元素的地球化学特征均与西太平洋诸岛(伊豆—马利亚纳、巴布亚新几内亚、新喀里多尼亚等)的玻镁安山岩相似。此外,超镁铁质构造岩中的橄榄石和顽火辉石富镁,指示残余地幔具强烈亏损的性质。尖晶石的Cr含量中等至较高,与深海橄榄岩及大洋中脊玄武岩中的尖晶石不同。堆晶岩和辉长岩中的古铜辉石富镁,斜长石富钙,也明显不同于典型大洋中脊环境的特征,表明丁青东蛇绿岩形成的环境不像大洋中脊或弧后盆地,而可能是在洋内俯冲带之上的岛弧底部。     

Calc-alkaline, Shoshonitic, and Primitive Tholeiitic Lavas from Monogenetic Volcanoes near Crater Lake, Oregon

Quaternary monogenetic volcanism in the High Cascades of Oregonis manifested by cinder cones, lava fields, and small shields.Near Crater Lake caldera, monogenetic lava compositions include:low-K (as low as 0?09% K₂O) high-alumina olivine tholeiite (HAOT);medium-K. calc-alkaline basalt, basaltic andesite, and andesite;and shoshonitic basaltic andesite (2?1% K₂O, 1750 ppm Sr at54% SiO₂). Tholeiites have MORB-like trace element abundancesexcept for elevated Sr, Ba, and Th and low high field strengthelements (HFSE), and they represent near-primary liquids. Theyare similar to HAOTs from the Cascades and adjacent Basin andRange, and to many primitive basalts from intraoceanic arcs.Calc-alkaline lavas show a well-developed arc signature of highlarge-ion lithophile elements (LILE) and low HFSE. Their Zrand Hf concentrations are at least partly decoupled from thoseof Nb and Ta; HREE are low relative to HAOT. Incompatible elementabundances and ratios vary widely among basaltic andesites.Some calc-alkaline lavas vented near Mount Mazama contain abundantgabbroic microxcnoliths, and are basaltic andesitic magmas contaminatedwith olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgOand compatible trace element contents that suggest only minorfractionation. There appears to be a compositional continuumbetween primitive tholeiitic and calc-alkaline lavas. Compositionalvariation within suites of comagmatic primitive lavas, boththoleiitic and calc-alkaline, mainly results from differentdegrees of partial melting. Sources of calc-alkaline primarymagmas were enriched in LILE and LREE by a subduction componentand contained residual garnet, whereas sources of HAOTs hadlower LILE and LREE concentrations and contained residual clinopyroxene.High and variable LILE and LREE contents of calc-alkaline lavasreflect variations in fluid-transported subduction componentadded to the mantle wedge, degree of partial melting, and possiblyalso interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesitesby fractionation of plagioclase+augite+magnetite+apatite ? orthopyroxeneor olivine, commonly accompanied by assimilation. Many andesitesare mixtures of andesitic or dacitic magma and a basaltic orbasaltic andesitic component, or are contaminated with gabbroicmaterial. Mingled basalt, andesite, and dacite of Williams Craterformed by multi-component, multi-stage mixing of basaltic andesiticmagma, gabbro, and dacitic magma. The wide range of compositionsvented from monogenetic volcanoes near Crater Lake is a resultof the thick crust coupled with mild tectonic extension superimposedon a subduction-related magmatic arc.     

Neoproterozoic zirconium-depleted boninite and tholeiitic series rocks from Adola, southern Ethiopia

In Adola, southern Ethiopia, mafic and ultramafic igneous rocks occur in narrow, 4–10 km wide, north-south-trending belts bounded by high-grade gneisses and migmatites. The mafic/ultramafic rocks are complexly deformed and metamorphosed in greenschist to lower amphibolite facies and are thought to be tectonically dismembered parts of an ophiolite complex. Preliminary geochemical and geochronological data highlight that the high-grade rocks in southern Ethiopia and northern Kenya include a significant portion of juvenile rocks that were accreted at the same time as ophiolitic rocks at 885-765 Ma. This is also the time of widespread oceanic magmatism and closure in the Arabian-Nubian Shield to the north.The Adola mafic rocks were previously described as island arc tholeiites and mid-ocean ridge basalts (MORB). New chemical analyses on the Megado belt rocks reveal the presence of boninites and related dacites interspersed with tholeiitic rocks. The Adola boninites are similar to the Cambrian boninites in western Tasmania in having relatively low Zr/Sm (≤32). Boninites with similarly low ratios have not been reported from elsewhere.The Adola tholeiites have high Ti/Zr (150–300). Mixing between tholeiite and boninite magmas may have resulted in elevated Ti/Zr (80–126) in some Adola boninites. Otherwise, Ti/Zr in the latter is low (20–40). Low Ti/Zr is characteristic of Tertiary boninites in the west Pacific. The fact that both Ti/Eu and Zr/Sm increase from the Adola and Tasmania type to the Tertiary boninites at constant Ti/Zr suggests that Ti might be an element that is also metasomatically added to the source of boninites and raises doubts about the role of amphibole in boninite petrogenesis.     

Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, cross-cutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.     

Are Bushveld U-type parent magmas boninites or contaminated komatiites?

Three distinct categories of magmas — Bushveld U-type parent magmas, boninites, and siliceous high magnesium basalts from Archaean greenstone belts —share the distictive geochemical characteristics of high MgO (9%–19%), low TiO₂(less than 1%) and high SiO₂(greater than 52%). Boninites are generally thought to form by hydrous melting of metasomatized, previously depleted upper mantle, while siliceous high magnesium basalts (SHMB) in greenstone belts have recently been recognized as the products of combined fractionation and crustal contamination of komatiites. Both these mechanisms can apparently give rise to similar end products, and both mechanisms have been proposed for the petrogenesis of Bushveld U-type magmas.A detailed comparison of the three magma types, using data drawn from the literature, shows a broad area of overlap in major elements and most trace elements. U-type magmas are generally intermediate in composition between SHMB and boninites. U-type magmas differ significantly from boninites, and are more similar to SHMB, in three important respects: their relatively high abundances of rare earth elements and degree of light rare earth enrichment; higher FeO/MgO ratio for a given MgO content; and Sm/Nd isotopic systematics indicative of crustal contamination. BU magmas are therefore more likely to be extreme examples of contaminated komatiitic parents than primary boninitic mantle melts. The striking similarity in major element chemistry of the three groups may be due to the near-coincidence in compositional space of the mediumpressure, hydrous olivine-orthopyroxene phase boundary, which controls the composition of boninites, with the lowpressure anhydrous phase boundary which controls differentiated SHMB and U-type magmas.     

《变质作用与大陆动力学学术讨论会》在北京召开

冲绳海槽火山岩目前发现有玄武岩、玄武安山岩、安山岩、粗面安山岩、粗面英安岩、英安岩和流纹岩。研究表明，冲绳海槽火山岩均属亚碱性系列，基性岩具有拉斑玄武岩系列和钙碱性系列的过渡性，中、酸性岩多属钙碱性系列；岩石形成于上新世以来，大部分都是富集型地幔玄武质岩浆在分离结晶不同阶段的产物。岩石在分离结晶演化趋势上的一致性和在岩石化学指数变异关系上的多样性是原来快速上升未发生混染的岩浆在断裂构造隔离下分枝独立演化的结果。     

Archaean volcanism and sedimentation near Meekatharra,Western Australia

Archaean volcanic rocks and volcanogenic sediments exposed in a regional syncline south of Meekatharra, Western Australia are described. Initial volcanic activity produced a suite of high-Mg basalts containing 10–19% MgO. Pillowed tholeiitic basalts overlie the high-Mg basalts. These lower units are thought to have been derived from a central fracture zone. The uppermost units consist of volcanogenic sediments interlayered with andesite and dacite flows which appear to have been derived from a marginal andesite pile to the east. The Archaean sequence has been tightly folded, cross-faulted and intruded by post-Archaean dykes.The central succession is predominantly submarine, although the marginal andesite pile may be in part subaerial. Whilst there are some similarities with the Marda complex to the southeast (Hallberg et al., 1976), the rocks near Meekatharra are more analogous to those associated with modern island arcs.     

