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1.
郭亮  张宏飞  潘发斌 《地学前缘》2012,19(3):228-239
文中对拉萨地块东南缘林芝杂岩中的含榴斜长角闪岩进行了详细的岩相学研究和锆石U-Pb定年。岩相学观察表明,含榴斜长角闪岩经历了峰期麻粒岩相变质和角闪岩相退变质作用。峰期麻粒岩相矿物组合为石榴子石+高Ti角闪石+紫苏辉石+斜长石+石英+金红石,其中的石榴子石、石英和角闪石中含有大量金红石出溶体,说明这些矿物的初始成分具有高Ti含量。角闪岩相退变质矿物组合为低Ti角闪石+斜长石+斜黝帘石+石英+金红石。利用Ti在石英中的含量(TitaniQ)温度计计算得到峰期麻粒岩相变质温度为803~924℃,后期角闪岩相退变质温度为555~732℃。样品中的锆石具有明显的核边结构,核部为典型岩浆型锆石,具有高的Th/U值,强烈富集HREE,明显的正Ce异常和负Eu异常,206Pb/238U年龄为(89.3±0.6)Ma,代表含榴斜长角闪岩原岩结晶年龄。锆石边部呈无环带结构,同核部相比,具有低的Th/U值,低的M-HREE和弱的Eu负异常,为变质峰期生长的锆石,206Pb/238U年龄为(81.1±0.8)Ma,代表麻粒岩相峰期变质年龄。我们认为约81Ma高温麻粒岩相变质作用可能与洋中脊俯冲造成的板片窗导致的软流圈上涌有关。  相似文献   

2.
在柴北缘超高压变质带东段,新识别出一个高压麻粒岩单元,其主要的岩石组合包括基性(长英质)高压麻粒岩、花岗质片麻岩、富铝质片麻岩(片岩)、石榴角闪岩和英云闪长岩。岩相学和变质反应序列、矿物化学和温压估算结果表明,蓝晶-石榴-黑云-二长片麻岩共经历了4阶段的变质演化:Ⅰ早期进变质阶段,以石榴石核部发育的黑云母、白云母、斜长石和石英等矿物包裹体为特征;Ⅱ峰期高压麻粒岩相阶段,矿物组合为石榴石+蓝晶石+条纹长石+斜长石+石英,金红石Zr温度计和GASP压力计限定其峰期温压条件为:t=800~840℃和p=1.4~1.6GPa;Ⅲ高角闪岩相退变质阶段,矿物组合为石榴石(边部)+黑云母+长石+石英;Ⅳ晚期低角闪岩相-绿片岩相退变质阶段,以蓝晶石周围出现的Ms+Pl±Zo和Mrg+Qtz±Ms±Pl后成合晶为特征。锆石LA-ICP-MSU-Pb定年结果指示高压麻粒岩相变质时代为431Ma。蓝晶-石榴-黑云-二长片麻岩具有顺时针的pt演化轨迹,与基性高压麻粒岩形成于相同的动力学过程。  相似文献   

3.
大别山北部鹿吐石铺含石榴子石斜长角闪岩早期经历了榴辉岩相及随后的麻粒岩相退变质阶段,现主要表现为角闪岩相矿物组合特征。它的全岩+角闪石Rb-Sr等时线年龄为172±3Ma(I=0.706095),代表了角闪岩相阶段的退变质年龄。  相似文献   

4.
大别山北部超高压变质大理岩及其地质意义   总被引:3,自引:2,他引:3  
岩石学研究表明 ,大别山北部镁铁 超镁铁质岩带中白云质大理岩至少经历过三期变质阶段 :(1)榴辉岩相峰期变质阶段 ,矿物组合主要为方解石 +白云石 +金红石 +镁橄榄石 +钛 斜硅镁石 +富镁的钛铁矿±文石±石榴子石 ;(2 )麻粒岩相退变质阶段 ,矿物组合主要为方解石 +白云石 +金云母 +镁橄榄石 +透辉石 +钛铁矿 +尖晶石±斜方辉石等 ;(3)角闪岩相退变质阶段 ,主要矿物组合为方解石 +白云石 +磷灰石 +磁铁矿+榍石等。它的峰期变质矿物组合 ,类似于苏 鲁超高压大理岩 ,形成压力至少大于 2 .5GPa。这进一步证明 ,大别山北部大多数高级变质岩 (包括大理岩等 )都曾经过超高压变质作用 ,应属于印支期扬子俯冲陆壳的一部分。  相似文献   

