北秦岭南台钼多金属矿床成岩成矿年龄及锆石Hf同位素组成

南台钼多金属矿床是北秦岭典型的斑岩-矽卡岩型矿床,矿区内出露的岩浆岩主要有花岗斑岩、石英斑岩脉和爆破角砾岩,花岗斑岩内及接触带发育斑岩型和矽卡岩型钼多金属矿化。锆石LA-ICPMS定年测得花岗斑岩的U-Pb年龄为(151±1)Ma(N=12,MSWD=0.32),矿区内6件辉钼矿的Re-Os同位素模式年龄介于(146±2)～(151±2)Ma,其加权平均年龄为(148.8±1.7)Ma(N=6,MSWD=0.84)。成岩年龄与成矿年龄在误差范围内基本一致,表明南台钼多金属矿床形成于晚侏罗世,与其以北的华北克拉通南缘的主要斑岩型钼矿床大规模成矿时间一致。该花岗斑岩的锆石Hf同位素组成显示:176Hf/177Hf初始比值介于0.281 864～0.282 454,εHf(t)=-28.8～-7.9,两阶段模式年龄TDM2为2 654～1 506 Ma,均变化于一个较宽的范围,表明花岗斑岩的源区物质具有多源的特征,其中以壳源组分为主,可能有少量幔源组分的混入,暗示了成矿物质也可能主要来源于地壳,但地幔组分对成矿也有贡献。     

大兴安岭中北段莫尔道嘎地区含矿斑岩的锆石U-Pb年龄、Hf同位素特征及成矿意义

处于大兴安岭中北段额尔古纳地块的莫尔道嘎地区发育大量花岗质岩石,本文报道了该地区与斑岩钼矿有关的花岗斑岩、花岗闪长斑岩的锆石U-Pb年龄、Hf同位素特征。锆石的LA-ICPMSU-Pb年龄测试结果显示,太平川含矿斑岩体的形成年龄分别为183.6、193.7和199.1Ma,表明花岗岩主要形成于早侏罗世,可能代表蒙古-鄂霍茨克洋闭合阶段的岩浆侵入事件。锆石的Hf同位素研究显示,3件含矿斑岩样品锆石εHf(t)分别为-3.2～0.4、-3.1～1.8和-3.7～-1.1,两阶段模式年龄分别为1322、1276和1394Ma,岩浆起源于中新元古代增生的地壳物质。结合额尔古纳地块已有的花岗岩锆石Hf同位素资料,认为额尔古纳地块在中新元古代曾发生过地壳增生,增生的地壳物质于早侏罗世发生熔融,形成花岗质岩浆并成矿。太平川含矿斑岩具有与乌奴格吐山含矿斑岩相似的大地构造背景、岩石地球化学特征和岩石年龄,推测太平川斑岩钼矿的成矿年代大致在195～180Ma。     

大兴安岭新林镇岩体的同位素特征及其地质意义

新林镇岩体位于大兴安岭北部,主要由花岗闪长岩、石英二长岩、二长花岗岩、碱长花岗岩组成,局部见到细粒辉长岩和闪长岩包体。岩石地球化学和岩石学特征表明,该杂岩体属于高钾钙碱性I型花岗岩。两个花岗闪长岩的锆石LA-ICP-MS U-Pb定年结果分别为(132±3)Ma和(131±3)Ma,属于早白垩世岩浆活动的产物。样品的Sr-Nd同位素组成比较均一,而Hf同位素特征变化较大,其εHf(t)变化介于1.32~8.32之间,Hf模式年龄与Nd模式年龄一致,表明花岗质岩浆主要起源于元古代增生的地壳物质,在岩石形成过程中有地幔组分的贡献。岩体的同位素特征将额尔古纳地块地壳增生时间限定在新元古代,而兴安地块地壳增生发生在新元古代—显生宙,暗示它们具有不同的地壳演化过程。     