Precambrian crustal components,plutonic associations,plate environment of the Hercynian Fold Belt of central Europe: Indications from a Nd and Sr isotopic study

Chichi-jima, Bonin Islands, consists of dominant Eocene submarine volcanic rocks, comprising boninites, andesites and dacites, and subordinate sedimentary rocks. The dacites occur frequently in breccias and pillows overlying a boninite pillow lava sequence. The boninite pillows are intruded by a multiple dike, in which a core boninite is chilled against outer dacites. A density-stratified chamber may have been capped by a dacite magma. The dacites, which can be divided into quartz dacite and quartz-free dacite, are differentiates from the boninite-forming magmas, because they vary continuously in composition from boninites through andesites. The quartz dacites, corresponding to rhyolite in SiO₂, are lower in Na₂O and K₂O than most orogenic dacites. Some of the dacites are characterized by ferropigeonite (Wo_7–16En_23–39Fs_68-54) phenocrysts and are clearly ferrodacite, producing variable amounts of Fs-rich normative pyroxenes. The relation of SiO₂ to total FeO/MgO ratio indicates that many of both types of dacites, with glasses in boninites, are enriched in total FeO despite the strong calc-alkalic affinity of boninites. The crystallization temperature of ferropigeonite with Mg value 30 in a quartz dacite is estimated to be 900° C and that in a quartz-free dacite to be 1050° C, which are unusually high for differentiated silicic rocks. Some Chichi-jima rocks are fresh, having a low ratio of Fe₂O₃ to FeO. On the basis of the experimental study of magmatic ferric-ferrous equilibria at 1 bar, the oxygen fugacities are calculated as 10^–13.6 bars at 900° C for a ferropigeonite quartz dacite and 10^–8.9 bars at 1200° C for a boninite with the lowest Fe³⁺/Fe²⁺. Both values lie below the quartz-fayalite-magnetite buffer line. The boninite series volcanic rocks have preserved low oxygen fugacities as well as high temperatures until the latest differentiation stage. The ferropigeonite phenocrysts have crystallized from the dacite magmas under the conditions of moderately high temperatures, very low oxygen fugacities and high total FeO and SiO₂ concentrations.     

Magma development of the Leka Ophiolite Complex, central Norwegian Caledonides

The magmatic products of the Leka Ophiolite Complex of Lower Ordovician age, indicate formation in different tectonic settings and generation from different mantle sources. Harzburgites of the mantle tectonite, clinopyroxenes from wehrlites of the ultramafic cumulates, the metabasalts of the dyke complex and earliest pillow lavas (IAT/MORB, boninites) all show characteristics compatible with formation above a subduction zone in an intra-oceanic setting. Nd-isotopes indicate that some of the IAT and boninites may have been derived from a source contaminated by continental material, and a CAB source differ significantly from that of the IAT and boninites. The later pillow lavas of MORB composition show only minor influence of subduction-related processes (minor or no negative Ta-anomalies), and the supposed latest volcanic sequence of an alkaline OIB-type, none at all. The MORB- and OIB-type magmas are thought developed by spreading in a back-arc setting, in which the latter magma type developed in a remote position from the subduction zone.     

内蒙西乌旗白音布拉格蛇绿岩地球化学特征

内蒙古西乌旗白音布拉格蛇绿岩带是新发现的内蒙古西乌旗迪彦庙蛇绿岩带的北带,主要由蛇纹石化方辉橄榄岩、层状-块状辉长岩、斜长岩、枕状玄武岩、角斑岩-石英角斑岩及硅质岩等构造单元组成.白音布拉格蛇绿岩中的熔岩按照地球化学特征可以分为三组:第1组属于玻安岩系,以富Si(SiO2=52.71％、61.22％)、Mg(MgO=6.81％和10.88％)和贫Ti(TiO2 =0.49％、0.51％)、HREE及HFSE为特征;第2组具有低Ti(TiO2 =0.62％～0.78％)、高Mg(MgO =5.20％ ～11.30％)的特征,LREE弱亏损、类似N-MORB的稀土配分模式,但相对N-MORB,又具有富集LILE,亏损Nb、Ta等高场强元素的特征,类似岛弧拉斑玄武岩(IAT);第3组表现为:岩石具有高Ti(TiO2=1.86％、1.91％)、高Mg(MgO=5.25％和5.46％)及高P(P2O5=0.23％、0.27％),LREE和HREE分异较为明显((La/Yb)N=2.32、2.53)等特征,类似OIB.根据玻安岩与IAT的存在,推测白音布拉格蛇绿岩产于岛弧和弧前环境.