5.
长期以来,陇山杂岩的归属问题一直存在争议。本文对出露于秦岭-祁连山结合部位的陇山杂岩中石榴黑云斜长片麻岩和石榴斜长角闪岩进行了详细的岩石学、P-T温压计算、独居石和榍石U-Pb年代学研究。通过详细的岩相学观察,石榴黑云斜长片麻岩的变质峰期矿物组合为石榴子石+黑云母+斜长石+石英;石榴斜长角闪岩中则识别出了以石榴子石+单斜辉石+角闪石+斜长石+石英为峰期的变质矿物组合。通过传统温压计计算,石榴黑云斜长片麻岩(样品21LS40)和石榴斜长角闪岩样品(样品21LS42-1)的峰期变质P-T条件分别为700℃、0.72GPa和710℃、0.74GPa。激光剥蚀电感耦合等离子体质谱(LA-ICP-MS) U-Pb数据表明,石榴黑云斜长片麻岩中独居石的206Pb/238U的加权平均年龄为407~435Ma。石榴斜长角闪岩中榍石的下交点年龄分别为410±7Ma、409±5Ma和426±10Ma,榍石中Zr含量温度计的计算结果分别为750℃、751℃和748℃(假定压力为0.7GPa)。本文从变质作用的角度出发,将陇山杂岩与秦岭杂岩进行温压条件和变质时代对比研究,认为陇山杂岩与东秦岭杂岩高压-超高压岩石的最后一期退变质作用和西秦岭天水地区的秦岭杂岩麻粒岩相变质作用类似,可能为北秦岭造山带的西延。  相似文献   

6.
东昆仑造山带近年来被厘定为早古生代高压-超高压变质带。带内广泛出露早古生代的中-高级变质基性岩,这些岩石记录了不同的变质温压和多期的变质年龄,是反演和制约东昆仑早古生代变质演化的重要样品。本文选取东昆仑浪木日地区的石榴斜长角闪岩为研究对象,开展了变质岩石学及锆石年代学研究。石榴斜长角闪岩呈团块状出露在黑云二长片麻岩中,主要组成矿物为石榴子石、角闪石、斜长石、透辉石和石英,含少量黑云母、绿泥石、金红石、钛铁矿和榍石。石榴子石变斑晶的核部含有绿帘石、角闪石、斜长石、金红石和石英包裹体,其成分从核部到边部,锰铝榴石逐渐降低、钙铝榴石和Mg/(Mg+Fe;)比值逐渐升高,为进变质作用形成的环带。岩石中的矿物结构关系和成分特征显示其经历了进变质、峰期变质和退变质三个阶段的变质演化,变质温压分别为:T≈610℃和P≈6.5kbar、T≈700℃和P≈10.5kbar以及T≈650℃和P≈4.5kbar。这三阶段的变质作用构成顺时针的变质P-T轨迹,指示岩石经历进变质升温升压至峰期阶段,随后经历近等温降压的退变质阶段。同时该P-T轨迹特征表明岩石形成于俯冲-碰撞的构造背景。对石榴斜长角闪岩中的锆石进行SIMS U-Pb定年,得到492.8±5.1Ma的谐和年龄。锆石的形态特征与典型的变质锆石一致,其内包裹的石榴子石、角闪石和斜长石组合与岩石的峰期矿物组合一致。因此,锆石在峰期变质阶段结晶,所测年龄~493Ma为角闪岩相峰期变质年龄。本文研究的石榴斜长角闪岩与该区高压-超高压榴辉岩在野外产状、P-T轨迹和变质年龄等方面密切相关,暗示ca.490Ma是该区高压-超高压变质作用的一个重要时间节点。石榴斜长角闪岩和榴辉岩之间的变质差异,表明东昆仑早古生代经历了多阶段的变质作用,不同岩石记录了原特提斯洋俯冲-碰撞过程的不同阶段。本文获得的变质P-T轨迹和变质年龄可为进一步探究东昆仑早古生代高压-超高压变质作用提供限定。  相似文献   

7.
运用单颗粒锆石逐层蒸发法和角闪石40Ar/39Ar阶段加热法研究了河南洛宁太华岩群斜长角闪岩的同位素年龄.获得锆石207Pb/206Pb年龄为2675±2 Ma,角闪石40Ar/39Ar坪年龄和等时线年龄分别为2372.98±47.46 Ma和2349.10±46.98 Ma.锆石207Pb/206Pb年龄代表了斜长角闪岩原岩的形成时代,而角闪石40Ar/39Ar年龄则为其变质时代,与Sm-Nd等时线年龄(2351±103Ma)相一致.上述年龄数据表明河南洛宁地区太华岩群形成于新太古代,在古元古代遭受过一次角闪岩相变质作用.  相似文献   