大别山千鹅冲钼矿区花岗岩的SHRIMP锆石U-Pb年龄、Hf同位素组成及微量元素特征

千鹅冲斑岩型钼矿床位于东秦岭-大别钼矿带东部的大别山地区。矿体主要赋存于千鹅冲隐伏花岗岩体上部(外接触带)的南湾组片岩中,少量产于花岗岩体内。矿体下部的隐伏岩体中主要见有二长花岗岩和花岗斑岩。SHRIMP锆石UPb定年表明,二长花岗岩和花岗斑岩的侵位年龄分别为130±2Ma(MSWD=1.4)和129±2Ma(MSWD=1.9),二者年龄一致,说明隐伏岩体形成于早白垩世。锆石Hf同位素分析结果表明,千鹅冲钼矿中二长花岗岩和花岗斑岩的εHf(t)值分别变化于-24.5～-2.7和-19.8～-11.2之间,变化范围较大,说明它们主要来源于古老地壳的部分熔融,也有年轻组分的参与。两阶段模式年龄(t DM2)和古元古代的继承锆石指示这些花岗岩的原岩中含有古元古代-太古代的基底岩石。二长花岗岩和花岗斑岩中的锆石的Ce4+/Ce3+比值平均值分别为287.4和55.9,说明形成二长花岗岩的岩浆具有更高的氧逸度,但钼成矿与形成较晚的花岗斑岩具有更紧密的成因联系。千鹅冲钼矿形成于大别造山带早白垩世的伸展构造体制下,造山带下地壳拆沉作用造成的软流圈上涌和壳幔相互作用可能为钼矿的形成提供了成矿物质。     

满洲里南部中生代花岗岩的锆石U--Pb年龄及Hf同位素特征

满洲里南部地区花岗岩主要由碱长花岗岩、正长花岗岩、二长花岗岩及花岗斑岩组成。采用LA--ICP--MS技术,对满洲里南部花岗岩进行的锆石U--Pb年龄测定表明,该区中生代花岗岩浆活动分为3期:中—晚三叠世(208~239 Ma)、早侏罗世(179~185 Ma)和晚侏罗世—早白垩世(137~151 Ma),与整个大兴安岭中生代花岗岩的年代学格架基本一致,与东部的张广才岭—小兴安岭地区中生代岩浆活动时代也可以对比。锆石LA--MC--ICP--MS Hf同位素研究显示,本区中生代花岗岩的锆石εHf(t)多数为+0.7~+9.5,二阶段模式年龄为0.6~1.2 Ga,表明花岗岩浆主要源于中—新元古代增生的地壳物质。结合额尔古纳地块其他花岗岩的锆石Hf同位素资料,认为额尔古纳地块在中—新元古代时期曾发生一次重要的地壳增生事件,与兴安地块的地壳增生时间为新元古代—显生宙的特点不同。     

长江中下游金牛盆地花岗斑岩和流纹斑岩的锆石U-Pb年龄、Hf同位素组成及其地质意义

金牛盆地位于鄂东南矿集区,是长江中下游成矿带重要的火山岩盆地之一.相对宁芜和庐枞盆地,金牛盆地找矿一直没有取得重大突破,对其中次火山岩的年代学、成因和成矿属性的研究也很少.本次选择盆地中心吴佰浩地区深部钻孔中的花岗斑岩和流纹斑岩,开展锆石U-Pb年龄和Hf同位素的研究工作,获得了流纹斑岩锆石206Pb/238U的加权平均年龄为128±1Ma (n=14,MSWD=2.5),锆石Hf同位素(176Hf/177Hf),和εHf(t)分别为0.28247～0.28262和-2.5～ -7.7;花岗斑岩锆石206 Pb/238U的加权平均年龄为129±1Ma (n=12,MSWD=1.3),锆石Hf同位素(176Hf/177Hf),和εHf(t)分别为0.28239～0.28259和-3.6～-10.7.本文确定金牛盆地中流纹斑岩和花岗斑岩的形成时代为129～128Ma,与金牛盆地火山岩的形成时代(130～125Ma)相当,暗示金牛盆地火山岩和次火山岩均形成于早白垩世,流纹斑岩和花岗斑岩是壳幔混合的产物.金牛盆地火山岩的形成时代与宁芜、、庐枞盆地相当,次火山岩的形成时代也与宁芜、庐枞盆地玢岩铁矿的成矿岩体相当.提出金牛盆地除应关注玢岩铁矿外,更应该关注与次火山岩有关的热液金矿.     