8.
通过岩石学、矿物学、稀土及微量元素地球化学和Nd、Sr、Ph、O同位素组成的研究,确定相山斜长角闪岩的原岩为基性火山岩(玄武岩),井形成于岛弧环境,主要衍生于弱亏损地幔源区,并受到地壳物质某种程度的混染。造岩矿物成分具有低角闪岩相变质作用的特征,表明它们是低角闪岩相变质作用的产物,变质作用的温压条件为550℃±,0.69Gpa±。根据斜长角闪岩原岩的形成年龄(1113Ma)及变质年龄值(726.6Ma)结合其地质地球化学特征,确认赣中相山地区存在元古宙岛弧。  相似文献   

9.
胶北地块斜长角闪岩的岩石学与年代学研究   总被引:1,自引:0,他引:1       下载免费PDF全文
胶北地块位于华北克拉通东部陆块,胶-辽-吉活动带的南端.胶北地区荆山杂岩中存在一组与高压基性麻粒岩密切共生的斜长角闪岩,是构成前寒武纪变质基底的重要组成部分.岩石学矿物学研究表明,斜长角闪岩记录了3个阶段的变质作用:峰期变质矿物组合(M1)为角闪石1+斜长石+榍石,根据NCKFMASHTO体系的成分视剖面图和角闪石压力计估算出温度条件T=660~715 ℃,压力条件P=0.65~0.71 GPa;其后经历了退变质作用(M2),矿物组合为角闪石2+绿帘石+斜长石+绿泥石+钠长石,估算温压条件为537~630 ℃/0.41~0.58 GPa;晚期发生前绿片岩相退变质作用(M3),其矿物组合为钠长石+葡萄石+绿泥石+方解石,其温压条件 < 400 ℃/0.35 GPa.斜长角闪石的CL图像显示其具有较弱的阴极发光效应和弱震荡环带,Th/U比值相对较小(0.06~0.43),锆石形态和内部结构指示锆石形成于深熔作用过程,21个锆石的LA-ICP-MS定年研究的结果表明,斜长角闪岩记录的最老206Pb/238U年龄为2 075±25 Ma,上交点年龄为1 845±23 Ma(MSWD=0.35),该组年龄记录了斜长角闪岩峰期变质作用时代的上限.斜长角闪岩在原岩形成以后,可能曾经历麻粒岩相变质作用,并记录了在胶-辽-吉带~1.85 Ga碰撞闭合过程中的深熔事件,此后经历了角闪岩相变质作用,及其二次退变质作用,终结于前绿片岩相的变质温压条件.   相似文献   

10.
刘平华  蔡佳  邹雷 《岩石学报》2017,33(9):2649-2674
石榴斜长角闪岩常蕴含着丰富的变质反应结构,对古元古代造山带构造热演化过程研究具有十分重要的科学意义。胶-辽-吉带辽东半岛北部三家子地区出露的石榴斜长角闪岩,主要以岩脉的形式顺层侵入至南辽河群(里尔峪岩组)含黑云母的斜长片麻岩之中。三家子石榴斜长角闪岩以发育典型的"白眼圈"结构为特征,并保留了三个不同演化阶段矿物组合,峰前矿物组合为分布于石榴子石内部细粒包体矿物,主要包括角闪石+石英+磁铁矿+钛铁矿(M_1);峰期矿物组合为石榴子石+角闪石+单斜辉石+斜长石(An=44~45)+石英+钛铁矿(M_2);峰后退变质阶段矿物组合为角闪石+斜长石(An=64~90)+石英+钛铁矿+磁铁矿+榍石(M_3)。相平衡模拟与矿物对地质温压计算表明,三家子石榴斜长角闪岩峰前变质阶段(M_1)、峰期变质阶段(M_2)与峰后退变质阶段(M_3)稳定的P-T条件分别为:P=0.68~0.72GPa、T=570~600℃,P=0.98~1.01GPa、T=690~710℃,P=0.52~0.61GPa、T=670~700℃。锆石矿物包体扫描电镜分析、锆石CL图像分析与锆石LAICP-MS U-Pb定年的综合研究表明,三家子石榴斜长角闪岩原岩形成时代为2.17~2.06Ga之间;近峰期高压角闪岩相变质的时代为1.96~1.94Ga;峰后近等温减压中-低压角闪岩相退变质时代为1.92~1.83Ga,记录该组年龄的变质锆石微区含有典型的中-低压角闪岩相矿物包体(角闪石+斜长石(An=60~90)+石英+磷灰石)。综合以上分析,本文初步认为三家子石榴斜长角闪岩具有顺时针P-T-t轨迹,其主要特点是从M_1到M_3表现为升温升压的变质过程,并达到变质作用的峰期阶段,峰后开始表现为近等温减压的变质过程,随后可能表现为冷却降温的退化变质过程。因此,它们与胶-辽-吉带古元古代造山作用有关的构造增厚作用有密切关系。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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