黑龙江鹿鸣钼矿区花岗质杂岩锆石U-Pb年龄、Hf同位素、辉钼矿Re-Os年龄及其地质意义

鹿鸣超大型钼矿(钼金属量89万吨,平均品位0.084%)产于小兴安岭-张广才岭成矿带北段,矿体呈细脉浸染状赋存于二长花岗斑岩和二长花岗岩体内,围岩蚀变有钾化、绢云母化、硅化、绿泥石化、碳酸盐化等,矿化类型主要为斑岩型矿化。鹿鸣矿区含矿岩体二长花岗斑岩和二长花岗岩的锆石U-Pb定年、Hf同位素及辉钼矿Re-Os同位素定年研究表明:二长花岗岩和二长花岗斑岩锆石的U-Pb年龄分别为186.8±2.1Ma和183.2±1.9Ma,形成于燕山早期,二长花岗斑岩晚于二长花岗岩。6个样品辉钼矿Re-Os等时线年龄为176.7±4.4Ma(MSWD=0.92),Re含量变化于30×10-6~49×10-6。二长花岗岩的锆石εHf(t)值变化于1.1~3.8,Hf单阶段模式年龄为729Ma,两阶段模式年龄为1055Ma;二长花岗斑岩的锆石εHf(t)值变化于0.4~5.9,Hf单阶段模式年龄为741Ma,两阶段模式年龄为1075Ma。研究表明成矿与二长花岗斑岩有关,并且二长花岗岩和二长花岗斑岩岩浆为中新元古代新生的地壳物质熔融的产物,成岩成矿作用与古太平洋板块俯冲作用(或佳木斯与松嫩地块的拼合)有关。     

湖南省东北部地区桃江县木瓜园钨多金属矿成岩成矿时代及其对区域成矿作用的启示

江南造山带的湘东北-赣西北-皖东南—浙西南地区存在一个北东向钨矿带,成因类型以斑岩型、矽卡岩型为主,近年在其西南方向新发现了木瓜园大型钨矿床,成矿过程与斑岩体密切相关。厘定了木瓜园矿区含矿花岗斑岩的锆石LA-ICP-MS U-Pb年龄(224.2±2.0)Ma(MSWD=0.65,n=17),辉钼矿Re-Os同位素等时线年龄(225.4±1.4)Ma(MSWD=0.71)及加权平均年龄(222.96±0.96)Ma(MSWD=1.08,n=5),表明矿区成岩与成矿时代均为晚三叠世,属于印支期;锆石初始176 Hf/177 Hf比值0.282 444～0.282 580,εHf(t)值为-1.9～-7.2,二阶段模式年龄(TDM2)为1 713～1 388Ma,表明含矿岩体岩浆源区主要为古元古代-中元古代古老地壳岩石,起源于下地壳古老物质的重熔。由于北东向钨矿带成岩成矿集中于燕山期,木瓜园成岩成矿集中于印支期,结合区域地质背景,推测该钨矿带西南方向不超过湘东北地区新宁-灰汤断裂,但湖南省东北部地区存在一次晚三叠世大规模成岩与局部钨钼多金属成矿过程,且具有较大的找矿潜力。     

皖南泾县茂林岩体锆石U-Pb年龄和Hf同位素特征

安徽茂林岩体为中国东部中生代皖南构造-岩浆带中的一个浅层侵入岩体,是檀树岭钼矿和湛岭钼矿的成矿母岩。该岩体的主要岩性为花岗闪长岩、花岗斑岩、斑状花岗闪长岩、二长花岗岩等。对茂林花岗闪长岩体进行LA-ICP-MS锆石UPb测年,结果显示锆石Th/U值为0.38~0.66,为典型的岩浆成因锆石。花岗闪长岩~(206)Pb/~(238)U年龄加权平均值为140.8±0.8Ma(n=19,MSWD=2.3),结合锆石自形、岩浆环带发育等特点,该年龄为茂林花岗闪长岩的成岩年龄,显示岩体形成于早白垩世。锆石Hf同位素分析结果显示,茂林花岗闪长岩锆石振荡岩浆环带具负εHf(t)值(-9.7~-6.2),揭示花岗闪长岩主要形成于下地壳的熔融。     

内蒙古克什克腾旗长岭子斜长花岗斑岩锆石U-Pb年龄、成因与碰撞造山作用

内蒙古克什克腾旗长岭子斜长花岗斑岩位于大兴安岭锡林浩特增生杂岩带内。本文对长岭子斜长花岗斑岩进行了主微量元素地球化学以及锆石U?Pb年代学和Lu?Hf同位素研究。长岭子斜长花岗斑岩锆石206Pb/238U加权平均年龄为(248.1±4.7)Ma,是早三叠世岩浆活动的产物;继承锆石除外,样品中锆石具有正的εHf(t)值(5.78~12.41),二阶段模式年龄TDM2分别为914~488 Ma。长岭子斜长花岗斑岩具有较高的SiO2、Na2O和Al2O3含量以及较低的Fe2O3、MgO和CaO含量,属于偏铝质?过铝质的低钾?钙碱性系列I型花岗岩,富集Rb、K、U、Th、Pb、Sr等大离子亲石元素,亏损Nd、Ta、Ti等高场强元素。同时,斜长花岗斑岩具有高Sr低Y以及高Sr/Y比等特点,具有典型的埃达克质岩石特征,形成于加厚下地壳的部分熔融。综合上述地球化学特征,本文认为长岭子斜长花岗斑岩来源于加厚新生下地壳的部分熔融,表明早三叠世兴蒙地区并非岛弧的环境,而是处于碰撞造山环境,古亚洲洋在该时期已经闭合。     

南秦岭下地壳组成及岩石圈的拆离俯冲作用

根据新提供的Pb同位素组成及岩石地球化学研究成果，本文进一步证实了位于北秦岭北界的明港地区发育的早中生代安山玄武质火山角砾岩岩筒所携带的下地壳捕虏体属于南秦岭。所恢复的南秦岭下地壳剖面自下而上为：底侵成因的变辉长岩-基性麻粒岩(其中含有榴辉岩及辉石岩的透镜体)-酸性麻粒岩。秦岭造山带总体的岩石因模型为：南秦岭(扬子块体)向北拆离俯冲，北秦岭地壳向华北仰冲，华北岩石因呈楔状插入秦岭造山带，拆离面约在中、下地壳之间。南秦岭俯冲岩片延伸的范围在平面上有可能达到400km。     

青藏高原综合观测研究站的回顾与展望

中国科学院青藏高原综合观测研究站从１９８８年建站到１９９８年以来,在各个方面均取得了长足的发展,横向生产性项目的开展和完成不仅解决了部队和地方的实际问题,而且缓和了观测研究站在运行过程中所面临的经费严重不足的问题,同时也为我所冻土专业研究人员提供了在生产中实践的机会,在基础理论研究方面,承担了国家攀登计划项目,国家基金项目,中国科学院重点项目和中国科学院冰冻圈专项项目等的研究工作,在多年冻土变化,     

Principles of spatial organization and evolution of the biosphere and the noosphere

In his last lifetime essay, “A Few Words about the Noosphere”, Academician V.I. Vernadsky (1944) wrote that all living organisms on the planet, including man, are integral to the biosphere of the Earth, its material and energy structure and cannot be physically independent of it even for a minute. However, the substrate that generates all living beings and is no less tightly bound to the biosphere has always been characterized by a significant geochemical heterogeneity, traced both in the vertical and in the lateral structure of all geospheres.

The present work is devoted to three most important aspects of modern geochemistry and biogeochemistry:

• — evolution of the ecological and geochemical state of the environment under conditions of a virgin (anthropogenically untouched) biosphere;
• — structural features of the geochemical organization of the modern noosphere;
• — specificity of the interaction of living matter with the environment under increasing anthropogenic load.

On the basis of theoretical concepts of biogeochemistry and geochemical ecology, formulated in the works of V.I. Vernadsky, A.P. Vinogradov, A.E. Fersman, B.B. Polynov, A.I. Perel’man, M.A. Glazovskaya, V.V. Kovalsky, E. Odum, B. Commoner, E.I. Kolchinskii and others, the author puts forward a hypothesis that there exist two qualitatively different stages in the evolution of the biosphere.The first stage is recognized as the period of natural evolution of the biosphere during which it evolves successively into a more complex and more biogeochemically specialized object. In the course of the geological time, this constantly results, on the one hand, in an increase in species diversity and the perfection of individual species, and, on the other hand, to directed improvement and a greater differentiation of the geochemical conditions of the environment. At this stage, the evolution of all systems of the biosphere that were controlled by the mechanisms of self-organization and self-regulation resulted in the establishment of a dynamic equilibrium, which was responsible for the cycling of all essential chemical elements and therefore providing ecologically optimal geochemical conditions in all ecological niches and for all species and biocenoses inhabiting the biosphere at any given moment.The beginning of the second stage is related to the appearance of reason and qualitative changes in the biosphere caused by the goal-directed activity of the human mind, as an entirely new geological force that appeared to be able not only to disrupt the functioning of natural mechanisms of self-regulation and selforganization, but also to transform the environment in the intersts of a single biological species, Homo sapiens. A direct consequence of this change was the uncontrolled transformation of the natural environment, during which the primary structure (geochemical background) created in the course of billions of years was eventually superimposed by a qualitatively new layer of anthropogenically-derived chemical elements and compounds, thus building an interference pattern of a new geochemical field with which practically all modern living organisms are now forced to interact.An outstanding feature of the new evolutionary stage of the natural environment, called by Vernadsky the noosphere, is that biogeochemical changes at this stage proceed at a rate which exceeds that required for the living matter to adapt to these changes. The result is the disruption of the existing parameters of the biological cycle, leading to the emergence of a significant number of endemic diseases of geochemical nature.The proposed approach was used to prove the anthropogenic genesis of existing geochemical endemic diseases and explain the mechanisms of their appearance. In addition, this approach allowed us to develop a new methodology for mapping zones of ecological and geochemical risk and noticeably simplify the procedure of monitoring distribution and prevention of all diseases of geochemical nature.     

铀钍的地球化学及对地壳演化和生物进化的影响

本文论述了在含挥发份和贫挥发份条件下Ｕ、Ｔｈ的迁移行为及其对地球和行星演化的影响,并阐述了造成地球独特地质演化历史的原因。提出了Ｕ、Ｔｈ在地球中的迁移模式以及该模式对地壳形成、演化的控制作用和对生物发展演化的可能影响。     

共和盆地层状地貌系统与青藏高原隆升及黄河发育

利用卫星遥感影像,结合实地调查和测年结果,对共和盆地层状地貌系统进行了解译、分析。研究表明,共和盆地层状地貌系统由山麓剥蚀面、洪积扇面、盆地面以及黄河阶地面构成,其空间结构、物质组成对发生于早更新世早期的青藏运动C幕和中更新世末期的共和运动反映清晰。青藏运动C幕使青藏高原主夷平面在高原差异性隆升中彻底解体,垂直变形量高达1700m。共和运动使黄河在0.11Ma进入共和盆地,其后黄河平均以3.5mm/a的侵蚀速率下切盆地,同时在盆地边部的山前古冲洪积扇以大致相近的速率被抬升,最终导致高差在2000m左右的层状地貌系统的出现。     

Wavelets and the Generalization of the Variogram

The experimental variogram computed in the usual way by the method of moments and the Haar wavelet transform are similar in that they filter data and yield informative summaries that may be interpreted. The variogram filters out constant values; wavelets can filter variation at several spatial scales and thereby provide a richer repertoire for analysis and demand no assumptions other than that of finite variance. This paper compares the two functions, identifying that part of the Haar wavelet transform that gives it its advantages. It goes on to show that the generalized variogram of order k=1, 2, and 3 filters linear, quadratic, and cubic polynomials from the data, respectively, which correspond with more complex wavelets in Daubechies's family. The additional filter coefficients of the latter can reveal features of the data that are not evident in its usual form. Three examples in which data recorded at regular intervals on transects are analyzed illustrate the extended form of the variogram. The apparent periodicity of gilgais in Australia seems to be accentuated as filter coefficients are added, but otherwise the analysis provides no new insight. Analysis of hyerpsectral data with a strong linear trend showed that the wavelet-based variograms filtered it out. Adding filter coefficients in the analysis of the topsoil across the Jurassic scarplands of England changed the upper bound of the variogram; it then resembled the within-class variogram computed by the method of moments. To elucidate these results, we simulated several series of data to represent a random process with values fluctuating about a mean, data with long-range linear trend, data with local trend, and data with stepped transitions. The results suggest that the wavelet variogram can filter out the effects of long-range trend, but not local trend, and of transitions from one class to another, as across boundaries.     

Evolution of the paleogeodynamic settings of the formation of the Lower and Middle Riphean sedimentary sequences of the Uchur-Maya region and the Bashkir meganticlinorium

The possibility to use some widely known standard discrimination diagrams such as the K₂O/Na₂O-SiO₂/Al₂O₃, SiO₂-K₂O/Na₂O, (Fe₂O₃* + MgO)-TiO₂, F1-F2, Th-La-Sc, Sc-Th-Zr/10, and Sc/Cr-La/Y for deciphering the paleogeodynamic settings of sedimentary sequences is considered with reference to the Lower and Middle Riphean (Mesoproterozoic) deposits of the Uchur-Maya region (Far East) and the Bashkir meganticlinorium (South Urals). It was shown that only some of them can be used with a certain degree of confidence for reconstructing the settings of the platform sedimentary sequences made up of both sandstones and fine-grained terrigenous rocks.